Plural Layers (e.g., Laminated Barrier, Etc.) Patents (Class 96/11)
  • Patent number: 8394183
    Abstract: An asymmetric membrane contains a porous layer and a dense layer adjacent thereto. The porous layer and the dense layer are formed of a polymeric material. The porous layer and/or dense layer contains a filler. The amount of the filler is 11 parts by mass or more per 100 parts by mass of the polymeric material contained in the asymmetric membrane.
    Type: Grant
    Filed: October 27, 2008
    Date of Patent: March 12, 2013
    Assignees: Shin-Etsu Polymer Co., Ltd., Denso Corporation, Shin-Etsu Chemical Co., Ltd.
    Inventors: Junya Ishida, Mitsuaki Negishi, Yuzo Morioka, Mika Kawakita, Katsunori Iwase, Manabu Maeda, Masahiko Minemura, Mamoru Hagiwara
  • Patent number: 8394181
    Abstract: A permselective material has a polymer having an organosiloxane skeleton and containing a dispersed solid additive. When oxygen and nitrogen are passed through a membrane having the permselective material, the relation between the permeability coefficients [cm3·cm·sec?1·cm?2·cmHg?1] of oxygen and nitrogen at a temperature of 23±2° C. under a pressure difference of 1.05 atm to 1.20 atm through the membrane is expressed by Formula (1): 0.94 ? P ? ( O 2 ) P ? ( N 2 ) < 1 ( 1 ) where P(O2) denotes the permeability coefficient of oxygen, while P(N2) denotes the permeability coefficient of nitrogen.
    Type: Grant
    Filed: December 26, 2007
    Date of Patent: March 12, 2013
    Assignees: Shin-Etsu Polymer Co., Ltd., DENSO CORPORATION, Shin-Etsu Chemical Co., Ltd.
    Inventors: Junya Ishida, Katsunori Iwase, Akira Yamamoto, Masahiko Minemura
  • Patent number: 8388744
    Abstract: The subject matter disclosed herein relates to gas separation membranes and, more specifically, to polyimide gas separation membranes. In an embodiment, a gas separation membrane includes a porous substrate, a substantially continuous polyimide membrane layer, and one or more layers of boehmite nanoparticles disposed between the porous substrate and the polyimide membrane layer to form a bond-coat layer. The bond-coat layer is configured to improve the adhesion of the polyimide membrane layer to the porous substrate, and the polyimide membrane layer has a thickness approximately 100 nm or less.
    Type: Grant
    Filed: August 30, 2011
    Date of Patent: March 5, 2013
    Assignee: General Electric Company
    Inventor: Kimberly Ann Polishchuk
  • Patent number: 8388743
    Abstract: One aspect of the present teachings includes a separation membrane arranged in a hollow case. A particular component concentration chamber and a particular component dilution chamber are arranged in series in the hollow case. The particular component concentration chamber is capable of increasing concentration of the particular component by allowing permeation of the particular gas through the separation membrane. The particular component dilution chamber is capable of increasing concentration of the particular component by not allowing permeation of the particular gas through the separation membrane. The particular component concentration chamber and the particular component dilution chamber are configured such that only a gas containing the particular component and permeated through the separation membrane or only a gas containing the particular component not permeated through the separation membrane in one of the chambers disposed on an upstream side (i.e.
    Type: Grant
    Filed: October 28, 2009
    Date of Patent: March 5, 2013
    Assignee: Aisan Kogyo Kabyshiki Kaisha
    Inventors: Masataka Suzuki, Takashi Suefuji, Akio Muraishi, Katsuhiko Makino, Toshiyuki Iwasaki, Takashi Mani
  • Patent number: 8377179
    Abstract: To provide a moisture control module which has a function to reduce or increase moisture in a gas permitted to flow in a hollow fiber and which is substantially free from air leakage and easy to produce; a process for producing such a moisture control module; and an apparatus for producing such a moisture control module. A moisture control module comprising a tubular hollow fiber 1, a braid fiber 3 plaited into a braid to cover the exterior of the hollow fiber 1, and a pipe 5 inserted in an end of the hollow fiber 1, wherein as the hollow fiber 1 and the braid fiber 3 present in a region with a prescribed length from said end have been heated at a prescribed temperature from outside, the braid fiber 3 is fused, and at the same time, the hollow fiber 1 is fixed by heat shrinkage to the pipe 5.
    Type: Grant
    Filed: August 13, 2010
    Date of Patent: February 19, 2013
    Assignee: AGC Engineering Co., Ltd.
    Inventor: Masato Kamada
  • Patent number: 8377170
    Abstract: A CO2-facilitated transport membrane of excellent carbon dioxide permeability and CO2/H2 selectivity, which can be applied to a CO2 permeable membrane reactor, is stably provided. The CO2-facilitated transport membrane is formed such that a gel layer 1 obtained by adding cesium carbonate to a polyvinyl alcohol-polyacrylic acid copolymer gel membrane is supported by a hydrophilic porous membrane 2. More preferably, a gel layer supported by a hydrophilic porous membrane 2 is coated with hydrophilic porous membranes 3 and 4.
    Type: Grant
    Filed: May 2, 2012
    Date of Patent: February 19, 2013
    Assignee: Renaissance Energy Research Corporation
    Inventors: Osamu Okada, Masaaki Teramoto, Reza Yegani, Hideto Matsuyama, Keiko Shimada, Kaori Morimoto
  • Patent number: 8372182
    Abstract: In various embodiments, a support system includes a multi-layer cover sheet with a number of layers. In certain embodiments, a source to move air inside and outside the multi-layer cover sheet can be provided. The source can include a source of positive pressure or negative pressure.
    Type: Grant
    Filed: February 16, 2012
    Date of Patent: February 12, 2013
    Assignee: Huntleigh Technology Limited
    Inventors: John H. Vrzalik, Alan L. Bartlett, Royce Johnson
  • Patent number: 8372783
    Abstract: Packaging using Gas Permeable Non-Woven Fabric based Film extends the shelf life and vase life of fresh cut flowers by changing the atmosphere in which these living products are stored and respires. The high oxygen and carbon dioxide permeability of the Gas Permeable Non-Woven Fabric based Film establishes an ideal atmosphere for the cut flowers, and therefore extends its shelf life and vase life. The establishment of lower oxygen and carbon dioxide atmospheres inside packages using Gas Permeable Non-Woven Fabric based film, also leads to reduction in the respiration rate of the cut flowers. The reduction in the respiration rate prevents loss of moisture, production of metabolic heat, and yellowing, browning, reduction in production levels of ethylene. Thus the created atmosphere is able to extend shelf life, maintain high quality and preserve nutrients of cut flowers items by naturally regulating respiration of said flower.
    Type: Grant
    Filed: August 9, 2010
    Date of Patent: February 12, 2013
    Inventors: Shubham Chandra, Bhavna Chandra
  • Patent number: 8366805
    Abstract: Composite structures are described that have a porous anodic oxide layer such as, for example, a porous anodic aluminum oxide layer. In one aspect, the present invention includes a composite gas separation module having a porous metal substrate; a porous anodic aluminum oxide layer, wherein the porous anodic aluminum oxide layer overlies the porous metal substrate; and a dense gas-selective membrane, wherein the dense gas-selective membrane overlies the porous anodic aluminum oxide layer. A composite filter is described having a porous non-aluminum metal substrate; and a porous anodic aluminum oxide layer, wherein the porous anodic aluminum oxide layer defines pores extending through the porous anodic aluminum oxide layer. Methods for fabricating composite gas separation modules and composite filters and methods for selectively separating hydrogen gas from a hydrogen gas-containing gaseous stream are also described.
    Type: Grant
    Filed: April 4, 2008
    Date of Patent: February 5, 2013
    Assignee: Worcester Polytechnic Institute
    Inventors: Yi Hua Ma, Ivan P. Mardilovich
  • Patent number: 8366804
    Abstract: The present invention discloses a new type of polyimide membranes including hollow fiber and flat sheet membranes with high permeances for air separations and a method of making these membranes. The new polyimide hollow fiber membranes have O2 permeance higher than 300 GPU and O2/N2 selectivity higher than 3 at 60° C. under 308 kPa for O2/N2 separation. The new polyimide hollow fiber membranes also have CO2 permeance higher than 1000 GPU and single-gas selectivity for CO2/CH4 higher than 20 at 50° C. under 791 kPa for CO2/CH4 separation.
    Type: Grant
    Filed: May 28, 2010
    Date of Patent: February 5, 2013
    Assignee: UOP LLC
    Inventors: Chunqing Liu, Raisa Minkov, Syed A. Faheem, Travis C. Bowen, Jeffrey J. Chiou
  • Patent number: 8367567
    Abstract: The Shelf Life Extending Container for fruits and vegetables extends the shelf life of various fresh fruits and vegetables and vase life of fresh cut flowers by changing the atmosphere in which these living products are stored and respires. The Shelf Life Extending Container does this by utilizing a Gas Permeable Non-Woven Fabric Based Film. The high oxygen and carbon dioxide permeability of the Gas Permeable Non-Woven Fabric Based Film establishes an ideal atmosphere for the multiple perishable items stored within the Shelf life Extending Container, and therefore extends their shelf life. The establishment of lower oxygen and carbon dioxide atmospheres within the Shelf Life Extending Container using the Gas Permeable Non-Woven Fabric Based Film, also leads to a reduction in the respiration rate of the perishable items stored.
    Type: Grant
    Filed: August 9, 2010
    Date of Patent: February 5, 2013
    Inventors: Shubham Chandra, Benjamin Scott Williams
  • Patent number: 8366811
    Abstract: There is provided herein a dryer polymer substance including a hetero-phase polymer composition including two or more polymers wherein at least one of the two or more polymers include sulfonic groups, wherein the substance is adapted to pervaporate a fluid. The fluid may include water, water vapor or both. There is also provided herein a process for the preparation of a dryer polymer substance adapted to pervaporate a fluid (such as water, water vapor or both) the process includes mixing two or more polymers, wherein at least one of the two or more polymers may include groups which are adapted to be sulfonated, to produce a hetero-phase polymer composition and processing the polymer blend into a desired form.
    Type: Grant
    Filed: March 3, 2009
    Date of Patent: February 5, 2013
    Assignee: Oridion Medical (1987) Ltd.
    Inventors: Amos Ophir, Eyal Cohen, David Dishon, Joshua Lewis Colman
  • Patent number: 8361196
    Abstract: A membrane selectively permeable to light gases comprises a membrane body formed by a first plate and a second plate. The second plate comprises a thin layer that is selectively gas-permeable. In the region of windows, this layer is exposed. There, support is provided by a porous bottom wall in the first plate or by narrow bores in the second plate. A heating device causes a radiation heating of the windows.
    Type: Grant
    Filed: April 9, 2010
    Date of Patent: January 29, 2013
    Assignee: Inficon GmbH
    Inventors: Vladimir Schwartz, Daniel Wetzig, Boris Chernobrod, Werner Grosse Bley
  • Patent number: 8361197
    Abstract: There is provided a zeolite separation membrane-provided article having gaps or pores larger than pores inherent to zeolite crystals and controlled within an appropriate range and being capable of achieving both high permeability and high separability for components with small difference in adsorption properties or a component having a smaller molecular diameter than the diameter of the pores, a method for producing the same, a method for separating mixed fluids, and a device for separating mixed fluids. The zeolite separation membrane-provided article is provided with a zeolite membrane having an N2 gas permeation speed at room temperature of 1.0×10?6 mol·m?2·s?1·Pa?1 or more and a permeation speed ratio of 1,3,5-trimethylbenzene/N2 at room temperature of 0.17 or more and being free from dyeing caused by the impregnation with Rhodamine B.
    Type: Grant
    Filed: September 13, 2011
    Date of Patent: January 29, 2013
    Assignee: NGK Insulators, Ltd.
    Inventors: Masaaki Kawai, Toshihiro Tomita, Nobuhiko Mori, Aya Satoh
  • Publication number: 20130022510
    Abstract: A method for fabricating a high-density zeolite membrane structure is described. The method includes the step of combining (i) a mineral zeolite material; (ii) at least one cement precursor; and (iii) an organic binder, with an aqueous component, to form an aqueous composite zeolite composition. The zeolite composition is then applied on a surface of a scaffold formed from a porous, metal oxide material. The zeolite composition is dried, and then heated under conditions to form a metal oxide-zeolite composite layer. This layer is exposed to a phosphate composition, under conditions sufficient to reduce the porosity to a level no greater than about 10%. A high-density zeolite cement composite membrane structure results. Related methods for separating hydrogen from a fluid stream, using the membrane structure, are also disclosed.
    Type: Application
    Filed: September 28, 2012
    Publication date: January 24, 2013
    Applicant: GENERAL ELECTRIC COMPANY
    Inventor: General Electric Company
  • Patent number: 8353977
    Abstract: A hydrogen separator exhibits excellent hydrogen separation performance and durability and prevents scattering of an iron-containing substance that causes defects of a selective hydrogen permeable metal membrane in a first passage by covering an iron-containing metal surface that is exposed in the first passage and forms at least part of the first passage and a member disposed in the first passage with an iron component scattering prevention film at least in an area positioned on an upstream side with respect to a downstream end of a permeable section of the selective hydrogen permeable metal membrane in a flow direction of a fluid that flows through the first passage.
    Type: Grant
    Filed: July 8, 2009
    Date of Patent: January 15, 2013
    Assignee: NGK Insulators, Ltd.
    Inventor: Kenichi Noda
  • Publication number: 20130008312
    Abstract: A method of making a crystalline silicoaluminophosphate-34 (SAPO-34) membrane. The method comprises the steps of providing a porous support having a pore size distribution such that a small proportion of its pores are larger than 10 microns, seeding the porous support with SAPO-34 seed crystals by capillary suspension infiltration to give a seeded support, and growing a SAPO-34 membrane layer on the surface of the seeded support.
    Type: Application
    Filed: March 3, 2011
    Publication date: January 10, 2013
    Inventors: Benedictus Clemens Bonekamp, Hendrik Jan Marsman, Johannis Pieter Overbeek, Paul Jason Williams
  • Publication number: 20130011249
    Abstract: A multi-layer filter, a gas turbine including a multi-layer filter, and a process of filtering are disclosed. The multi-layer filter includes a nano-fiber layer positioned to receive an airflow, a coalescing base medium layer, and a membrane layer. The coalescing base medium and the membrane layer are positioned for the airflow to travel through the nano-fiber layer and the coalescing base medium layer, then through the membrane layer. The gas turbine includes an inlet and the multi-layer filter in a filter portion.
    Type: Application
    Filed: July 8, 2011
    Publication date: January 10, 2013
    Applicant: GENERAL ELECTRIC COMPANY
    Inventors: Brad Aaron KIPPEL, Steve HINER
  • Publication number: 20130008313
    Abstract: The filter of the invention is a cartridge filter comprising a structure that can maintain a filter medium in an air stream to filter particulates to protect a gas turbine power system. The filter combines a mechanically adequate filter structure and an effective filter medium for to obtain a useful system.
    Type: Application
    Filed: September 14, 2012
    Publication date: January 10, 2013
    Applicant: Donaldson Company, Inc.
    Inventors: Michael W. Handley, Mark Brandenhoff, Kirit Patel, Timothy D. Sporre
  • Publication number: 20130005561
    Abstract: Composite membranes that are adapted for separation, purification, filtration, analysis, reaction and sensing. The composite membranes can include a porous support structure having elongate pore channels extending through the support structure. The composite membrane also includes an active layer comprising an active layer material, where the active layer material is completely disposed within the pore channels between the surfaces of the support structure. The active layer is intimately integrated within the support structure, thus enabling great robustness, reliability, resistance to mechanical stress and thermal cycling, and high selectivity. Methods for the fabrication of composite membranes are also provided.
    Type: Application
    Filed: February 29, 2012
    Publication date: January 3, 2013
    Applicant: Synkera Technologies, Inc.
    Inventors: Dmitri Routkevitch, Oleg G. Polyakov
  • Patent number: 8343257
    Abstract: The instant invention generally provides polymer pi-bond-philic filler composite comprising a molecularly self-assembling material and a pi-bond-philic filler, and a process of making and an article comprising the polymer pi-bond-philic filler composite. The instant invention also generally provides a process of separating a pi-bond-philic gas from a separable gas mixture comprising the pi-bond-philic gas.
    Type: Grant
    Filed: November 20, 2009
    Date of Patent: January 1, 2013
    Assignee: Dow Global Technologies LLC
    Inventors: Scott T. Matteucci, Shawn D. Feist, Peter N. Nickias, Leonardo C. Lopez, Michael S. Paquette, Jeffrey C. Munro
  • Publication number: 20120325087
    Abstract: Hydrogen selective coatings, coated articles and methods for their formation and for hydrogen separation or purification. The coatings are formed by atomic layer deposition of suitable metal oxides with desirable hydrogen activation energy or hydrogen flux, e.g., silicon dioxide, and can be borne on a nonporous, thin-film metal or cermet substrate, e.g., a palladium sheet or layer. The coated substrate may include a porous support for the sheet or layer. The coated article may be used as a purification membrane and the coating can protect the metal layer from contaminants in the gas or process stream from which hydrogen is being purified. In some embodiments, the coated article can provide such protection at elevated temperatures in excess of 300° C.; and in other embodiments, can provide protection at temperatures in excess of 600° C. and even in excess of 800° C.
    Type: Application
    Filed: March 21, 2011
    Publication date: December 27, 2012
    Applicant: T3 SCIENTIFIC LLC
    Inventors: Chung Yi A. Tsai, Siu-Yue Tam
  • Patent number: 8337588
    Abstract: Supported zeolite Y membranes exhibiting exceptionally high CO2 selectivities when used in CO2/N2 gas separations are produced by a seeding/secondary (hypothermal) growth approach in which a structure directing agent such as tetramethylammonium hydroxide is included in the aqueous crystal-growing composition used for membrane formation.
    Type: Grant
    Filed: April 12, 2010
    Date of Patent: December 25, 2012
    Assignee: The Ohio State University Research Foundation
    Inventors: Krenar Shqau, Jeremy C. White, Prabir K. Dutta, Hendrik Verweij
  • Publication number: 20120318145
    Abstract: The invention relates to membranes, in particular oxygen separation membranes, which enable improved gas separation conditions with respect to cost, price, size, weight, and noise. The membrane, in particular oxygen separation membrane, according to the invention comprises a support layer (28) and a separation layer (30), wherein the separation layer (30) is permeable for oxygen and has a sorptive affinity for at least one other gas, in particular for nitrogen, wherein the membrane (20) is designed such that substantially only the separation layer (30) is heatable by a heating device.
    Type: Application
    Filed: February 4, 2011
    Publication date: December 20, 2012
    Applicant: KONINKLIJKE PHILIPS ELECTRONICS N.V.
    Inventors: Rainer Hilbig, Joachim Opitz
  • Patent number: 8333826
    Abstract: A filter media including a scrim, a polytetrafluoroethylene (PTFE) media substrate upon the scrim, and a layer of expanded polytetrafluoroethylene (ePTFE) membrane adhered to the PTFE media substrate on the scrim. The filter media is pleatable and has air permeability of approximately 3-10 cubic feet/min at a 0.5 inch H2O pressure drop and an original filtration efficiency greater than 99.0% when tested in an unused, unpleated condition with a 0.3 micron challenge aerosol at a flow rate of 10.5 feet/min and when tested after a cleanable dust performance test according to ASTM D6830.
    Type: Grant
    Filed: February 10, 2010
    Date of Patent: December 18, 2012
    Assignee: BHA Group, Inc.
    Inventors: Alan Smithies, Karmin Lorraine Olson
  • Patent number: 8328906
    Abstract: The present disclosure relates to a high molecular weight, monoesterified polyimide polymer. Such high molecular weight, monoesterified polyimide polymers are useful in forming crosslinked polymer membranes for the separation of fluid mixtures. According to its broadest aspect, the method of making a crosslinked membrane comprises the following steps: (a) preparing a polyimide polymer comprising carboxylic acid functional groups from a reaction solution comprising monomers and at least one solvent; (b) treating the polyimide polymer with a diol at esterification conditions in the presence of dehydrating conditions to form a monoesterified polyimide polymer; and (c) subjecting the monoesterified fiber to transesterification conditions to form a crosslinked fiber membrane, wherein the dehydrating conditions at least partially remove water produced during step (b). The crosslinked membranes can be used to separate at least one component from a feed stream including more than one component.
    Type: Grant
    Filed: November 28, 2011
    Date of Patent: December 11, 2012
    Assignees: Chevron U.S.A. Inc., Georgia Tech Research Corporation
    Inventors: Stephen J. Miller, Imona C. Omole, William J. Kronos
  • Publication number: 20120304863
    Abstract: A membrane selectively permeable to light gases comprises a membrane body formed by a first plate and a second plate. The second plate comprises a thin layer that is selectively gas-permeable. In the region of windows, this layer is exposed. There, support is provided by a porous bottom wall in the first plate or by narrow bores in the second plate. A heating device causes a radiation heating of the windows.
    Type: Application
    Filed: August 10, 2012
    Publication date: December 6, 2012
    Inventors: Vladimir Schwartz, Daniel Wetzig, Boris Chernobrod, Werner Grosse Bley
  • Publication number: 20120310027
    Abstract: A reactor comprising a first zone comprising a dehydrogenation catalyst and a second zone separated from said first zone by a proton conducting membrane comprising a mixed metal oxide of formula (I) LnaWbO12?y wherein Ln is Y or an element numbered 57 to 71; the molar ratio of a:b is 4.8 to 6, preferably 5.3 to 6; and y is a number such that formula (I) is uncharged, e.g. y is 0?y?1.8.
    Type: Application
    Filed: February 10, 2011
    Publication date: December 6, 2012
    Applicant: PROTIA AS
    Inventors: Christian Kjølseth, Per Christian Vestre
  • Patent number: 8323379
    Abstract: A method of improving the blood compatibility of a blood-contacting surface includes immobilizing carbonic anhydrase on the surface, wherein the surface exhibits carbonic anhydrase activity of at least 20% of maximum theoretical activity of the surface based on monolayer surface coverage of carbonic anhydrase.
    Type: Grant
    Filed: October 24, 2011
    Date of Patent: December 4, 2012
    Assignee: University of Pittsburgh—of the Commonwealth System of Higher Education
    Inventors: William J. Federspiel, Alan J. Russell, Heung-Il Oh, Joel Kaar
  • Publication number: 20120297984
    Abstract: Disclosed herein is a gas separation membrane for a DEM production process, including: a porous support having a carbon dioxide permeability of more than 300 GPU (GPU=1×10?6 cm3/cm2·sec·cmHg) and an inner diameter of 100˜1000 ?m; and a composite membrane provided on an inner or outer surface of the porous support and coated with a separating material having a permeation selectivity of carbon dioxide/hydrogen of 4 or more. The gas separation membrane is advantageous in that it can improve efficiency of the separation process by selectively separating and removing carbon dioxide from a gas mixture of carbon dioxide and hydrogen produced during a process of producing DME which is a next-generation clean fuel.
    Type: Application
    Filed: May 21, 2012
    Publication date: November 29, 2012
    Applicant: Korea Gas Corporation
    Inventors: Jong Tae Chung, Young Soon Baek, Won Jun Cho, Young Sam Oh, Seong Yong Ha, Hyung Chul Koh, Chung Seop Lee
  • Publication number: 20120297977
    Abstract: A composite membrane for separating a gas from a mixed gas stream includes a fibrous non-woven substrate including consolidated synthetic thermoplastic fibers, and coextensively disposed on a surface of the fibrous non-woven substrate a continuous polysulfide rubber film adhered thereto. A method of separating a gas component from a mixed gas stream includes 1) contacting a surface of the above-described composite membrane with the mixed gas stream under conditions such that a product gas enriched in the gas component diffuses through the composite membrane; and 2) collecting the product gas.
    Type: Application
    Filed: May 22, 2012
    Publication date: November 29, 2012
    Inventor: Aaron Oken
  • Patent number: 8317900
    Abstract: The invention relates to a method for producing membrane, in particular gas separation membrane, wherein the membrane comprises a selective separating layer. The following steps are carried out: a) a polymer solution is produced from at least one polymer and at least one polyglycol ether, b) the polymer solution is cast into a film, c) in a further step, the selective separating layer is produced from the film, preferably by drying. The invention, among other things, further relates to a membrane, in particular gas separation membrane, comprising a selective separating layer.
    Type: Grant
    Filed: December 22, 2010
    Date of Patent: November 27, 2012
    Assignee: Helmholtz-Zentrum Geesthacht Zentrum fur Material-und Kustenforschung GmbH
    Inventors: Klaus-Viktor Peinemann, Grete Johannsen, Wilfredo Yave Rios, Anja Car
  • Patent number: 8313557
    Abstract: The present invention is generally directed to a system for recovering CO2 from seawater or aqueous bicarbonate solutions using a gas permeable membrane with multiple layers. At elevated pressures, gaseous CO2 and bound CO2 in the ionic form of bicarbonate and carbonate diffuse from the seawater or bicarbonate solution through the multiple layers of the membrane. Also disclosed is the related method of recovering CO2 from seawater or aqueous bicarbonate solutions.
    Type: Grant
    Filed: June 25, 2009
    Date of Patent: November 20, 2012
    Assignee: The United States of America, as represented by the Secretary of the Navy
    Inventors: Heather D. Willauer, Dennis R Hardy, M. Kathleen Lewis, Ejiogu C. Ndubizu, Frederick Williams
  • Patent number: 8309484
    Abstract: A photocatalyst system for volatile organic compounds with two parts that include a photocatalyst layer on a substrate and a porous overlayer. The photocatalyst layer is reactive with volatile organic compounds when UV light is projected on it. The overlayer is situated on the photocatalyst layer. The overlayer is UV transparent and has an interconnected pore network that allows contaminated air to pass through the overlayer. The size and the shape of the interconnected pores acts to selectively exclude certain contaminants that can deactivate the photocatalyst.
    Type: Grant
    Filed: May 31, 2007
    Date of Patent: November 13, 2012
    Assignee: Carrier Corporation
    Inventors: Treese Hugener-Campbell, Thomas Henry Vanderspurt, David F. Ollis, Stephen O. Hay, Timothy N. Obee, Wayde R. Schmidt, Michael A. Kryzman
  • Patent number: 8303691
    Abstract: A composite membrane comprising a discriminating layer and a porous support layer for the discriminating layer, CHARACTERISED IN THAT the discriminating layer comprises at least 60 wt % of oxyethylene groups and the porous support layer has a CO2 gas flux of 5 to 150×10?5 m3 (STP)/m2·s·kPa at a feed pressure of 2.07 kPa. The membranes are particularly useful for purifying waste gas streams e.g. by removing greenhouse gases.
    Type: Grant
    Filed: April 6, 2009
    Date of Patent: November 6, 2012
    Assignee: Fujifilm Manufacturing Europe B.V.
    Inventor: Yujiro Itami
  • Patent number: 8303692
    Abstract: A polymer membrane, based on a facilitated transport mechanism, for separating olefins from paraffins, and a method for fabricating is provided. In the polymer membrane for facilitated transport, silver nanoparticles are partially cationized and play a role as a carrier for transporting olefins across the membrane, with p-benzoquinone serving as an electron acceptor.
    Type: Grant
    Filed: December 13, 2006
    Date of Patent: November 6, 2012
    Assignee: Industry-University Cooperation Foundation Hanyang University
    Inventors: Yong-Soo Kang, Kook-Heon Char, Sang-Wook Kang
  • Patent number: 8293143
    Abstract: A method to prepare a thin ceramic or metallic solid-state composition comprising three phases: a material (A), a material (B), and pores, wherein the porous matrix of material (A) has a porosity gradient in the range of about 0% to about 80%, and wherein the pores are partially or completely filled with material (B). Various compositions and methods of use for the prepared composition are also disclosed.
    Type: Grant
    Filed: February 11, 2008
    Date of Patent: October 23, 2012
    Assignee: L'Air Liquide Societe Anonyme pour l'Etude et l'Exploitation des Procedes Georges Claude
    Inventors: Thierry Chartier, Francois Guillotin
  • Patent number: 8293170
    Abstract: The present scent distributor is a cartridge for attaching to a permeable substrate such as an air filter or humidifier pad. The cartridge housing is configured to hold the scenting media, said housing including a body and a cover; a plurality of openings in said housing to allow air to flow through at least a portion of said housing for interaction with the scenting media; a restrictor that slidingly engages with said housing to selectively restrict the flow of air through said housing; and an attachment device on said housing to attach said housing to a porous substrate.
    Type: Grant
    Filed: November 3, 2011
    Date of Patent: October 23, 2012
    Assignee: RPS Products, Inc.
    Inventor: Daniel E. Schuld
  • Publication number: 20120255437
    Abstract: An air dryer cartridge assembly, used in a compressed air system, includes a rigid porous layer, a fibrous material layer, a diffusing layer and a desiccant for filtering and drying compressed air passing in a first direction during a charging cycle. The compressed air passes through diffusing layer, the fibrous material layer and the rigid porous layer in a second direction during a purging cycle. The desiccant, which is downstream of the rigid porous layer, the fibrous material layer and the diffusing layer during the charging cycle, reduces moisture in the compressed air during the charging cycle. The use of diffusing layer downstream of the fibrous material layer during a charging cycle disperses the compressed air so that moisture removal is improved in the desiccant.
    Type: Application
    Filed: April 6, 2011
    Publication date: October 11, 2012
    Applicant: BENDIX COMMERCIAL VEHICLE SYSTEMS LLC
    Inventors: William P. Fornof, Leonard A. Quinn
  • Publication number: 20120255899
    Abstract: According to example embodiments, a separation membrane includes a graphene on at least one surface of a polymer support. The graphene may include a plurality of grains defined by grain boundaries.
    Type: Application
    Filed: April 10, 2012
    Publication date: October 11, 2012
    Applicants: Industry-University Cooperation Foundation Hanyang University, SAMSUNG ELECTRONICS CO., LTD.
    Inventors: Jae-young Choi, Ho-bum Park
  • Patent number: 8282708
    Abstract: Methods for the purification of steam, systems for purifying steam, methods for measuring and/or controlling steam flow rates, and uses for purified steam are provide. Also provided are substantially gas-impermeable membranes, such as perfluorinated ionomers (e.g., perfluoroethylene-sulfonic-acid/tetrafluoroethylene membranes), having a high ratio of water vapor permeation relative to gas permeation through the membrane. Also provided are methods of operation of such membranes at relatively high operating temperatures for the purification of steam and for operation of such membranes at relatively low temperature and sub-atmospheric pressures for the purification of steam. In a preferred embodiment, the system 400 for purifying steam comprises heater 404 for creating a source of a steam feed, and a purification device 416 for housing a substantially gas-impermeable membrane 424. In the operation of system 400, water, such as deionized water, is added to vessel 402 to provide a source of the steam feed.
    Type: Grant
    Filed: September 12, 2006
    Date of Patent: October 9, 2012
    Assignee: RASIRC
    Inventors: Jeffrey J. Spiegelman, Richard D. Blethen
  • Patent number: 8282713
    Abstract: A filter media including a scrim, a polytetrafluoroethylene (PTFE) media substrate upon the scrim, and a layer of expanded polytetrafluoroethylene (ePTFE) membrane adhered to the PTFE media substrate on the scrim. The filter media is pleatable and has air permeability of approximately 3-10 cubic feet/min at a 0.5 inch H2O pressure drop and an original filtration efficiency greater than 99.0% when tested in an unused, unpleated condition with a 0.3 micron challenge aerosol at a flow rate of 10.5 feet/min and when tested after a cleanable dust performance test according to ASTM D6830.
    Type: Grant
    Filed: December 16, 2009
    Date of Patent: October 9, 2012
    Assignee: BHA Group, Inc.
    Inventors: Alan Smithies, Karmin Lorraine Olson
  • Publication number: 20120247329
    Abstract: The invention relates to a method of separating oxygen from an oxygen containing gas, said method comprising the steps of: compressing and heating the oxygen containing gas in a plasma pump (16), guiding the heated and compressed oxygen containing gas to the primary side of a dense inorganic membrane (58), thereby heating the inorganic membrane by the oxygen containing gas to a temperature at which it is permeable for oxygen, and creating a pressure difference between the primary side and a secondary side of the inorganic membrane (58), wherein an oxygen flow through the inorganic membrane (58) is created, thereby separating the oxygen from the oxygen containing gas.
    Type: Application
    Filed: December 14, 2010
    Publication date: October 4, 2012
    Applicant: KONINKLIJKE PHILIPS ELECTRONICS N.V.
    Inventor: Rainer Hilbig
  • Publication number: 20120247328
    Abstract: MOF nanocrystals having a narrow size distribution, as well as methods of making and using same are disclosed.
    Type: Application
    Filed: February 17, 2012
    Publication date: October 4, 2012
    Applicant: GEORGIA TECH RESEARCH CORPORATION
    Inventors: Andrew BROWN, Sankar NAIR, David SHOLL, Cantwell CARSON
  • Publication number: 20120241371
    Abstract: Membranes for fluid separation are disclosed. These membranes have a matrix layer sandwiched between an active layer and a porous support layer. The matrix layer includes 1-D nanoparticles that are vertically aligned in a porous polymer matrix, and which substantially extend through the matrix layer. The active layer provides species-specific transport, while the support layer provides mechanical support. A matrix layer of this type has favorable surface morphology for forming the active layer. Furthermore, the pores that form in the matrix layer tend to be smaller and more evenly distributed as a result of the presence of aligned 1-D nanoparticles. Improved performance of separation membranes of this type is attributed to these effects.
    Type: Application
    Filed: March 23, 2012
    Publication date: September 27, 2012
    Inventors: Ravindra Revanur, Valentin Lulevich, Il Juhn Roh, Jennifer E. Klare, Sangil Kim, Aleksandr Noy, Olgica Bakajin
  • Publication number: 20120240771
    Abstract: A plasma spray method for the manufacture of an ion conductive membrane is provided which ion conductive membrane has an ion conductivity, in which method the membrane is deposited as a layer (11) onto a substrate (10) in a process chamber, wherein a starting material (P) is sprayed onto a surface of the substrate (10) in the form of a process beam (2) by means of a process gas (G), wherein the starting material is injected into a plasma at a low process pressure, which is at most 10,000 Pa, and is partially or completely molten there. Oxygen (O2; 22) is supplied to the process chamber (12) during the spraying at a flow rate which amounts to at least 1%, preferably at least 2%, of the overall flow rate of the process gas.
    Type: Application
    Filed: March 15, 2012
    Publication date: September 27, 2012
    Applicant: Sulzer Markets and Technology AG
    Inventors: Malko Gindrat, Rajiv J. Damani
  • Patent number: 8268056
    Abstract: Disclosed is a method for manufacturing a separator. The method includes (S1) preparing a porous planar substrate having a plurality of pores, (S2) preparing a slurry containing inorganic particles dispersed therein and a polymer solution including a first binder polymer and a second binder polymer in a solvent, and sequentially coating the slurry on the porous substrate through a first discharge hole and a non-solvent incapable of dissolving the second binder polymer on the slurry through a second discharge hole adjacent to the first discharge hole, and (S3) simultaneously removing the solvent and the non-solvent by drying. According to the method, a separator with good bindability to electrodes can be manufactured in an easy manner. In addition, problems associated with the separation of inorganic particles in the course of manufacturing an electrochemical device can be avoided.
    Type: Grant
    Filed: December 20, 2011
    Date of Patent: September 18, 2012
    Assignee: LG Chem, Ltd.
    Inventors: Joo-Sung Lee, Jang-Hyuk Hong, Jong-Hun Kim, Bo-Kyung Ryu
  • Patent number: 8268042
    Abstract: The instant invention generally provides polymer inorganic clay composite comprising a molecularly self-assembling material and an inorganic clay, and a process of making and an article comprising the polymer inorganic clay composite.
    Type: Grant
    Filed: November 20, 2009
    Date of Patent: September 18, 2012
    Assignee: Dow Global Technologies LLC
    Inventors: Leonardo C. Lopez, Scott T. Matteucci
  • Patent number: 8262778
    Abstract: The invention relates to polymeric ultrafiltration or microfiltration membranes of, for instance, poly(ethylene chlorotrifluoroethylene) (HALAR®), PVDF or PP, incorporating PVME or vinyl methyl ether monomers. The PVME may be present as a coating on the membrane or dispersed throughout the membrane or both. The membranes are preferably hydrophilic with a highly asymmetric structure with a reduced pore size and/or absence of macrovoids as a result of the addition of PVME. The PVME maybe cross-linked. The invention also relates to methods of hydrophilising membranes and/or preparing hydrophilic membranes via thermal or diffusion induced phase separation processed.
    Type: Grant
    Filed: August 10, 2011
    Date of Patent: September 11, 2012
    Assignee: Siemens Industry, Inc.
    Inventors: Daniel Mullette, Joachim Muller, Neeta Patel
  • Patent number: 8262779
    Abstract: The present invention discloses microporous aluminophosphate (AlPO4) molecular sieve membranes and methods for making and using the same. The microporous AlPO4 molecular sieve membranes, particularly small pore microporous AlPO-14 and AlPO-18 molecular sieve membranes, are prepared by three different methods, including in-situ crystallization of a layer of AlPO4 molecular sieve crystals on a porous membrane support, coating a layer of polymer-bound AlPO4 molecular sieve crystals on a porous membrane support, and a seeding method by in-situ crystallization of a continuous second layer of AlPO4 molecular sieve crystals on a seed layer of AlPO4 molecular sieve crystals supported on a porous membrane support.
    Type: Grant
    Filed: August 16, 2010
    Date of Patent: September 11, 2012
    Assignee: UOP LLC
    Inventors: Chunqing Liu, Stephen T. Wilson, David A. Lesch