Plural Layers (e.g., Laminated Barrier, Etc.) Patents (Class 96/11)
-
Patent number: 11986774Abstract: Disclosed are methods of preparing a porous ceramic support for an ultra-thin enzyme-assisted membrane, and a new membrane that can be used for gas filtration purposes to remove/separate carbon dioxide or other gases from a gas mixture such as those from power production or enhanced oil recovery or fuel production or air, and recycle/collect/utilize carbon dioxide. In some embodiments, a method may include blocking the pores of a porous substrate with a removable medium, and polishing the surface, coating a silica sol-gel solution onto the support, and removing the blocking medium and sol-gel surfactant to leave a well-confined porous structure.Type: GrantFiled: March 17, 2022Date of Patent: May 21, 2024Assignee: Memzyme, LLCInventors: Caroline Rempe, Ying-Bing Jiang, Yongqian Gao, Jimin Guo
-
Patent number: 11492264Abstract: Seed crystals are crystals of zeolite to be attached onto a support in production of a zeolite membrane complex including the support and a zeolite membrane formed on the support. The specific surface area of the seed crystals is not smaller than 10 m2/g and not larger than 150 m2/g. The strength obtained from a crystal component at a diffraction angle 2? indicating a maximum peak in a range of diffraction angle 2? from 12° to 25° in an X-ray diffraction pattern obtained by emitting X-ray to the seed crystals is not less than once and not more than 30 times that obtained from an amorphous component. It is thereby possible to improve adherence of the seed crystals to the support.Type: GrantFiled: March 11, 2019Date of Patent: November 8, 2022Assignee: NGK Insulators, Ltd.Inventors: Ryotaro Yoshimura, Aya Miura, Kenichi Noda
-
Patent number: 11406927Abstract: An air filter medium includes a first porous PTFE membrane and a second porous PTFE membrane. The air filter medium has a first main surface and a second main surface, and the first porous PTFE membrane and the second porous PTFE membrane are arranged so that an air flow moving from the first main surface to the second main surface passes through the first porous PTFE membrane and subsequently through the second porous PTFE membrane. A contact angle of the first porous PTFE membrane with water is in the range of 154° to 165°.Type: GrantFiled: September 25, 2017Date of Patent: August 9, 2022Assignee: NITTO DENKO CORPORATIONInventors: Takashi Niki, Masaaki Mori, Shiho Wada, Atsushi Daimon, Toshiki Yanagi
-
Patent number: 11213782Abstract: An air filter medium includes a first porous PTFE membrane and a second porous PTFE membrane. The air filter medium (10) has a first main surface and a second main surface, and the first porous PTFE membrane and the second porous PTFE membrane are arranged so that an air flow moving from the first main surface to the second main surface passes through the first porous PTFE membrane and subsequently through the second porous PTFE membrane. A thickness of the first porous PTFE membrane is in the range of 4 to 40 ?m and a specific surface area of the first porous PTFE membrane is 0.5 m2/g or less.Type: GrantFiled: September 25, 2017Date of Patent: January 4, 2022Assignee: NITTO DENKO CORPORATIONInventors: Takashi Niki, Masaaki Mori, Shiho Wada, Atsushi Daimon, Toshiki Yanagi
-
Patent number: 11090628Abstract: A catalytic membrane reactor and methods of operating and producing the same are provided that efficiently produces highly pure hydrogen (H2) from ammonia (NH3) as well as operates according to other chemical conversion processes. In one embodiment, a tubular ceramic support made from porous yttria-stabilized zirconia has an outer surface that is impregnated with a metal catalyst such as ruthenium and then plated with a hydrogen permeable membrane such as palladium. An inner surface of the ceramic support is impregnated with cesium to promote conversion of ammonia to hydrogen and nitrogen (N2). The resulting catalytic membrane reactor produces highly pure hydrogen at low temperatures and with less catalytic loading. Therefore, ammonia can be used to effectively transport hydrogen for use in, for example, fuel cells in a vehicle.Type: GrantFiled: February 24, 2020Date of Patent: August 17, 2021Assignee: Colorado School of MinesInventors: James Douglas Way, Colin A. Wolden
-
Patent number: 9795931Abstract: Methods for forming an ultrathin GO membrane are provided. The method can include: dispersing a single-layered graphene oxide powder in deionized water to form a single-layered graphene oxide dispersion; centrifuging the graphene oxide dispersion to remove aggregated graphene oxide material from the single-layered graphene oxide dispersion; thereafter, diluting the single-layered graphene oxide dispersion by about ten times or more through addition of deionized water to the graphene oxide dispersion; and thereafter, passing the single-layered graphene oxide dispersion through a substrate such that a graphene oxide membrane is formed on the substrate. Filtration membranes are also provided and can include: a graphene oxide membrane having a thickness of about 1.8 nm to about 180 nm, with the graphene oxide membrane comprises about 3 to about 30 layers of graphene oxide flakes.Type: GrantFiled: June 12, 2015Date of Patent: October 24, 2017Assignee: University of South CarolinaInventors: Miao Yu, Hang Li
-
Patent number: 9789445Abstract: A composite oxygen ion transport membrane having a dense layer, a porous support layer, an optional intermediate porous layer located between the porous support layer and the dense layer and an optional surface exchange layer, overlying the dense layer. The dense layer has electronic and ionic phases. The ionic phase is composed of scandia doped, yttrium or cerium stabilized zirconia. The electronic phase is composed of a metallic oxide containing lanthanum, strontium, chromium, iron and cobalt. The porous support layer is composed of zirconia partially stabilized with yttrium, scandium, aluminum or cerium or mixtures thereof. The intermediate porous layer, if used, contains the same ionic and electronic phases as the dense layer. The surface exchange layer is formed of an electronic phase of a metallic oxide of lanthanum and strontium that also contains chromium, iron and cobalt and an ionic phase of scandia doped zirconia stabilized with yttrium or cerium.Type: GrantFiled: September 14, 2015Date of Patent: October 17, 2017Assignee: PRAXAIR TECHNOLOGY, INC.Inventors: Jonathan A. Lane, Zigui Lu, Pawel J. Plonczak
-
Patent number: 9616379Abstract: The present invention relates to a method for preparing a hydrogen separation membrane capable of preventing the plating of Pd inside a porous support and a porous shielding layer when a separation membrane is prepared; a hydrogen separation membrane prepared therefrom; and a use thereof. In addition, the present invention relates to a device for preparing a hydrogen separation membrane; and a method for preparing a hydrogen separation membrane using the device, and in particular, relates to a device for preparing a hydrogen separation membrane capable of stably growing a Pd-containing separation membrane for hydrogen gas separation as a plating solution grows from the upper surface of a porous support to a uniform thickness by simply shielding the lower surface of the porous support when a hydrogen separation membrane is prepared using an electroless plating method.Type: GrantFiled: July 25, 2014Date of Patent: April 11, 2017Assignee: Korea Institute of Energy ResearchInventors: Shin Kun Ryi, Beom Seok Seo, Jong Soo Park, Dong Wook Lee, Sung Wook Lee
-
Patent number: 9486742Abstract: The present disclosure is directed to biomimetic membranes and methods of manufacturing such membranes that include structural features that mimic the structures of cellular membrane channels and produce membrane designs capable of high selectivity and high permeability or adsorptivity. The membrane structure, material and chemistry can be selected to perform liquid separations, gas separation and capture, ion transport and adsorption for a variety of applications.Type: GrantFiled: October 6, 2011Date of Patent: November 8, 2016Assignee: Sandia CorporationInventors: Susan Rempe, C. Jeffrey Brinker, David Michael Rogers, Ying-Bing Jiang, Shaorong Yang
-
Patent number: 9415343Abstract: The present invention relates to a hydrogen separation membrane which coats granular ceramic onto the surface of a porous metal support and which coats a hydrogen permeation metal thereon so as to inhibit diffusion between the support and a hydrogen separation layer, and to a method for manufacturing same. As a result, the metal support can be modularized with ease, the hydrogen permeation layer can be made thinner to increase the amount of hydrogen permeation, the use of a separation material can be minimized, and the hydrogen separation membrane can have higher competitiveness.Type: GrantFiled: January 2, 2013Date of Patent: August 16, 2016Assignee: Korea Institute of Energy ResearchInventors: Jong-Soo Park, Kyung-Ran Hwang, Shin-Kun Ryi, Tae-Hwan Kim, Chun-Boo Lee, Sung-Wook Lee
-
Patent number: 9358506Abstract: A hydrogen separation system and membrane is described for extracting hydrogen from gasifier streams at near atmospheric pressure and ambient temperature conditions. The system can be inserted between a small gasifier and an internal combustion engine which runs a genset to optionally co-produce hydrogen and electricity.Type: GrantFiled: August 19, 2014Date of Patent: June 7, 2016Assignee: V-GRID ENERGY SYSTEMSInventor: Michael Cheiky
-
Patent number: 9266067Abstract: Disclosed are a composite separation membrane structure for a gas sensor for real-time monitoring of degradation of insulating oil of a power transformer, a gas sensor apparatus including the same, and a method and an apparatus for measuring gas concentration using the same. It is possible to locally diagnose whether there is a fault in the power transformer and what kind of fault occurs where in the power transformer by quantitatively measuring the concentration of several gases dissolved in the insulating oil in real time. As a result, breakdown of the power transformer may be prevented and remaining service life of the insulating oil in the power transformer may be predicted.Type: GrantFiled: August 3, 2012Date of Patent: February 23, 2016Assignee: KOREA INSTITUTE OF SCIENCE AND TECHNOLOGYInventors: Hosung Kong, Hung Gu Han, Jung Wook Lee
-
Patent number: 9149762Abstract: A defect-free hydrogen separation membrane includes a metal thin membrane. The metal thin membrane includes a first metal layer composed of palladium on a porous support without substantial penetration into surface pores of the porous support and a second metal layer on the first metal layer. The second metal layer is a product of palladium deposition and closes defects being open on the surface of the first metal layer.Type: GrantFiled: March 7, 2011Date of Patent: October 6, 2015Assignees: National Institute of Advanced Industrial Science and Technology, JX Nippon Oil & Energy CorporationInventors: Yasuyuki Matsumura, Takashi Maeda, Minoru Ogawa, Eiji Negishi
-
Publication number: 20150143995Abstract: A composite membrane comprising: a) a porous support; b) a gutter layer; and c) a discriminating layer; wherein at least 10% of the discriminating layer is intermixed with the gutter layer.Type: ApplicationFiled: June 26, 2013Publication date: May 28, 2015Inventors: Takeshi Umehara, Masatoshi Nakanishi, Yujiro Itami, Hiroyuki Noda, Akihiro Kurima, Kimiko Iwahashi
-
Publication number: 20150135957Abstract: A semipermeable gas separation membrane is plasma deposited from liquid organosiloxane monomer having at least three silicon atoms and an alpha hydrogen atom. The semipermeable membrane may be employed as a gas-selective membrane in combination with a porous substrate.Type: ApplicationFiled: November 19, 2013Publication date: May 21, 2015Applicant: Applied Membrane Technology, inc.Inventor: Ashok K. Sharma
-
Patent number: 9011581Abstract: The invention relates to a vent array comprising a plurality of venting regions comprising a porous PTFE matrix material and a nonporous material comprising a substrate material having a plurality of perforations, wherein the substrate material fills the pores of a porous PTFE matrix material to form nonporous regions, the nonporous regions interconnecting the plurality of venting regions.Type: GrantFiled: December 9, 2014Date of Patent: April 21, 2015Assignee: W. L. Gore & Associates, Inc.Inventor: Andrew J. Holliday
-
Patent number: 9011580Abstract: Techniques are generally described herein for the design and manufacture of hydrogen generation apparatuses and systems. Other embodiments may also be disclosed and claimed. Some methods described herein pressing together a first end plate, one or more intermediate plates, and a second end plate using a press to form a hydrogen purifier module, and placing a plurality of clips around the hydrogen purifier module to hold the first end plate, the one or more intermediate plates, and the second end plate together.Type: GrantFiled: November 17, 2010Date of Patent: April 21, 2015Assignee: Azur Energy LLCInventor: David Edlund
-
Publication number: 20150104357Abstract: The present invention provides a porous silica aerogel composite membrane and method for making the same and a carbon dioxide sorption device. The porous silicon oxide aerogel composite membrane includes a porous aluminum oxide membrane having a plurality of macro pores with an average diameter larger than 50 nm and a porous silica aerogel membrane formed on at least one side of the porous aluminum oxide membrane and the macro pores of surface layers of the porous aluminum oxide membrane where the porous silica aerogel membrane has a plurality of meso pores with an average diameter of 2˜50 nm and is derived from methyltrimethoxysilane precursor by a sol-gel synthetic method.Type: ApplicationFiled: April 9, 2014Publication date: April 16, 2015Applicant: CHUNG YUAN CHRISTIAN UNIVERSITYInventors: Yi-Feng Lin, Chia-Chieh Ko, Kuo-Lun Tung, Chien-Hua Chen, Kai-Shiun Chang
-
Patent number: 9005344Abstract: The present application is directed to a hydrophobic membrane assembly (28) used within a gas-generating apparatus. Hydrogen is separated from the reaction solution by passing through a hydrophobic membrane assembly (28) having a hydrophobic lattice like member (36) disposed within a hydrogen output composite (32) further enhancing the ability of the hydrogen output composite's ability to separate out hydrogen gas and prolonging its useful life.Type: GrantFiled: January 3, 2014Date of Patent: April 14, 2015Assignees: Societe Bic, The Commissariat a L'energie Atomique et Aux Energies Alternatives (CEA)Inventors: Andrew J. Curello, Michael Curello, Constance R. Stepan
-
Patent number: 9005345Abstract: An apparatus for gas separation a composite gas separation membrane having a gas separation layer disposed on a surface of a porous support. The gas separation layer has a plurality of gas permeable inorganic nano-particles embedded in a dense polymer forming substantially only discrete gas transport channels through the dense polymer layer, wherein direct fluid communication is provided from a feed side of the composite gas separator membrane to the porous support. Preferably, the inorganic nano-particles are porous molecular sieve particles, such as SAPO-34, ALPO-18, and Zeolite Y nano-particles.Type: GrantFiled: September 19, 2012Date of Patent: April 14, 2015Assignee: Gas Technology LimitedInventors: Shiguang Li, Shaojun Zhou, Miao Yu, Moises A Carreon
-
Publication number: 20150096444Abstract: An air filter assembly includes a felt of hollow specialty polymer fibers having nonporous walls.Type: ApplicationFiled: October 4, 2013Publication date: April 9, 2015Applicant: BHA Altair, LLCInventors: Todd Joseph Scheerer, Vishal Bansal
-
Publication number: 20150096445Abstract: A self-closing filter includes a housing to be attached to a sidewall of a self-inflating pneumatic tire. The housing includes a cavity to be in fluid communication with an atmospheric air inlet of a pneumatic control valve for the self-inflating tire. The self-closing filter further includes a filtration media to block contaminants from entering the cavity while allowing atmospheric air to be drawn through the filtration media into the cavity by a pump of the self-inflating tire. The self-closing filter still further includes a valve attached to the housing. The valve is selectively actuatable to an open state and to a closed state. The filtration media is exposed to an atmosphere impinging upon the tire when the valve is in the open state. The closed state is to prevent exposure of the filtration media to the contaminants when the valve is in the closed state.Type: ApplicationFiled: December 15, 2014Publication date: April 9, 2015Inventors: Larry P. Bennett, Lalit M. Patil
-
Publication number: 20150096443Abstract: An air filter assembly includes a felt of hollow commodity polymer fibers having nonporous walls.Type: ApplicationFiled: October 4, 2013Publication date: April 9, 2015Applicant: BHA Altair, LLCInventors: Todd Joseph Scheerer, Vishal Bansal
-
Patent number: 8999039Abstract: The invention relates to membranes, in particular oxygen separation membranes, which enable improved gas separation conditions with respect to cost, price, size, weight, and noise. The membrane, in particular oxygen separation membrane, according to the invention comprises a support layer (28) and a separation layer (30), wherein the separation layer (30) is permeable for oxygen and has a sorptive affinity for at least one other gas, in particular for nitrogen, wherein the membrane (20) is designed such that substantially only the separation layer (30) is heatable by a heating device.Type: GrantFiled: February 4, 2011Date of Patent: April 7, 2015Assignee: Koninklijke Philips N.V.Inventors: Rainer Hilbig, Joachim Opitz
-
Publication number: 20150090125Abstract: Embodiments for a tubular ceramic-carbonate dual-phase membrane and methods for manufacturing the tubular ceramic-carbonate dual-phase membrane are disclosed.Type: ApplicationFiled: September 5, 2014Publication date: April 2, 2015Inventors: Jerry Y.S. Lin, Jose Ortiz-Landeros, Xue-Liang Dong
-
Patent number: 8991027Abstract: The present invention is directed toward spiral wound modules along with methods for making and using the same. Several embodiments are described including methods for making spiral wound filtration modules using membrane sheet provided from a roll, wherein the membrane sheet is unrolled and assembled in a direction parallel to the permeate collection tube of the module.Type: GrantFiled: January 20, 2014Date of Patent: March 31, 2015Assignee: Dow Global Technologies LLCInventors: Steven D. Jons, Allyn R. Marsh, III
-
Patent number: 8992669Abstract: The hydrogen separation membrane module according to the present invention is used for separating hydrogen from a gas to be treated containing hydrogen, and is provided with a tubular hydrogen separation membrane being selectively permeable to hydrogen, a casing for the hydrogen separation membrane, an insertion member being arranged on the inside of the hydrogen separation membrane and having an outer surface that defines a flow path of the gas to be treated together with an inner surface of the hydrogen separation membrane, a gas supply port for supplying the gas to be treated to the inside of the hydrogen separation membrane, a gas discharge port for discharging a non-permeating gas that does not permeate the hydrogen separation membrane, from a downstream side of the flow path, and a hydrogen discharge port provided in the casing, for discharging hydrogen having permeated the hydrogen separation membrane.Type: GrantFiled: May 31, 2011Date of Patent: March 31, 2015Assignees: JX Nippon Oil & Energy Corporation, Japan Petroleum Energy CenterInventors: Masakazu Ikeda, Shunsuke Maekawa, Kaori Takano
-
Patent number: 8986432Abstract: Filter media, as well as related assemblies, systems and methods. Filter media may contain one or more layers formed of a meltblown material.Type: GrantFiled: July 1, 2009Date of Patent: March 24, 2015Assignee: Hollingsworth & Vose CompanyInventors: John A. Wertz, David T. Healey, William S. Freeman, John L. Manns, Mark Rowlands
-
Publication number: 20150059578Abstract: A water vapour transport membrane comprises a nanofibrous layer disposed on a macroporous support layer, the nanofibrous layer coated with a water permeable polymer. A method for making a water vapour transport membrane comprises forming a nanofibrous layer on a macroporous support layer and applying a water permeable polymer to the nanofibrous layer. The water permeable polymer can be applied for so that the nanofibrous layer is substantially or partially filled with the water permeable polymer, or so that the coating forms a substantially continuous layer on one surface of the nanofibrous layer. In some embodiments of the method, the nanofibrous layer is formed by electro-spinning at least one polymer on at least one side of the porous support layer. In some embodiments, the support layer is formable and the method further comprises forming a three-dimensional structure from the water vapour transport membrane, for example, by compression molding, pleating or corrugating.Type: ApplicationFiled: November 6, 2014Publication date: March 5, 2015Inventors: Ryan Nicholas HUIZING, Frank K. KO
-
Patent number: 8968447Abstract: A separation membrane including an alloy including a Group 5 element and Ir, wherein the alloy includes a body centered cubic crystal structure.Type: GrantFiled: November 26, 2012Date of Patent: March 3, 2015Assignee: Samsung Electronics Co., Ltd.Inventors: Hyeon Cheol Park, Kwang Hee Kim, Byung Ki Ryu, Jae Ho Lee
-
Patent number: 8968566Abstract: A novel separator assembly for a spiral flow reverse osmosis apparatus is provided. In one embodiment, the separator assembly comprises a central core element comprising at least two permeate exhaust conduits and not comprising a concentrate exhaust conduit. Each permeate exhaust conduit defines an exhaust channel and one or more openings allowing fluid communication between an exterior surface of the permeate exhaust conduit and the exhaust channel, said permeate exhaust conduits independently defining a cavity between said conduits. The cavity is configured to accommodate a first portion of a membrane stack assembly comprising at least one feed carrier layer, at least two permeate carrier layers, and at least two membrane layers. A first portion of the membrane stack assembly is disposed within the cavity, and a second portion of the membrane stack assembly is wound around the central core element and forms a multilayer membrane assembly disposed around the central core element.Type: GrantFiled: June 10, 2011Date of Patent: March 3, 2015Assignee: General Electric CompanyInventors: Philip Paul Beauchamp, Michael Kent Cueman, Daniel Jason Erno, Todd Alan Anderson, Dean David Marschke
-
Publication number: 20150053086Abstract: The present invention concerns a breathable product for protective mass transportation and cold chain applications, in particular a reflective sheet for covering temperature sensitive products the reflective sheet having at least a first layer made of a highly reflective moisture vapor permeable substrate having an outer side and an inner side, wherein said inner side comprises in addition at least a metal layer deposited by a PVD process to provide a thermal insulation through high reflection low convection while providing controlled moisture vapor permeability.Type: ApplicationFiled: August 15, 2012Publication date: February 26, 2015Applicant: E I DU PONT DE NEMOURS AND COMPANYInventors: Serge Rebouillat, Malik Zeniti, Guy Hopp, Sylvain Wallerich, Noel Stephen Brabbs, Sabine Gabriel, Ioannis V. Bletsos
-
Patent number: 8956443Abstract: A device for trapping flammable gases such as hydrogen comprises active means (3) inside a casing (1) which is closed except for openings which are plugged by filters (2) that normally allow only the gases that are to be trapped to pass through them. The trapping maintains a reduced pressure inside the casing, which continually draws in the gases produced outside. The trap can operate without any maintenance and for long periods of time, even in a completely enclosed environment.Type: GrantFiled: February 10, 2012Date of Patent: February 17, 2015Assignee: TN IntellectualInventors: Valentin Rohr, Elisa Leoni, Jocelyn Prigent, Michel LaTroche
-
Patent number: 8956444Abstract: The invention relates to a vent array comprising a plurality of venting regions comprising a porous PTFE matrix material and a nonporous material comprising a substrate material having a plurality of perforations, wherein the substrate material fills the pores of a porous PTFE matrix material to form nonporous regions, the nonporous regions interconnecting the plurality of venting regions.Type: GrantFiled: March 12, 2013Date of Patent: February 17, 2015Assignee: W. L. Gore & Associates, Inc.Inventor: Andrew J. Holliday
-
Publication number: 20150044267Abstract: A filter material for entrapping particles and actively affecting the trapped particles within the filter. The fabric has a blend of hydrophilic superabsorbent fibers and non-superabsorbent hydrophilic fibers that is sufficiently porous as to allow gaseous flow through the fabric. The fabric having a thickness and the fabric has as a coating of a mixture of a chemically or physically active compound and a liquid carrier forming an active composition on both the outer surface of the hydrophilic superabsorbent fibers, and the hydrophilic superabsorbent fibers have a central volume also retaining the active composition. The central volume of the hydrophilic superabsorbent fibers acting as a reservoir for replacement of the active compound into the coating when concentration of active compounds in the coating are reduced to a concentration less than concentrations of the active compound within the central volume; and the liquid carrier is an aqueous liquid.Type: ApplicationFiled: October 28, 2014Publication date: February 12, 2015Applicant: LIBERMAN DISTRIBUTING AND MANUFACTURING CO., D/B/A LIDCO PRODUCTS ("LIDCO")Inventors: David A. Gray, Robert M. Hume, Mark A. Litman
-
Publication number: 20150027307Abstract: The present invention relates to a method for preparing a hydrogen separation membrane capable of preventing the plating of Pd inside a porous support and a porous shielding layer when a separation membrane is prepared; a hydrogen separation membrane prepared therefrom; and a use thereof. In addition, the present invention relates to a device for preparing a hydrogen separation membrane; and a method for preparing a hydrogen separation membrane using the device, and in particular, relates to a device for preparing a hydrogen separation membrane capable of stably growing a Pd-containing separation membrane for hydrogen gas separation as a plating solution grows from the upper surface of a porous support to a uniform thickness by simply shielding the lower surface of the porous support when a hydrogen separation membrane is prepared using an electroless plating method.Type: ApplicationFiled: July 25, 2014Publication date: January 29, 2015Inventors: Shin Kun Ryi, Beom Seok Seo, Jong Soo Park, Dong Wook Lee, Sung Wook Lee
-
Publication number: 20150028259Abstract: In one embodiment, a membrane of proton-electron conducting ceramics that is useful for the conversion of a hydrocarbon and steam to hydrogen has a porous support coated with a film of a Perovskite-type oxide. By including the Zr and M in the oxide in place of Ce, the stability can be improved while maintaining sufficient hydrogen flux for efficient generation of hydrogen. In this manner, the conversion can be carried out by performing steam methane reforming (SMR) and/or water-gas shift reactions (WGS) at high temperature, where the conversion of CO to CO2 and H2 is driven by the removal of H2 to give high conversions.Type: ApplicationFiled: September 30, 2014Publication date: January 29, 2015Inventors: ERIC D. WACHSMAN, HEE SUNG YOON, TAKKEUN OH, JIANLIN LI
-
Publication number: 20150020686Abstract: The present invention relates to a hydrogen separation membrane which coats granular ceramic onto the surface of a porous metal support and which coats a hydrogen permeation metal thereon so as to inhibit diffusion between the support and a hydrogen separation layer, and to a method for manufacturing same. As a result, the metal support can be modularized with ease, the hydrogen permeation layer can be made thinner to increase the amount of hydrogen permeation, the use of a separation material can be minimized, and the hydrogen separation membrane can have higher competitiveness.Type: ApplicationFiled: January 2, 2013Publication date: January 22, 2015Applicant: Korea Institute of Energy ResearchInventors: Jong-Soo Park, Kyung-Ran Hwang, Shin-Kun Ryi, Tae-Hwan Kim, Chun-Boo Lee, Sung-Wook Lee
-
Patent number: 8936668Abstract: A water vapor transport membrane comprises a nanofibrous layer disposed on a macroporous support layer, the nanofibrous layer coated with a water permeable polymer. A method for making a water vapor transport membrane comprises forming a nanofibrous layer on a macroporous support layer and applying a water permeable polymer to the nanofibrous layer. The water permeable polymer can be applied for so that the nanofibrous layer is substantially or partially filled with the water permeable polymer, or so that the coating forms a substantially continuous layer on one surface of the nanofibrous layer. In some embodiments of the method, the nanofibrous layer is formed by electro-spinning at least one polymer on at least one side of the porous support layer. In some embodiments, the support layer is formable and the method further comprises forming a three-dimensional structure from the water vapor transport membrane, for example, by compression molding, pleating or corrugating.Type: GrantFiled: June 7, 2012Date of Patent: January 20, 2015Assignee: Dpoint Technologies Inc.Inventors: Ryan Nicholas Huizing, Frank K. Ko
-
Publication number: 20150008180Abstract: An object of the present invention is to provide a honeycomb shaped porous ceramic body in which a strength deteriorates less than before after a separation layer is formed, a manufacturing method for the porous ceramic body, and a honeycomb shaped ceramic separation membrane structure. A honeycomb shaped porous ceramic body 9 includes a honeycomb shaped substrate 30 and an intermediate layer. At least a part of the intermediate layer of the honeycomb shaped porous ceramic body 9 has a structure in which aggregate particles are bonded to one another by a component of an inorganic bonding material. The inorganic bonding material is titania.Type: ApplicationFiled: September 22, 2014Publication date: January 8, 2015Inventors: Tetsuya UCHIKAWA, Makoto MIYAHARA, Makiko ICHIKAWA, Kenji YAJIMA, Makoto TERANISHI, Hideyuki SUZUKI
-
Patent number: 8926733Abstract: A method for preparing a polymeric material includes: providing a polymeric matrix having at least one polymer and at least one porogen; and degrading the at least one porogen at a temperature T?1.1 Tg, where Tg is a glass transition temperature of the polymeric matrix. The degrading step includes exposing the polymeric matrix to thermal degradation, chemical degradation, electrical degradation and/or radiation degradation, wherein the polymeric material has a permeability at least 1.2 times a permeability of the polymeric matrix for a gas, and a selectivity of the polymeric material is at least 0.35 times a selectivity of the polymeric matrix for a gas pair. The method preferably provides gas separation membranes that exceed Robeson's upper bound relationship for at least one gas separation pair. Novel polymeric materials, gas separation membranes and fluid component separation methods are also described.Type: GrantFiled: May 13, 2011Date of Patent: January 6, 2015Assignee: Air Products and Chemicals, Inc.Inventors: Shiying Zheng, Lloyd M. Robeson, M. Keith Murphy, Jeffrey R. Quay
-
Patent number: 8926732Abstract: The present invention provides gels, solutions, films, membranes, compositions, and other materials containing polymerized and/or non-polymerized room-temperature ionic liquids (RTILs). These materials are useful in catalysis, gas separation and as antistatic agents. The RTILs are preferably imidazolium-based RTILs which are optionally substituted, such as with one or more hydroxyl groups. Optionally, the materials of the present invention are composite materials comprising both polymerized and non-polymerized RTILs. The RTIL polymer is formed from polymerized RTIL cations typically synthesized as monomers and polymerized in the presence of the non-polymerized RTIL cations to provide a solid composite material. The non-polymerized RTIL cations are not covalently bound to the cationic polymer but remain as free cations within the composite material able to associate with charged subunits of the polymer. These composite materials are useful in catalysis, gas separation, and antistatic applications.Type: GrantFiled: July 23, 2010Date of Patent: January 6, 2015Assignee: The Regents of the University of Colorado, a Body CorporateInventors: Jason E. Bara, Trevor K. Carlisle, Evan S. Hatakeyama, Douglas L. Gin, Richard D. Noble, Robert L. Kerr, Andrew L. LaFrate
-
Patent number: 8911540Abstract: A method of fabricating a gas separation membrane includes providing a coextruded multilayer film that includes a first polymer layer formed of a first polymer material and a second polymer layer formed of a second polymer material, the first polymer material having a first gas permeability. The coextruded multilayer film is axially oriented such that the second polymer layer has a second gas permeability that is greater than the first gas permeability.Type: GrantFiled: May 1, 2013Date of Patent: December 16, 2014Assignee: Case Western Reserve UniversityInventors: Eric Baer, Shannon Armstrong, Benny D. Freeman, Donald R. Paul, Grant Offord
-
Publication number: 20140360938Abstract: A zeolite membrane composite for use in separation of a highly-permeative component through permeation from a vapor mixture or a liquid mixture comprising multiple components, the zeolite membrane composite comprising an inorganic porous support and a zeolite membrane provided thereon, wherein the zeolite membrane contains zeolite of a CHA-type aluminosilicate, and in a X-ray diffraction pattern obtained through irradiation to the zeolite membrane surface with X-ray, a peak intensity at around 2?=17.9° has a value of less than 0.5 times a peak intensity at around 2?=20.8° and a peak intensity at around 2?=9.6° has a value of 2.0 times or more and less than 4.0 times a peak intensity at around 2?=20.8°.Type: ApplicationFiled: August 25, 2014Publication date: December 11, 2014Applicant: MITSUBISHI CHEMICAL CORPORATIONInventors: Mikio Hayashi, Miki Yamada, Takahiko Takewaki
-
Publication number: 20140360939Abstract: A porous support-zeolite membrane composite comprising an inorganic porous support and a zeolite membrane provided on, wherein the zeolite membrane contains a zeolite having a microporous structure of 8-membered oxygen ring or less, and a molar ratio of SiO2/Al2O3 in the zeolite membrane surface is larger by at least 20 than a molar ratio of SiO2/Al2O3 in the zeolite membrane itself, or a water adsorption of the porous support-zeolite membrane composite at a relative pressure of 0.8, as determined from a water vapor adsorption isotherm of the porous support-zeolite membrane composite, is at least 82% of a water adsorption of the porous support-zeolite membrane composite under the same condition as above after one-week immersion of the porous support-zeolite membrane composite in an aqueous 90 mass % acetic acid solution at room temperature.Type: ApplicationFiled: August 25, 2014Publication date: December 11, 2014Applicant: MITSUBISHI CHEMICAL CORPORATIONInventors: MIKI YAMADA, Takahiko Takewaki, Mikio Hayashi, Naoko Fujita, Hidekazu Miyagi
-
Publication number: 20140360367Abstract: This invention relates to organopolysiloxane compounds. In some embodiments, the organopolysiloxane compound includes a siloxane unit having at least one trialkylsilyl pendant group attached thereto through an organic group spacer. The present invention also relates to methods of making the organopolysiloxane, a hydrosilylation-curable silicone composition including the organopolysiloxane, a cured product of the silicone composition, a membrane including the cured product, a method of making the membrane, and a method of separating components in a feed mixture using the membrane.Type: ApplicationFiled: December 27, 2012Publication date: December 11, 2014Inventors: Dongchan Ahn, James S. Hrabal, Alexandra N. Lichtor
-
Patent number: 8906136Abstract: A water vapor transport membrane comprises a nanofibrous layer disposed on a macroporous support layer, the nanofibrous layer coated with a water permeable polymer. A method for making a water vapor transport membrane comprises forming a nanofibrous layer on a macroporous support layer and applying a water permeable polymer to the nanofibrous layer. The water permeable polymer can be applied for so that the nanofibrous layer is substantially or partially filled with the water permeable polymer, or so that the coating forms a substantially continuous layer on one surface of the nanofibrous layer. In some embodiments of the method, the nanofibrous layer is formed by electro-spinning at least one polymer on at least one side of the porous support layer. In some embodiments, the support layer is formable and the method further comprises forming a three-dimensional structure from the water vapor transport membrane, for example, by compression molding, pleating or corrugating.Type: GrantFiled: June 7, 2012Date of Patent: December 9, 2014Assignee: Dpoint Technologies Inc.Inventors: Ryan Nicholas Huizing, Frank K. Ko
-
Publication number: 20140352533Abstract: The invention provides methods for making silicoaluminophosphate-34 (SAPO-34) membranes comprising interlocking SAPO-34 crystals. In the methods of the invention, the SAPO-34 membranes are formed through in situ crystallization on a porous support using a synthesis mixture initially including a SAPO-34 forming gel and a plurality of SAPO-34 crystals dispersed in the gel. The invention also provides supported SAPO-34 membranes made by the methods of the invention. The invention also provides methods for separating a first gas component from a gas mixture, the methods comprising the step of providing a membrane of the invention.Type: ApplicationFiled: January 10, 2013Publication date: December 4, 2014Inventors: John L. Falconer, Eric W. Ping, Rongfei Zhou, Richard D. Noble, Hans Funke
-
Patent number: 8900344Abstract: Hydrogen selective coatings, coated articles and methods for their formation and for hydrogen separation or purification. The coatings are formed by atomic layer deposition of suitable metal oxides with desirable hydrogen activation energy or hydrogen flux, e.g., silicon dioxide, and can be borne on a nonporous, thin-film metal or cermet substrate, e.g., a palladium sheet or layer. The coated substrate may include a porous support for the sheet or layer. The coated article may be used as a purification membrane and the coating can protect the metal layer from contaminants in the gas or process stream from which hydrogen is being purified. In some embodiments, the coated article can provide such protection at elevated temperatures in excess of 300° C.; and in other embodiments, can provide protection at temperatures in excess of 600° C. and even in excess of 800° C.Type: GrantFiled: March 21, 2011Date of Patent: December 2, 2014Assignee: T3 Scientific LLCInventors: Chung Yi A. Tsai, Siu-Yue Tam
-
Patent number: 8900351Abstract: Provided is a filter medium including a porous polytetrafluoroethylene (PTFE) membrane and a gas-permeable supporting member that are integrated to ensure sufficient stiffness, having excellent gas permeability, and providing excellent bonding between respective layers included in the filter medium. The gas-permeable supporting member includes: a substrate having gas-permeability; and a fiber layer that is placed on the substrate so as to be in contact with the porous PTFE membrane. The gas-permeable supporting member has a structure in which fibers of the fiber layer enter into the substrate and are entangled with the substrate so that the fiber layer is bonded to the substrate. The fiber layer contains polyolefin-containing fibers that are bonded to the porous membrane.Type: GrantFiled: November 11, 2008Date of Patent: December 2, 2014Assignee: Nitto Denko CorporationInventors: Masaaki Mori, Masatoshi Suzuki