Abstract: High-quality bimetallic PtxCu100-x (x=54-80 at. %) nanocubes can be prepared from a hot organic solution. Synthetic conditions, such as the ratio of oleylamine/tetraoctylammonium bromide as well as the doses of 1-dodecanethiol and 1,2-tetradecanediol have been optimized to ensure a formation of Pt—Cu nanocubes. Electrochemical evaluation shows that the catalytic activity of Pt60Cu40 nanocubes for methanol oxidation is superior, in comparison with those of spherical Pt60Cu40 nanocubes and Pt nanocubes with similar sizes, implying that the {100}-terminated Pt60Cu40 nanocubes offer a higher activity for methanol oxidation reaction than those with mixed crystallographic facets do.

Abstract: Hydrophobic metal nanoparticles are prepared by reducing a metal precursor in a non-polar or low polar organic solvent with or without volume expansion by adding CO2.

Abstract: Methods for sealing a porous dielectric are presented including: receiving a substrate, the substrate including the porous dielectric; exposing the substrate to an organosilane, where the organosilane includes a hydrolysable group for facilitating attachment with the porous dielectric, and where the organosilane does not include an alkyl group; and forming a layer as a result of the exposing to seal the porous dielectric. In some embodiments, methods are presented where the organosilane includes: alkynyl groups, aryl groups, flouroalkyl groups, heteroarlyl groups, alcohol groups, thiol groups, amine groups, thiocarbamate groups, ester groups, ether groups, sulfide groups, and nitrile groups. In some embodiments, method further include: removing contamination from the porous dielectric and a conductive region of the substrate prior to the exposing; and removing contamination from the conductive region after the forming.

Abstract: Methods for integrating the production of cellulose nanocrystals (CNC) and cellulose nanofibrils (CNF) from cellulose are provided. The methods use milder acid hydrolysis conditions than those for maximal CNC production to achieve reduced degradation of cellulose into soluble sugars. Also provided are negatively charged cellulosic solid residues (CSRs) in the form of cellulose fibers (CF) and/or cellulose microfibrils (CMF) during the acid hydrolysis, as well as CNFs fabricated from the CSRs.

Abstract: A method for synthesis of silicon nanowires provides a growth reactor having a decomposition zone and a deposition zone. A precursor gas introduced into the decomposition zone is disassociated to form an activated species that reacts with catalyst materials located in the deposition zone to deposit nano-structured materials on a low melting point temperature substrate in the deposition zone. A decomposition temperature in the decomposition zone is greater than a melting point temperature of the low melting point temperature substrate. The silicon nanowire are grown directly on the low melting point temperature substrate in the deposition zone to prevent the higher temperatures in the decomposition zone from damaging the molecular structure and/or integrity of the lower melting point temperature substrate located in the deposition zone.

Abstract: A bimetallic catalyst supported on a transition metal oxide is described. A method to make and use the bimetallic catalyst is also described. A method for preparing supported bimetallic catalysts of coinage group metal and a combination of a coinage group metal and a platinum metal group is described. A method for direct synthesis of adipic acid (AA) adopting green catalytic oxidation route of cyclohexane (CH) using the bimetallic catalysts is described. The reaction to convert CH into AA in the presence of bimetallic catalyst is carried in an autoclave in the temperature range of 25 to 300° C. The CH conversion was over 21% with AA selectivity of 34% and ca. 63% selectivity of cyclohexanone and cyclohexanol together over Au—Pd/TiO2 bimetallic catalyst.

Abstract: A modified compound that has at least one further functional group, in particular a bio- or macromolecule, comprising at least one x-fold (x?1) chemoselectively incorporated phosphoramidate group of general formula (I), NPO(OR1)(OR1?), and/or at least one x-fold (x?1) chemoselectively incorporated phosphonamide group of general formula (Ia), NPO(R1)(OR1?). R1 and R1? is selected from the group containing glycerol, polyglycerol, PEG polymers of the general empirical formula C2nH4n+2On+1 with n?1, Cn-alkyl chains with n?1; functionalized Cn-alkyl chains with n?1, aryls, heteroaryl, silyl, lipids, fluorophores, saccharides, peptides, crown ethers, or a linker, which links the aforementioned groups. R1 and R1? can be identical to or different from one another.

Abstract: Described is a metal oxide support material containing nanoscaled iron-platinum group metal particles having a particle size in the range of 0.5 to 10 nm. At least 70% of the nanoscaled iron-platinum group metal particles are located on an outside surface layer of the metal oxide support material. The outside surface layer has an average volume of less than 50% based on the total volume of the metal oxide support material. Additionally, described is a process for preparation of metal oxide support materials containing nanoscaled iron-platinum group metal particles. Furthermore, described is the use of metal oxides containing nanoscaled iron-platinum group metal particles as catalysts, for example as a diesel oxidation catalyst for the treatment of exhaust gas emissions from a diesel engine.

Abstract: The present invention relates to a nanophosphor and a synthesis method thereof, and provides a nanophosphor comprising a first compound of Formula 1, wherein the first compound is fluoride-based one which is co-doped with Ce3+ and Tb3+. NaGd1?p?q?rMrF4:Ce3+p,Tb3+q ??(1) In the Formula 1, descriptions on the p, q, r and M are overlapped with what was described in the detailed description of the present invention, so their concrete description are omitted. The nanophosphor has good light emission intensity and magnetic property as well as up-conversion and/or down-conversion property able to emit visible light after excitation by infrared and/or ultraviolet rays, so can be applied to a contrast agent and a counterfeit prevention code.

Abstract: The invention relates to a method for the synthesis of glutathione-capped cadmium-telluride (GSH-CdTe) quantum dots in an aqueous medium, including the steps of: a) preparing a precursor solution of cadmium in a citrate buffer; b) adding glutathione (GSH) to the preceding mixture via strong agitation; c) adding a telluride (potassium or sodium telluride) oxyanion as a telluride donor to the preceding mixture; d) allowing the preceding mixture to react; and e) stopping the reaction by incubation at low temperature.

Abstract: The present invention provides molybdenum and tungsten nanostructures, for example, nanosheets and nanoparticles, and methods of making and using same, including using such nanostructures as catlysts for hydrogen evolution reactions.

Abstract: A method for preparing semiconductor nanocrystals is disclosed. The method comprises adding a precursor mixture comprising one or more cation precursors, one or more anion precursors, and one or more amines to a ligand mixture including one or more acids, one or more phenol compounds, and a solvent to form a reaction mixture, wherein the molar ratio of (the one or more phenol compounds plus the one or more acids plus the one or more amine compounds) to the one or more cations initially included in the reaction mixture is greater than or equal to about 6, and heating the reaction mixture at a temperature and for a period of time sufficient to produce semiconductor nanocrystals having a predetermined composition. Methods for forming a buffer layer and/or an overcoating layer thereover are also disclosed. Semiconductor nanocrystals and compositions including semiconductor nanocrystals of the invention are also disclosed.

Abstract: This disclosure concerns a method of making silicon carbide involving adding one from the group of rice husk material, sorghum, peanuts, maple leaves, and/or corn husk material to a container, creating a vacuum or an inert atmosphere inside the container, applying conventional heating or microwave heating, heating rapidly, and reacting the material and forming silicon carbide (SiC).

Abstract: A method of synthesizing branched gold nanoparticles is described, starting from an aqueous solution of gold nanoparticle spherical seeds, which is subjected to a growth treatment with an aqueous solution comprising hydroxylamine or a salt thereof as a reducing agent and 4-(2-hydroxyethyl)-1-piperazineethanesulfonic acid (HEPES) as an agent that directs the shape of the nanostructure, and by subsequent addition of an aqueous solution of chloroauric acid (HAuCl4). The structural features and the properties of the branched gold nanoparticles obtained by the method of the invention are also described.

Abstract: A material may include a medium and carbon nanotubes dispersed in the medium. Fluorescent moieties may be attached to functional groups on a first quantity of the carbon nanotubes. The fluorescent moieties may be in a concentration in the material sufficient to make the material fluoresce in the presence of radiation. The fluorescent moieties may have an emission wavelength that is in or below the visible spectrum. The carbon nanotubes may be dispersed in the medium in a concentration sufficient to make the material electrically conductive at or above the material's electrical percolation threshold. Any suitable product may include the material. Methods for verifying the authenticity of the product may include detecting emissive radiation, testing electrical conductivity, and determining the presence of a structural characteristic of the carbon nanotubes.

Abstract: Disclosed is a method for preparing hematite iron oxide having various nanostructures, including: preparing a mixture solution by adding iron chloride and caffeine to a solvent and magnetically stirring; and performing hydrothermal synthesis, wherein the solvent is selected from water, ethanol, propanol and methanol. In accordance with the present disclosure, hematite iron oxide (?-Fe2O3) superstructures of various shapes, including grape, cube, dumbbell and microsphere shapes, can be synthesized in different solvents using caffeine. The shapes can be controlled variously via a simple one-step synthesis route without using a growth-inducing agent and without separation based on size. The prepared hematite iron oxide exhibits high coercivity at room temperature owing to its fine crystal structures and anisotropic shapes.

Abstract: In one aspect, the invention relates to an inorganic nanoparticle or nanocrystal, also referred to as a quantum dot, capable of emitting white light. In a further aspect, the invention relates to an inorganic nanoparticle capable of absorbing energy from a first electromagnetic region and capable of emitting light in a second electromagnetic region, wherein the second electromagnetic region comprises an at least about 50 nm wide band of wavelengths and to methods for the preparation thereof. In further aspects, the invention relates to a frequency converter, a light emitting diode device, a modified fluorescent light source, an electroluminescent device, and an energy cascade system comprising the nanoparticle of the invention. This abstract is intended as a scanning tool for purposes of searching in the particular art and is not intended to be limiting of the present invention.

Abstract: Provided is a composite including copper nanoparticles or copper(I) oxide nanoparticles and a thioether-containing organic compound represented by X(OCH2CHR1)nOCH2CH(OH)CH2SZ [X represents an alkyl group; R1 represents a hydrogen atom or a methyl group; n represents an integer of 2 to 100; R1 is independent between repeating units and may be the same or different; and Z represents an alkyl group, an allyl group, an aryl group, an arylalkyl group, —R2—OH, —R2—NHR3, or —R2—(COR4)m (where R2 represents a saturated hydrocarbon group; R3 represents a hydrogen atom, an acyl group, an alkoxycarbonyl group, or a benzyloxycarbonyl group; R4 represents a hydroxy group, an alkyl group, or an alkoxy group; and m represents 1 to 3)].

Abstract: A process for preparing a palladium nanoparticle ink comprises reacting a reaction mixture comprising a palladium salt, a stabilizer, a reducing agent, and an optional solvent to directly form the palladium nanoparticle ink. During the formation of the palladium nanoparticle ink, the palladium nanoparticles are not isolated from the reaction mixture.

Abstract: The invention relates to a method for the preparation of nanoparticles in ionic liquids. Specifically, the invention relates to a simple, quick and effective method for the preparation of dispersions of nanoparticles (nanofluids) in an ionic liquid.

Abstract: The present invention relates to a process for the production of nanoparticles or nanostructured particles with the help of a 2-emulsion method, particles being produced through targeted coalescence of miniemulsions in a high-pressure homogenized.

Abstract: Described herein are methods of controlling metal nanowire morphologies by adjusting the reaction conditions of a polyol synthesis. In particular, by purging the reaction with an inert gas, batch-to-batch consistency can be achieved.

Abstract: A method of preparing a precious metal nitride nanoparticle composition, includes the step of ionizing nitrogen in the gas phase to create an active nitrogen species as a plasma. An atomic metal species of the precious metal is provided in the gas phase. The active nitrogen species in the gas phase is contacted with the atomic metal species of the precious metal in the gas phase to form a precious metal nitride. The precious metal nitride is deposited on the support. Precious metal nanoparticle compositions are also disclosed.

Abstract: Disclosed are an apparatus and a method for manufacturing composite nanoparticles. The apparatus comprises: a first precursor supply unit vaporizing a first precursor and supplying it to a reaction unit; a second precursor supply unit vaporizing a second precursor and supplying it to the reaction unit; the reaction unit producing composite nanoparticles by reacting the vaporized first precursor with the vaporized second precursor; an oxygen supply line supplying an oxygen source to the reaction unit; and a collection unit collecting the composite nanoparticles produced by the reaction unit. Since gas phase synthesis occurs in different stages using the U-shaped reaction chamber, aggregation is prevented and composite nanoparticles of uniform size and high specific surface area can be produced easily.

Abstract: A method for the production of silver nanowire comprising the steps of: heating a first solution comprising a polyol and a salt; adding a second solution comprising a polyol and a silver nitrate; adding a third solution comprising a polyol and an organic polymer as a template carrier creating a combined solution; stirring the combined solution at an elevated temperature for a time period followed by cooling the combined solution; and washing the combined solution and isolating the silver nanowires.

Abstract: Calcium-phosphate based nanoparticles (CAPNP) are synthesized which are simultaneously intrinsically magnetic and fluorescent, and extrinsically surface modified to serve an attachment function. Doping calcium phosphates during colloidal synthesis results in 10 nm particles that are stable in aqueous media and at physiological pH. The scalable, one-step synthesis produces several modified CAPNPs. By introducing metal dopants into the base crystal lattice during synthesis, magnetically, electronically and optically enhanced nanoparticle dispersions were similarly synthesized.

Abstract: The present invention provides a method for producing silver nanoparticles by employing ethanolamine. The method of this invention can be easily operated and no organic solvent is required. Ethanolamine first reacts with a mixture of poly(oxyalkylene)-amine/epoxy or copolymers of poly(styrene-co-maleic anhydride) (abbreviated as SMA) to generate polymeric polymers. The polymeric polymers then reduce silver ions to silver atoms which are dispersed in the form of silver nanoparticles. Functional groups of the polymeric polymers can chelate with silver ions and be stably compatible with water or organic solvents, whereby the silver nanoparticles can be stably dispersed without aggregation and the produced silver nanoparticles.

Abstract: An urchin-like copper oxide material manufacturing method, comprising following steps: providing copper powder of length about 5 to 150 ?m; placing the copper powder on an aluminum oxide plate to be heated up; and heating up the aluminum oxide plate in a reaction temperature of 300° C. to 700° C., to obtain urchin-like copper oxide material on the aluminum oxide plate. By employing the manufacturing method, it only requires a simple thermal oxidation process to synthesize and obtain various types of urchin-like copper oxides having good stability and reproducibility, hereby achieving excellent performance in various opto-electronic applications.

Abstract: A composition containing fine silver particles which have a uniform particle size, can form a fine drawing pattern, and have a small environmental impact, a method for producing that composition, a method for producing fine silver particles, and a paste having fine silver particles are provided. The fine silver particles are produced by carrying out a fluid preparation step of preparing a reduction fluid, a silver reaction step, and a filtration/washing step. The reaction step is carried out by adding an aqueous silver nitrate fluid to a reduction fluid whose temperature has been increased to a range between 40 and 800 ° C. The aqueous silver nitrate fluid is added at a stretch. The composition containing fine silver particles is produced by dispersing the composition containing the fine silver particles in a polar fluid.

Abstract: The various embodiments herein provide a method of producing silver nanoparticles using an electromagnetic levitation melting process. The method comprises levitating and melting a silver sample using a suitable levitation coil and stabilizing a droplet of molten silver. The silver droplet is heated and levitated simultaneously by an induction furnace as a generator. Argon gas is used to provide the inert atmosphere and also applied to cool and condense the silver vapor into a silver nano powder to obtain a silver nano particle. The synthesized silver nanoparticles are collected by brushing them off the brass cylinder using inert gas and are kept in pure Hexane. The size of the nanoparticles is controlled by rate of cooling and heating temperature. The electromagnetic levitation melting method is applied to provide the high purity of silver nano particles with no vacuum equipments.

Abstract: A simple, room-temperature method of producing CuO-doped zinc oxide nanoparticles was established by reacting zinc nitrate hexahydrate, copper nitrate trihydrate and cyclohexylamine (CHA) at room temperature. These nanoparticles may be used for photocatalytic degradation of cyanide in aqueous solutions. The degradation of cyanide is effective because electrons transfer from the p-type copper oxide to the n-type zinc oxide.

Abstract: A method of producing silver nanofilaments that is relatively fast and may be carried out at normal room temperatures (e.g., from about 10° C. to about 25° C.). The method of producing silver nanofilaments includes the steps of adding a solid silver salt to liquid ether to form a mixture, adding a liquid fatty acid to the mixture, adding a reducing agent to the mixture, allowing the ingredients to react, and recovering silver nanofilaments.

Abstract: Described herein is a time-gated, two-step FRET relay effective to provide temporal transference of a prompt FRET pathway, or provide spectro-temporal encoding analytical signals and other information. A FRET relay assembly includes a long lifetime FRET donor (for example, a lanthanide complex), a semiconductor quantum dot (QD) configured as an intermediate acceptor/donor in FRET, and a fluorescent dye configured as a terminal FRET acceptor, wherein the long lifetime FRET donor has an excited state lifetime of at least one microsecond and the QD and fluorescent dye each have excited state lifetimes of less than 100 nanoseconds.

Abstract: The present disclosure provides a method for producing a manganese oxide/graphene nanocomposite including synthesizing a manganese oxide/graphene nanocomposite through liquid phase reaction at a room temperature, a manganese oxide/graphene nanocomposite produced by the method, and an electrode material and a super-capacitor electrode including the manganese oxide/graphene nanocomposite.

Abstract: Carbon nanotube (CNT) yarns and sheets having enhanced mechanical strength using infused and bonded nano-resins. A CNT yarn or sheet is surface-activated to produce open bonds in the CNT walls prior to resin infusion. The CNT yarn or sheet is infused with a low viscosity nano-resin that penetrates spaces between individual CNTs and is cured to cross-link and chemically bond to the CNT walls, either directly or through a functional molecule, to bond the individual CNTs or ropes to each other. The nano-resin can comprise dicyclopentadiene having an uncured viscosity near that of water. The cross-linking process involves ring-opening metathesis polymerization and catalysis of the nano-resin in combination with a functionalizing material such as norbornene, to enhance bonding between the carbon and nano-resin. The process increases load capability, tensile strength, and elastic modulus of the yarns and sheets, for use as a structural component in composite materials.

Abstract: Disclosed is a method for preparing silver nanowire. The method includes: providing a first solution and a second solution; mixing the first solution and the second solution to obtain a third solution including a plurality of silver nanowires; and performing a purification procedure on the third solution to obtain the silver nanowires. Particularly, the first solution includes a capping agent dispersed in a first alcohol solvent, and the second solution includes a silver salt and a metal precursor dispersed in a second alcohol solvent, wherein the metal precursor has a formula: MXn or MXn.m(H2O) wherein M is Cu2+, Sn4+, or Ni2+, X is Cl?, Br?, I?, SCN?, SO42?, NO3?, or C2O42?, n is 1-4, m is 1-6, and M has a valence equal to the absolute value of the product of n and a valence of X.

Abstract: Photocatalytic composite materials, namely materials capable of promoting photo-initiated chemical reactions and processes for producing such materials, are provided. The invention further provides processes for producing photocatalytic composite materials which includes a macroporous matrix, the macroporous matrix having a surface grafting of preformed titanium dioxide nanocrystals, wherein the macroporous matrix may be produced by a sol-gel technique from a precursor of the macroporous matrix in the presence of a template-forming polymer and of hydrophobically-functionalized nano-crystalline titanium-dioxide particles.

Abstract: According to one embodiment, a transparent conductive material is used for a transparent conductive film. The transparent conductive material includes nanographene having a polar group at a surface of the nanographene.

Abstract: A method for preparing magnetic materials is disclosed. The magnetic materials are prepared by implanting low energy magnetic ions into a substrate and annealing with a charged particle beam. Magnetic materials comprising magnetic nanoclusters in the near-surface region of a substrate are also disclosed. The magnetic materials are useful in, for example, magneto-electronic devices such as magnetic sensors.

Abstract: Compositions made by metallothermal reduction from aerogels and phase separated glasses and glass ceramics formed and methods of producing such compositions are provided. The compositions have novel structures that incorporate nanoporous silicon and other metal, metalloid, or metal-oxide nanowires in form of three-dimensional scaffolds. Additional compositions possess unusual photoluminescence properties that indicate possible applications in lighting and electronics.

Abstract: Magnetic ion-exchange polymer microspheres and a method for preparing the same are provided. The method for preparing the magnetic ion-exchange polymer microspheres includes swelling the ion-exchange resins and allowing the magnetic nano-particles to enter the interior of the ion-exchange resins. The magnetic ion-exchange resins of the present invention have various functional groups can be introduced onto the surfaces thereof. Therefore, the magnetic ion-exchange resins of the present invention can be applied in many areas, and thereby they have high economic value.

Abstract: A method for manufacturing a core-shell type supported catalyst, wherein alloy particles having a core-shell structure with a different interior and exterior are supported on a complex carbon support. The method includes: 1) dissolving and dispersing a carbon support in a solvent using a stabilizer; 2) dissolving a core precursor in the solution, and adding a strong reducing agent to reduce and support a transition metal of the core precursor on a surface of the carbon support; 3) filtering and washing the carbon support on which the transition metal is supported; 4) re-dispersing the filtered and washed carbon support in a shell precursor aqueous solution; and 5) adding a weak reducing agent to the solution of step 4) at 60˜80° C. so that metal ions of a shell precursor are selectively reduced and deposited on the transition metal.

Abstract: In various embodiments, methods for synthesizing single-crystalline zero-valent metal nanorings, such as single-crystalline copper nanorings, are described herein. The methods include providing a solution containing a metal cation, a complexing agent bound to the metal cation, thereby forming a metal complex that is at least partially soluble in the solution, and a reducing agent operable for reducing the metal complex to a zero-valent metal and then heating the solution for a sufficient time and at a sufficient temperature until zero-valent metal nanorings form. The solution may be an aqueous solution in an embodiment. Single-crystalline metal nanorings produced by the methods described herein may have a diameter less than about 100 ?m and a wall thickness between about 10 nm and about 500 nm.

Abstract: Silica composite particles include silicon oxide and titanium in an amount of from 0.001% by weight to 10% by weight, wherein the silica composite particles have an average particle diameter of from 30 nm to 500 nm, a particle size distribution index of from 1.1 to 1.5, and an average degree of circularity of primary particles of from 0.5 to 0.85.

Abstract: A thermoelectric material that comprises a ternary main group matrix material and nano-particles and/or nano-inclusions of transition metal oxide dispersed therein. A process for making the thermoelectric material that includes reacting a reduced metal precursor with an oxidized metal precursor in the presence of transition metal oxide nanoparticles.

Abstract: A thermoelectric material that comprises a ternary main group matrix material and nano-particles and/or nano-inclusions of a Group 2 or Group 12 metal oxide dispersed therein. A process for making the thermoelectric material that includes reacting a reduced metal precursor with an oxidized metal precursor in the presence of nanoparticles.

Abstract: A high pressure tubular reactor for production of nanoparticles by precipitation has unidirectional fluid flows of precursor and supercritical water directed from inner and outer coaxial inlets to an outlet via a reaction zone immediately downstream of the inlets. The inner inlet is for supercritical fluid, and the outer inlet is for a precursor.

Abstract: Selective gas-reducing methods for making shape-defined metal-based nanoparticles. By avoiding the use of solid or liquid reducing reagents, the gas reducing reagent can be used to make shape well-defined metal- and metal alloy-based nanoparticles without producing contaminates in solution. Therefore, the post-synthesis process including surface treatment become simple or unnecessary. Weak capping reagents can be used for preventing nanoparticles from aggregation, which makes the further removing the capping reagents easier. The selective gas-reducing technique represents a new concept for shape control of nanoparticles, which is based on the concepts of tuning the reducing rate of the different facets. This technique can be used to produce morphology-controlled nanoparticles from nanometer- to submicron- to micron-sized scale. The Pt-based nanoparticles show improved catalytic properties (e.g., activity and durability).

Abstract: The present invention relates to a process for preparing uniform silver nanoparticles. In particular, the present invention is directed to a process for preparing silver nanoparticles comprising: (i) heating a mixture of a silver precursor and a surfactant under inert atmosphere to prepare silver nanoparticles; and (ii) separating the silver nanoparticles from the reaction products of the step (i).

Abstract: A Fe—Ni compound oxide is used as an oxygen carrier for chemical looping combustion process, wherein the structure of the Fe—Ni compound oxide is a single-phase spinel structure. The method for manufacturing the Fe—Ni compound oxide of the invention includes the following steps: mixing Fe2O3 and NiO to obtain a mixing solution and ball milling the mixing solution by the solid state ball milling method; drying the mixing solution to obtain a precipitate; granulating the precipitate and then calcining the granulated precipitate to obtain the Fe—Ni compound oxide. Accordingly, the Fe—Ni compound oxide manufactured by the method of the invention is provided with high oxidation rate and high reduction rate, and capable of keeping loops and producing hydrogen gas.