Abstract: A hydrolysis resistant aqueous emulsion includes a hydrolyzable silicon containing compound. This emulsion is formed by a method that includes the step of (A) forming a seed emulsion that includes (1) an emulsifier, (2) water, and (3) a first oil phase. The method also includes the step of (B) adding a second oil phase, including a hydrolyzable silicon containing compound, to the seed emulsion. A weight ratio of the second oil phase including the hydrolyzable silicon containing compound to the first oil phase in the seed emulsion is from 0.5 to 50. Moreover, a total weight of the first and second oil phases in the emulsion is at least 60 weight percent.

Abstract: A hardcoat comprising a host matrix, a nanoporous filler in which the dispersed phase is a gas, and nonporous nanoparticles. Also, coating and curable compositions useful for preparing the hardcoat, methods of preparing the hardcoat and compositions, articles comprising the hardcoat or composition, and uses thereof.

Abstract: An alkoxy-functional organopolysiloxane resin and polymer is disclosed that comprises the reaction product of a reaction of (i) an alkenyl-functional siloxane resin comprising R3SiO1/2 units and SiO4/2 units; (ii) an alkoxysilane-functional organosiloxane compound having at least one silicon-bonded hydrogen atom at a molecular terminal; (iii) an endcapper according to the formula to the formula R23Si—(R22SiO)s—SiR22H or R23Si—(R22SiO)t—(HR2SiO)—SiR23, or combinations thereof; and (iv) a polyorganosiloxane having an average, per molecule, of at least 2 aliphatically unsaturated organic groups in the presence of a (v) hydrosilylation catalyst. In this alkoxy-functional organopolysiloxane resin and polymer, each R2 is independently a hydrocarbon radical and the subscripts s and t independently have values ranging from 0 to 10.

Abstract: Silicone acrylate copolymer composition, namely, silicone resin-acrylate copolymers and methods of preparing the same. The silicone acrylate composition may include a silicone resin coupled with an acrylate polymer via a linking group. The silicone acrylate composition may be formed by preparing an acrylate or a (meth)acrylate functional resin and carrying out acrylate polymerization in the presence of a functionalized resin. A silane-functional acrylate polymer may be prepared, followed by a reaction to couple a resin to the silane-functional acrylate polymer. The resulting copolymer may then be used as desired, e.g., added to a silicone and acrylate mixture to create a non-separating blend.

Abstract: The present disclosure relates to a method of making an optical assembly. An optical device is secured in a fixture, the optical device having an optical surface, wherein a silicone film is positioned with respect to the optical surface, the silicone film having a distal surface relative to the optical surface. The method includes, among other features, imprinting the distal surface of the silicone film to create a surface imprint in the distal surface of the silicone film.

Abstract: Aminofunctional silicone compositions are disclosed comprising: an organopolysiloxane having an average formula of (CH3)3SiO[(CH3)2SiO]x [(CH3)RNSiO]ySi(CH3)3 with less than 1 weight % of nitrogen in its formula, where RN is an aminofunctional group, x is ?100, y is ?1 with the proviso the sum of x+y is from 250 to 350; wherein the viscosity of the silicone composition ranges from 1000 to 2500 cP at 25° C. and is measured by a Brookfield RV DV viscometer equipped with Pro CP 52 spindle at 20 RPM; and the aminofunctional silicone composition contains less than 0.1 weight % of D4 and less than 0.1 weight % D5 cyclic siloxanes.

Abstract: An anchor for securing together interior and exterior building components includes a first end having an outer side for engaging the interior building component and an inner side opposite the outer side. The anchor further includes a second end having an outer side and an inner side opposite the outer side of the second end for engaging the exterior building component. A thermal break for reducing thermal bridging between the exterior and interior building components is disposed in a space between the inner sides of the ends and has a first coupling surface bonded to the inner side of the first end and a second coupling surface bonded to the inner side of the second end. An assembly includes the anchor for securing together the interior and exterior building components.

Abstract: Chemical processes comprise selectively synthesizing diisopropylamino-disilanes and reduction of chloride in aminosilanes, and the compositions comprise the diisopropylamino-disilanes and at least one reaction by-product prepared thereby. The diisopropylamino-disilanes are diisopropylamino-pentachlorodisilane and diisopropylamino-disilane.

Abstract: A photovoltaic cell module, a photovoltaic array including at least two modules, and a method of forming the module are provided. The module includes a first outermost layer and a photovoltaic cell disposed on the first outermost layer. The module also includes a second outermost layer disposed on the photovoltaic cell and sandwiching the photovoltaic cell between the second outermost layer and the first outermost layer. The method of forming the module includes the steps of disposing the photovoltaic cell on the first outermost layer, disposing a silicone composition on the photovoltaic cell, and compressing the first outermost layer, the photovoltaic cell, and the second layer to form the photovoltaic cell module.

Abstract: The present invention relates to methods of separating one or more components from a feed composition, methods of desorbing one or more components from an absorbent fluid, as well as systems and apparatus that can carry out the methods. In one embodiment, the present invention provides a method of separating one or more components from a feed composition including contacting at least some of a first component of a feed composition including the first component with an absorbent fluid, to provide a contacted composition and a used absorbent fluid including at least some of the first component contacted with the absorbent fluid. In some embodiments the absorbent fluid can be an organosilicon fluid including an organosilicon including at least one of a hydroxy group, an ether group, an acrylate group, a methacrylate group, an acrylamide group, a methacrylamide group, and a polyether group.

Abstract: A method for decreasing the vapor permeability of a water and air barrier treated substrate that includes treating the substrate with a liquid applied, vapor permeable air and water barrier coating composition comprising a cross-linked polysiloxane dispersion composition.

Abstract: A method of making a diakyl-, diaryl-, or alkylaryl-dihalosilane in a Grignard coupling reaction with a high degree of selectivity is provided. More specifically, a Grignard reagent comprising an alkyl- or aryl-magnesium halide is allowed to react with an alkyl- or aryl-trihalosilane precursor or reagent to produce a product mixture of R2SiX2 and R3SiX, wherein each R is independently selected to be an alkyl or aryl group and X is a halogen group, such that the R2SiX2 product is formed with a high degree of selectivity. High selectivity is defined as the mass ratio of R2SiX2 product to the R3SiX product that is formed in the reaction being greater than 7:1.

Abstract: A cross-linked composition comprises the reaction product of a first reactant having at least one hydroxyl or amine (functional) group, a second reactant having at least one hydroxyl or amine (functional) group, and a siloxane having at least two terminal anhydride groups reactive with the functional groups of the first and second reactants. The first reactant is selected from the group of first siloxanes having at least one hydroxyl or amine group, a first organic alcohol having at least one hydroxyl group, a first organic amine having at least one amine group, or combinations thereof. The second reactant is selected from the group of second siloxanes having at least one hydroxyl or amine group, a second organic alcohol having at least one hydroxyl group, a second organic amine having at least one amine group, or combinations thereof. If utilized, the first siloxanes and/or second siloxanes are different from the siloxane.

Abstract: Provided in various embodiments are compositions for topical application to the skin of a mammal, methods for their preparation, and their uses in skin care compositions to reduce adhesion of unwanted particles to the skin. When a hydrophobic non-volatile solvent and a hydrophobic non-volatile high melting point material with a melting point in the range of 60° C. and 100° C. are combined with a hydrophobic volatile solvent which compatibilizes the hydrophobic non-volatile solvent and the hydrophobic non-volatile high melting point material and the hydrophobic non-volatile high melting point material is selected to be at least partially incompatible with the hydrophobic non-volatile solvent in the absence of the hydrophobic volatile solvent, the resulting composition may be applied to skin to reduce adhesion of unwanted particles to the skin.

Abstract: Described are hydrosilylation-curable polyorganosiloxane compositions containing sulfur, including hydrosilylation-curable polyorganosiloxane prepolymers and hydrosilylation-cured polyorganosiloxane polymer products made therefrom, as well as methods of preparing and using the same, devices comprising or prepared from the same, and sulfur-functional organosiloxanes useful therein.

Abstract: The present invention provides an optical member comprising a silicone material having excellent antifouling property while having good light transmittance, heat resistance, and strength, and an optical semiconductor device and illumination apparatus having excellent antifouling property. The present invention is an optical member comprising a silicone material containing a fluorinated surface, the proportion of F atoms being from 0.1 to 45 at % and/or the ratio of F atoms relative to C atoms being from 0.01 to 1.00 in the atomic composition percentage according to X-ray photoelectron spectroscopy (XPS) of the fluorinated surface.

Abstract: Vacuum lamination methods for forming conformally coated articles having a preformed lamination layer conformally coated to or on an object such as an LED array are provided. These vacuum lamination methods utilize a single heating step to heat a middle portion of the preformed lamination layer to a flowable condition prior to the preformed lamination layer being conformally coated over the article, such as the array of light emitting diodes disposed on an inner portion of a first side of a submount wafer.

Abstract: A one or more component moisture cure Organosiloxane composition that has strength in an uncured state (commonly referred to in the industry as “green strength”) and its uses. The composition comprises an organopolysiloxane polymer having a viscosity of at least 1000 mPa·s at 25° C. and not less than two silicon-bonded hydroxyl groups and/or silicon bonded hydrolysable groups; a suitable catalyst; a cross-linker adapted to react with organopolysiloxane polymer when catalysed with the catalyst; and optionally one or more rheology modifiers and 0 to 10% by weight of the composition of one or more extenders or plasticisers but in particular the composition contains a precipitated calcium carbonate filler in an amount of from 50 to 70 weight % of the total composition.

Abstract: A method of forming an SiC crystal including placing in an insulated graphite container a seed crystal of SiC, and supporting the seed crystal on a shelf, wherein cushion rings contact the seed crystal on a periphery of top and bottom surfaces of the seed crystal, and where the graphite container does not contact a side surface of the seed crystal; placing a source of Si and C atoms in the insulated graphite container, where the source of Si and C atoms is for transport to the seed crystal to grow the SiC crystal; placing the graphite container in a furnace; heating the furnace; evacuating the furnace; filling the furnace with an inert gas; and maintaining the furnace to support crystal growth to thereby form the SiC crystal.

Abstract: A method of making a trihalosilane comprising contacting an organotrihalosilane according to the formula RS1X3 (I), wherein R is C1-C10 hydrocarbyl and each X independently is halo, with hydrogen, wherein the mole ratio of the organotrihalosilane to hydrogen is from 0.009:1 to 1:2300, in the presence of a catalyst comprising a metal selected from (i) Re, (ii) a mixture comprising Re and at least one element selected from Pd, Ru, Mn, Cu, and Rh, (iii) a mixture comprising Ir and at least one element selected from Pd and Rh, (iv) Mn, (v) a mixture comprising Mn and Rh, (vi) Ag, (vii) Mg, and (viii) Rh at from 300 to 800° C. to form a trihalosilane.