Gas And Liquid Contact Apparatus For Gas Separation Including Means To Regenerate, Purify, Or Separate Contact Liquid Patents (Class 96/234)
- With heavier component mechanical mover, trap, chamber, or recess in gravitational separator (Class 96/237)
- With lighter component removal means in gravitational separator (Class 96/238)
- With baffle, plate, or weir within gravitational separator to aid contact liquid regeneration, purification, or separation (Class 96/239)
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Patent number: 8409512Abstract: Methods and apparatuses are described for contacting an oxidizing solution such as an aqueous hydrogen peroxide composition of hydrogen peroxide and at least one additive that catalyzes the decomposition of the hydrogen peroxide into hydroxyl radicals with an atmospheric effluent containing odorous and/or noxious components. These components are absorbed by the aqueous hydrogen peroxide composition to produce an atmospheric effluent having reduced amounts of the odorous and/or noxious components. Various methods are described for adding the hydrogen peroxide and the decomposition additive.Type: GrantFiled: September 24, 2010Date of Patent: April 2, 2013Assignee: Steen Research, LLCInventors: Stephen R. Temple, Michael J. Stoltz
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Patent number: 8408025Abstract: A raw material recovery method for recovering a raw material of an organic metallic compound, which has the property of being stable toward a specific refrigerant without being decomposed thereby, from exhaust gas discharged from a treatment container in which a metallic thin film is formed on the surface of an object to be treated by using source gas obtained by vaporizing the raw material is characterized by being provided with a solidification step for solidifying the unreacted source gas by cooling the exhaust gas by bringing the exhaust gas into contact with the refrigerant and reprecipitating the raw material, and a recovery step for separating and recovering the raw material reprecipitated in the solidification step from the refrigerant. To provide a method for controlling an exhaust gas flow rate so that flow of gas in a processing chamber becomes uniform.Type: GrantFiled: August 4, 2009Date of Patent: April 2, 2013Assignee: Tokyo Electron LimitedInventors: Atsushi Gomi, Yasushi Mizusawa, Tatsuo Hatano, Masamichi Hara, Kaoru Yamamoto, Chiaki Yasumuro
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Publication number: 20130074693Abstract: A method for treating a process gas with a liquid comprises contacting a process gas with a hygroscopic working fluid in order to remove a constituent from the process gas. A system for treating a process gas with a liquid comprises a hygroscopic working fluid comprising a component adapted to absorb or react with a constituent of a process gas, and a liquid-gas contactor for contacting the working fluid and the process gas, wherein the constituent is removed from the process gas within the liquid-gas contactor.Type: ApplicationFiled: September 23, 2011Publication date: March 28, 2013Applicant: ENERGY & ENVIRONMENTAL RESEARCH CENTER FOUNDATIONInventors: Christopher L. Martin, Ye Zhuang
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Patent number: 8398743Abstract: A method for processing flue-gas, in an exemplary embodiment, includes providing an absorber unit having a membrane contactor, channeling a combustion flue gas along a first surface of the membrane contactor, and channeling an ammonia-based liquid reagent along a second opposing surface of the membrane contactor. The method also includes partially separating the ammonia-based liquid from the flue gas such that the ammonia-based liquid and the flue gas contact at gas-liquid interface areas, defined by a plurality of pores of the membrane contactor, to separate CO2 from the flue gas by a chemical absorption of CO2 within the ammonia-based liquid to produce a CO2-rich ammonia-based liquid.Type: GrantFiled: May 8, 2007Date of Patent: March 19, 2013Assignee: General Electric CompanyInventors: Jennifer Lynn Molaison, Alan Smithies
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Patent number: 8398757Abstract: A CO2 recovering apparatus includes a CO2 absorber that brings flue gas containing CO2 and O2 into contact with CO2 absorbing liquid to reduce CO2 in the flue gas; and a regenerator that reduces CO2 in CO2 absorbing liquid (rich solvent) that absorbed CO2 in the CO2 absorber to regenerate the CO2 absorbing liquid, so that the regenerated CO2 absorbing liquid (lean solvent) having CO2 reduced in the regenerator is reused in the CO2 absorber. A lower liquid reservoir is located at the bottom of the CO2 absorber, and an air-bubble gathering member is arranged therein to gather air bubbles included in the absorbing liquid.Type: GrantFiled: October 29, 2009Date of Patent: March 19, 2013Assignees: Mitsubishi Heavy Industries, Ltd., The Kansai Electric Power Co., Inc.Inventors: Masaki Iijima, Masahiko Tatsumi, Yasuyuki Yagi, Kouki Ogura
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Patent number: 8398917Abstract: A method for reducing biological contamination of indoor air, which method includes providing a concentrated salt solution, which is either (i) a brine capable of responding to aeration thereof by a rapid increase of its Redox potential, wherein the rate of said increase is greater than the rate of increase observed for a 45% (w/w) calcium chloride solution subjected to identical aeration conditions; or (ii) a brine which is passed through an electrolytic cell in order to raise its Redox potential; circulating said concentrated salt solution through a treatment zone; causing a stream of biologically contaminated air to flow through said treatment zone, such that said contaminated air is contacted with said salt solution in said treatment zone; and withdrawing purified air from said treatment zone.Type: GrantFiled: February 29, 2008Date of Patent: March 19, 2013Assignee: Megair Ltd.Inventors: Ron Itzhak, David Itzhak
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Patent number: 8398748Abstract: Contemplated configurations and methods include a solvent regenerator (58) that has an upper (93) and a lower stripping section (94). Cooled rich solve is used as reflux while heated rich solvent (11) is used as a source of stripping agent in the upper section (91). A reboiler (62) in the lower section provides further stripping agent, hi especially preferred configurations, a portion of lean solved from the regenerator (58) is further stripped in a separate or integrated regenerator (62) to form an ultra-lean solvent. Both lean and ultra-lean solvents are preferably used in a two-stage absorber (52) to thereby from the rich solvent and an offgas that is very low in acid gas.Type: GrantFiled: April 18, 2006Date of Patent: March 19, 2013Assignee: Fluor Technologies CorporationInventor: John Mak
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Publication number: 20130064745Abstract: Combining flue gas treatment, and in particular CO2 sequestration, with hardening of reverse osmosis (RO) permeate. Flue gas is compressed and injected into pressurized water, being either cooling water or RO permeate. The water with dissolved CO2 is either dispensed into the sea for biological fixation of the CO2 or, in the case of RO permeate, mixed with limestone to harden the product water.Type: ApplicationFiled: June 2, 2011Publication date: March 14, 2013Applicant: I.D.E. TECHNOLOGIES LTD.Inventor: Boris Liberman
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Publication number: 20130055729Abstract: Acid gas is removed from a high pressure feed gas that contains significant quantities of CO2 and H2S. In especially preferred configurations and methods, feed gas is contacted in an absorber with a lean and an ultra-lean solvent that are formed by flashing rich solvent and stripping a portion of the lean solvent, respectively. Most preferably, the flash vapors and the stripping overhead vapors are recycled to the feed gas/absorber, and the treated feed gas has a CO2 concentration of less than 2 mol % and a H2S concentration of less than 10 ppmv, and more typically less than 4 ppmv.Type: ApplicationFiled: February 17, 2010Publication date: March 7, 2013Inventor: John Mak
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Patent number: 8388747Abstract: Produced natural gas containing carbon dioxide is dehydrated and chilled to liquefy the carbon dioxide and then fractionated to produce a waste stream of liquid carbon dioxide and hydrogen sulfide. Natural gas liquids may be first separated and removed before fractionation. After fractionation, the waste stream is pressurized and transmitted to a remote injection well for injection either for disposal of the waste stream and preferably to urge hydrocarbons toward the producing well. A hydrocarbon stream proceeds from fractionation to a methanol absorber system which removes carbon dioxide gas. The hydrocarbon stream is thereafter separated into at least hydrocarbon gas, nitrogen and helium. Some of the nitrogen is reintroduced into a fractionation tower to enhance the recovery of hydrocarbons. A methanol recovery system is provided to recover and reuse the methanol. The hydrocarbons are sold as natural gas and the helium is recovered and sold. Excess nitrogen is vented.Type: GrantFiled: August 22, 2008Date of Patent: March 5, 2013Inventor: Donald Leo Stinson
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Patent number: 8377175Abstract: Presented is a method and apparatus for treating an exhaust gas. A series of filters and conditioning units are used to separate and extract various substances from the exhaust gas, typically originating from an industrial process. In an exemplary embodiment, a cyclone filter, a ceramic filter, a baghouse filter, and a pair of gas conditioners are used to initially separate and extract iron-rich dust from an exhaust gas and then extract zinc from the gas.Type: GrantFiled: February 26, 2010Date of Patent: February 19, 2013Assignee: ArcelorMittal Investigacion y Desarrollo, S.L.Inventor: Naiyang Ma
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Patent number: 8377185Abstract: This invention is a dust removal system for dust gas which comprises at least an atomizer. The atomizer comprises an atomizing chamber and an atomizing mechanism; the atomizing chamber includes an inlet for the dust gas and an outlet for the gas after mixture; the atomizing mechanism comprises a water chamber, the first atomizing ball, the second atomizing ball, an umbrella-shaped atomizer, and a regulating mechanism; the water chamber includes the first and second water inlet and the first and second water outlet; the regulating mechanism adjusts the fit clearance between the first atomizing ball and the first water outlet, the fit clearance between the second atomizing ball and the second water outlet, and the flare angle of the umbrella surface of the umbrella-shaped atomizer. The beneficial effect is: the two-stage atomization—coordinating the atomizing balls and the water outlets, and using an umbrella-shaped atomizer—guarantees the atomizing effect.Type: GrantFiled: October 29, 2010Date of Patent: February 19, 2013Assignee: Shenzhen Sunxing Light Alloys Materials Co., Ltd.Inventors: Xuemin Chen, Qingdong Ye, Sihai Zhou
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Patent number: 8377184Abstract: A CO2 recovery apparatus according to a first embodiment of the present invention includes: a CO2 absorber that brings flue gas containing CO2 into contact with CO2 absorbing liquid to reduce CO2 in the flue gas; a regenerator that reduces CO2 in CO2 absorbing liquid (rich solvent) that has absorbed the CO2 in the CO2 absorber to regenerate the CO2 absorbing liquid, so that the regenerated absorbing liquid (lean solvent), having CO2 reduced in the regenerator, is reused in the CO2 absorber; a first compressor to a fourth compressor that compress the CO2 gas released from the regenerator; and an O2 reducing apparatus arranged between the second compressor and a second cooler to reduce O2 in the CO2 gas.Type: GrantFiled: October 27, 2009Date of Patent: February 19, 2013Assignee: Mitsubishi Heavy Industries, Ltd.Inventors: Keiji Fujikawa, Takuya Hirata, Tatsuya Tsujiuchi, Tsuyoshi Oishi
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Publication number: 20130032029Abstract: Acid gas is removed from a feed gas in an absorber that produces a treated feed gas and a rich solvent. The treated feed gas is passed through an H2S scavenger bed, and the H2S scavenger bed is regenerated using H2S depleted acid gas flashed from the rich solvent. Most preferably, the off gas from the regenerating bed is injected into a formation.Type: ApplicationFiled: September 29, 2010Publication date: February 7, 2013Inventor: John Mak
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Patent number: 8353980Abstract: An apparatus and process for removing acidic gases from flue gases produced by, for example, utility and industrial facilities. The acidic gases are removed as the flue gas flows upward through a contact zone within a passage, where the flue gas is contacted with an ammonium sulfate-containing scrubbing solution to absorb the acidic gases from the flue gas. The scrubbing solution and absorbed acidic gases therein are then accumulated, and ammonia and an oxygen-containing gas are injected into the accumulated scrubbing solution to react the absorbed acidic gases and produce ammonium sulfate. An acid solution is flowed across the passage above the contact zone of the passage, and the scrubbed flue gas is flowed upward through the acid solution to remove unreacted ammonia from the scrubbed flue gas. The acid solution is then removed from the passage after the acid solution has been contacted by the scrubbed flue gas.Type: GrantFiled: December 3, 2009Date of Patent: January 15, 2013Assignee: Marsulex Environmental Technologies CorporationInventor: David William Murphy
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Publication number: 20130008310Abstract: The present disclosure relates to a method for stripping acid gases, exemplified by carbon dioxide, from absorption media and/Alcohol selected from those having a boiling point lower than the boiling point of the absorption medium and/or adsorption medium.Type: ApplicationFiled: December 8, 2010Publication date: January 10, 2013Applicant: UNIVERSITY OF REGINAInventors: Adisorn Aroonwilas, Amornvadee Veawab
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Publication number: 20120325086Abstract: A nitrogen-flush scrubber system for a controlled atmosphere room in which the amount of nitrogen required to flush the regenerated scrubber beds is significantly reduced. The present invention provides a dual-bed scrubber system in which low oxygen air salvaged from the active scrubber bed is used to flush high oxygen air from the regenerated scrubber bed prior to nitrogen flush. The scrubber system may include two scrubber beds that are used alternately to scrub air from the CA room. One scrubber bed is used as an active scrubber bed to remove carbon dioxide from the air. The inactive scrubber bed may be regenerated while it is inactive. When the active scrubber bed becomes sufficiently saturated, the control system may switch the active scrubber bed, using the regenerated bed as the active scrubber bed and allowing the saturated bed to be regenerated. Before switching, the regenerated bed is purged to reduce the oxygen level, which increased during regeneration.Type: ApplicationFiled: June 24, 2011Publication date: December 27, 2012Inventor: James C. Schaefer
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Publication number: 20120318142Abstract: A method and system for increasing the efficiency and environmental compatibility of combustion systems, preferably for heat recovery from a wet flue gas and/or for flue gas purification, especially of flue gas from the combustion of high water-content fuels, such as biomass, especially wood, and for reducing the volumetric flow of the flue gas and/or for recovery of water from the flue gas, wherein the flue gas is brought into contact with a measured quantity of concentrated hygroscopic in at least one absorber unit and the measured quantity of hygroscopic material is diluted and heated with absorption of water from the flue gas. Heated is extracted from the heated and diluted hygroscopic material after which it is concentrated in at least one separating unit by separation of water and the resulting measured quantity of concentrated hygroscopic material obtained is routed at least partially to the absorber unit.Type: ApplicationFiled: June 14, 2011Publication date: December 20, 2012Applicant: ALODYNE, LLCInventors: Jennifer Packard WEBER, Jeffrey Goodman PACKARD
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Publication number: 20120312166Abstract: The invention relates to a system and a method for purifying ship diesel exhaust gases of fine dust particles, and of certain burnt gases, having a spray tower, a venturi washer, a cyclone and a disc centerifuge.Type: ApplicationFiled: December 17, 2010Publication date: December 13, 2012Applicant: BAYER INTELLECTUAL PROPERTY GMBHInventors: Mischa Theis, Karl Reither
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Patent number: 8313569Abstract: An air washer adsorbs outside contaminated air to disks, which have water films formed thereon, and settles contaminants in water in a water reservoir, thus purifying and humidifying air.Type: GrantFiled: November 19, 2007Date of Patent: November 20, 2012Assignee: WiniaMando Inc.Inventors: Jun Hyung Park, Seung Dae Yang, Hwa Ohk Kim, Joon Ho Jang, Il Ho So
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Patent number: 8292989Abstract: A power generation plant (112), a method, and a CO2 capture system (122) for removing carbon dioxide (104) from a flue gas stream (106) are disclosed. As shown in FIG. 2, a CO2 capture system (122), comprises an absorber vessel (202), a water wash vessel (210), and a stripper (214). The CO2 capture system (122) can be configured to introduce both a lean ionic ammonia solution (204) from a regeneration system (124) and a flue gas stream (106) from a cooling system (120) and to provide a rich ionic ammonia solution (206) to a regeneration system (124), wherein the introduction of the lean ionic ammonia solution (204) to the flue gas stream (106) produces a flue gas substantially devoid CO2 (224). The water wash vessel (210) can be configured to receive the flue gas substantially devoid CO2 (224) and produce ammoniated water (212) by introducing water (218) to the flue gas substantially devoid CO2 (224).Type: GrantFiled: October 30, 2009Date of Patent: October 23, 2012Assignee: ALSTOM Technology LtdInventors: Frederic Z. Kozak, Arlyn V. Petig, Vikram Shabde
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Publication number: 20120260800Abstract: The invention relates to a scrubber unit arrangement for cleaning exhaust gas. The arrangement comprises a scrubber unit for receiving a flow of exhaust gas, a pump means for supplying a scrubbing medium to the scrubber unit from a source of scrubbing medium, and means for discharging scrubbing medium from the scrubber unit. In order to provide an energy efficient scrubbing process, the scrubber unit arrangement further comprises a turbine unit, which is arranged to receive discharged scrubbing medium from the scrubber unit. Scrubbed exhaust gas is separately discharged from the scrubber unit.Type: ApplicationFiled: November 5, 2010Publication date: October 18, 2012Applicant: WARTSILA FINLAND OYInventor: Ari Suominen
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Patent number: 8287630Abstract: A grease water separation apparatus includes an air chamber in communication with an indoor grill; a water scattering member comprising a space in communication with the air chamber, at least one sprinkling duct, and a pump in communication with the sprinkling duct; a heat exchanger connected to the water scattering member and comprising a grease filter and grease holes; a liquid collector connected to the heat exchanger and comprising a water reservoir in communication with the pump, a grease reservoir for collecting grease from the grease holes, and a grease water mixing reservoir; a water-grease separator connected to the heat exchanger and being in communication therewith, the water-grease separator comprising a hollow cylinder having an air outlet and an inlet within the water-grease separator, and a water-grease outlet for flowing water and grease to the grease water mixing reservoir; a centrifugal fan; and an air filter.Type: GrantFiled: July 2, 2010Date of Patent: October 16, 2012Inventor: Wen-Li Li
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Publication number: 20120245737Abstract: Gas purification systems generally include an analyzing unit including a plurality of sensors and/or probes for continuously analyzing a solvent cyclic capacity in real time, the plurality of sensors and/or probes in fluid communication with rich amine and lean amine solution carrying conduits and the water wash conduits; and a system control unit configured to receive outputs from the analyzing unit for monitoring and controlling the solvent cyclic capacity in real time. Also disclosed are computer implemented methods for providing the real time control.Type: ApplicationFiled: February 22, 2012Publication date: September 27, 2012Applicant: ALSTOM TECHNOLOGY LTDInventors: ZHENG LIU, NARESHKUMAR B. HANDAGAMA, RASESH R. KOTDAWALA, BARATH BABURAO, VIKRAM S. SHABDE
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Publication number: 20120238793Abstract: Provided are gas processing facilities for the separation of components in a gas stream and methods of using the same. The facility includes one or more co-current contactors. Each contactor includes a mass transfer vessel having a mixing section. The mixing section receives a gas stream and a liquid contacting stream. The mixing section mixes theses two streams and releases a two-phase flow. Each contactor also includes a separator that receives the two-phase fluid stream from the mass transfer vessel in-line, and then separates a vapor phase from a liquid phase. The separator has a gas-phase outlet configured to release the vapor phase as a treated gas stream, and a liquid-phase outlet configured to release the liquid phase as a loaded treating solution. The contactors may be used to remove water or other contaminant from a natural gas stream or other gas stream.Type: ApplicationFiled: July 22, 2011Publication date: September 20, 2012Inventors: John T. Cullinane, Edward J. Grave, Paul S. Northrop
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Patent number: 8268060Abstract: A dehumidifier system having a dehumidifier section within which liquid desiccant absorbs moisture from air flowing therethrough and a dehumidifier section within which the desiccant is regenerated employs a heat exchanger for maintaining a relatively high temperature differential between the desiccant contained within the dehumidifier and regenerator sections. The desiccant which is conducted to either the dehumidifier section or the regenerator section is separated into multiple streams, and the multiple streams are treated differently from one another before being discharged into preselected segments of the air flow moving through the corresponding one of the dehumidifier section and the regenerator section. A control scheme in the system is capable of altering, and thereby improving, the concentration level of desiccant utilized in the system.Type: GrantFiled: October 15, 2007Date of Patent: September 18, 2012Assignee: Green Comfort Systems, Inc.Inventors: Larry N. Hargis, Robert W. Dibble, Stephen D. Heberle
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Patent number: 8262776Abstract: A system and method for producing biofuel from pollutant-fed algae are disclosed. Specifically, the system includes a scrubber with a chamber for receiving a pollutant-contaminated fluid stream. Further, a scrubber solution is received in the chamber for scrubbing the pollutant-contaminated fluid stream. Also, the system includes a bioreactor that is provided with an input port to receive the scrubber solution with pollutants for use as nutrients to support algae cell growth. Further, the system includes an algae separator that removes the algae from the bioreactor and a device for processing the algae into biofuel. In order to recycle the scrubber solution, the algae separator is in fluid communication with the scrubber. With this arrangement, the effluence from the bioreactor may be recycled for use as the scrubber solution.Type: GrantFiled: October 13, 2006Date of Patent: September 11, 2012Assignee: General AtomicsInventors: David A. Hazlebeck, Eric H. Dunlop
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Patent number: 8257476Abstract: A first contaminant selected from oxygen and carbon monoxide is removed from impure liquid carbon dioxide using a mass transfer separation column system which is reboiled by indirect heat exchange against crude carbon dioxide fluid, the impure liquid carbon dioxide having a greater concentration of carbon dioxide than the crude carbon dioxide fluid. The invention has particular application in the recovery of carbon dioxide from flue gas generated in an oxyfuel combustion process or waste gas from a hydrogen PSA process. Advantages include reducing the level of the first contaminant to not more than 1000 ppm.Type: GrantFiled: September 17, 2010Date of Patent: September 4, 2012Assignee: Air Products and Chemicals, Inc.Inventors: Vincent White, Rodney John Allam
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Publication number: 20120216680Abstract: An apparatus to promote gas-liquid contact and facilitate enhanced mass transfer. The dispersed bubble reactor (DBR) operates in the dispersed bubble flow regime to selectively absorb gas phase constituents into the liquid phase. The dispersion is achieved by shearing the large inlet gas bubbles into fine bubbles with circulating liquid and additional pumped liquid solvent when necessary. The DBR is capable of handling precipitates that may form during absorption or fine catalysts that may be necessary to promote liquid phase reactions. The DBR can be configured with multistage counter current flow sections by inserting concentric cylindrical sections into the riser to facilitate annular flow. While the DBR can absorb CO2 in liquid solvents that may lead to precipitates at high loadings, it is equally capable of handling many different types of chemical processes involving solids (precipitates/catalysts) along with gas and liquid phases.Type: ApplicationFiled: February 23, 2012Publication date: August 30, 2012Applicant: Southern CompanyInventors: Pannalal Vimalchand, Guohai Liu, WanWang Peng, Alexander Bonsu
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Publication number: 20120195740Abstract: A drain discharge equipment of a compressor having a separator for separating drain discharged from the compressor to compressed air and liquid drain, which is disposed on some part of a drain capture pipe connected between stages and/or to an outlet of the compressor to compress air with a liquid sprayed, and discharging the liquid drain separated by the separator to outside the compressor through a discharge pipe system, characterized in that the separator is provided with a device for intermittently discharging the liquid drain separated by the separator to the discharge pipe system.Type: ApplicationFiled: January 11, 2012Publication date: August 2, 2012Applicant: Hitachi, Ltd.Inventor: Mitsuhiro KARISHUKU
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Patent number: 8231719Abstract: An absorbent liquid according to the present invention is an absorbent liquid for absorbing CO2 or H2S or both from gas, in which the absorbent liquid includes an alkanolamine as a first compound component, and a second component including a nitrogen-containing compound having in a molecule thereof two members or more selected from a primary nitrogen, a secondary nitrogen, and a tertiary nitrogen or a nitrogen-containing compound having in a molecule thereof all of primary, secondary, and tertiary nitrogens. The absorbent liquid has an excellent absorption capacity performance and an excellent absorption reaction heat performance, as compared to an aqueous solution containing solely an alkanolamine and a nitrogen-containing compound in the same concentration in terms of wt %, and can recover CO2 or H2S or both from gas with smaller energy.Type: GrantFiled: June 12, 2006Date of Patent: July 31, 2012Assignees: Mitsubishi Heavy Industries, Ltd., The Kansai Electric Power Co., Inc.Inventors: Ryuji Yoshiyama, Masazumi Tanoura, Noriko Watari, Shuuji Fujii, Yukihiko Inoue, Mitsuru Sakano, Tarou Ichihara, Masaki Iijima, Tomio Mimura, Yasuyuki Yagi, Kouki Ogura
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Patent number: 8226754Abstract: An FGD system is provided which can be retrofitted on existing utility coal-fired boilers. The design is based on a horizontal co-current scrubber capable of generating a pressure rise across the absorber. Modifications to existing plant equipment are minimized by the co-current horizontal scrubber design. The system includes features, which eliminate much equipment typically associated with other FGD designs, and reduces the use of support equipment such as tanks, agitators, and pumps. It also minimizes or eliminates the need for new buildings.Type: GrantFiled: October 13, 2009Date of Patent: July 24, 2012Assignee: URS CorporationInventors: Jonas Klingspor, J. David Colley, Greg N. Brown
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Publication number: 20120167760Abstract: In one embodiment, a carbon dioxide separating and recovering system includes an absorption tower to cause carbon dioxide to be absorbed in an absorbing solution, a regeneration tower to release the carbon dioxide from the absorbing solution, and at least one measuring apparatus to measure an ultrasound propagation speed in the absorbing solution. Each of the at least one measuring apparatus calculates a dissolved carbon dioxide concentration in the adsorbing solution, based on a temperature measured by a temperature measuring unit, the ultrasound propagation speed measured by an ultrasound propagation speed measuring unit, and a correlation expression which shows a relationship between the dissolved carbon dioxide concentration and the ultrasound propagation speed in the absorbing solution, and is changed according to the temperature of the absorbing solution.Type: ApplicationFiled: January 4, 2012Publication date: July 5, 2012Applicant: KABUSHIKI KAISHA TOSHIBAInventors: Daigo MURAOKA, Koshito Fujita, Takashi Ogawa, Hideo Kitamura, Satoshi Saito, Masatoshi Hodotsuka
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Publication number: 20120167766Abstract: A process and system for separating CO2 from a flue gas stream is disclosed. The process involves (a) contacting a flue gas stream containing water vapor and CO2 with an ionic absorbent under absorption conditions to absorb at least a portion of the CO2 from the flue gas stream and form a CO2-absorbent complex; wherein the ionic absorbent comprises a cation and an anion comprising an amine moiety; and (b) recovering a gaseous product having a reduced CO2 content.Type: ApplicationFiled: December 30, 2010Publication date: July 5, 2012Applicants: University of South Alabama, Chevron U.S.A.Inventors: Daniel Chinn, Russell Evan Cooper, Zunqing He, James H. Davis, JR., Kevin N. West, Hye Kyung Timken, Michael S. Driver
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Patent number: 8206490Abstract: A separator scrubber (58) and isolation loop (78) decontaminates a fuel reactant stream of a fuel cell (12). Water passes over surfaces of an ammonia dissolving means (61) within the scrubber (58) while the fuel reactant stream simultaneously passes over the surfaces to remove contaminants from the fuel reactant into the water. An accumulator (68) collects the separated contaminants and water, and an isolation loop pump (84) directs flow of the separated contaminant stream through the isolation loop (78). A heat exchanger (86) and an ion exchange bed (88) modify the heat of, and remove contaminants from, the separated contaminant stream, and the isolation loop (78) directs the decontaminated stream back onto the packed bed (62)-. Separating contaminants from the fuel reactant stream and then isolating and concentrating the separated contaminants within the ion exchange bed (88) minimizes cost and maintenance requirements.Type: GrantFiled: September 20, 2006Date of Patent: June 26, 2012Assignee: UTC Fuel Cells, LLCInventors: Albert P. Grasso, John L. Preston, Jr., Francis Kocum, Richard J. Assarabowski, Derek Hildreth
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Publication number: 20120152119Abstract: A system and process are disclosed for selective removal and recovery of H2S from a gaseous volume, e.g., from natural gas. Anhydrous organic, sorbents chemically capture H2S gas to form hydrosulfide salts. Regeneration of the capture solvent involves addition of an anti-solvent that releases the captured H2S gas from the capture sorbent. The capture sorbent and anti-solvent are reactivated for reuse, e.g., by simple distillation.Type: ApplicationFiled: December 17, 2010Publication date: June 21, 2012Applicant: BATTELLE MEMORIAL INSTITUTEInventors: David J. Heldebrant, Phillip K. Koech, James E. Rainbolt, Mark D. Bearden, Feng Zheng
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Patent number: 8202349Abstract: A method for processing pre-combustion syngas includes, in an exemplary embodiment, providing an absorber unit having a membrane contactor having a plurality of micro-pores, channeling pre-combustion syngas along a first surface of the membrane contactor, channeling an amine based solvent along a second opposing surface of the membrane contactor, and contacting the solvent with the syngas such that the solvent and the syngas contact at gas-liquid interface areas, defined by the plurality of micro-pores in the membrane contactor, to separate CO2 from the flue gas by a chemical absorption of CO2 into the solvent to produce a solvent containing CO2.Type: GrantFiled: June 30, 2009Date of Patent: June 19, 2012Assignee: General Electric CompanyInventor: Jennifer Lynn Molaison
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Patent number: 8147593Abstract: An absorbing solution according to the present invention is an absorbing solution that absorbs CO2 or H2S in gas or both of CO2 and H2S. The absorbing solution is formed by adding desirably 1 to 20 weight percent of tertiary monoamine to a secondary-amine composite absorbent such as a mixture of secondary monoamine and secondary diamine. Consequently, it is possible to control degradation in absorbing solution amine due to oxygen or the like in gas. As a result, it is possible to realize a reduction in an absorption loss, prevention of malfunction, and a reduction in cost. This absorbing solution is suitably used in an apparatus for removing CO2 or H2S or both of CO2 and H2S.Type: GrantFiled: April 3, 2006Date of Patent: April 3, 2012Assignees: Mitsubishi Heavy Industries, Ltd., The Kansai Electric Power Co., Inc.Inventors: Tomio Mimura, Yasuyuki Yagi, Kouki Ogura, Masaki Iijima, Toru Takashina, Hiroshi Tanaka, Takuya Hirata
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Patent number: 8147787Abstract: Refinery off gases are treated in a plant in two processing steps, wherein the off gases are first scrubbed in a wash column using lean oils for removal of heavy mercaptans and C5+ hydrocarbons, and wherein a hydrotreater is then used for saturating olefinic hydrocarbons and reducing sulfurous compounds. Most preferably, lean recycle oil is used for temperature control of the hydrotreater reactor(s) in configurations where the lean oil from a hydrotreater reactor outlet separator is mixed with the reactor feed to so cool the hydrotreater reactor via evaporation.Type: GrantFiled: February 14, 2008Date of Patent: April 3, 2012Assignee: Fluor Technologies CorporationInventors: John Mak, Robert Henderson
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Publication number: 20120067081Abstract: A plant for producing an argon-rich stream from a mixture formed by a purge fluid in an ammonia production plant comprises: at least one phase separator; a methane scrubbing column; a methane separation column; a nitrogen/argon separation column; a line for sending the mixture into at least one phase separator, to produce at least a hydrogen-enriched gas and a hydrogen-depleted liquid; a line for sending at least a portion of the hydrogen-depleted liquid into the bottom of the methane scrubbing column, to form an overhead gas and a bottoms liquid; a line for sending at least a portion of the bottoms liquid from the methane scrubbing column to the methane separation column, to produce a methane-enriched bottoms liquid and a methane-depleted overhead gas; a line for sending at least a portion of the methane-depleted overhead gas to the nitrogen/argon separation column, to form a nitrogen-enriched fluid as overhead of said column; a line for withdrawing an argon-rich liquid as bottoms of said column, serving asType: ApplicationFiled: June 3, 2010Publication date: March 22, 2012Applicant: L'Air Liquide Societe Anonyme Pour L'Etude Et L'Exploitatin Des Procedes Georges ClaudeInventors: Alain Briglia, Antonie Hernandez, Bemard Saulnier, Laurent Samy, Jean-Marc Tsevery, Marie-Pascal Victor
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Publication number: 20120067219Abstract: Disclosed is a measurement device with which it is possible to quickly measure the carbon dioxide content of an absorbent solution circulating through a carbon dioxide recovery system.Type: ApplicationFiled: March 25, 2010Publication date: March 22, 2012Applicant: Kabushiki Kaisha ToshibaInventors: Takashi Ogawa, Masatoshi Hodotsuka, Yukio Oohashi, Manabu Sakurai, Susumu Yamanaka, Naomi Tsuchiya, Haruhiko Hirata
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Patent number: 8137444Abstract: Systems and methods for lowering levels of carbon dioxide and other atmospheric pollutants are provided. Economically viable systems and processes capable of removing vast quantities of carbon dioxide and other atmospheric pollutants from gaseous waste streams and sequestering them in storage-stable forms are also discussed.Type: GrantFiled: March 10, 2010Date of Patent: March 20, 2012Assignee: Calera CorporationInventors: Kasra Farsad, Robert W. Elliott, Richard P. O'Connor, William Randall Seeker, Kyle Self, Justin Wall
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Publication number: 20120055336Abstract: This invention provides a machining device with waste collection equipment, which is suitable for collecting an easily charged waste and the like, and a machining method using the machining device. In the machining device with waste collection equipment, which collects waste generated by a predetermined machining processing, the waste collection equipment is provided with a transfer path through which the waste is transferred using an air flow, a water supply device which is provided at an intermediate portion of the transfer path and supplies a predetermined amount of water to the waste thereby applying antistatic treatment to the waste, a cyclone which applies separation processing to the waste subjected to the antistatic treatment, and a collection tank which collects the waste subjected to the separation processing by the cyclone.Type: ApplicationFiled: December 8, 2010Publication date: March 8, 2012Applicant: NAKATA COATING CO., LTD.Inventor: Takemi Matsuno
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Patent number: 8128737Abstract: A system, method and apparatus for treating a waste gas stream containing on or more hydrocarbon contaminants such polycyclic aromatic hydrocarbons (PAH). The system, method and apparatus may include a heat treatment chamber having a recycling apparatus that includes a supply of a food oil solvent; a mixing device to mix the solvent with the waste gas stream. The system, method and apparatus dissolve the hydrocarbon contaminants from the gas stream into a solvent containing the food oil.Type: GrantFiled: January 7, 2009Date of Patent: March 6, 2012Assignee: Lummus Technology Inc.Inventors: Franklin D. Lomax, Jr., Owens Owen, Paul Bizot, Milan Skarka
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Patent number: 8123842Abstract: Systems and processes disclosed herein relate to the utilization of direct contact condensing to provide heat to a solvent regeneration loop in an acid gas removal process. A first direct contact condenser can be included in the upper section of a concentrator that removes acid gas from a rich solvent stream. A first slip stream can be heated in the first direct contact condenser and can be combined with the rich solvent stream in the lower section of the stripper. A second direct contact condenser can be included in the lower section of an absorber that removes acid gas from a feed gas. A second slip stream can be heated in the second direct contact condenser, and can be combined with the rich solvent stream before the rich solvent stream is provided to the concentrator.Type: GrantFiled: January 16, 2009Date of Patent: February 28, 2012Assignee: UOP LLCInventors: Junfeng Pan, Richard Huang, Lamar A. Davis
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Publication number: 20120031274Abstract: An aeration apparatus is immersed in diluted used seawater which is water to be treated and generates fine air bubbles in the diluted used seawater. The aeration apparatus includes: an air supply line L5 for supplying air 122 through blowers 121A to 121D serving as discharge unit; a fresh water tank 140 and a supply pump P1 that are used as moisture supplying unit for supplying fresh water 141 serving as moisture to the air supply line L5; and aeration nozzles 123 including diffuser membranes 11 having slits, through which the air containing the moisture is supplied to the aeration nozzles 123.Type: ApplicationFiled: August 5, 2011Publication date: February 9, 2012Applicant: MITSUBISHI HEAVY INDUSTRIES, LTD.Inventors: Keisuke Sonoda, Shozo Nagao
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Publication number: 20120017762Abstract: CO2 is absorbed from a gas mixture by bringing the gas mixture into contact with an absorbent that comprises water and at least one amine of the formula (I), wherein R1 and R2, independently of each other, are hydrogen or an alkyl group. According to the invention, absorption media comprise sulfolane or an ionic liquid in addition to water and an amine of the formula (I). A device according to the invention for removing CO2 from a gas mixture comprises an absorption unit, a desorption unit, and an absorption medium according to the invention that is conducted in the circuit.Type: ApplicationFiled: January 29, 2010Publication date: January 26, 2012Applicant: Evonik Degussa GmbHInventors: Matthias Seiler, Jörn Rolker, Rolf Schneider, Bernd Glöckler, Axel Kobus, Wolfgang Benesch, Thomas Riethmann, Hermann Winkler, Jens Reich, Helmut Brüggemann
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Patent number: 8088200Abstract: In a method for removing acid gases from a fluid stream, the fluid stream, which is in contact with an absorption medium within an absorber, is passed through a first absorption zone in the absorber to remove a majority of acid gases from the fluid stream. The fluid stream is susequently passed through a second absorption zone in the absorber to further remove acid gases from the fluid stream. The loaded absorption medium is passed into a first regeneration zone to obtain a partially regenerated absorption medium, and a part of the partially regenerated absorption medium is passed into the first absorption zone. The other part of the partially regenerated absorption medium is passed into a second regeneration zone to obtain a regenerated absorption medium. A part of the regenerated absorption medium is passed into the first absorption zone and the other part is passed into the second absorption zone.Type: GrantFiled: February 14, 2007Date of Patent: January 3, 2012Assignee: BASF SEInventors: Rupert Wagner, Randolf Hugo
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Patent number: 8083837Abstract: A deputation process and corresponding apparatus for purification of the air of a closed environment characterized by indoor pollution, in which, in order to reduce the pollution, a water tank is provided that contains a multiplicity of active biomasses designed to absorb and metabolize the pollutant substances that are contained in the water and come from the air of the closed environment, and elements of water-air contact, designed precisely to transfer the pollutant substances from the closed environment into the water within the tank.Type: GrantFiled: November 3, 2006Date of Patent: December 27, 2011Assignee: Ingegneria Ambientale SRLInventors: Uranio Mazzanti, Paolo De Filippis, Marco Scarsella
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Patent number: 8080087Abstract: A method of drying liquid and gaseous hydrocarbons by contacting a feed stream of the hydrocarbon with an aqueous solution of a salt drying agent prior to passing the stream through a salt dryer to remove part of the water in the stream. The aqueous solution of the salt drying agent is generated in the salt dryer when the partly dried stream comes into contact with the drying salt and forms the solution. The solution is circulated in a loop from the salt dryer to the incoming feed and then through a liquid/liquid coalescer which removes a portion of the water together with dissolved salt from the mixture before the mixture is passed on to the salt dryer where further removal of water occurs. The salt dryer is off-loaded by a substantial factor by the initial partial dehydration and does not require to remove such a large amount of water; the salt consumption is therefore reduced in proportion to the amount of water removed in the treatment steps which precede the dryer.Type: GrantFiled: October 24, 2008Date of Patent: December 20, 2011Assignee: ExxonMobil Research & Engineering CompanyInventors: Robert J. Falkiner, Bal K. Kaul