Patents Assigned to Monosol, LLC.
  • Patent number: 11473039
    Abstract: The present disclosure relates to pouches made from a combination of chemically different water-soluble films and optionally containing a composition (e.g. a household care composition or non-household care composition) that is at least partially enclosed by the water-soluble films in at least one compartment.
    Type: Grant
    Filed: October 14, 2019
    Date of Patent: October 18, 2022
    Assignee: MONOSOL, LLC
    Inventors: Philip Frank Souter, Robby Renilde Francois Keuleers, Regine Labeque, Florence Catherine Courchay, Marc Rene Bert Renmans, David M. Lee, Steven G. Friedrich, Lee K. Yeung, Shinsuke Nii
  • Patent number: 11459433
    Abstract: A water-soluble film including a polyvinyl alcohol copolymer resin, a plasticizer, an anti-block filler, and a release modifier is disclosed herein. Also disclosed are related packets incorporating the film, and related methods of making and using the film and packets.
    Type: Grant
    Filed: September 11, 2020
    Date of Patent: October 4, 2022
    Assignee: MONOSOL, LLC
    Inventors: Shinsuke Nii, David M. Lee, Jennifer L. Childers
  • Patent number: 11453754
    Abstract: Disclosed herein are water-soluble films including a polyvinyl alcohol (PVOH) resin blend and optionally one or more additional components such as plasticizers, fillers, surfactants, and other additives. The PVOH resin blend includes a first copolymer including a first anionic monomer unit and a second PVOH copolymer including a second anionic monomer unit. When the PVOH copolymers are blended in particular proportions and/or selected with regard to various criteria related to physical and chemical film properties, the resulting water-soluble film formed from the PVOH resin blend exhibits maintained film stiffness, and pouch tautness when in contact with liquid pouch contents, maintain acceptable clarity properties, and/or demonstrate acceptable band release without impairing the ultimate solubility of the water-soluble film.
    Type: Grant
    Filed: April 12, 2019
    Date of Patent: September 27, 2022
    Assignee: MONOSOL, LLC
    Inventors: Jennifer L. Childers, Richard Goetz, Percy Bromby, II, Akio Nishimi, Mitsunori Asada, David M. Lee
  • Publication number: 20220228305
    Abstract: The disclosure provides a nonwoven web, said nonwoven web including a plurality of fibers including a blend of fiber forming materials, the blend of fiber forming materials including a first polyvinyl alcohol polymer. The blend of fiber forming materials further comprises a second polyvinyl alcohol polymer or does not include carboxymethyl cellulose, hydroxypropyl methylcellulose or starch. The nonwoven web can be water-dispersible, optionally water-soluble, and/or flushable. The disclosure further provides a pouch including a nonwoven web including a plurality of fibers according to the disclosure. In some embodiments, the water dispersible pouch can include a laminate comprising a water-soluble film and a nonwoven web of the disclosure.
    Type: Application
    Filed: April 24, 2020
    Publication date: July 21, 2022
    Applicant: MONOSOL, LLC
    Inventors: Victoria BRIDEWELL, Richard GOETZ, Nicholas ZEESE, Jonathon KNIGHT, Yoshimi NONAKA, Naoyuki IWACHIDO
  • Patent number: 11352468
    Abstract: Perfume microcapsule-containing films, related solutions, and containers including the films (e.g. detergent packets) are disclosed, together with their methods of preparation and use.
    Type: Grant
    Filed: April 18, 2017
    Date of Patent: June 7, 2022
    Assignees: MONOSOL, LLC, Givaudan SA
    Inventors: David M. Lee, Yashodhan S. Parulekar, Jonathon Knight, Stephanie Kolb
  • Publication number: 20220074083
    Abstract: Methods of treating fibers comprising a polymer including at least one of a vinyl acetate moiety or a vinyl alcohol moiety, and resulting fibers or the products comprising the resulting fibers are disclosed. In an example embodiment, a method of treating fibers includes contacting a surface of a fiber comprising the polymer with a modification agent to chemically modify at least a portion of the polymer with the modification agent in a region of the fiber comprising at least the surface of the fiber to form a modified fiber.
    Type: Application
    Filed: September 3, 2021
    Publication date: March 10, 2022
    Applicant: MONOSOL, LLC
    Inventors: Nicholas ZEESE, Jonathon Knight, Richard Goetz, Victoria Bridewell, Alyssa Shuey
  • Publication number: 20220074130
    Abstract: Methods of treating fibers comprising a polymer including at least one of a vinyl acetate moiety or a vinyl alcohol moiety, and resulting fibers or the products comprising the resulting fibers are disclosed. In an example embodiment, a fiber having a surface region and an interior region, includes a polymer comprising at least one of a vinyl acetate moiety or a vinyl alcohol moiety chemically modified with a modification agent. The fiber has a transverse cross-section including the interior region comprising the polymer having a first degree of modification and the surface region comprising the polymer having a second degree of modification greater than the first degree of modification.
    Type: Application
    Filed: September 3, 2021
    Publication date: March 10, 2022
    Applicant: MONOSOL, LLC
    Inventors: Nicholas ZEESE, Jonathon KNIGHT, Richard GOETZ, Victoria BRIDEWELL, Alyssa SHUEY
  • Publication number: 20210387444
    Abstract: Disclosed herein are multilayer water-dispersible articles including a water-dispersible substrate layer having a thickness in a range of about 5 ?m to about 10 mm, and a water-dispersible coating layer on the substrate layer, the coating layer having a thickness in a range of about 0.5 to about 250 ?m, wherein water-dispersible article has a moisture vapor transmission rate (MVTR) of about 20 g H2O/m2/day or less, such as 10 g H2O/m2/day or less.
    Type: Application
    Filed: October 28, 2019
    Publication date: December 16, 2021
    Applicant: MONOSOL. LLC
    Inventors: Jonathan KNIGHT, Nate MIRANDA
  • Patent number: 11193092
    Abstract: Disclosed herein are water-soluble films including a polyvinyl alcohol (PVOH) resin When the PVOH copolymer are selected with regard to various criteria related to physical and chemical film properties, the resulting water-soluble film formed from the PVOH resin blend exhibits maintained film stiffness, and pouch tautness when in contact with liquid pouch contents, maintain acceptable clarity properties, and/or demonstrates acceptable band release without impairing the ultimate solubility of the water-soluble film.
    Type: Grant
    Filed: May 2, 2019
    Date of Patent: December 7, 2021
    Assignee: MONOSOL, LLC
    Inventors: Richard Goetz, Jennifer L. Childers
  • Patent number: 11168289
    Abstract: Disclosed herein are water-soluble films including a polyvinyl alcohol (PVOH) polymer and a combination of at least three plasticizers. The combination of plasticizers includes dipropylene glycol as a first plasticizer, a sugar alcohol such as sorbitol as a second plasticizer, and a polyol such as glycerin as a third plasticizer. When the PVOH polymer and plasticizers are blended in particular proportions and/or selected with regard to various criteria related to physical and chemical film properties, the resulting water-soluble film formed from the PVOH resin blend exhibits beneficial combinations four) of aged tensile strength, aged melting transition delta elevation, aged adhesion value, and/or resistance to seal peeling, which provide strong film seals that retain their water-solubility characteristics.
    Type: Grant
    Filed: December 4, 2019
    Date of Patent: November 9, 2021
    Assignee: MONOSOL, LLC
    Inventors: Steven G. Friedrich, David M. Lee, Regine Labeque, Florence Catherine Courchay
  • Patent number: 11104497
    Abstract: A water-soluble film, comprising a first water-soluble film, wherein the first water soluble film disintegrates in water within less than about 24 hours and dissolves in water within less than about 48 hours as measured by the MSTM-205 at 20° C. The disclosure provides a water-soluble film comprising a first water-soluble film that disintegrates in water within less than 24 hours and dissolves in water within less than 48 hours as measured by MSTM-205 at 20° C. The first water-soluble film optionally may be further characterized in that it does not disintegrate in water for at least about 1 hour and does not dissolve in water for at least about 1 hour as measured by MSTM-205 at 20° C. The disclosure further provides a water-soluble film comprising a first water-soluble film characterized in that the degradation and/or dissolution of the first water-soluble film is adapted to be activated by consumer handling.
    Type: Grant
    Filed: October 2, 2015
    Date of Patent: August 31, 2021
    Assignee: MONOSOL, LLC
    Inventors: David M. Lee, Jennifer L. Childers, Lee K. Yeung, Ken Jenke, Jonathon Knight, Nicholas Zeese, P. Scott Bening, Yashodhan S. Parulekar, Sumeet Kumar
  • Patent number: 11028352
    Abstract: The invention relates to enzyme containing water-soluble films, and their use in detergents.
    Type: Grant
    Filed: March 14, 2014
    Date of Patent: June 8, 2021
    Assignees: NOVOZYMES A/S, MONOSOL LLC, NOVOZYMES NORTH AMERICA, INC.
    Inventors: Ole Simonsen, Victor Casella
  • Patent number: 10913832
    Abstract: Disclosed herein are water-soluble films including a polyvinyl alcohol (PVOH) resin blend and optionally one or more additional components such as plasticizers, fillers, surfactants, and other additives. Also disclosed herein are articles including the water-soluble film and containing a composition such as a household care composition. The PVOH resin blend includes a PVOH copolymer including one or more types of anionic monomer units such as a PVOH terpolymer and a PVOH polymer such as a partially or completely hydrolyzed PVOH homopolymer. When the PVOH copolymer and PVOH polymer are blended in particular proportions and/or selected with regard to various criteria related to the 4% solution viscosity of one or both of the PVOH polymer(s) and PVOH copolymer(s), the resulting water-soluble film formed from the PVOH resin blend exhibits substantially improved aqueous dissolution properties.
    Type: Grant
    Filed: November 11, 2019
    Date of Patent: February 9, 2021
    Assignee: MONOSOL, LLC
    Inventors: Steven G. Friedrich, David M. Lee, Thomas J. Yogan, Regine Labeque
  • Patent number: 10907117
    Abstract: A water-soluble unit dose article comprising a first water-soluble film and a second water-soluble film sealed together along a seal area, and optionally comprising a composition contained within the unit dose article, wherein the first water-soluble film and the second water-soluble film are chemically different to one another.
    Type: Grant
    Filed: June 12, 2017
    Date of Patent: February 2, 2021
    Assignee: MONOSOL, LLC
    Inventors: Philip Frank Souter, Robby Renilde Francois Keuleers, Regine Labeque, Florence Catherine Courchay, Marc Rene Bert Renmans
  • Patent number: 10899518
    Abstract: The disclosure provides a water soluble pouch including at least two sealed compartments, the pouch including outer walls including water soluble film including a water soluble resin, and an inner wall including water soluble film including a water soluble resin, the outer wall films being sealed to the inner wall film, the outer wall films being characterized by: a dissolution time of 300 seconds or less, the water soluble resin of the outer wall films having a viscosity in a range of 14.5 cP to 25 cP, and a pouch strength of at least 200 N, and the inner wall film being characterized by: a dissolution time of 300 seconds or less, the water soluble resin of the inner film having viscosity in a range of 12 cP to 14.5 cP, and a tackiness value of at least 1500 g/s.
    Type: Grant
    Filed: June 12, 2017
    Date of Patent: January 26, 2021
    Assignee: MONOSOL, LLC
    Inventors: Robby Renilde Francois Keuleers, Steven G. Friedrich, Lee K. Yeung, Shinsuke Nii
  • Patent number: 10844183
    Abstract: Disclosed herein are water-soluble films including a polyvinyl alcohol (PVOH) resin blend and optionally one or more additional components such as plasticizers, fillers, surfactants, and other additives. Also disclosed herein are articles including the water-soluble film and containing a composition such as a household care composition. The PVOH resin blend includes a PVOH copolymer including one or more types of anionic monomer units such as a PVOH terpolymer and a PVOH polymer such as a partially or completely hydrolyzed PVOH homopolymer. When the PVOH copolymer and PVOH polymer are blended in particular proportions and/or selected with regard to various criteria related to the 4% solution viscosity of one or both of the PVOH polymer(s) and PVOH copolymer(s), the resulting water-soluble film formed from the PVOH resin blend exhibits substantially improved aqueous dissolution properties.
    Type: Grant
    Filed: October 13, 2015
    Date of Patent: November 24, 2020
    Assignee: MONOSOL, LLC
    Inventors: Steven G. Friedrich, David M. Lee, Thomas J. Yogan, Regine Labeque
  • Patent number: 10829621
    Abstract: Disclosed herein are water-soluble films and resulting packets including a water soluble film, wherein the water-soluble film includes a water-soluble mixture of polyvinyl alcohol, a compatibilizing agent, and a sugar alcohol plasticizer that is a solid at room temperature, wherein the water-soluble film is substantially transparent.
    Type: Grant
    Filed: January 11, 2013
    Date of Patent: November 10, 2020
    Assignee: MONOSOL, LLC
    Inventors: David M. Lee, Jennifer L. Childers
  • Patent number: 10815346
    Abstract: A water-soluble film including a polyvinyl alcohol copolymer resin, a plasticizer, an anti-block filler, and a release modifier is disclosed herein. Also disclosed are related packets incorporating the film, and related methods of making and using the film and packets.
    Type: Grant
    Filed: January 29, 2016
    Date of Patent: October 27, 2020
    Assignee: MONOSOL, LLC
    Inventors: Shinsuke Nii, David M. Lee, Jennifer L. Childers
  • Patent number: 10808210
    Abstract: The disclosure provides a water-soluble film, including polyvinyl alcohol (PVOH) and (PVOH) and an acrylate resin (e.g., methyl acrylate), wherein the water-soluble film remains intact for at least 3 minutes when submerged in water heated to a temperature of about 40° C., as determined by Bleach Compatibility Method A (described herein). The disclosure further provides a packet or pouch comprising water-soluble film of the disclosure. The packet or pouch can optionally include two or more compartments. The disclosure further provides a pouch including a first sealed compartment containing a first composition, the first sealed compartment comprising the water-soluble film according to the disclosure. Optionally, the first composition can include a bleach composition.
    Type: Grant
    Filed: March 13, 2014
    Date of Patent: October 20, 2020
    Assignee: MONOSOL, LLC
    Inventors: David M. Lee, Nicholas Zeese, Jennifer L. Childers, Stephen Bullock
  • Publication number: 20200299473
    Abstract: Perfume microcapsule-containing films, related solutions, and containers including the films (e.g. detergent packets) are disclosed, together with their methods of preparation and use.
    Type: Application
    Filed: April 18, 2017
    Publication date: September 24, 2020
    Applicants: MonoSol, LLC, Givaudan SA
    Inventors: David M. LEE, Yashodhan S. PARULEKAR, Jonathon KNIGHT, Stephanie KOLB