Patents Represented by Attorney John J. Tomaszewski
  • Patent number: 5182006
    Abstract: A method for producing smooth metal coatings on zincated aluminum substrates using a specially formulated zincating bath containing an additive comprising a bath soluble cationic condensation polymer represented by the general formula: ##STR1## wherein: Z represents a group of atoms necessary to complete a heterocylic compound having a five or six membered ring containing at least 2 nitrogen atoms;R is nothing or the alkyl group of an alkylating agent;X is Cl, Br or I, andn is >1.
    Type: Grant
    Filed: February 4, 1991
    Date of Patent: January 26, 1993
    Assignee: Enthone-OMI Inc.
    Inventors: Juan Haydu, Vincent Paneccasio, Jr., Patricia A. Cacciatore
  • Patent number: 5141778
    Abstract: A method for producing extremely smooth metal coatings on zincated aluminum substrates using a special double zincating procedure and/or a specially formulated electroless metal plating bath employing a unique plating process.
    Type: Grant
    Filed: January 23, 1991
    Date of Patent: August 25, 1992
    Assignee: Enthone, Incorporated
    Inventors: Eugene F. Yarkosky, Patricia A. Cacciatore
  • Patent number: 5133948
    Abstract: Bismuth impurity is removed from copper electrolyte by contacting the electrolyte with an effective amount of finely divided lead oxide.
    Type: Grant
    Filed: July 11, 1991
    Date of Patent: July 28, 1992
    Assignee: ASARCO Incorporated
    Inventors: Michael G. King, Jonathan S. Jackson, Wing H. Heung
  • Patent number: 5110353
    Abstract: Fume generated by roasting speiss is contacted with an oxygen-containing gas at an elevated temperature for a sufficient time to product arsenic and antimony products which may be separated from each other by means such as condensation. Further, in the roasting of antimony-containing phases (such as speiss) the presence of arsenic can enhance the volatility of the antimony.
    Type: Grant
    Filed: January 29, 1991
    Date of Patent: May 5, 1992
    Assignee: ASARCO Incorporated
    Inventors: Taie Li, Thomas P. Clement, II, John P. Hager
  • Patent number: 5108786
    Abstract: A method for making printed circuit boards wherein the resistance of catalyzed nonconductive surfaces to solutions used in the processing stages, e.g., KOH used to remove an etch resist covering through-holes and the desired circuit lines, is enhanced by treating the catalyzed surface with an accelerator to activate the catalyst, treating the accelerated surface with a reducing agent, followed by baking.
    Type: Grant
    Filed: November 20, 1990
    Date of Patent: April 28, 1992
    Assignee: Enthone-OMI, Inc.
    Inventor: Martin Bayes
  • Patent number: 5108552
    Abstract: A process for electrodespositing a conductive material on a substrate is disclosed which comprises movably mounting the substrate in a first conductive liquid electroplating bath which contains the conductive material, maintaining substantially constant conditions of temperature and liquid circulation in the first bath, passing an electric current through the substrate and the first bath so as to deposit the conductive material on the substrate, periodically transferring the substrate to a second liquid bath, the second bath containing a liquid of the same composition or lower concentrations of dissolved ingredients as compared to the first bath, weighing the substrate when immersed in the second bath and calculating therefrom the weight in air of conductive material deposited, returning the substrate to the first bath, and continuing the plating in a series of stages of plating, weighing in liquid and plating until the desired deposit is built up.Apparatus for carrying on the method is also disclosed.
    Type: Grant
    Filed: July 25, 1991
    Date of Patent: April 28, 1992
    Assignee: Enthone-OMI, Inc.
    Inventor: Guy Desthomas
  • Patent number: 5103892
    Abstract: Continuous casting of discrete solid shapes from a molten material using modified continuous casting machines and processes are disclosed. In a conventional twin belt continuous caster, for example, forming means such as dividers are employed on the upper belt to define a mold cavity in the casting region of the machine. Different size and shape forming means may be used to provide a variety of cast products.
    Type: Grant
    Filed: July 17, 1991
    Date of Patent: April 14, 1992
    Assignee: ASARCO Incorporated
    Inventor: John R. Hugens, Jr.
  • Patent number: 5061351
    Abstract: A vinyl-pyridine or vinyl-quinoline quaternary derivative is provided to enhance the brightness and operating properties of tin aqueous sulfuric acid plating baths.
    Type: Grant
    Filed: July 23, 1990
    Date of Patent: October 29, 1991
    Assignee: Enthone-OMI, Inc.
    Inventors: John H. Commander, Vincent Paneccasio, Jr.
  • Patent number: 5032426
    Abstract: A method and apparatus is provided for applying liquid coatings such as solder masks sequentially to both sides of a printed circuit board substrate whereby only one drying operation would be needed to dry the liquid coatings. An isolation platen having openings corresponding to the coated parts of the board is used to provide a space between the coated part and the opposite side of the platen.
    Type: Grant
    Filed: May 15, 1989
    Date of Patent: July 16, 1991
    Assignee: Enthone, Incorporated
    Inventor: Harold R. Sumner, Jr.
  • Patent number: 4985216
    Abstract: A process is provided for the reduction roasting of ores using a C.sub.2 to C.sub.8 hydrocarbon. The process is particularly applicable to manganese dioxide containing ores and provides enhanced reduction of the manganese to lower oxidation states at low operating temperatures for manganese dioxide ores and provides increased silver recoveries from refractory manganese-silver ores.
    Type: Grant
    Filed: July 20, 1988
    Date of Patent: January 15, 1991
    Assignee: ASARCO Incorporated
    Inventors: Mamdouh M. El Tawil, Adrian E. Albrethsen
  • Patent number: 4956097
    Abstract: A method for waste treating metal containing solutions comprising decomposing the metal from the solution in the substantial absence of air and separating the decomposed (precipitated) metal from the solution.
    Type: Grant
    Filed: October 12, 1989
    Date of Patent: September 11, 1990
    Assignee: Enthone, Incorporated
    Inventor: Constantine I. Courduvelis
  • Patent number: 4936127
    Abstract: The method of making copper rod by rolling is significantly improved by effectively controlling the water-soluble oil emulsion used to lubricate the rolls by employing a conductivity probe to maintain the conductivity of the emulsion within desired operating limits.
    Type: Grant
    Filed: May 25, 1989
    Date of Patent: June 26, 1990
    Assignee: Asarco Incorporated
    Inventor: Darrel W. Breitling
  • Patent number: 4902191
    Abstract: A mobile truck for moving containers and other articles comprising a base, supporting standards at opposite sides of the base, a handle pivotally attached at the upper ends of the standards, a lift supporting member pivotally attached to the handle and to a suitable lifter arm, the lifter arm having attached at one end a lifting device and the other end of the lifter arm being pivotally attached to a connecting bar, with the other end of the connecting bar being pivotally attached to the truck base.
    Type: Grant
    Filed: December 9, 1985
    Date of Patent: February 20, 1990
    Assignee: Asarco Incorporated
    Inventors: Joseph B. Cumbest, Johnnie L. Briggs, Francis R. Jones
  • Patent number: 4891061
    Abstract: Arsenic and antimony are separated from speiss by a roasting operation employing pyrite and coke and the arsenic is separated from the resultant product by a water pressure leaching operation.
    Type: Grant
    Filed: April 21, 1986
    Date of Patent: January 2, 1990
    Assignee: ASARCO Incorporated
    Inventors: Thomas P. Clement, II, John R. Wettlaufer, Jack A. Scott
  • Patent number: 4859300
    Abstract: The permanganate process for treating plastics, e.g., printed circuit boards, to enhance the adhesion of metal plating to the plastic is improved by employing electrolysis to either maintain a certain permanganate level in the operating bath or to regenerate a spent or used bath.
    Type: Grant
    Filed: January 9, 1989
    Date of Patent: August 22, 1989
    Assignee: Enthone, Incorporated
    Inventors: Thomas E. Sullivan, Juan Haydu
  • Patent number: 4840820
    Abstract: A process is provided for improving the electroless nickel plating of aluminum which has been pretreated with a barrier coating such as zinc by employing multiple plating baths under controlled operating conditions.
    Type: Grant
    Filed: October 15, 1985
    Date of Patent: June 20, 1989
    Assignee: Enthone, Incorporated
    Inventors: Paul B. Schultz, Eugene F. Yarkosky
  • Patent number: 4808221
    Abstract: Fume generated by roasting speiss is contacted with an oxygen-containing gas at an elevated temperature for a sufficient time to produce arsenic and antimony products which may be separated from each other by means such as condensation. Further, in the roasting of antimony-containing phases (such as speiss) the presence of arsenic can enhance the volatility of the antimony.
    Type: Grant
    Filed: August 25, 1987
    Date of Patent: February 28, 1989
    Assignee: Asarco Incorporated
    Inventors: Thomas P. Clement, II, Taie Li, John P. Hager
  • Patent number: 4789445
    Abstract: The invention relates to an improved electrodeposition process for the recovery of metals by controlling the concentration of certain impurities in the electrolyte. For a zinc sulfate electrolyte, control of only the antimony impurity level below a predetermined value provides an efficient electrodeposition process.
    Type: Grant
    Filed: November 19, 1986
    Date of Patent: December 6, 1988
    Assignee: ASARCO Incorporated
    Inventors: Martin Goffman, Val Kudryk
  • Patent number: 4775557
    Abstract: A process for specially conditioning and etching a polycarbonate resin prior to metal plating to enhance the coverage and adhesiveness of metal plating to the resin. The swellant composition comprises a compound represented by the general formula,R.sub.1 (OC.sub.n H.sub.2n).sub.m O--R.sub.2wherein R.sub.1 and R.sub.2 are independently selected from the group consisting of aryl groups and alkyl groups of 1-4 carbon atoms, n is 2 to 4 and m is 1 to 5.The swelled resin is then etched using, preferably, a highly alkaline composition such as a solution containing greater than about 100 g/l NaOH. Other etchants such as chromic acid may also be used.The resin is now ready for plating using conventional techniques.
    Type: Grant
    Filed: November 9, 1987
    Date of Patent: October 4, 1988
    Assignee: Enthone, Incorporated
    Inventors: Edwin W. Bastenbeck, Juan Haydu, Richard A. Bellemare, Jr.
  • Patent number: 4753688
    Abstract: A process is provided for increasing the strength of antimony-lead alloys by specially treating an alloy which contains an effective amount of arsenic in the alloy, the process comprising working the alloy, rapidly heat treating the alloy, which includes quenching, for a period of time sufficient to activate a strengthening mechanism in the alloy. The process is especially useful for the manufacture of battery grids on a continuous production line.
    Type: Grant
    Filed: November 28, 1986
    Date of Patent: June 28, 1988
    Assignee: Asarco Incorporated
    Inventor: Michael Myers