Abstract: A moisture exchange module has a bundle of moisture-permeable hollow fiber membranes and at least one line element for supplying a gas stream that flows through the hollow fibers in an inner flow. The at least one line element opens out into an inflow region, which is of at least approximately the same cross section as the bundle of hollow fiber membranes. According to the present invention, the at least one line element opens out into the inflow region at an angle of from 60° to 120° with respect to the longitudinal axis of the bundle of hollow fiber membranes without the longitudinal axes of the one line element and of the bundle of hollow fiber membranes intersecting one another. An annular diverter means for diverting the gas flow are provided between the cross section of the line elements through which gas can flow and the inflow region.

Abstract: The present invention provides for a process for producing carbon monoxide. A feed gas stream of hydrogen, carbon monoxide and carbon dioxide is directed to a membrane unit which separates the feed gas stream into two streams. The stream containing carbon monoxide is directed to second membrane unit for further purification and the steam containing the carbon dioxide and hydrogen is fed to a reverse shift reactor to produce more carbon monoxide. The carbon monoxide recovered from the reverse shift reactor is purified in a third membrane unit and directed back to the first membrane unit and is further purified and recovered as additional carbon monoxide product.

Abstract: A method and apparatus for reducing the effect of integrity loss in a hollow fiber membrane module, said module including a plurality of hollow fiber membranes (5), at least one end of the fiber membranes (5) being supported in a pot (6), the method including the step of increasing flow resistance of the liquid through the lumen (8) of the fiber membrane (5) in the region of the pot (6).

Abstract: Assemblies for use in separation of a fluid feed. Assemblies typically include an elongated housing having a fluid feed stream inlet, a residual stream outlet and a permeate stream outlet. The housing contains at least one membrane separation element to form a membrane separation element linear string that at least in part defines a linear permeate passage tube. A permeate adapter is joined with an end of the linear permeate passage tube. The permeate adapter includes a receiving opening for receiving an end of the linear permeate passage tube. The adapter defines a permeate passageway extending therethrough and includes a plurality of permeate discharge openings disposed such as to place the receiving opening and the permeate discharge openings in fluid flow communication.

Abstract: A hydrogen permeation membrane is provided having a cP2 Pearson symbol (Pm3m space group) structure. Suitable alloys include an “A” element from Periodic Table groups 3b-5b and an “M” element from the Periodic Table groups 6b-1b present at a stoichiometry that achieves the inventive crystal structure. Zr and Nb are the preferred A elements followed in preference by Ti and V. First Periodic Table row elements from groups 6b-1b are the preferred B elements. The inventive alloys also find applications as hydrogen getters, Ni-metal hydride battery materials, and hydrogen storage materials.

Abstract: A nanostructured substrate is disclosed having a plurality of substrate openings disposed between the nanostructures on the substrate. When a desired fluid comes into contact with the substrate, at least a portion of the fluid is allowed to pass through at least one of the openings. In a first embodiment, the fluid is caused to pass through the openings by causing the fluid to penetrate the nanostructures. In a second embodiment, the substrate is a flexible substrate so that when a mechanical force is applied to the substrate, such as a bending or stretching force, the distance between nanoposts or the diameter of nanocells on the substrate increases and the liquid penetrates the nanostructures. In another embodiment, a first fluid, such as water, is prevented from penetrating the nanostructures on the substrate while a second fluid is permitted to pass through the substrate via the openings in the substrate.

Abstract: It is to provide an improved method for preparation of microsphere from an emulsion wherein an organic phase containing an organic solvent having a boiling point lower than that of water and a hardly-water-soluble polymer is emulsified in an aqueous phase by an in-water drying method, which comprises: (1) using an apparatus equipped with a gas separation membrane; (2) supplying the emulsion to be subjected to in-water drying to one side of said gas separation membrane; (3) evaporating off the organic solvent contained in said emulsion to the other side of said gas separation membrane, which can remove the organic solvent with high efficiency and can be carried out in a closed system and hence is favorable from the environmental viewpoint.

Abstract: A system and method for separation of a gas, e.g., carbon dioxide, from a gaseous mixture using a hollow fiber membrane module. The module contains an absorbent solution that is effective in absorbing the gas for an extended period, e.g., eight hours, without regeneration or replacement. The absorbent solution is then regenerated by passing a sweep gas through the hollow fibers in the module. The separation system is particularly useful for fuel cell and battery applications.

Abstract: SAPO membranes and methods for their preparation and use are described. The SAPO membranes are prepared by contacting at least one surface of a porous membrane support with an aged synthesis gel. A layer of SAPO crystals is formed on at least one surface of the support. SAPO crystals may also form in the pores of the support. SAPO-34 membranes of the invention can have improved selectivity for certain gas mixtures, including mixtures of carbon dioxide and methane.

Abstract: A method and apparatus for separating a component from a multi-component feed gas stream has a flow conduit (14) having a semi-permeable section (15) that permeates the component to be separated from feed gas stream (12). A sweep gas is provided at a first velocity on the permeate sides of flow conduit (14) and the velocity of sweep gas (13) is accelerated so that the velocity of sweep gas (13) along at least a portion of the permeate side of flow conduit (14) is greater than the first velocity. The mixture of permeate and sweep gas (13) is then decelerated by diffuser (20), thereby recovering as pressure a portion of the energy of feed gas stream (12).

Abstract: A coupler for a spiral membrane filtration element having a spiral membrane enclosed within a rigid outerwrap includes a center support, a plurality of spokes extending outwardly from the center support, a circular rim coupled with the spokes, with the face of the rim being perpendicular to the axis of the overwrap. The rim includes a channel on its face for receiving a compressible seal, and a plurality of receptacles around its outer surface for joining two face-to-face adjacent couplers when a pair of aligned keepers is placed in each receptacle. Exemplary embodiments of the coupler and filtration elements and filtration assemblies are provided, as well as an associated method.

Abstract: There is provided a high efficient gas separation membrane of two or more layers, which comprises a separating layer of 3-dimensional nanostructure and a supporting layer, wherein the 3-dimensional nanostructure can maximize a surface area per unit permeation area.

Abstract: A mixed matrix membrane for separating gas components from a mixture of gas components is disclosed. The membrane comprises a continuous phase polymer with inorganic porous particles, preferably molecular sieves, interspersed in the polymer. The polymer has a CO2/CH4 selectivity of at least 20 and the porous particles have a mesoporosity of at least 0.1 cc STP/g. The mixed matrix membrane exhibits an increase in permeability of least 30% with any decrease in selectivity being no more than 10% relative to a membrane made of the neat polymer. The porous particles may include, but are not limited to, molecular sieves such as CVX-7 and SSZ-13, and/or other molecular sieves having the required mesoporosity. A method for making the mixed matrix membrane is also described. Further, a method is disclosed for separating gas components from a mixture of gas components using the mixed matrix membrane with mesoporous particles.

Abstract: Novel porous PTFE membranes are described possessing a unique combination of high strength, low flow resistance, and small pore size. Additionally, unique constructions with superior filtration and venting properties incorporating porous PTFE membranes are described.

Abstract: A membrane contactor includes a housing, a stack of membrane mats, and a cap. The housing has a closed end and an open end. The closed end includes an outlet port. The cap is united to the open end and includes an inlet port. A stack of membrane mats is within the housing stacked substantially perpendicular to the longitudinal axis of the housing. Each membrane mat has a plurality of hollow fiber members. A potting material bonds the membrane mats to each other and simultaneously bonds one end of the stack to the closed end and bonds the other end of the stack to the cap. The potting material forms an internal chamber and at least one external chamber within the housing. The hollow fiber members extend through the potting material from the internal chamber into the external chambers. The inlet port and the outlet port are in communication with the internal chamber. At least one side port is in communication with the external chambers.

Abstract: A system for supplying a compressed fluid with a reduced moisture content comprising a membrane dryer for receiving a compressed fluid and removing moisture therefrom, a compressed fluid source located upstream of the membrane dryer, a check valve located upstream of the membrane dryer to prevent backflow therethrough, an accumulator for receiving the compressed fluid discharged from the membrane dryer and an inlet on the membrane dryer for receiving a portion of a compressed fluid from the compressed fluid source wherein the portion of the compressed fluid is diverted from a compressed fluid located upstream of the membrane dryer.

Abstract: A process for the manufacture of a polyimide hollow fibre comprising: (i) providing a dope solution comprising one or more polyimides dissolved in a solvent comprising 60-100 wt % N-methylpyrollidone and 0-40 wt % ethanol, (ii) providing a bore fluid, (iii) generating a tube of the dope solution filled with the bore fluid, (iv) bringing the product of step (iii) into contact with a coagulation solvent to form a hollow fiber.

Abstract: An apparatus and method to separate a mixture of gases—such as carbon dioxide and methane—by an inorganic membrane comprising a ceramic support and a silica layer made from a silicon elastomer sol. The apparatus and method can efficiently separate the gaseous mixture and can also cope with the extreme conditions found in e.g. hydrocarbon producing wells. A method of manufacturing the apparatus is also disclosed.

Abstract: A separation membrane module having hollow fibers, wherein a plurality of hollow fibers are heated and melted to bond and thermally fuse the external surfaces of the hollow fibers with each other; and a method of manufacturing a separation membrane module having hollow fibers whereby the ends of a plurality of hollow fibers are inserted into a sheath, the sheath and the hollow fibers are tightly bonded together to form spaces, and the sheath portion into which hollow fibers have been inserted is heated up to the temperature at which the surfaces of the hollow fibers melt, with the spaces thus formed kept in a decompressed state, so that the exterior surfaces of the hollow fibers are thermally fused and integrated together.

Abstract: The present invention discloses a method and apparatus for separating particles and dissolved matter from a fluid stream. Specifically, the present invention includes a first pressure source which transports untreated fluid into a separator annulus with a filter element disposed therein. The untreated fluid is placed under appropriate pressure sufficient to produce turbulent flow, increased particle kinetics and/or cavitation physics allowing the desired fluid to penetrate and pass into and through the filter media. The filtered fluid is then transported to a collection tank. The contaminant particulate matter retained on the exterior of the filter media may be removed by the instantenous reverse pressurization of the separator annulus by a second pressure source thereby removing the contaminant particles away from contact with the filter media, and which may then be transported to a waste collection tank or a concentrator for further treatment.

Abstract: A method of separating oxygen from an oxygen containing feed and reacting the oxygen with a reactive substance and an oxygen ion transport membrane element utilized for such purposes. The oxygen ion transport membrane element has a self-supporting dense layer and a surface porous feature in contact with and supported by the dense layer. The porous surface feature may be a layer, a layer having discontinuities or a series of repeating geometrical forms. The dense layer and the porous surface feature are capable of conducting oxygen ions and electrons. The porous surface feature at least in part forms the anode side of the oxygen ion transport membrane element at which the reactive substance reacts with the separated oxygen and has a thickness less than that of the dense layer and a greater surface area than that of a surface of the dense layer adjoining the porous layer. Pores within the porous surface feature have a pore aspect ratio of pore size to pore length of between about 0.1 and about 5.

Abstract: The instant invention is a hollow fiber membrane contactor, and method of making same. The hollow fiber membrane contactor includes (1) a shell, said shell having a internal bonding surface, an interlocking geometry ring being provided on said internal bonding surface; (2) a unitized structure; (3) a potting material joining said unitized structure to said shell at said interlocking geometry ring thereby forming an interlocking seal therebetween; and (4) end caps, said end caps being adjoined to lateral ends of said shell. The method of making a hollow fiber membrane contactor includes (1) providing a shell, said shell having a internal bonding surface; (2) providing an interlocking geometry ring on said internal bonding surface; (3) forming a unitized structure; (4) placing the unitized structure into said shell (5) potting said unitized structure to said shell at said interlocking geometry ring thereby forming an interlocking seal therebetween; and (6) adjoining end caps to lateral ends of said shell.

Abstract: According to the module 10, the other end 22 of each of the plurality of porous cylindrical bodies 12 the one end 20 of each of which is closed is opened to the gas chamber 58 between the end cap 18 and the end cover 54, and the end cap 18 is provided with the through-hole 53 leading from the gas chamber 56 outward, and the gas chamber 58 leads outward by means of a path passing through the through-hole 53 and through the porous cylindrical body 12. The module 10 can have a gas-passing path from the peripheral wall 24 of the porous cylindrical-body 12 outward through the gas chamber 58 and through the through-hole 53.

Abstract: A composition of and a method of making high performance hollow fiber membranes is described. The membranes have a high resistance to plasticization by use of a predetermined amount of crosslinking. The preferred polymer material for the membrane is a polyimide polymer comprising covalently bonded ester crosslinks. The resultant hollow fiber membrane exhibits a high permeability of CO2 in combination with a high CO2/CH4 selectivity. Another embodiment provides a method of making the hollow fiber membrane from a monesterified polymer followed by final crosslinking after hollow fiber formation.

Abstract: A composite oxygen ion transport element that has a layered structure formed by a dense layer to transport oxygen ions and electrons and a porous support layer to provide mechanical support. The dense layer can be formed of a mixture of a mixed conductor, an ionic conductor, and a metal. The porous support layer can be fabricated from an oxide dispersion strengthened metal, a metal-reinforced intermetallic alloy, a boron-doped Mo5Si3-based intermetallic alloy or combinations thereof. The support layer can be provided with a network of non-interconnected pores and each of said pores communicates between opposite surfaces of said support layer. Such a support layer can be advantageously employed to reduce diffusion resistance in any type of element, including those using a different material makeup than that outlined above.

Abstract: A method of supplying oxygen rich air to the passengers and crew on board a passenger aircraft by use of a highly permeable oxygen enrichment unit, wherein the fiber tubes of the hollow fiber membranes used to separate normal air into oxygen rich and nitrogen rich fractions in the oxygen enrichment unit are subjected to a modification technique before the tubes are coated with a selective polymer.

Abstract: A mass transfer device having a fluid permeable core wound with many stands of a hollow fiber. A bulk fluid enters the interior of the core, passes through the side wall of the core, and along the outer surfaces of the hollow fibers. A baffle positioned in the center of the core so that the bulk fluid passes outwardly upstream of the baffle and inwardly through the core along the downstream of the block.

Abstract: A method of producing composite, hollow fibre gas separation membranes, wherein external surfaces of the porous hollow fibre tubes used in the construction of the membranes are subjected to a modification technique before the external surfaces are coated with a thin layer of selective polymer so as to increase the number of pores in the fibre surface.

Abstract: A mixed matrix membrane is provided which comprises a continuous phase organic polymer and small pore molecular sieves dispersed therein. The molecular sieves have a largest minor crystallographic free diameter of 3.6 Angstroms or less. When these molecular sieves are properly interspersed with a continuous phase polymer, the membrane will exhibit a mixed matrix membrane effect, i.e., a selectivity increase of at least 10% relative to a neat membrane containing no molecular sieves. Finally, methods for making and using such mixed matrix membranes to separate gases from a mixture containing two or more gases are also disclosed.

Abstract: An oxygen transport membrane reactor having an oxygen transport membrane and a downstream fuel injector located within a chamber. The oxygen transport membrane and fuel injector are enclosed by a duct that constrains an incoming oxygen containing feed to flow along the outer surface of the duct and then reverse direction and flow within the duct and past the oxygen transport membrane and then the fuel injector. The oxygen transport membrane permeates part of the oxygen within the oxygen containing feed by ion transport to form a retentate. The retentate is used to support combustion of the fuel injected by the fuel injector. The resulting heat is used to heat the incoming oxygen containing feed by indirect heat exchange which in turn is used to heat the oxygen transport membrane.

Abstract: A sealing technique is established in which a seal can be easily formed and which is excellent in reliability and a heat cycle property in a high temperature region of 800° C. or higher, so as to provide a composite body preferably used for a device for producing pure oxygen, oxygen-rich air, and the like, a membrane reactor represented by that for partial oxidation of a hydrocarbon gas, a solid oxide fuel cell, an oxygen purification device, a heat exchanger, or the like. The present invention makes it possible to increase a possibility of practical use in a wide area which has been delayed in development owing to a bottleneck of improvement in a sealing property. Particularly, its application to the device for producing pure oxygen, oxygen-rich air, or the like, the membrane reactor represented by that for partial oxidation of the hydrocarbon gas, the solid oxide fuel cell, the oxygen purification device, the heat exchanger, or the like can greatly contribute to acceleration of the development.

Abstract: A process for controlling the volume of dry air, dried to a predetermined degree of dryness, from a sweep manifold of an air dryer system, flowing over a plurality of gas/liquid fluid separating membranes, comprising: diverting a predetermined volume of dried air to the manifold; sensing one of the flow volume and humidity values of the remainder of the dried air or the pressure differential within the system; and utilizing one of the differential pressure to control the predetermined volume of dried air and utilizing a controller for achieving the predetermined degree of dryness by controlling at least one solenoid valve which, in turn, controls the flow volume of the predetermined volume of dried air diverted to the manifold.

Abstract: An elongated flow-through degassing apparatus includes an elongated gas and liquid impermeable outer tube and one or more gas-permeable, liquid-impermeable elongated inner tubes extending within the outer tube and at least partially through a chamber defined within the outer tube. The apparatus also includes inlet and outlet connection structures operably coupled to respective portions of the outer tube and the inner tubes to further enable a sealed engagement between the outer tube and the inner tubes, and to provide for connection devices to operably couple the degassing apparatus of the present invention to respective spaced apart components. The degassing apparatus is sufficiently flexible so as to be readily manipulatable into desired configurations.

Abstract: A hydrogen purification system and method that utilizes a hydrogen separator with a novel composite structure. The hydrogen separator has a first porous layer of a hydrogen permeable material, such as a palladium alloy. A solid layer of the same hydrogen permeable material is then disposed onto the first porous layer. A pressure differential is created across the structure of the composite hydrogen separator. The porous layer of hydrogen permeable material supports the solid layer and enables the solid layer to withstand large pressure differentials. Furthermore, the porous layer of the hydrogen permeable material bonds to the solid layer, thereby greatly increasing the effective surface area of the solid layer that is exposed to hydrogen gas. Accordingly, a large flow rate of hydrogen gas can be obtained in a small amount of space.

Abstract: Method for processing an article comprising a mixed conducting metal oxide material, which method comprises (a) contacting the article with an oxygen-containing gas and reducing or increasing the temperature of the oxygen-containing gas; (b) when the temperature of the oxygen-containing gas is reduced, reducing the oxygen activity in the oxygen-containing gas; and (c) when the temperature of the oxygen-containing gas is increased, increasing the oxygen activity in the oxygen-containing gas.

Abstract: A device or apparatus for contacting a liquid with a gas is provided. The device or apparatus has at least one gas inlet for introducing the gas into the liquid and a fiber housing with at least one liquid inlet and at least one liquid outlet. The fiber housing is surrounding and defining an outer bound for a plurality of fibers extending longitudinally in the fiber housing, whereby longitudinally extending interspaces are provided between the fibers. These interspaces thereby define flow passages for the liquid and gas. There is also provided a system and a method for contacting a liquid with a gas.

Abstract: Medical devices for removing gasses, such as gas bubbles and/or dissolved gasses, from a liquid to be delivered to a patient, and methods of use and making of such devices. In at least some embodiments, a gas permeable membrane material is used in the construction of the gas removal devices. In some embodiments, layers of gas permeable membrane material are used to construct a filter structure for removing gas from the liquid. In other embodiments, hollow tubes and/or fibers of the gas permeable membrane material are used to construct a filter structure for removing gas from the liquid. The gas removal devices may be used in any of a broad variety of liquid delivery systems and/or configurations.

Abstract: A device and method for separating water into hydrogen and oxygen is disclosed. A first substantially gas impervious solid electron-conducting membrane for selectively passing protons or hydrogen is provided and spaced from a second substantially gas impervious solid electron-conducting membrane for selectively passing oxygen. When steam is passed between the two membranes at dissociation temperatures the hydrogen from the dissociation of steam selectively and continuously passes through the first membrane and oxygen selectively and continuously passes through the second membrane, thereby continuously driving the dissociation of steam producing hydrogen and oxygen. The oxygen is thereafter reacted with methane to produce syngas which optimally may be reacted in a water gas shift reaction to produce CO2 and H2.

Abstract: An apparatus and method to separate a mixture of gases, such as carbon dioxide and methane, by a ceramic membrane having a ceramic support and a silica layer. The invention can efficiently separate the gaseous mixture and can also cope with the extreme conditions found in, e.g., hydrocarbon producing wells. A method of manufacturing the apparatus is also disclosed.

Abstract: A hydrogen diffusion cell that is used to purify contaminated hydrogen gas. The hydrogen diffusion cell has at least one hydrogen diffusion structure that separates a first area from a second area. Normally, the pressure in the first area is kept higher than the pressure in the second area. This causes a pressure differential that causes hydrogen gas to permeate from the first area to the second area. However, an extreme pressure differential can occur when the second area is at its maximum pressure and the first area is inadvertently vented to ambient pressure. Under this extreme pressure differential hydrogen gas permeates from the second area back into the first area at a maximum reverse flow rate. A flow restrictor is provided that limits the flow of gas exiting the first area to a flow rate no greater than the maximum reverse flow rate.

Abstract: A method of separating or concentrating hydrocarbon-containing gas mixtures such as hydrogen from hydrocarbons, carbon dioxide from hydrocarbons, nitrogen from hydrocarbons, and hydrocarbons from one another using a selectively permeable membrane. The method is well suited to separate hydrocarbon-containing mixtures such as those generated by petroleum refining industries, petrochemical industries, natural gas processing, and the like. The membranes exhibit extremely good resistance to plasticization by hydrocarbon components in the gas mixture under practical industrial process conditions.

Abstract: A tubular hydrogen permeable metal membrane and fabrication process comprises obtaining a metal alloy foil having two surfaces, coating the surfaces with a metal or metal alloy catalytic layer to produce a hydrogen permeable metal membrane, sizing the membrane into a sheet with two long edges, wrapping the membrane around an elongated expandable rod with the two long edges aligned and overlapping to facilitate welding of the two together, placing the foil wrapped rod into a surrounding fixture housing with the two aligned and overlapping foil edges accessible through an elongated aperture in the surrounding fixture housing, expanding the elongated expandable rod within the surrounding fixture housing to tighten the foil about the expanded rod, welding the two long overlapping foil edges to one another generating a tubular membrane, and removing the tubular membrane from within the surrounding fixture housing and the expandable rod from with the tubular membrane.

Abstract: A high temperature hydrogen gas separation membrane employing a physically interlocking barrier layer to form a spinel or intermetallic architecture bonding the metal barrier layer onto the surface of a fibrous metal medial structural support substrate. A tantalum/niobium interface layer is deposited on the barrier layer. The final layer is a precious metal such as palladium, which is deposited on the tantalum/niobium interface layer.

Abstract: The present invention provides a selectively gas permeable membrane that has a superior combination of permeability and selectivity. The membrane composition includes a Type 1 copolyimide uniformly blended with a Type 2 copolyimide, which polymers are defined by chemical structure more specifically in this disclosure. The invention also provides a method of using the membrane of the copolyimide blend to separate components of gas mixtures.

Abstract: A DDR type zeolite membrane formed on a substrate includes silica as a main component. The DDR type zeolite membrane separates at least one type of a gas component from a mixed gas containing at least two types of gases selected from a group consisting of carbon dioxide (CO2), hydrogen (H2), oxygen (O2), nitrogen (N2), methane (CH4), normal butane (n-C4H10), isobutane (i-C4H10), sulfur hexafluoride (SF6), ethane (C2H6), ethylene (C2H4), propane (C3H8), propylene (C3H6), carbon monoxide (CO), and nitrogen monoxide (NO). Each single gas permeance at room temperature and 100° C. are different, respectively, in order to separate at least one selected gas component from the mixed gas.

Abstract: The invention relates to a filter comprising membranes made of hollow fibers in which the hollow fibers are arranged as a bundle in a tubular housing. The housing comprises an end cap on each of its ends, whereby the hollow fiber bundle is placed between the ends of the housing. The ends of the hollow fiber bundle each comprise a support ring that surrounds the same and are cast inside said support ring. The support rings are displaceably mounted in the housing in order to compensate for, among other things, axial contractions of the hollow fiber bundle occurring during heat sterilization.

Abstract: A process for removing oxygen from a copper plating solution is provided. The solution is passed through a degasser comprising a shell and hollow hydrophobic fiber porous membranes wherein the shell while a vacuum is drawn on the surfaces of the fibers opposite the fiber surfaces contacted by the solution. Gas passed through the fiber walls while liquid is prevented from infiltrating the fiber pores. The composition of the solution is monitored so that the composition can be retained substantially constant by adding components of the solution as needed.

Abstract: Novel compositions suitable for fabrication of CO2-selective membranes are disclosed. In one aspect, the present invention is directed to compositions comprising polyimide/polyamine blends and copolymers, and to compositions comprising interfacially polymerized polyamides. In another aspect this invention is directed to novel CO2-selective membranes comprising such polyimide/polyamine blends and copolymers, and to novel CO2-selective membranes comprising interfacially polymerized polyamides. In yet another aspect, the present invention is directed to a novel water-gas-shift (WGS) reactor comprising the novel CO2-selective membranes. Advantageously, the use of the novel CO2-selective membrane allows alteration of the normal WGS reaction equilibrium, shifting the reaction towards production of H2. Carbon dioxide on the high pressure, feed gas side of the membrane reactor reacts with the novel membranes of the present invention at the interface between the feed gas and the membrane.

Abstract: Solvent-resistant polybenzimidazole membranes, methods of making them and crosslinking them and composite membranes and hollow fiber membrane modules from them are disclosed.

Abstract: In an apparatus for filtering and separating a flow medium by way of membranes disposed in a pressurized housing, which has an inlet for supplying the flow medium to the housing and outlets for discharging the retentate and the permeate from the housing, the membrane structure comprises a central permeate collection and discharge structure to which a plurality of membrane pillows are connected so as to extend therefrom in a spiral pattern and each membrane pillow is in communication with a permeate inlet opening in the permeate collection and discharge structure through which permeate is conducted out of the membrane pillow into the central permeate collection and discharge structure and to the retentate outlet.