Hollow Fiber Or Cylinder Patents (Class 96/10)
  • Patent number: 8221525
    Abstract: A method of oxygen enrichment in which a gaseous mixture containing O2 molecules and N2 molecules is provided to a feed side of a SAPO molecular sieve, oxygen enrichment membrane having pore sizes suitable for discriminating between O2 molecules and N2 molecules, resulting in selective transport of the O2 molecules through the membrane to a permeate side of the membrane. Also disclosed is a method for producing the membrane.
    Type: Grant
    Filed: July 16, 2010
    Date of Patent: July 17, 2012
    Assignee: Gas Technology Institute
    Inventors: Shiguang Li, Qinbai Fan
  • Patent number: 8221531
    Abstract: A method of making a crosslinked polyimide membrane is described. A monoesterified membrane is formed from a monoesterified polyimide polymer. The monoesterified membrane is subjected to transesterification conditions to form a crosslinked membrane. The monoesterified membrane is incorporated with an organic titanate catalyst before or after formation of the monoesterified membrane. A crosslinked polyimide membrane made using the aforementioned method and a method of using the membrane to separate fluids in a fluid mixture also are described.
    Type: Grant
    Filed: December 31, 2007
    Date of Patent: July 17, 2012
    Assignee: Chevron U.S.A. Inc.
    Inventors: John D. Wind, Stephen J. Miller, Oluwasijibomi O. Okeowo
  • Publication number: 20120174790
    Abstract: A water vapor permeable membrane is provided comprising a dense layer and a support layer that are adjacent to each other, wherein the dense layer contains voids with a void length of 0.1 ?m or less and the dense layer has a thickness of 0.1 ?m or more and 2 ?m or less while in the support layer, void (a), i.e. the void with the largest length in the 2 ?m thick region measured from the boundary between the dense layer and the support layer into the support layer, has a length of 0.3 ?m or more and void (b), i.e. the void with the largest length in the region ranging between 2 ?m and 4 ?m measured from the boundary into the support layer, has a length of 0.5 ?m or more, the length of the void (b) being larger than that of the void (a). A water vapor permeable membrane having both a high water vapor permeability and a low air leakage is provided.
    Type: Application
    Filed: August 21, 2009
    Publication date: July 12, 2012
    Applicant: Toray Industries, Inc.
    Inventors: Masahiro Osabe, Kazumi Tanaka, Hiroyuki Sugaya
  • Patent number: 8216342
    Abstract: A method for producing membranes which contain at least one solid layer on one side of a porous substrate by treating the side of the support, which is to be coated, with a synthetic solution that forms the solid layer. The inventive method is characterized in that the space located behind the side of the porous support, which is not to be coated, is filled with an inert fluid during the production of the solid layer on the porous support, “behind” being from the perspective of the support. The pressure and/or the temperature of the fluid is/are selected such that the synthetic solution is essentially prevented from entering in contact with the side of the porous support, which is not to be coated.
    Type: Grant
    Filed: January 13, 2005
    Date of Patent: July 10, 2012
    Assignee: BASF SE
    Inventors: Stefan Bitterlich, Hartwig Voβ, Gunter Schuch, Armin Diefenbacher, Manfred Noack, Ronald Schäfer, Ingolf Voigt, Hannes Richter, Jürgen Caro
  • Patent number: 8197578
    Abstract: A liquid degasser for a space device including a gas permeable material configured for contact with a flow of liquid to be de-gassed on one side and a vacuum on the other side, and wherein the gas permeable material allows gas in the liquid to diffuse to the vacuum to remove the gas from the liquid.
    Type: Grant
    Filed: July 25, 2007
    Date of Patent: June 12, 2012
    Assignee: Busek Company, Inc.
    Inventors: Vladimir J. Hruby, Nate Demmons, Tom Roy, Doug Spence, Eric Ehrbar, Jurg Zwahlen, Charles Gasdaska
  • Patent number: 8197576
    Abstract: A CO2-facilitated transport membrane of excellent carbon dioxide permeability and CO2/H2 selectivity, which can be applied to a CO2 permeable membrane reactor, is stably provided. The CO2-facilitated transport membrane is formed such that a gel layer 1 obtained by adding cesium carbonate to a polyvinyl alcohol-polyacrylic acid copolymer gel membrane is supported by a hydrophilic porous membrane 2. More preferably, a gel layer supported by a hydrophilic porous membrane 2 is coated with hydrophilic porous membranes 3 and 4.
    Type: Grant
    Filed: January 22, 2009
    Date of Patent: June 12, 2012
    Assignee: Renaissance Energy Research Corporation
    Inventors: Osamu Okada, Masaaki Teramoto, Reza Yegani, Hideto Matsuyama, Keiko Shimada, Kaori Morimoto
  • Patent number: 8192524
    Abstract: Disclosed herein are processes for producing a CO2-depleted product gas stream. The processes involve feeding a natural gas feed stream comprising greater than about 10 vol % CO2 to at least one membrane unit comprising a plurality of polymer membranes to provide a CO2-rich permeate comprising at least 95 vol % CO2 and a CO2-depleted product gas stream. The polymer membranes comprise a crosslinked polyimide polymer having covalent ester crosslinks and have a CO2 permeance of at least 20 GPU and a CO2/CH4 selectivity of greater than 20, at 35 degrees C. and a feed pressure of 100 psia. Also disclosed herein is an apparatus incorporating the crosslinked polyimide polymer for producing a CO2-depleted product gas stream from a natural gas feed stream.
    Type: Grant
    Filed: January 29, 2009
    Date of Patent: June 5, 2012
    Assignee: Chevron U.S.A. Inc.
    Inventors: Daniel Chinn, Siji Okeowo, Jeff D. Euhus, Shabbir Husain
  • Patent number: 8182590
    Abstract: A process for forming a porous nanoscale membrane is described. The process involves applying a nanoscale film to one side of a substrate, where the nanoscale film includes a semiconductor material; masking an opposite side of the substrate; etching the substrate, beginning from the masked opposite side of the substrate and continuing until a passage is formed through the substrate, thereby exposing the film on both sides thereof to form a membrane; and then simultaneously forming a plurality of randomly spaced pores in the membrane. The resulting porous nanoscale membranes, characterized by substantially smooth surfaces, high pore densities, and high aspect ratio dimensions, can be used in filtration devices, microfluidic devices, fuel cell membranes, and as electron microscopy substrates.
    Type: Grant
    Filed: May 1, 2006
    Date of Patent: May 22, 2012
    Assignee: University of Rochester
    Inventors: Christopher C. Striemer, Philippe M. Fauchet, Thomas R. Gaborski, James L. McGrath
  • Patent number: 8182591
    Abstract: A vertically directed dryer unit (10) for compressed air, comprising a dryer cartridge (22) which, together with a housing (16, 18, 20), defines an inlet head area (92) and an outlet head area (72). A plurality of hollow membrane fibers (30) extend inside the cartridge between the two head areas, the wall material thereof being more permeable with respect to water vapor than air. An outlet valve (90) is provided between the outlet head area (72) and an outlet (74) of the drier unit. Said valve only opens when the pressure in the outlet head area (72) produces sufficient pressure for the provision of purging air. The purging air is fed to the outer surface of the membrane fibers (30) via a throttle element (70).
    Type: Grant
    Filed: September 27, 2005
    Date of Patent: May 22, 2012
    Assignee: Durr Dental GmbH & Co. KG
    Inventors: Alfred Deubler, Varleriu Fischer
  • Patent number: 8182686
    Abstract: A hollow fiber membrane separation device with two flow spaces, of which a first space is formed by the capillary tube passages of a hollow-fiber bundle cast at its ends into a sealing compound, and a second space is formed by a housing enclosing the fiber bundle. The first space is sealed off by caps, placed on the sealing compounds, with seals running over the peripheral areas of the sealing compounds. The housing, into which the hollow-fiber bundle is drawn, at each end of its casing has tooth-like or pinnacle-like projections formed by axial notches or indentations running out freely. The tooth-like or pinnacle-like projections have extensions extending from the sides of the projections and extending to the adjacent tooth-like or pinnacle-like projection.
    Type: Grant
    Filed: June 8, 2006
    Date of Patent: May 22, 2012
    Assignee: Fresenius Medical Care Deutschland GmbH
    Inventors: Friedrich Witthaus, Gerhard Breith
  • Patent number: 8182592
    Abstract: A gas separation membrane module has a vessel housing a hollow fiber element including a hollow fiber bundle consisting of a number of hollow fiber membranes (1) and a tube sheet (2) holding one end of the hollow fiber bundle. The interior of the vessel is partitioned by the tube sheet (2) into two spaces consisting of a raw gas chamber and a permeate gas chamber. A high-pressure mixed gas is fed into the raw gas chamber where gas separation is carried out. The gas separation membrane module has a configuration where during operation, the tube sheet (2) is supported by means of a perforated plate (8) in the vessel by a pressure from the mixed gas fed to maintain airtightness between the two spaces and when the tube sheet (2) receives a pressure in the reverse direction to that applied during the operation of the gas separation membrane module, the tube sheet (2) is forced to move within the vessel by the pressure in the reverse direction, thereby losing airtightness between the two spaces.
    Type: Grant
    Filed: December 27, 2007
    Date of Patent: May 22, 2012
    Assignee: Ube Industries, Ltd.
    Inventors: Tomohide Nakamura, Nozomu Tanihara, Shunsuke Nakanishi
  • Publication number: 20120123079
    Abstract: The invention relates to polyimide membranes and to a phase inversion method for the production thereof. The polyimide membranes can be used to separate different gas mixtures.
    Type: Application
    Filed: July 22, 2010
    Publication date: May 17, 2012
    Applicant: Evonik Fibres GmbH
    Inventors: Markus Ungerank, Goetz Baumgarten
  • Patent number: 8177889
    Abstract: A gas removal device 1 includes a decompression chamber 2 with an inlet 11 and an outlet 12 through which a liquid to be degassed flows therein and thereout, and a degassing element 5 that is accommodated in the decompression chamber 2 while having one end connected to the inlet 11 and another end connected to the outlet 12, and that allows the liquid to be degassed entering into the inlet 11 to pass through the degassing element 5. The degassing element 5 includes a tube bundle 15 composed of a plurality of flexible gas-permeable tubes 151, and a tying member 16 tying the plurality of gas-permeable tubes 151 to form the tube bundle 15. The tube bundle 15 is bent in a shape of coil with multiple turns in such a manner that a portion tied by the tying member 16 is included in a bent portion BP.
    Type: Grant
    Filed: September 19, 2007
    Date of Patent: May 15, 2012
    Assignee: Nitto Denko Corporation
    Inventor: Hajime Ooya
  • Publication number: 20120111191
    Abstract: A composition of and a method of making high performance crosslinked membranes are described. The membranes have a high resistance to plasticization by use of crosslinking. The preferred polymer material for the membrane is a polyimide polymer comprising covalently bonded ester crosslinks. The resultant membrane exhibits a high permeability of CO2 in combination with a high CO2/CH4selectivity. Another embodiment provides a method of making the membrane from a monesterified polymer followed by final crosslinking after the membrane is formed.
    Type: Application
    Filed: December 17, 2010
    Publication date: May 10, 2012
    Inventors: William J. Koros, David Wallace, John D. Wind, Stephen J. Miller, Claudia Staudt-Bickel
  • Patent number: 8167983
    Abstract: The present invention relates to compositions for producing membranes, the compositions comprising at least 0.1% by weight of highly branched polymer, at least 0.5% by weight of linear polymer and at least 30% by weight of solvent. The present invention additionally describes membranes obtainable from the compositions, and methods of producing these membranes.
    Type: Grant
    Filed: December 17, 2007
    Date of Patent: May 1, 2012
    Assignee: Evonik Degussa GmbH
    Inventors: Matthias Seiler, Stefan Bernhardt, Rolf Schneider, Roland Wursche, Franz-Erich Baumann
  • Patent number: 8167982
    Abstract: A vertically directed dryer unit for compressed air, comprising a dryer cartridge which, together with a housing, defines an inlet head area and an outlet head area. A plurality of hollow membrane fibers extend inside the cartridge between the two head areas, the wall material thereof being more permeable with respect to water vapor than air. An outlet valve is provided between the outlet head area and an outlet of the drier unit. Said valve only opens when the pressure in the outlet head area produces sufficient pressure for the provision of purging air. The purging air is fed to the outer surface of the membrane fibers via a throttle element.
    Type: Grant
    Filed: January 13, 2010
    Date of Patent: May 1, 2012
    Assignee: Beko Technologies GmbH
    Inventors: Alfred Deubler, Valeriu Fischer
  • Patent number: 8163064
    Abstract: A leak-proof membrane element (1) for the selective separation or cleaning of gas, wherein a metal foil (membrane) (3) is deposited onto a supporting stock (substrate) (2, 20) having connection means (4, 21, 34) on the ends/edges of the substrate allowing the membrane element to be installed in a housing. A metal foil (3), having a thickness of less that 10 micrometers and being selectively permeable for specific gases, is arranged in flakes or wound with overlapping joints (8) on the outside of the substrate (2, 20), any joints being welded together by diffusion bonding so that the foil forms a continuous, leak-proof metal membrane layer. The substrate being made of a material (metal, ceram, polymer, or combinations thereof) exhibiting a very high gas flux for the gas(es) that the membrane is to let through.
    Type: Grant
    Filed: September 28, 2007
    Date of Patent: April 24, 2012
    Assignee: Sinvent AS
    Inventors: Rune Bredesen, Dag Slotfeldt-Ellingsen, Hallgeir Klette
  • Patent number: 8163065
    Abstract: A carbon dioxide permeable membrane is described. In some embodiments, the membrane includes a body having a first side and an opposite second side; a plurality of first regions formed from a molten carbonate having a temperature of about 400 degrees Celsius to about 1200 degrees Celsius, the plurality of first regions forming a portion of the body and the plurality of first regions extending from the first side of the body to the second side of the body; a plurality of second regions formed from an oxygen conductive solid oxide, the plurality of second regions combining with the plurality of first regions to form the body and the plurality of second regions extending from the first side of the body to the second side of the body; and the body is configured to allow carbon dioxide to pass from the first side to the second side.
    Type: Grant
    Filed: March 21, 2011
    Date of Patent: April 24, 2012
    Assignee: The Trustees of Columbia University in the City of New York
    Inventors: Klaus S. Lackner, Alan C. West, Jennifer L. Wade
  • Patent number: 8163071
    Abstract: Disclosed is a hollow fiber that includes a hollow positioned at the center of the hollow fiber, macropores positioned at adjacent to the hollow, and mesopores and picopores positioned at adjacent to macropores, and the picopores are three dimensionally connected to each other to form a three dimensional network structure. The hollow fiber includes a polymer derived from polyamic acid, and the polyamic acid includes a repeating unit obtained from aromatic diamine including at least one ortho-positioned functional group with respect to an amine group and dianhydride.
    Type: Grant
    Filed: May 19, 2009
    Date of Patent: April 24, 2012
    Assignee: IUCF-HYU (Industry-University Cooperation Foundation Hanyang University)
    Inventors: Young Moo Lee, Ho Bum Park, Sang Hoon Han, Chul Ho Jung
  • Patent number: 8147594
    Abstract: An air dryer includes a housing with an air inlet, an air outlet and a liquid drain outlet; and a membrane separator having surfaces extending between a first and second ends of the membrane. A first passage in the housing is connected to the air inlet and air outlet at it respective ends and extends between the first and second ends of the membrane separator along the surfaces of the membrane separator. A second passage in the housing is connected to the drain outlet and air outlet at it respective ends and extends between the first and second ends of the membrane along a surface of the membrane separator. A valve is connected between the second passage and the drain outlet for controlling the draining of the liquid and sweep air flow through the second passage. The dryer is to be inserted in a reservoir at its inlet or outlet. A coalescing filter may be provided in the housing in series with the membrane separator and the housing would include a second drain for the coalescing filter.
    Type: Grant
    Filed: January 29, 2007
    Date of Patent: April 3, 2012
    Assignee: New York Air Brake Corporation
    Inventors: Eric Wright, Richard Kohar
  • Patent number: 8147596
    Abstract: A hydrogen-permeable film has a ceramic material of a nitride or oxide of a metal element belonging to group IVB, VB or VIB and hydrogen-permeable metal particles of at least one kind selected from palladium (Pd), niobium (Nb), vanadium (V), tantalum (Ta) and alloys thereof dispersed in the ceramic material. A ratio of the hydrogen-permeable metal particles in the hydrogen-permeable film is 20 to 70 mass %, and a thickness of the hydrogen-permeable film is 5 to 1,000 nm.
    Type: Grant
    Filed: December 27, 2007
    Date of Patent: April 3, 2012
    Assignee: Mikuni Corporation
    Inventor: Katsuhiko Fukui
  • Patent number: 8142662
    Abstract: A dehydrating system is designed to maintain the availability of a plant having the dehydrating system using a water separation membrane by allowing a water separation membrane unit to be replaced while the plant is in operation. The dehydrating system comprises at least two water separation membrane units in use arranged parallel to the direction of flow of a fluid to be processed, is configured so that at least one spare water separation membrane unit can be installed parallel to the direction of flow of the fluid to be processed with respect to the at least two water separation membrane units, having monitoring devices for the product fluid to be taken out, and maintains the properties of the product fluid by operating the spare water separation membrane unit depending on the properties of the product fluid monitored by the monitoring devices.
    Type: Grant
    Filed: May 13, 2009
    Date of Patent: March 27, 2012
    Assignee: Mitsubishi Heavy Industries, Ltd.
    Inventors: Hiroyuki Osora, Yoshio Seiki, Atsuhiro Yukumoto, Yukio Tanaka, Shinji Ogino, Haruaki Hirayama
  • Patent number: 8142546
    Abstract: An artificial lung includes a housing, a tubular hollow fiber membrane bundle contained in the housing and providing a multiplicity of hollow fiber membranes having a gas exchange function, a gas inflow port and a gas outflow port communicating with each other through hollow portions of the hollow fiber membranes, and a blood inflow port and a blood outflow port through which blood is distributed. The tubular hollow fiber membrane bundle has a cylindrical overall shape, and a filter member having a bubble-trapping function is provided on an outer peripheral portion of the tubular hollow fiber membrane bundle.
    Type: Grant
    Filed: April 12, 2011
    Date of Patent: March 27, 2012
    Assignee: Terumo Kabushiki Kaisha
    Inventors: Mitsuaki Ogihara, Hidetaka Nakayama
  • Publication number: 20120067211
    Abstract: A dense hydrogen-permeable layer, such as palladium or palladium alloy, is deposited on a porous hollow fiber. A porous hollow fiber is defined as having an inner diameter of approximately 30 microns to approximately 1500 microns and an outer diameter of approximately 100 microns to approximately 2000 microns. This allows an order-of-magnitude increase in the surface per volume ratio in a hydrogen separation or purification module, or a membrane reformer or reactor.
    Type: Application
    Filed: March 22, 2011
    Publication date: March 22, 2012
    Applicant: L'Air Liquide Societe Anonyme Pour L'Etude Et L'Exploitation Des Procedes Georges Claude
    Inventors: Pascal Tessier, Edgar S. Sanders, JR., Pascal J. Tromeur
  • Patent number: 8137436
    Abstract: A passive humidifier membrane includes polyolefin with a plurality of pores, wherein the average pore size of the plurality of pores is 0.05 ?m to 0.4 ?m as established by a PMI Capillary Flow Porometer. The humidifier membrane is virtually airtight while providing a high transfer rate of water. Transfer of heat is also high. The humidifier membrane is particularly suitable for heat exchange and water transfer between fluids and, it is particularly useful for applications inside or outside fuel cells such as PEMFC. The membrane is also particularly useful in the application as humidifier for air or oxygen.
    Type: Grant
    Filed: October 9, 2007
    Date of Patent: March 20, 2012
    Assignee: Lydall Solutech B.V.
    Inventors: Gijsbertus Hendrikus Maria Calis, Edwin Henricus Adriaan Steenbakkers, Paul Osenar, Richard M. Formato, Paul Sabin, Seth Avis
  • Publication number: 20120060692
    Abstract: The invention relates to a diaphragm pipe for permeative separation of hydrogen from gas mixtures containing hydrogen, a method for the production thereof as well as a reactor comprising a diaphragm pipe, wherein the diaphragm pipe comprises a porous pipe (S) made of a sintered metal and a diaphragm (M) containing palladium or made of palladium enclosing the outer surface of the sintered metal pipe (5). The sintered metal pipe (S) has at least on one end a fitting (F) made of gasproof material, which is firmly connected with the sintered metal pipe (S).
    Type: Application
    Filed: March 30, 2010
    Publication date: March 15, 2012
    Inventors: Wolfgang Haring, Nicole Schodel, Axel Behrens, Klaus Klapper, Matthias Ruttinger, Karlheinz Scheiber, Markus Kogl, Marco Brandner
  • Patent number: 8133307
    Abstract: A dehumidification type air system is configured such that a switching valve and an air-used device are connected through a dehumidifying member made of a polymer permeation membrane with moisture permeability, and by bringing a moisture emitting face of the dehumidifying member into contact with the atmosphere, supply air supplied from the switching valve through the dehumidifying member to the air-used device is dehumidified by the dehumidifying member, while the moisture permeating through the dehumidifying member is diffused from the moisture emitting face to the atmosphere through natural evaporation.
    Type: Grant
    Filed: October 31, 2007
    Date of Patent: March 13, 2012
    Assignee: SMC Corporation
    Inventor: Toshihiro Suzuki
  • Patent number: 8123833
    Abstract: A process for producing a gas-containing cleaning water which contains a specific gas dissolved in water, which process comprises dissolving the specific gas into water under an increased pressure exceeding an atmospheric pressure to prepare a gas-containing water having a concentration of the gas exceeding solubility of the gas under an atmospheric pressure and, then, removing a portion of the dissolved gas by decreasing pressure on the gas-containing water; an apparatus for producing a gas-containing cleaning water which comprises an apparatus for dissolving a gas (14) in which a specific gas is dissolved into water under a pressure exceeding the atmospheric pressure and an apparatus for removing a portion of a dissolved gas (15) in which the pressure on the gas-containing water obtained from the apparatus for dissolving a gas is decreased to a pressure lower than the pressure under which the gas has been dissolved so that a portion of the dissolved gas is removed; and a cleaning apparatus using the gas-con
    Type: Grant
    Filed: March 12, 2007
    Date of Patent: February 28, 2012
    Assignee: Kurita Water Industries Ltd.
    Inventors: Hiroshi Morita, Hiroto Tokoshima
  • Patent number: 8117822
    Abstract: The carbon-free gas turbine is a power-producing turbine driven by the combustion of hydrocarbon fuels with oxygen. The carbon-free gas turbine includes at least one combustor for combusting gaseous fuel with oxygen. The at least one combustor includes a housing containing at least one oxygen transport reactor. The oxygen transport reactor includes an outer wall and an inner cylindrical ion transport membrane. The membrane receives pressurized air and separates gaseous oxygen therefrom, transporting the oxygen into a central region thereof for combustion with the gaseous hydrocarbon fuel, producing gaseous carbon dioxide and water vapor. A first turbine is driven by the gaseous carbon dioxide and water vapor produced by the at least one combustor and drives a first compressor. The first compressor provides the pressurized air supplied to the at least one combustor. A second turbine is driven by pressurized nitrogen gas resulting from the combustion.
    Type: Grant
    Filed: April 19, 2010
    Date of Patent: February 21, 2012
    Assignee: King Fahd University of Petroleum & Minerals
    Inventors: Mohamed Abdel-Aziz Habib, Amro Mohammad Al-Qutub
  • Patent number: 8114199
    Abstract: A membrane dryer includes a shell having an inner tube and an outer tube and a bundle of hollow fibers supported in the shell. A dryer air inlet into the hollow fibers and a sweep air outlet from the inner tube are at a first end of the shell. A dryer air outlet into the hollow fibers and a sweep air inlet from the inner tube are at a second end of the shell. The inner tube has a first set of circumferential openings into the sweep air space adjacent the first end of the shell and a second set of circumferential openings into the sweep air space adjacent the first end of the shell; and a second plug is in the inner tube between the first and second set of openings.
    Type: Grant
    Filed: October 12, 2010
    Date of Patent: February 14, 2012
    Assignee: New York Air Brake Corporation
    Inventor: Randall W. Nichols
  • Patent number: 8110027
    Abstract: An air separation module and blanket has an air separation module having an air inlet, an oxygen outlet and a nitrogen outlet. At least one tank has air separation elements for separating oxygen from air, and delivers the separated oxygen to the oxygen outlet, and delivers nitrogen to the nitrogen outlet. A resistance heating element is positioned between the blanket and the air separation module. Further, an inventive blanket for use with the air separation module is also disclosed and claimed.
    Type: Grant
    Filed: April 17, 2009
    Date of Patent: February 7, 2012
    Assignee: Hamilton Sundstrand Corporation
    Inventor: William Joseph Beeson
  • Patent number: 8101009
    Abstract: This abstract discusses membranes needed to separate fluids for the production of oxygen-enriched air, nitrogen-enriched-air, for the separation of carbon dioxide from hydrocarbons, and the separation of hydrogen from various petrochemical and oil refining streams. Membranes are needed that provide a resistance to interaction with process components or contaminants, provide the mechanical strength required to withstand high membrane differential pressures and high process temperatures, and exhibit sufficient maximum strain such that membranes are not brittle and can easily be formed into desirable membrane forms. Membranes of polyimide polymers, particularly polyimide polymers sold under the trade name P-84, are annealed in a controlled annealing step to improve the mechanical properties of the polymers used to make separation membranes.
    Type: Grant
    Filed: September 8, 2008
    Date of Patent: January 24, 2012
    Assignee: L'Air Liquide Societe Anonyme pour l'Etude Et L'Exploitation des Procedes Georges Claude
    Inventors: Okan Max Ekiner, John W. Simmons
  • Patent number: 8075669
    Abstract: There is described a composite material such as venting materials and vents containing said venting materials. The vents are air- or more generally gas-permeable venting composites that are oleophobic and liquid repellent.
    Type: Grant
    Filed: April 22, 2008
    Date of Patent: December 13, 2011
    Assignee: Gore Enterprise Holdings, Inc.
    Inventors: Klaus Meindl, Wolfgang Buerger
  • Patent number: 8075671
    Abstract: A method and apparatus for separation of H2 gas from a gaseous mixture utilizing an H2 gas permeable metallic membrane supported directly on a porous substrate made up of at least one porous polymeric hollow fiber. In accordance with one preferred embodiment, the porous substrate is made up of a plurality of porous polymeric hollow fibers, forming a porous hollow fiber membrane. In accordance with one embodiment, a cooling fluid is disposed in contact with the hollow fiber, thereby enabling advantageous operation of the H2 gas separation process at elevated temperatures in the range of about 200° F. to about 800° F.
    Type: Grant
    Filed: June 8, 2009
    Date of Patent: December 13, 2011
    Assignee: Gas Technology Institute
    Inventors: Shaojun James Zhou, Howard S. Meyer
  • Publication number: 20110296984
    Abstract: A scrubber for controlling carbon dioxide levels in a shipping container containing respiring produce is disclosed. The scrubber is relatively small, utilizes a gas-selective membrane having a CO2/O2 selectivity ratio greater than 1:1, and fits inside the shipping container (such as a sea van container). In contrast to current methods of controlling CO2 levels in shipping containers, such as the use of hydrated lime, the scrubbers of the present invention are efficient, relatively inexpensive, do not take up shipping space within the container, and do not present handling or disposal issues. A method for controlling the carbon dioxide levels inside a shipping container containing respiring produce, utilizing the carbon dioxide scrubbers defined, is also disclosed.
    Type: Application
    Filed: June 2, 2011
    Publication date: December 8, 2011
    Applicant: Chiquita Brands International, Inc.
    Inventors: Richard F. Macleod, Frederick Robert Forgnone, William Garrison Lester
  • Patent number: 8070860
    Abstract: An H2-permeable membrane system (117) comprises an electroless-deposited plating (115) of Pd or Pd alloy on a porous support (110, 110?). The Pd plating comprises face-centered cubic crystals cumulatively having a morphology of hexagonal platelets. The permeability to H2 of the membrane plating (115) on the porous support is significantly enhanced, being at least greater than about 1.3×10?8 mol·m?1·s?·Pa?0.5 at 350° C., and even greater than about 3.4×10?8 mol·m?1·s?1·Pa?0.5. The porous support (110, 110?) may be stainless steel (1100 and include a thin ceramic interlayer (110?) on which the Pd is plated. The method of providing the electroless-deposited plating includes preheating a Pd electroless plating solution to near a plating temperature substantially greater than room temperature, e.g. 60° C., prior to plating.
    Type: Grant
    Filed: September 28, 2006
    Date of Patent: December 6, 2011
    Assignee: United Technologies Corporation
    Inventors: Thomas Henry Vanderspurt, Ying She, Zissis Dardas, Craig Walker, James D. MacLeod
  • Patent number: 8066799
    Abstract: The present disclosure relates to a high molecular weight, monoesterified polyimide polymer. Such high molecular weight, monoesterified polyimide polymers are useful in forming crosslinked polymer membranes for the separation of fluid mixtures. According to its broadest aspect, the method of making a crosslinked membrane comprises the following steps: (a) preparing a polyimide polymer comprising carboxylic acid functional groups from a reaction solution comprising monomers and at least one solvent; (b) treating the polyimide polymer with a diol at esterification conditions in the presence of dehydrating conditions to form a monoesterified polyimide polymer; and (c) subjecting the monoesterified fiber to transesterification conditions to form a crosslinked fiber membrane, wherein the dehydrating conditions at least partially remove water produced during step (b). The crosslinked membranes can be used to separate at least one component from a feed stream including more than one component.
    Type: Grant
    Filed: January 10, 2008
    Date of Patent: November 29, 2011
    Assignees: Chevron U.S.A. Inc., Georgia Tech Research Corporation
    Inventors: Stephen J. Miller, Imona C. Omole, William J. Kronos
  • Patent number: 8048198
    Abstract: The present invention discloses a new type of high performance mixed matrix membranes (MMMs) and methods for making and using the same. The MMMs comprise a continuous polymer matrix and at least two types of molecular sieves dispersed therein. The continuous polymer matrix in the MMM contains at least one type of polymer. The MMM in the form of a dense film, asymmetric flat sheet membrane or otherwise prepared exhibits simultaneously improved selectivity and permeability for gas separations compared to polymer membranes made from a continuous polymer matrix without any molecular sieves or with only one type of molecular sieve. MMMs of the present invention are suitable for a wide range of gas, vapor, and liquid separations such as alcohol/water, CO2/CH4, H2/CH4, O2/N2, CO2/N2, olefin/paraffin, iso/normal paraffins, and other light gases separations.
    Type: Grant
    Filed: November 8, 2007
    Date of Patent: November 1, 2011
    Assignee: UOP LLC
    Inventors: Chunqing Liu, David A. Lesch, Stephen T. Wilson
  • Patent number: 8048209
    Abstract: A degassing device (203) comprises a first chamber (21) having an inlet for a liquid, and a second chamber (22) having an opening (23) closed by a hydrophobic membrane (24) and an outlet (25) for discharging the liquid. The first chamber (21) has a downstream portion that partially extends within the second chamber (22) and communicates therewith by a passageway (28). The second chamber (22) has a downstream portion that extends below the passageway (28) and asymmetrically surrounds the downstream portion of the first chamber (21).
    Type: Grant
    Filed: November 2, 2004
    Date of Patent: November 1, 2011
    Assignee: Gambro Lundia AB
    Inventors: Jürgen Dannenmaier, Hermann Goehl, Thomas Ertl, Jacques Chevallet, Francesco Ribolzi
  • Patent number: 8043411
    Abstract: A device for removal of at least a portion of carbon dioxide from an aqueous fluid includes at least one membrane through which carbon dioxide can pass to be removed from the fluid and immobilized carbonic anhydrase on or in the vicinity of a first surface of the membrane to be contacted with the fluid such that the immobilized carbonic anhydrase comes into contact with the fluid. The first surface exhibits carbonic anhydrase activity of at least 20% of maximum theoretical activity of the first surface of the membrane based on monolayer surface coverage of carbonic anhydrase in the case that the carbonic anhydrase is immobilize on the first surface.
    Type: Grant
    Filed: June 16, 2010
    Date of Patent: October 25, 2011
    Assignee: University of Pittsburgh - of the Commonwealth System of Higher Education
    Inventors: William J. Federspiel, Allan J. Russell, Heung-Il Oh, Joel Kaar
  • Patent number: 8038960
    Abstract: A reformer that produces reformed gas from a hydrocarbon material includes a reforming chamber having an inner cylinder and an outer cylinder; a reforming catalyst filled in the reforming chamber; a burner that heats the reforming catalyst and fuel of reformed gas; a combustion gas outer flow channel through which combustion gas of the burner flows along an outer side surface of the reforming chamber; a combustion gas inner flow channel through which the combustion gas of the burner flows along an inner side surface of the reforming chamber; and a plurality of return pipes as a reformed gas flow channel.
    Type: Grant
    Filed: January 24, 2005
    Date of Patent: October 18, 2011
    Assignee: Idemitsu Kosan Co., Ltd.
    Inventor: Kazuyuki Higashino
  • Patent number: 8034160
    Abstract: This invention relates to gas generators and methods for their use. In some embodiments, the invention relates to devices and methods of generating a gas enriched in a specific component. In other embodiments, the devices are configured to pressurize and regulate the temperature of atmospheric air prior to passing said air through a selectively permeable gas membrane. In further embodiments, a device is also configured to preheat said selectively permeable gas membrane.
    Type: Grant
    Filed: April 25, 2008
    Date of Patent: October 11, 2011
    Assignee: Nitro-Lift Technologies, Inc.
    Inventor: Danny Daniels
  • Publication number: 20110232484
    Abstract: There is disclosed an asymmetric gas separation membrane exhibiting both improved gas separation performance and improved mechanical properties, which is made of a soluble aromatic polyimide comprised of a repeating unit represented by general formula (1): wherein B in general formula (1) B comprises 10 to 70 mol % of tetravalent unit B1 represented by general formula (B1) and 90 to 30 mol % of tetravalent unit B2 represented by general formula (B2), and A in general formula (1) comprises 10 to 50 mol % of bivalent unit A1 represented by general formula (A1a) or the like and 90 to 30 mol % of bivalent unit A2 represented by general formula (A2a) or the like.
    Type: Application
    Filed: September 30, 2009
    Publication date: September 29, 2011
    Applicant: UBE INDUSTRIES, LTD.
    Inventors: Toshimune Yoshinaga, Makoto Nakamura, Tomonori Kanougi, Yoji Kase, Kenji Fukunaga
  • Publication number: 20110204089
    Abstract: A gas recovery system for a beverage dispensing system, the gas recovery system comprising: means for drawing gas from an at least partially used beverage container, a compressor downstream of said at least partially used beverage container; a gas separator downstream of said compressor, a gas storage vessel downstream of said gas separator; wherein in use the gas recovery system is configured to draw gas from the at least partially used beverage container and to separate said gas into component gases by passing said gas through said gas separator, and to selectively direct at least one of the separated component gases to said gas storage vessel.
    Type: Application
    Filed: January 16, 2009
    Publication date: August 25, 2011
    Inventor: Robert Walter Shettle
  • Publication number: 20110200897
    Abstract: The present disclosure is directed to a system for delivery of a target material and/or energy. The system includes a source configured to provide a mixture containing the target material and a non-target material, a delivery conduit coupled to the source to receive the mixture from the source, and an in-line extraction device concentric to the delivery conduit. The in-line extraction device is configured to selectively extract the target material and/or energy from the mixture in the delivery conduit and to delivery it to a downstream facility.
    Type: Application
    Filed: February 14, 2011
    Publication date: August 18, 2011
    Applicant: McAlister Technologies, LLC
    Inventor: Roy Edward McAlister
  • Patent number: 7998247
    Abstract: A gas separation membrane and a method of manufacturing such gas separation membrane that comprises a porous substrate treated with a layer of metal-coated inorganic oxide particles and with the layer of such metal-coated inorganic oxide particles being coated with an overlayer of a gas-selective material.
    Type: Grant
    Filed: May 13, 2010
    Date of Patent: August 16, 2011
    Assignee: Shell Oil Company
    Inventors: John Charles Saukaitis, Alan Anthony Del Paggio
  • Patent number: 7998254
    Abstract: A helically wound hollow membrane module having a core with a plurality of helically wound layers of semi-permeable hollow fibers wound on the core. The fiber wind angle with respect to any one layer of fibers may be essentially constant along the axial length of the module, except in one or both end or tubesheet regions, where the wind angle may be increased, in at least some of the layers relative to the essentially constant wind angle, to produce an area of decreasing diameter.
    Type: Grant
    Filed: September 21, 2007
    Date of Patent: August 16, 2011
    Assignee: Porous Media Corporation
    Inventors: John Henry Burban, Jeffrey William Berg, Brent Joseph Steffensmeier, Joseph Charles Tuma, Carl Matthew Geisz, Craig Jonathan Cuta
  • Publication number: 20110192281
    Abstract: A composition includes a first polymer having monomers each containing an imidazole group, and a second polymer, the first and second polymers being a polymer blend. The first polymer, the second polymer, or both may be cross-linked. The carbonized composition, polymeric and carbon membranes (either in the form of a flat sheet or a hollow fiber) made from the composition are also described.
    Type: Application
    Filed: October 7, 2009
    Publication date: August 11, 2011
    Applicant: National University of Singapore
    Inventors: Seyed Saeid Hosseini, Tai-Shung Chung
  • Patent number: 7972415
    Abstract: A breathing air purification device and method having a carbon-monoxide free sweep stream. Water vapor is removed from a compressed air stream using a membrane dryer, comprising, a membrane having a permeate portion and a non-permeate portion, a membrane housing which encases the membrane, a membrane feed inlet conduit connected to the membrane and a non-permeate gas outlet conduit fluidly connected to the non-permeate portion of the membrane. The sweep stream used to cleanse the outer permeate portion of the membrane dryer is taken from a catalyst filter. The catalyst filter includes a cartridge containing a bed of catalyst, two end pieces maintaining the cartridge within a catalyst bed housing and having outlet holes, a catalyst inlet conduit connected to the bed of catalyst and a product gas outlet conduit connected to the outlet holes. A sweep inlet tube provides a gas connection from the catalyst filter component to the permeate portion of the membrane.
    Type: Grant
    Filed: December 11, 2008
    Date of Patent: July 5, 2011
    Assignee: SPX Corporation
    Inventors: Timothy J. Fox, Mark F. Honath
  • Patent number: 7972417
    Abstract: A hydrogen purification method that is used to separate hydrogen gas from a source gas. A hydrogen separator into which flows the source. Within the hydrogen separator is at least one hydrogen permeable tube that is made of a hydrogen permeable material. A support tube is provided for each hydrogen permeable tube. A support tube is coaxially aligned with the hydrogen permeable tube, wherein a micro-channel exists between the hydrogen permeable tube and the support tube in an area of overlap. The source gas is introduced into the micro-channel. The source gas spreads thinly over the hydrogen permeable tube in the micro-channel. The restrictions of the micro-channel cause the source gas to embody turbulent flow characteristics as it flows through the micro-channel. The turbulent flow causes the hydrogen separator to separate hydrogen from the source gas in a highly efficient manner.
    Type: Grant
    Filed: March 21, 2008
    Date of Patent: July 5, 2011
    Inventors: Peter R. Bossard, Jacob Mettes