Plural Separate Barriers Patents (Class 96/7)
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Patent number: 8394183Abstract: An asymmetric membrane contains a porous layer and a dense layer adjacent thereto. The porous layer and the dense layer are formed of a polymeric material. The porous layer and/or dense layer contains a filler. The amount of the filler is 11 parts by mass or more per 100 parts by mass of the polymeric material contained in the asymmetric membrane.Type: GrantFiled: October 27, 2008Date of Patent: March 12, 2013Assignees: Shin-Etsu Polymer Co., Ltd., Denso Corporation, Shin-Etsu Chemical Co., Ltd.Inventors: Junya Ishida, Mitsuaki Negishi, Yuzo Morioka, Mika Kawakita, Katsunori Iwase, Manabu Maeda, Masahiko Minemura, Mamoru Hagiwara
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Patent number: 8394173Abstract: There is described a method for the removal of gaseous contaminants from the housings of devices sensitive to the presence of such contaminants by means of nanostructured sorbers, wherein the sorber is in the form of a fiber containing an active material at its inside. Nanostructured sorbers and their manufacturing method are also described.Type: GrantFiled: April 1, 2008Date of Patent: March 12, 2013Assignee: Saes Getters S.p.A.Inventors: Roberto Giannantonio, Lorena Cattaneo
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Publication number: 20130055892Abstract: Methods for the purification of steam, systems for purifying steam, methods for measuring and/or controlling steam flow rates, and uses for purified steam are provide. Also provided are substantially gas-impermeable membranes, such as perfluorinated ionomers (e.g., perfluoroethylene-sulfonic-acid/tetrafluoroethylene membranes), having a high ratio of water vapor permeation relative to gas permeation through the membrane. Also provided are methods of operation of such membranes at relatively high operating temperatures for the purification of steam and for operation of such membranes at relatively low temperature and sub-atmospheric pressures for the purification of steam. In a preferred embodiment, the system 400 for purifying steam comprises heater 404 for creating a source of a steam feed, and a purification device 416 for housing a substantially gas-impermeable membrane 424. In the operation of system 400, water, such as deionized water, is added to vessel 402 to provide a source of the steam feed.Type: ApplicationFiled: August 28, 2012Publication date: March 7, 2013Applicant: RASIRCInventors: Jeffrey J. Spiegelman, Richard D. Blethen
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Patent number: 8388743Abstract: One aspect of the present teachings includes a separation membrane arranged in a hollow case. A particular component concentration chamber and a particular component dilution chamber are arranged in series in the hollow case. The particular component concentration chamber is capable of increasing concentration of the particular component by allowing permeation of the particular gas through the separation membrane. The particular component dilution chamber is capable of increasing concentration of the particular component by not allowing permeation of the particular gas through the separation membrane. The particular component concentration chamber and the particular component dilution chamber are configured such that only a gas containing the particular component and permeated through the separation membrane or only a gas containing the particular component not permeated through the separation membrane in one of the chambers disposed on an upstream side (i.e.Type: GrantFiled: October 28, 2009Date of Patent: March 5, 2013Assignee: Aisan Kogyo Kabyshiki KaishaInventors: Masataka Suzuki, Takashi Suefuji, Akio Muraishi, Katsuhiko Makino, Toshiyuki Iwasaki, Takashi Mani
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Publication number: 20130042762Abstract: A gas filter comprises a housing (30) having a gas inlet (55), a gas outlet (65) and at least one chamber (70) therebetween containing carbon nanotubes (110). The chamber (70) has a port (90) and is configured for simultaneous gas ingress to and gas egress from the carbon nanotubes (110) through the port (90).Type: ApplicationFiled: March 29, 2011Publication date: February 21, 2013Inventor: Dimitris Drikakis
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Patent number: 8337590Abstract: The invention relates to a device for drying a gas, in particular air, that comprises at least one chamber (5) with an inlet (5a) for the flow of gas to be treated and an outlet (5b) for the flow of treated gas, said chamber being limited by at least one membrane (6) having a water vapor perviousness that is significantly higher than the perviousness to other gases or vapors, a humidity absorbing material being provided or flowing against the membrane (6) on the side opposite the chamber. The device includes a stack of plates (P1, P2) provided with central openings (A, B); each chamber (5) is formed by a central opening (A) located between two parallel membranes (6) while the humidity absorbing material is provided against each membrane (6); each plate (P1) is sandwiched between two plates (P2, P3) including a housing (B, B1) for the humidity absorbing material; and a plurality of chambers (5) are stacked and connected in series.Type: GrantFiled: February 4, 2009Date of Patent: December 25, 2012Assignee: R + I AllianceInventors: Ignacio Valor Herencia, Juan Manuel Juarez Galan
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Patent number: 8328912Abstract: An air dryer having an internal orifice designed into an outlet end cap that eliminates the need for external valves or regulators to control the flow of air through the dryer. The internal orifice, which can be press-fit or threaded into the end cap, provides a consistent and stable outlet flow and dew point and eliminates the need for instruments to measure outlet flow and dew point. The orifice size can be easily changed for changing outlet flow and dew point. A protective tubular shroud is provided for shielding a membrane module of the dryer, and for routing sweep gas to a bottom vent.Type: GrantFiled: February 19, 2010Date of Patent: December 11, 2012Assignee: Parker-Hannifin CorporationInventors: Douglas Moore, William D. Howes, Karli M. Raymond, Paul E. Smith
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Publication number: 20120304862Abstract: Porous membrane contactors and/or their methods of manufacture and/or use are provided. In at least selected embodiments, the present invention is directed to flat panel hollow fiber or flat sheet membrane contactors and/or their methods of manufacture and/or use. In at least certain particular embodiments, the present invention is directed to hollow fiber array flat panel contactors, contactor systems, and/or their methods of manufacture and/or use. In at least particular possibly preferred embodiments, the contactor is adapted for placement in an air duct (such as an HVAC ductwork) and has a rectangular frame or housing enclosing at least one wound hollow fiber array or membrane bundle.Type: ApplicationFiled: June 1, 2012Publication date: December 6, 2012Inventors: Gareth P. Taylor, Timothy D. Price, Amitava Sengupta, Paul A. Peterson, C. Glen Wensley
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Patent number: 8317907Abstract: A water vapor transfer assembly for a fuel cell system includes at least one water vapor transfer device. The water vapor transfer device permits a transfer of water from a wet stream to a dry stream. The water vapor transfer device is disposed between a pair of end plates. The end plates each have a plurality of outwardly extending ribs. The water vapor transfer device and the end plates are disposed within a housing having a pair of wet stream apertures and a pair of dry stream apertures formed therein. The housing further includes a plurality of channels formed adjacent the dry stream apertures. The channels are in fluid communication with the wet stream apertures. The outwardly extending ribs of the end plates cooperate with the channels to define a tortuous bypass flow path between the wet stream apertures of the housing.Type: GrantFiled: June 8, 2010Date of Patent: November 27, 2012Assignee: GM Global Technology Operations LLCInventors: David A. Martinchek, Ian R. Jermy
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Patent number: 8303690Abstract: A hollow fiber carbon membrane is provided, which has excellent gas separation performance, unbreakable flexibility and high utility. The hollow fiber carbon membrane comprises carbonized substance obtained by calcination of a hollow fiber-like material formed from a polyphenylene oxide derivative, and has an external diameter in the range of 0.08 mm to 0.25 mm. The polyphenylene oxide derivative substantially comprises repeating units represented by the following (a) and (b) (in the structural formula, R11 and R12 independently represent hydrogen atom or sulfone group, except that R11 and R12 are both hydrogen atoms), wherein the ratio A (%) of the repeating unit (b) to the repeating units (a)+(b) satisfies 15%<A<60%.Type: GrantFiled: July 31, 2008Date of Patent: November 6, 2012Assignee: National Institute of Advanced Industrial Science and TechnologyInventors: Miki Yoshimune, Kenji Haraya
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Publication number: 20120255443Abstract: A module and an apparatus incorporating such module utilizing a plurality of tubular membrane elements, each configured to separate oxygen from an oxygen containing feed stream when an electric potential difference is applied to induce oxygen ion transport in an electrolyte thereof. The tubular membrane elements can be arranged in a bundle that is held in place by end insulating members. The insulating members can be positioned within opposed openings of end walls of a heated enclosure and can incorporate bores to allow an oxygen containing feed stream to flow past exposed ends of the tubular membrane elements for cooling the end seals of such elements. Further, first and second manifolds can be provided in a module in accordance with the present invention to collect separated oxygen from two separate portions of the tubular membrane elements.Type: ApplicationFiled: April 8, 2011Publication date: October 11, 2012Inventors: Gervase Maxwell Christie, David M. Reed, Jerrine L. Neff, Arthur C. Selover
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Patent number: 8268042Abstract: The instant invention generally provides polymer inorganic clay composite comprising a molecularly self-assembling material and an inorganic clay, and a process of making and an article comprising the polymer inorganic clay composite.Type: GrantFiled: November 20, 2009Date of Patent: September 18, 2012Assignee: Dow Global Technologies LLCInventors: Leonardo C. Lopez, Scott T. Matteucci
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Patent number: 8268055Abstract: A membrane gas dryer includes an upstream fitting assembly, a downstream fitting assembly, a purge tube, and a sample element. The upstream fitting assembly and the downstream fitting assembly include fitting bodies and barrier sleeves. The fitting bodies and the barrier sleeves form purge plenums that are in fluid communication with the purge tube. Sealing interfaces on the fitting bodies maintain fluid-tight seals around the purge plenums as the barrier sleeves rotate about fitting bodies. The sample element includes a water-permeable membrane and passes inside the purge tube such that moisture in a sample gas flowing in a downstream direction through the sample element between the fitting body to the downstream fitting body passes moisture through the water-permeable membrane and into a purge gas flowing in the purge tube in one of an upstream direction or a downstream direction between the purge plenums.Type: GrantFiled: April 14, 2011Date of Patent: September 18, 2012Assignee: Perma Pure LLCInventors: T. Paul Smith, David J. Burke
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Patent number: 8257466Abstract: Hydrogen-producing fuel processing systems, hydrogen purification membranes, hydrogen purification devices, fuel processing and fuel cell systems that include hydrogen purification devices, and methods for operating the same. In some embodiments, operation of the fuel processing system is initiated by heating at least the reforming region of the fuel processing system to at least a selected hydrogen-producing operating temperature. In some embodiments, an electric heater is utilized to perform this initial heating. In some embodiments, use of the electric heater is discontinued after startup, and a burner or other combustion-based heating assembly combusts a fuel to heat at least the hydrogen producing region, such as due to the reforming region utilizing an endothermic catalytic reaction to produce hydrogen gas.Type: GrantFiled: November 14, 2011Date of Patent: September 4, 2012Assignee: Idatech, LLCInventors: David J. Edlund, William A. Pledger, R. Todd Studebaker
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Patent number: 8245978Abstract: A method and system for providing nitrogen-enriched air (NEA) to aircraft fuel tanks using multiple air separation modules (ASMs). The ASMs employ membranes having different permeabilities and selectivities which are particularly selected to meet the varying NEA needs of the fuel tanks during flight.Type: GrantFiled: June 30, 1998Date of Patent: August 21, 2012Assignee: L'Air Liquide Societe Anonyme pour l'Etude et l'Exploitation des Procedes Georges ClaudeInventors: Karl S. Beers, Charles L. Anderson
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Patent number: 8226750Abstract: A hydrogen purifier utilizing a hydrogen-permeable membrane to purify hydrogen from mixed gases containing hydrogen is disclosed. Improved mechanical support for the permeable membrane is described, enabling forward or reverse differential pressurization of the membrane, which further stabilizes the membrane from wrinkling upon hydrogen uptake.Type: GrantFiled: May 5, 2009Date of Patent: July 24, 2012Assignee: Genesis Fueltech, Inc.Inventor: Peter David DeVries
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Patent number: 8221530Abstract: A water trap (1) improved with respect to handling and operational safety includes: two semipermeable membranes (2) and at least one tank (7), wherein the membranes have a water penetration pressure greater than 750 hPa and are made of the same or different PTFE laminates. The gas flow is divided in a ratio between 10:90 and 25:75 into the flush-/purge branch and analysis branch to the sensors (12) and a path parallel to the sensors (12), respectively, with the aid of the membranes and downstream filter elements and via the material and configuration.Type: GrantFiled: June 4, 2010Date of Patent: July 17, 2012Assignee: Draeger Medical GmbHInventors: Gerd Peter, Thomas Maxeiner, Thomas Wuske
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Publication number: 20120174790Abstract: A water vapor permeable membrane is provided comprising a dense layer and a support layer that are adjacent to each other, wherein the dense layer contains voids with a void length of 0.1 ?m or less and the dense layer has a thickness of 0.1 ?m or more and 2 ?m or less while in the support layer, void (a), i.e. the void with the largest length in the 2 ?m thick region measured from the boundary between the dense layer and the support layer into the support layer, has a length of 0.3 ?m or more and void (b), i.e. the void with the largest length in the region ranging between 2 ?m and 4 ?m measured from the boundary into the support layer, has a length of 0.5 ?m or more, the length of the void (b) being larger than that of the void (a). A water vapor permeable membrane having both a high water vapor permeability and a low air leakage is provided.Type: ApplicationFiled: August 21, 2009Publication date: July 12, 2012Applicant: Toray Industries, Inc.Inventors: Masahiro Osabe, Kazumi Tanaka, Hiroyuki Sugaya
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Patent number: 8182590Abstract: A process for forming a porous nanoscale membrane is described. The process involves applying a nanoscale film to one side of a substrate, where the nanoscale film includes a semiconductor material; masking an opposite side of the substrate; etching the substrate, beginning from the masked opposite side of the substrate and continuing until a passage is formed through the substrate, thereby exposing the film on both sides thereof to form a membrane; and then simultaneously forming a plurality of randomly spaced pores in the membrane. The resulting porous nanoscale membranes, characterized by substantially smooth surfaces, high pore densities, and high aspect ratio dimensions, can be used in filtration devices, microfluidic devices, fuel cell membranes, and as electron microscopy substrates.Type: GrantFiled: May 1, 2006Date of Patent: May 22, 2012Assignee: University of RochesterInventors: Christopher C. Striemer, Philippe M. Fauchet, Thomas R. Gaborski, James L. McGrath
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Publication number: 20120118146Abstract: The present invention relates to systems and methods for dehumidifying air by establishing humidity gradients in a plurality of dehumidification units, which are arranged in series and/or in parallel. Water vapor from air entering each stage of the plurality of dehumidification units is extracted by the dehumidification units without substantial condensation into low pressure water vapor chambers. For example, in one embodiment, the water vapor is extracted through water vapor permeable membranes of the dehumidification units into the low pressure water vapor chambers. As such, the air exiting each of the dehumidification units is less humid than the air entering the dehumidification units. The low pressure water vapor extracted from the air is subsequently compressed to a slightly higher pressure (i.e., just high enough to facilitate condensation), condensed, and removed from the system at ambient conditions.Type: ApplicationFiled: November 12, 2010Publication date: May 17, 2012Applicant: THE TEXAS A&M UNIVERSITY SYSTEMInventors: David E. Claridge, Charles H. Culp, Jeffrey S. Haberl
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Publication number: 20120118148Abstract: The present disclosure relates to systems and methods for dehumidifying air by establishing a humidity gradient across a water selective permeable membrane in a dehumidification unit. Water vapor from relatively humid atmospheric air entering the dehumidification unit is extracted by the dehumidification unit without substantial condensation into a low pressure water vapor chamber operating at a partial pressure of water vapor lower than the partial pressure of water vapor in the relatively humid atmospheric air. For example, water vapor is extracted through a water permeable membrane of the dehumidification unit into the low pressure water vapor chamber. As such, the air exiting the dehumidification unit is less humid than the air entering the dehumidification unit. The low pressure water vapor extracted from the air is subsequently condensed and removed from the system at ambient conditions.Type: ApplicationFiled: November 11, 2011Publication date: May 17, 2012Applicant: The Texas A&M University SystemInventors: Charles H. Culp, David E. Claridge
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Publication number: 20120118155Abstract: The present disclosure relates to systems and methods for dehumidifying air by establishing a humidity gradient across a water selective permeable membrane in a dehumidification unit. Water vapor from relatively humid atmospheric air entering the dehumidification unit is extracted by the dehumidification unit without substantial condensation into a low pressure water vapor chamber operating at a partial pressure of water vapor lower than the partial pressure of water vapor in the relatively humid atmospheric air. For example, water vapor is extracted through a water permeable membrane of the dehumidification unit into the low pressure water vapor chamber. As such, the air exiting the dehumidification unit is less humid than the air entering the dehumidification unit. The low pressure water vapor extracted from the air is subsequently condensed and removed from the system at ambient conditions.Type: ApplicationFiled: November 11, 2011Publication date: May 17, 2012Applicant: The Texas A&M Unversity SystemInventors: David E. Claridge, Charles H. Culp
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Patent number: 8177890Abstract: A Pd alloy membrane and method of making are described.Type: GrantFiled: June 26, 2009Date of Patent: May 15, 2012Assignee: The Ohio State UniversityInventors: Krenar Shqau, Hendrik Verweij
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Publication number: 20120111192Abstract: Disclosed is a method for separating carbon dioxide from a flue gas from energy conversion, wherein the flue gas is first supplied to a membrane unit, comprising at least one membrane module having a CO2-selective membrane, with a portion of the CO2 being separated in the module from the flue gas as an enriched CO2 permeate. The flue gas thus depleted (retentate) is subsequently supplied to at least one additional CO2 separating unit, in which a portion of the CO2 is separated from the flue gas by an adsorbent or absorbent. Also disclosed is a device that is suitable for carrying out the aforementioned methods for separating CO2 from a flue gas using a membrane unit, comprising at least one membrane module having a CO2-selective membrane and having an additional CO2 separating unit, comprising an adsorbent or absorbent.Type: ApplicationFiled: March 19, 2010Publication date: May 10, 2012Inventors: Jewgeni Nazarko, Ernst Riensche, Martin Bram, Li Zhao
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Patent number: 8172913Abstract: A shared or common environment membrane reactor containing a plurality of planar membrane modules with top and bottom thin foil membranes supported by both an intermediary porous support plate and a central base which has both solid extended members and hollow regions or a hollow region whereby the two sides of the base are in fluid communication. The membrane reactor operates at elevate temperatures for generating hydrogen from hydrogen rich feed fuels.Type: GrantFiled: March 19, 2009Date of Patent: May 8, 2012Inventors: Thomas R. Vencill, Anand S. Chellappa, Shailendra B. Rathod
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Patent number: 8157900Abstract: Hydrogen-processing assemblies, components of hydrogen-processing assemblies, and fuel-processing and fuel cell systems that include hydrogen-processing assemblies. The hydrogen-processing assemblies include a hydrogen-separation assembly positioned within the internal volume of an enclosure in a spaced relation to at least a portion of the internal perimeter of the body of the enclosure.Type: GrantFiled: June 9, 2011Date of Patent: April 17, 2012Assignee: Idatech, LLCInventors: William A. Pledger, Vernon Wade Popham, R. Todd Studebaker, Kyle Taylor
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Patent number: 8157899Abstract: A particulate material processing apparatus has a vessel and a processing tank. The vessel has a charging port for charging a particulate material into the vessel. The processing tank receives the particulate material charged from the charging port. The processing tank is shaped so as to narrow towards the bottom. At least the lower part of the processing tank is made of a gas-permeable material that allows the process gas for processing the particulate material to pass through. The upper part of the processing tank has lower gas permeability than the lower part of the processing tank.Type: GrantFiled: November 14, 2008Date of Patent: April 17, 2012Assignee: Daikin Industries, Ltd.Inventors: Tomohiro Isogai, Katsuya Nakai, Tatsuo Suzuki, Taku Hirakawa, Hiroyuki Shimada
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Patent number: 8147596Abstract: A hydrogen-permeable film has a ceramic material of a nitride or oxide of a metal element belonging to group IVB, VB or VIB and hydrogen-permeable metal particles of at least one kind selected from palladium (Pd), niobium (Nb), vanadium (V), tantalum (Ta) and alloys thereof dispersed in the ceramic material. A ratio of the hydrogen-permeable metal particles in the hydrogen-permeable film is 20 to 70 mass %, and a thickness of the hydrogen-permeable film is 5 to 1,000 nm.Type: GrantFiled: December 27, 2007Date of Patent: April 3, 2012Assignee: Mikuni CorporationInventor: Katsuhiko Fukui
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Patent number: 8142547Abstract: A method for extraction of gas from liquid provides for reliable and accurate extraction of gases dissolved in fluids and routing the extracted gas to an analytical instrument. An extraction module comprises one or more fluorosilicone membranes molded into the shape of a flattened disk. The membranes are retained in a housing in a spaced apart relationship. The membrane is permeable to target gas(es), but not to the fluid. Porous support members support the membranes and prevent damage to them and the housing defines separate fluid flow paths for the fluid and the gas extracted from it. Fluid is passed over the membrane in a first fluid phase; target compounds in the fluid diffuse across the membrane to a second fluid phase until equilibrium is achieved.Type: GrantFiled: November 15, 2011Date of Patent: March 27, 2012Assignee: Serveron CorporationInventors: Steven Mahoney, Thomas Waters
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Patent number: 8142662Abstract: A dehydrating system is designed to maintain the availability of a plant having the dehydrating system using a water separation membrane by allowing a water separation membrane unit to be replaced while the plant is in operation. The dehydrating system comprises at least two water separation membrane units in use arranged parallel to the direction of flow of a fluid to be processed, is configured so that at least one spare water separation membrane unit can be installed parallel to the direction of flow of the fluid to be processed with respect to the at least two water separation membrane units, having monitoring devices for the product fluid to be taken out, and maintains the properties of the product fluid by operating the spare water separation membrane unit depending on the properties of the product fluid monitored by the monitoring devices.Type: GrantFiled: May 13, 2009Date of Patent: March 27, 2012Assignee: Mitsubishi Heavy Industries, Ltd.Inventors: Hiroyuki Osora, Yoshio Seiki, Atsuhiro Yukumoto, Yukio Tanaka, Shinji Ogino, Haruaki Hirayama
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Patent number: 8114193Abstract: An ion transport membrane system comprising (a) a pressure vessel having an interior, an exterior, an inlet, and an outlet; (b) a plurality of planar ion transport membrane modules disposed in the interior of the pressure vessel and arranged in series, each membrane module comprising mixed metal oxide ceramic material and having an interior region and an exterior region, wherein any inlet and any outlet of the pressure vessel are in flow communication with exterior regions of the membrane modules; and (c) one or more gas manifolds in flow communication with interior regions of the membrane modules and with the exterior of the pressure vessel. The ion transport membrane system may be utilized in a gas separation device to recover oxygen from an oxygen-containing gas or as an oxidation reactor to oxidize compounds in a feed gas stream by oxygen permeated through the mixed metal oxide ceramic material of the membrane modules.Type: GrantFiled: January 18, 2008Date of Patent: February 14, 2012Assignee: Air Products and Chemicals, Inc.Inventors: VanEric Edward Stein, Michael Francis Carolan, Christopher M. Chen, Phillip Andrew Armstrong, Harold W. Wahle, Theodore R. Ohrn, Kurt E. Kneidel, Keith Gerard Rackers, James Erik Blake, Shankar Nataraj, Rene Hendrik Elias Van Doorn, Merrill Anderson Wilson
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Patent number: 8101129Abstract: In a nano filter structure for breathing and a manufacturing method of the nano filter structure, a semiconductor process technology is used for manufacturing a nano filter structure comprising a top gate, a bottom gate, a plurality of sidewall gates and a plurality of supports. The sidewall gates include a plurality of filterable gratings, and the filterable gratings are controlled precisely to a nanoscale by a semiconductor process technology. Therefore, the nano filterable gratings can be manufactured easily and quickly, and the multilayer design of the filterable gratings enhances the aperture ratio of a filter material, such that users can inhale or exhale easily through the filter material.Type: GrantFiled: October 13, 2009Date of Patent: January 24, 2012Inventor: Shu-Yuan Chuang
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Patent number: 8080093Abstract: Provided is a liquid supply apparatus including: a liquid supply path which supplies a liquid from an upstream side, which is a liquid supply source, to a downstream side in which the liquid is consumed; a defoaming chamber which is provided in the liquid supply path and defoams air bubbles included in the liquid; and a depressurization chamber which is provided at a position adjacent to the defoaming chamber with a partition interposed therebetween and is depressurized such that the pressure thereof becomes lower than the pressure of the defoaming chamber, wherein the partition allows permeation of gas by the depressurization of the depressurization chamber and restricts permeation of the liquid, and wherein the partition is configured by a partition wall having rigidity.Type: GrantFiled: December 10, 2008Date of Patent: December 20, 2011Assignee: Seiko Epson CorporationInventors: Hiroyuki Ito, Hideya Yokouchi
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Patent number: 8075675Abstract: A gas extraction apparatus provides for reliable and accurate extraction of gases dissolved in fluids and routing the extracted gas to an analytical instrument. An extraction module comprises one or more fluorosilicone membranes molded into the shape of a flattened disk. The membranes are retained in a housing in a spaced apart relationship. The membrane is permeable to target gas(es), but not to the fluid. Porous support members support the membranes and prevent damage to them and the housing defines separate fluid flow paths for the fluid and the gas extracted from it.Type: GrantFiled: June 12, 2008Date of Patent: December 13, 2011Assignee: Serveron CorporationInventors: Steven Mahoney, Thomas Waters
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Patent number: 8075670Abstract: A hydrogen permeable module includes a hydrogen permeable membrane that permeates hydrogen, an outer peripheral part of the hydrogen permeable membrane being restricted, an inside of the outer peripheral part of the hydrogen permeable membrane being not restricted. The hydrogen permeable module permeates the hydrogen by constantly keeping a pressure of a primary side to a pressure that is equal to or more than a pressure of a secondary side. The inside of the outer peripheral part of the hydrogen permeable membrane is not restricted so as to be capable of expanding to the secondary side.Type: GrantFiled: March 23, 2009Date of Patent: December 13, 2011Assignees: The Japan Steel Works, Ltd., National University Corporation Kitami Institute of TechnologyInventors: Tsuyoshi Sasaki, Tomohiro Ueno, Toshiki Kabutomori, Kiyoshi Aoki, Kazuhiro Ishikawa
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Publication number: 20110296984Abstract: A scrubber for controlling carbon dioxide levels in a shipping container containing respiring produce is disclosed. The scrubber is relatively small, utilizes a gas-selective membrane having a CO2/O2 selectivity ratio greater than 1:1, and fits inside the shipping container (such as a sea van container). In contrast to current methods of controlling CO2 levels in shipping containers, such as the use of hydrated lime, the scrubbers of the present invention are efficient, relatively inexpensive, do not take up shipping space within the container, and do not present handling or disposal issues. A method for controlling the carbon dioxide levels inside a shipping container containing respiring produce, utilizing the carbon dioxide scrubbers defined, is also disclosed.Type: ApplicationFiled: June 2, 2011Publication date: December 8, 2011Applicant: Chiquita Brands International, Inc.Inventors: Richard F. Macleod, Frederick Robert Forgnone, William Garrison Lester
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Publication number: 20110293863Abstract: A recipient for containing moist substrate, which recipient includes a flexible polymer wall having an outer surface and at least one gas exchanging membrane, which gas exchanging membrane is hermetically sealed to the outer surface of the flexible polymer wall along a sealing line. The sealing line defining a hermetically sealed area of the flexible polymer wall. The flexible polymer wall includes at least one aperture, being provided in this hermetically sealed area of the flexible polymer wall. The recipient further includes a mechanism for creating an air chamber circumscribed by the hermetically sealed area and the gas exchanging membrane, for preventing moist substrate to contact the gas exchanging membrane when the recipient is filled with moist substrate.Type: ApplicationFiled: August 11, 2011Publication date: December 1, 2011Inventor: Frans VANDENHOVE
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Patent number: 8066800Abstract: A method for separating CO2 from a processed fluid includes exposing a film to the processed fluid and reacting the CO2 with tetrahedrally coordinated zinc hydroxide moieties contained within the film to facilitate the transport of the CO2 through the film.Type: GrantFiled: October 23, 2009Date of Patent: November 29, 2011Assignee: Hamilton Sundstrand CorporationInventor: Haralambos Cordatos
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Patent number: 8057575Abstract: Hydrogen-producing fuel processing systems, hydrogen purification membranes, hydrogen purification devices, fuel processing and fuel cell systems that include hydrogen purification devices, and methods for operating the same. In some embodiments, operation of the fuel processing system is initiated by heating at least the reforming region of the fuel processing system to at least a selected hydrogen-producing operating temperature. In some embodiments, an electric heater is utilized to perform this initial heating. In some embodiments, use of the electric heater is discontinued after startup, and a burner or other combustion-based heating assembly combusts a fuel to heat at least the hydrogen producing region, such as due to the reforming region utilizing an endothermic catalytic reaction to produce hydrogen gas.Type: GrantFiled: October 21, 2010Date of Patent: November 15, 2011Assignee: Idatech, LLCInventors: David J. Edlund, William A. Pledger, R. Todd Studebaker
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Patent number: 8034168Abstract: Disclosed herein are combustion systems and power plants that incorporate sweep-based membrane separation units to remove carbon dioxide from combustion gases. In its most basic embodiment, the invention is a combustion system that includes three discrete units: a combustion unit, a carbon dioxide capture unit, and a sweep-based membrane separation unit. In a preferred embodiment, the invention is a power plant including a combustion unit, a power generation system, a carbon dioxide capture unit, and a sweep-based membrane separation unit. In both of these embodiments, the carbon dioxide capture unit and the sweep-based membrane separation unit are configured to be operated in parallel, by which we mean that each unit is adapted to receive exhaust gases from the combustion unit without such gases first passing through the other unit.Type: GrantFiled: April 22, 2011Date of Patent: October 11, 2011Assignee: Membrane Technology & Research, IncInventors: Johannes G. Wijmans, Timothy C Merkel, Richard W. Baker
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Patent number: 8034160Abstract: This invention relates to gas generators and methods for their use. In some embodiments, the invention relates to devices and methods of generating a gas enriched in a specific component. In other embodiments, the devices are configured to pressurize and regulate the temperature of atmospheric air prior to passing said air through a selectively permeable gas membrane. In further embodiments, a device is also configured to preheat said selectively permeable gas membrane.Type: GrantFiled: April 25, 2008Date of Patent: October 11, 2011Assignee: Nitro-Lift Technologies, Inc.Inventor: Danny Daniels
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Publication number: 20110232491Abstract: Hydrogen-processing assemblies, components of hydrogen-processing assemblies, and fuel-processing and fuel cell systems that include hydrogen-processing assemblies. The hydrogen-processing assemblies include a hydrogen-separation assembly positioned within the internal volume of an enclosure in a spaced relation to at least a portion of the internal perimeter of the body of the enclosure.Type: ApplicationFiled: June 9, 2011Publication date: September 29, 2011Applicant: IDATECH, LLCInventors: William A. Pledger, Vernon Wade Popham, R. Todd Studebaker, Kyle Taylor
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Patent number: 8025715Abstract: A gas separation process for treating flue gases from combustion processes, and combustion processes including such gas separation. The invention involves routing a first portion of the flue gas stream to be treated to a carbon dioxide capture step, while simultaneously flowing a second portion of the flue gas across the feed side of a membrane, flowing a sweep gas stream, usually air, across the permeate side, then passing the permeate/sweep gas to the combustor.Type: GrantFiled: September 13, 2010Date of Patent: September 27, 2011Assignee: Membrane Technology and Research, IncInventors: Johannes G. Wijmans, Timothy C. Merkel, Richard W. Baker
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Patent number: 8016923Abstract: Disclosed herein are combustion systems, power plants, and flue gas treatment systems that incorporate sweep-based membrane separation units to remove carbon dioxide from combustion gases. In its most basic embodiment, the invention is a combustion system that includes three discrete units: a combustion unit, a carbon dioxide capture unit, and a sweep-based membrane separation unit. In a preferred embodiment, the invention is a power plant including a combustion unit, a power generation system, a carbon dioxide capture unit, and a sweep-based membrane separation unit. In yet another embodiment, the invention is a flue gas treatment system that incorporates three membrane separation units with a carbon dioxide liquefaction unit.Type: GrantFiled: March 24, 2011Date of Patent: September 13, 2011Assignee: Membrane Technology and Research, IncInventors: Richard W. Baker, Johannes G Wijmans, Timothy C Merkel, Haiqing Lin, Ramin Daniels, Scott Thompson
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Patent number: 7985279Abstract: A gas separator having excellent humidifying performance, pressure loss, volume efficiency, and durability humidifies gases used in an on-vehicle fuel cell. The gas separator has upper and lower surfaces of pleat elements of a pleat molding covered by a plate having intake and exhaust ports. The pleat molding is formed by pleating a compound membrane formed of a gas separating membrane and at least one layer of permeable reinforcement material. The pleat element is formed by disposing a reinforcement frame at the outer side part of the molding. The ratio (R=L/H) of a shortest distance (L) between the intake and exhaust ports to a height (H) of the pleat molding is 0.1 to 7.0, and the ratio (W/Le) of the width (W) to the length (Le) of the pleat molding is 0.3 to 10.0. The gas separator operates at a volume flow ratio of 200 or higher.Type: GrantFiled: May 16, 2005Date of Patent: July 26, 2011Assignee: Asahi Kasei Chemicals CorporationInventors: Takahiko Kondo, Takuya Hasegawa, Naohiro Morimoto, Hidetoshi Masugi
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Patent number: 7972420Abstract: Hydrogen-processing assemblies, components of hydrogen-processing assemblies, and fuel-processing and fuel cell systems that include hydrogen-processing assemblies. The hydrogen-processing assemblies include a hydrogen-separation assembly positioned within the internal volume of an enclosure in a spaced relation to at least a portion of the internal perimeter of the body of the enclosure.Type: GrantFiled: May 18, 2007Date of Patent: July 5, 2011Assignee: Idatech, LLCInventors: William A. Pledger, Vernon Wade Popham, R. Todd Studebaker, Kyle Taylor
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Patent number: 7959716Abstract: A hydrogen permeable membrane is disclosed. The membrane is prepared by forming a mixture of metal oxide powder and ceramic oxide powder and a pore former into an article. The article is dried at elevated temperatures and then sintered in a reducing atmosphere to provide a dense hydrogen permeable portion near the surface of the sintered mixture. The dense hydrogen permeable portion has a higher initial concentration of metal than the remainder of the sintered mixture and is present in the range of from about 20 to about 80 percent by volume of the dense hydrogen permeable portion.Type: GrantFiled: September 30, 2009Date of Patent: June 14, 2011Assignee: UChicago Argonne, LLCInventors: Sun-Ju Song, Tae H. Lee, Ling Chen, Stephen E. Dorris, Uthamalingam Balachandran
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Patent number: 7955423Abstract: Solid-state membrane modules comprising at least one membrane unit, where the membrane unit has a dense mixed conducting oxide layer, and at least one conduit or manifold wherein the conduit or manifold comprises a dense layer and at least one of a porous layer and a slotted layer contiguous with the dense layer. The solid-state membrane modules may be used to carry out a variety of processes including the separating of any ionizable component from a feedstream wherein such ionizable component is capable of being transported through a dense mixed conducting oxide layer of the membrane units making up the membrane modules. For ease of construction, the membrane units may be planar.Type: GrantFiled: March 21, 2005Date of Patent: June 7, 2011Assignee: Air Products and Chemicals, Inc.Inventors: John Howard Gordon, Dale M. Taylor
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Patent number: 7947116Abstract: A method for separating a hydrogen-rich product stream from a feed stream comprising hydrogen and at least one carbon-containing gas, comprising feeding the feed stream, at an inlet pressure greater than atmospheric pressure and a temperature greater than 200° C., to a hydrogen separation membrane system comprising a membrane that is selectively permeable to hydrogen, and producing a hydrogen-rich permeate product stream on the permeate side of the membrane and a carbon dioxide-rich product raffinate stream on the raffinate side of the membrane. A method for separating a hydrogen-rich product stream from a feed stream comprising hydrogen and at least one carbon-containing gas, comprising feeding the feed stream, at an inlet pressure greater than atmospheric pressure and a temperature greater than 200° C.Type: GrantFiled: February 5, 2007Date of Patent: May 24, 2011Assignee: Eltron Research & Development, Inc.Inventors: Michael Mundschau, Xiaobing Xie, Carl Evenson, IV, Paul Grimmer, Harold Wright
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Patent number: 7947117Abstract: This invention describes a new hydrogen purification process that employs a combination of at least three membrane separation units. This process allows non-stationary operations and is particularly suitable for the production of hydrogen for the purpose of its use in a fuel cell.Type: GrantFiled: July 18, 2008Date of Patent: May 24, 2011Assignee: IFP Energies NouvellesInventors: Fabrice Giroudiere, Elsa Jolimaitre, Nicolas Boudet, Helene Rodeschini