Patents Assigned to Henkel & Cie G.m.b.H.
-
Patent number: 3984543Abstract: Therapeutic methods employing cyclic aminophosphonic acids having the formula ##EQU1## wherein R is a member selected from the group consisting of hydrogen and alkyl having from 1 to 6 carbon atoms and n is an integer from 1 to 4; as well as their water-soluble salts. The cyclic aminophosphonic acids are excellent sequestering agents especially for alkaline earth metal ions, useful in cosmetic preparations such as toothpastes and mouthwashes where they prevent formation of tartar and plaque and in therapy in the treatment of diseases related to the abnormal deposition or dissolution of difficulty soluble calcium salts in the animal body.Type: GrantFiled: August 1, 1975Date of Patent: October 5, 1976Assignee: Henkel & Cie G.m.b.H.Inventors: Walter Ploger, Manfred Schmidt-Dunker, Christian Gloxhuber
-
Patent number: 3984385Abstract: Organic sulfonic acid hydrazides are accelerators for aerostable anaerobically-setting adhesive compositions. They can be used with stabilizers. Preferred hydrazides of this group are the aryl sulfonic acid hydrazides, for example benzene sulfonic acid hydrazide. These provide rapid setting time with good ultimate strength, and have little adverse effect on the storage stability of the compounds when access of air is permitted.Type: GrantFiled: August 25, 1975Date of Patent: October 5, 1976Assignee: Henkel & Cie G.m.b.H.Inventors: Werner Gruber, Joachim Galinke, Jurgen Keil
-
Patent number: 3980045Abstract: A process and an apparatus for the application of liquid freshening, brightening or finishing agents to textile threads or yarn, in which a free-falling jet of liquid is directed onto the threads with the additional use of reduced pressure.Type: GrantFiled: April 29, 1975Date of Patent: September 14, 1976Assignee: Henkel & Cie G.m.b.H.Inventor: Wolfgang Zollner
-
Patent number: 3979385Abstract: A process for the production of 1-aminoalkane-1,1-diphosphonates of the formula ##SPC1##Wherein R.sub.1 is a member selected from the group consisting of hydrogen, lower alkyl and phenyl, R.sub.2 and R.sub. 3 are members selected from the group consisting of hydrogen, alkyl having 1 to 22 carbon atoms, cycloalkyl having 5 to 6 carbon atoms, phenyl, alkylphenyl having 7 to 18 carbon atoms, phenylalkyl having 7 to 18 carbon atoms and together with the nitrogen atom, piperidino, pyrrolidino and morpholino, and X is a member selected from the group consisting of hydrogen, alkali metal, ammonium, pyridinium, guanidinium and mono-, di-, and tri-lower-alkanol-ammonium with the proviso that at least one of R.sub.1, R.sub.2 and R.sub.Type: GrantFiled: May 31, 1974Date of Patent: September 7, 1976Assignee: Henkel & Cie G.m.b.H.Inventors: Klaus Wollmann, Walter Ploger, Karl-Heinz Worms
-
Patent number: 3977859Abstract: Antimicrobial and algicidal compositions active against bacteria, fungi and algae containing from 0.1% to 10% by weight of reaction products of .epsilon.-caprolactam with N-alkylalkylene diamines of the formula ##EQU1## wherein R denotes a straight- or branch-chained, saturated or unsaturated aliphatic hydrocarbon substituent with 10 to 18 carbon atoms, R.sub.1 denotes hydrogen or an aliphatic hydrocarbon substituent with 1 to 4 carbon atoms, where n is an integer of from 2 to 6, preferably 3, and where the molar ratio of the reaction partners N-alkylalkylene diamine: .epsilon.-caprolactam is 1:1 to 1:10, and the reaction is carried out for 3 to 20 hours in the liquid phase at temperatures above 180.degree.C, preferably at about 250.degree.C. These reaction products are useful in compositions to prevent the growth of microorganisms, such as bacteria, fungi and algae.Type: GrantFiled: April 16, 1975Date of Patent: August 31, 1976Assignee: Henkel & Cie G.m.b.H.Inventors: Hans-Werner Eckert, Gunter Koppensteiner
-
Patent number: 3975280Abstract: A storage-stable, readily-soluble detergent additive comprising particles, at least 70% of which have a diameter within the range of 0.1 mm to 1 mm consisting of from 1% to 75% by weight of at least one active material enhancing the washing, bleaching or biocidal effects of a detergent, substantially surrounded by and embedded in from 25% to 99% by weight of an enveloping material consisting of a mixture ofA. from 20% to 90% by weight of said mixture of at least one compound having a melting point above 30.degree.C, selected from the group consisting of fatty acids and fatty alcohols,B. from 0 to 50% by weight of said mixture of at least one water-soluble compound selected from the group consisting of poly-oxy-lower alkylene glycols, non-ionic surface-active compounds and anionic surface-active compounds, andC.Type: GrantFiled: March 19, 1975Date of Patent: August 17, 1976Assignee: Henkel & Cie G.m.b.H.Inventors: Klaus Hachmann, Gunther Jakobi, Rudolf Weber, Alexander Boeck, Dieter Jung
-
Patent number: 3971626Abstract: A process for preparing waterproof leathers by fat-liquoring with an aqueous liquor containing esters of citric acid with higher fatty alcohols which are used as the impregnating agent, characterized in that the fat-liquoring agent contains a mixture emulsified in water which consists of (A) an acid ester of citric acid with a higher fatty alcohol having chain lengths of 12 to 22 carbon atoms and (B) an organic alcohol solvent for the citric acid ester which is totally or partially soluble in water and which have a boiling point above 100.degree.C.Type: GrantFiled: October 29, 1974Date of Patent: July 27, 1976Assignee: Henkel & Cie G.m.b.H.Inventors: Rudi Heyden, Adolf Asbeck
-
Patent number: 3969417Abstract: This invention relates to an improvement in the process of alkoxylation of compounds containing alcoholic hydroxyl groups by reacting compounds containing hydroxyl groups with alkylene oxides in the presence of alkoxylation catalysts. The said improvement involves the use of a tertiary oxonium salt with a substantially non-polarizable halogeno-complex anion as the said alkoxylation catalyst. Use of such catalysts gives lower amounts of unreacted alcohols in the products, particularly when secondary alkanols of 8 to 24 carbon atoms are employed.Type: GrantFiled: April 3, 1975Date of Patent: July 13, 1976Assignee: Henkel & Cie G.m.b.H.Inventors: Wilfried Umbach, Werner Stein
-
Patent number: 3969134Abstract: Process for rinsing of dishes in dishwashing machines having one or several clear-rinsing cycles using an aqueous solution of an adduct of from 5 to 20 moles of ethylene oxide and from 1 to 10 moles of propylene oxide to a secondary alkanol with a linear alkane chain of from 10 to 20 carbon atoms as clear-rinsing agents for use in the process.Type: GrantFiled: February 11, 1972Date of Patent: July 13, 1976Assignee: Henkel & Cie G.m.b.H.Inventors: Heimold Batka, Theodor Altenschopfer
-
Patent number: 3967999Abstract: A high-frequency plastic welding flux, characterized in that the dispersion contains a redispersible powder of a polymer prepared by suspension polymerization which consists of polyvinyl chloride and/or copolymers of vinyl chloride with monomers copolymerizable with vinyl chloride; as well as a process for using this flux for high-frequency welding.Type: GrantFiled: October 29, 1974Date of Patent: July 6, 1976Assignee: Henkel & Cie G.m.b.H.Inventors: Dieter Sommerfeld, Bernhard Kowald, Monika Winkels
-
Patent number: 3966968Abstract: This invention relates to N,N'-disubstituted thioureas of the formula ##SPC1##Where X represents CO, SO.sub.2 or CH.sub.2, R' represents lower alkyl, a heterocycle or a possibly substituted phenyl, and R.sub.1, R.sub.2, and R.sub.3 represent hydrogen, lower alkyl, chlorine, bromine, nitro and carboxyl; as well as their methods of production and their use as antimicrobial substances, particularly against gram positive bacteria.Type: GrantFiled: December 18, 1973Date of Patent: June 29, 1976Assignee: Henkel & Cie G.m.b.H.Inventors: Hans Andree, Gunther Koppensteiner, Heinz-Ulrich Stracke
-
Patent number: 3965265Abstract: A process for the prevention of the growth of microorganisms, especially in industrial water, comprises contacting these microorganisms with an effective antimicrobial amount of a reaction product of .epsilon.-caprolactam and an N-alkylalkylene diamine with the reaction being carried out in the liquid phase for 3 to 20 hours at a temperature about 180.degree.C. The process further comprises incorporating into said industrial water an effective amount of a sequestering agent comprising a water-soluble phosphonic acid which forms a complex with a divalent metal, a water-soluble salt of the acid and the mixtures thereof, with the weight ratio of sequestering agent to reaction product being 1:10 to 10:1.Type: GrantFiled: January 20, 1975Date of Patent: June 22, 1976Assignee: Henkel & Cie G.m.b.H.Inventors: Gunter Koppensteiner, Hans-Werner Eckert, Volker Wehle
-
Patent number: 3965171Abstract: A process for the production of ether polycarboxylic acids comprising reacting alkali metal salts of ether carboxylic acids with carbon dioxide in the presence of a silicon compound selected from the group of alkali metal alkoxy-silanolates and alkali metal alkoxy-polysiloxanolates and, optionally, inert diluents at temperatures of 200.degree. to 350.degree.C under pressure, acidify the resulting alkali metal salt of an ether polycarboxylic acid and recovering said ether polycarboxylic acid.Type: GrantFiled: September 25, 1975Date of Patent: June 22, 1976Assignee: Henkel & Cie G.m.b.H.Inventor: Horst-Jurgen Krause
-
Patent number: 3965024Abstract: Washing agent compositions and washing assistant compositions containing from 0.5% to 70% by weight of a phosphonopolycarboxylate having the formula ##EQU1## WHEREIN Me is H, alkali metal, or H.NR.sub.3, R.sub.1 is H or CH.sub.3, R.sub.2 is H, alkyl having 1 to 4 carbon atoms or --CH.sub.2 --CHR--COOMe, R.sub.3 is H, alkyl or alkylol having 1 to 6 carbon atoms, and X is a direct bond or the groups ##EQU2## from 0 to 96.5% of other sequestering and non-sequestering, preferably phosphorus-free builders, and from 3% to 45% by weight of at least one surface-active compound of an anionic or non-ionic nature, whereby a 1% aqueous solution thereof has a pH of between 6 and 11.5. Preferably said phosphonopolycarboxylate sequestering agents are present as water-soluble salts capable of complex formation with alkaline earth metal ions. The invention also resides in the process of sequestering alkaline earth metal ions using aqueous solutions of the washing agent composition.Type: GrantFiled: November 21, 1973Date of Patent: June 22, 1976Assignee: Henkel & Cie G.m.b.H.Inventors: Edmund Schmadel, Gunter Jakobi, Karl-Heinz Worms, Helmut Blum
-
Patent number: 3965170Abstract: A process for the production of ether polycarboxylic acids comprising reacting alkali metal salts of ether carboxylic acids with carbon dioxide in the presence of an alkali metal alkoxy-silano-carbonate and, optionally, inert diluents at temperatures of 200.degree.C to 350.degree.C under pressure, acidify the resulting alkali metal salt of an ether polycarboxylic acid and recovering said ether polycarboxylic acid.Type: GrantFiled: September 25, 1975Date of Patent: June 22, 1976Assignee: Henkel & Cie G.m.b.H.Inventor: Horst-Jurgen Krause
-
Patent number: 3962433Abstract: A method for the treatment of diseases relating to the abnormal deposition or dissolution of difficutly soluble calcium salts in the body of warm-blooded animals which consists of administering orally, parenterally or topically to said warm-blooded animals, a safe but effective amount of at least one pharmacologically acceptable phosphonoalkane-polycarboxylic acid and water-soluble salts thereof.Type: GrantFiled: December 3, 1974Date of Patent: June 8, 1976Assignee: Henkel & Cie G.m.b.H.Inventors: Karl-Heinz Worms, Christian Gloxhuber, Manfred Schmidt-Dunker, Helmut Blum
-
Patent number: 3961634Abstract: Process and composition for bleaching hair containing oxidizing agents which liberate active oxygen, and which contain keratose so as to reduce damage to the hair.Type: GrantFiled: July 23, 1974Date of Patent: June 8, 1976Assignee: Henkel & Cie G.m.b.H.Inventor: Peter Busch
-
Patent number: 3962116Abstract: Heat dried, finely-divided compositions of optical brighteners and fillers comprising as said fillers at least partly of a finely-divided water-insoluble silicate compound containing at least some combined water and having a calcium binding power of at least 50 mg CaO/gm of anhydrous active substance and the formula on the anhydrous basis(M.sub.2 /.sub.n O).sub.x . Me.sub.2 O.sub.3 . (SiO.sub.2).sub.ywhere M is a cation of the valence n, exchangeable with calcium, x is a member of from 0.7 to 1.5, Me is a member selected from the group consisting of aluminum and boron, and y is a number from 0.8 to 6, preferably from 1.3 to 4, in an amount of at least 5% by weight of the mixture, as well as a process for producing the same comprising the steps of mixing said silicate compound, while at least still moist from its production, with said optical brighteners and converting the entire mixture of components into a pourable product.Type: GrantFiled: January 15, 1975Date of Patent: June 8, 1976Assignees: Henkel & Cie G.m.b.H., Deutsche Gold- und Silber-Scheideanstalt vormals RoesslerInventors: Helmut Bloching, Heinz Smolka, Milan Johann Schwuger
-
Patent number: 3962432Abstract: A method for the treatment of diseases relating to the abnormal deposition or dissolution of difficulty soluble calcium salts in the body or mouths of warm-blooded animals which consists of administering orally, parenterally or topically to said warm-blooded animals, a safe but effective amount of at least one pharmacologically acceptable aminoalkane diphosphonic acid derivative or a water-soluble salt thereof.Type: GrantFiled: December 3, 1974Date of Patent: June 8, 1976Assignee: Henkel & Cie G.m.b.H.Inventor: Manfred Schmidt-Dunker
-
Patent number: 3960888Abstract: Pyrrolidone-5,5-diphosphonic acids having the formula ##EQU1## wherein R is a member selected from the group consisting of hydrogen and alkyl having from 1 to 6 carbon atoms; as well as their water-soluble salts. The pyrrolidone-5,5-diphosphonic acids are excellent sequestering agents especially for alkaline earth metal ions. They are stabilizers for percompounds and are useful in the delaying of the setting times for gypsum. In addition, the compounds are useful as cosmetic preparations such as toothpastes and mouthwashes where they prevent formation of tartar and plaque and are useful in therapy in the treatment of diseases related to the abnormal deposition or dissolution of difficultly soluble calcium salts in the animal body.Type: GrantFiled: August 20, 1974Date of Patent: June 1, 1976Assignee: Henkel & Cie G.m.b.H.Inventors: Walter Ploger, Manfred Schmidt-Dunker, Christian Gloxhuber