Patents Assigned to Chemische Werke Huls, AG
  • Patent number: 4195162
    Abstract: Polylaurolactam powder coating compositions for the coating of metals at high temperatures are obtained by grinding low molecular weight and brittle polylaurolactam with subsequent condensation by heating of the powder to temperatures of below its melting point.A. For the production of pigment free polylaurolactam powders, the low molecular weight granules are ground at temperatures of between 0.degree. and 45.degree. C. which have a relative viscosity of between 1.25 and 1.45 (measured in a 0.5 percent mecresol solution at 25.degree. C.) and have been produced by the polymerization of laurolactam in the presence of 2-10 percent by weight of water, 0.3-0.7 percent by weight of phosphoric acid at temperatures of between 265.degree. and 300.degree. C. in the absence of chain stabilizers under internal pressure, with subsequent granulating, and extraction between 25.degree. and 70.degree. C. with methanol or ethanol. The subsequent condensation is conducted at temperatures of between 140.degree. C.
    Type: Grant
    Filed: July 13, 1978
    Date of Patent: March 25, 1980
    Assignee: Chemische Werke Huls AG
    Inventors: Rainer Feldmann, Hans-Joachim Panoch, Heinz Scholten, Roland Feinauer
  • Patent number: 4190731
    Abstract: The oxo process wherein propene is hydroformylated and then distilled to separate n-butyraldehyde, iso-butyraldehyde, n-butanol, iso-butanol, n-butyl formate, iso-butyl formate and distillation residues having an acid number of about 80 to 130 is improved by adding to the distillation residues molar to twice molar amounts, relative to the acid content, of n-butanol, isobutanol or mixtures thereof, carrying out an esterification in the presence of catalytically active amounts of sulphonic acids at temperatures from about 50.degree. to 200.degree. C., separating off the water of reaction, distilling the esterification reaction product and hydrogenating the distillate thereof.
    Type: Grant
    Filed: September 7, 1978
    Date of Patent: February 26, 1980
    Assignee: Chemische Werke Huls AG
    Inventors: Rudolph Nehring, Manfred zur Hausen, Werner Neumann
  • Patent number: 4172161
    Abstract: An improved method of coating glass bottles by flame spraying with pulverulent copolyamides which uses a copolyamide containing at least 30% by weight of laurolactam. The copolyamides, obtained by the hydrolytic polycondensation process are first subjected to a molecule-orienting treatment, then ground into powders at low temperatures, and these powders are sifted to a particle size distribution so that the proportion of powder having a particle size of between 30 and 100 microns is greater than 70 to 100%, and the proportion of powder having a particle size of less than 30 microns is 0 to 30%.
    Type: Grant
    Filed: July 13, 1977
    Date of Patent: October 23, 1979
    Assignee: Chemische Werke Huls AG
    Inventors: Rainer Feldmann, Karl-Adolf Muller, Hans J. Panoch
  • Patent number: 4143093
    Abstract: Textile fibers and articles having increased dye affinity are prepared by spinning a mixture of 85-97% by weight of poly(ethylene terephthalate) or poly(1,4-cyclohexylenedimethylene terephthalate) and 3-15% by weight of poly(ethylene dodecanedioate) and aftertreating the spun threads in a conventional spun threads in a conventional way.
    Type: Grant
    Filed: March 23, 1978
    Date of Patent: March 6, 1979
    Assignee: Chemische Werke Huls AG
    Inventor: Jorn Ruter
  • Patent number: 4143094
    Abstract: A process for the production of pol-(butylene terephthalate) of sufficiently high molecular weight for subsequent extrusion processing without the need of a solid phase post-condensation and at polycondensation pressures greater than now in general use. Polycondensation is carried out in the presence of small amounts of copolymers of an .alpha.-olefin or styrene with free or esterified maleic acid or anhydride.
    Type: Grant
    Filed: March 25, 1977
    Date of Patent: March 6, 1979
    Assignee: Chemische Werke Huls, AG
    Inventors: Klaus Burzin, Jorn Ruter, Roland Feinauer
  • Patent number: 4143025
    Abstract: Polylaurolactam powder coating compositions for the coating of metals at high temperatures are obtained by grinding low molecular weight and brittle polylaurolactam with subsequent condensation by heating of the powder to temperatures of below its melting point.A. for the production of pigment free polylaurolactam powders, the low molecular weight granules are ground at temperatures of between 0.degree. and 45.degree. C. which have a relative viscosity of between 1.25 and 1.45 (measured in a 0.5 percent m-cresol solution at 25.degree. C.) and have been produced by the polymerization of laurolactam in the presence of 2 - 10 percent by weight of water, 0.3 - 0.7 percent by weight of phosphoric acid at temperatures of between 265.degree. and 300.degree. C. in the absence of chain stabilizers under internal pressure, with subsequent granulating, and extraction between 25.degree. and 70.degree. C. with methanol or ethanol. The subsequent condensation is conducted at temperatures of between 140.degree. C.
    Type: Grant
    Filed: September 10, 1976
    Date of Patent: March 6, 1979
    Assignee: Chemische Werke Huls AG
    Inventors: Rainer Feldmann, Hans-Joachim Panoch, Heinz Scholten, Roland Feinauer
  • Patent number: 4117251
    Abstract: Straight-chain, primary alcohols are prepared by reacting straight-chain 1-bromoalkanes having 6 to 20 carbon atoms with alkali salts of monocarboxylic acids having 4 to 22 carbon atoms in the presence of 1 to 10 mole percent of monocarboxylic acids or alcohols based upon the alkali salt of the carboxylic acid and at temperatures ranging from 150.degree. to 300.degree. C. The esters formed are saponified in alkaline medium to the straight-chain, primary alcohols and separated.
    Type: Grant
    Filed: March 17, 1977
    Date of Patent: September 26, 1978
    Assignee: Chemische Werke Huls AG
    Inventors: Manfred Kaufhold, Gottfried Bankwitz
  • Patent number: 4115530
    Abstract: Process for the production of gaseous hydrogen chloride by extraction of dilute aqueous hydrochloric acid with amines.(a) The aqueous hydrochloric acid is extracted with an amine or with a mixture of an amine and an inert organic solvent which is immiscible with water and has a lower boiling point than the amine employed, the amines utilized being tertiary alkyl amines, tertiary aryl dialkyl amines, secondary arylalkyl amines, primary alkylaryl amines, or mixtures thereof, which contain 14-32 carbon atoms in the nitrogen-bound side chains, and among these at most one nitrogen-bound methyl group and at least one aliphatic residue containing at least 6 carbon atoms, and wherein the acid constant K.sub.a of the amine is smaller than 10.sup.-3.(b) An inert, water-immiscible organic solvent which has a lower boiling point than the amine employed is added to the extract, unless the solvent has already been added in stage (a).
    Type: Grant
    Filed: July 14, 1977
    Date of Patent: September 19, 1978
    Assignee: Chemische Werke Huls AG
    Inventors: Alfred Coenen, Kurt Kosswig, Gunter Prominski
  • Patent number: 4115460
    Abstract: Method for producing hexachlorocyclobutene from hexachlorobutadiene, wherein technical hexachlorobutadiene is rectified at a pressure of 2-10 mm Hg with a reflux ratio of 300-600, and the hexachlorobutadiene remaining in the sump during this procedure, after a heat treatment at 150.degree.-200.degree. C., is recycled into the rectifying column together with fresh, technical hexachlorobutadiene. The product rich in hexachlorocyclobutene, withdrawn overhead, is optionally subjected to a fractional crystallization.
    Type: Grant
    Filed: February 28, 1977
    Date of Patent: September 19, 1978
    Assignee: Chemische Werke Huls AG
    Inventor: Wolfgang Muller
  • Patent number: 4115640
    Abstract: The rheological properties of paste-formable, powdered polymerizates produced by polymerizing vinyl chloride or a mixture of vinyl chloride and a copolymerizable monomer in an aqueous emulsion in the presence of a water-soluble catalyst and an alkali metal salt of a fatty acid as the polymerization emulsifier and spray drying the resultant polymerizate, are improved by treating the powdered polymerizate with a gas which forms an acid in an aqueous solution.
    Type: Grant
    Filed: September 13, 1976
    Date of Patent: September 19, 1978
    Assignee: Chemische Werke Huls AG
    Inventor: Josef Kalka
  • Patent number: 4104261
    Abstract: An improvement in the process of melt spinning ethylene terephthalate polyester to produce textile fibers with decreased pilling in the threads, fibers or fabrics made therefrom. The ethylene terephthalate is melt polymerized in the presence of a condensation catalyst to a final temperature of about 250.degree.-300.degree. C and a final pressure of less than 10 mm mercury to form an anhydrous melt. A vinyl copolymer having more than two carboxyl and/or hydroxyl groups is added to the melt polymerization at a concentration of about 0.005 to 2.0 percent referred to the dicarboxylic acid component. Melt spinning of the modified polyester is then carried out. The vinyl copolymer has the following general formula- ##STR1## where N IS AN INTEGER FROM 10 TO 10,000;a is zero or an integer from 1 to 100;b is an integer from 1 to 100;R.sup.1 through R.sup.6 are hydrogen, an alkyl group with 1 to 3 carbon atoms or an oxalkyl group -OR.sup.7 ;R.sup.
    Type: Grant
    Filed: January 21, 1977
    Date of Patent: August 1, 1978
    Assignee: Chemische Werke Huls, AG
    Inventors: Karl-Heinz Magosch, Roland Feinauer, Jorn Ruter