Patents Assigned to Monosol, LLC.
  • Patent number: 8728449
    Abstract: Water-soluble articles such as films, which can be made resistant to contact with small amounts of water, and methods of making the same are disclosed. The water-soluble article is formed from a water-soluble film-forming composition, such as polyvinyl alcohol, and includes a salt that is distributed more closely to at least one of the surfaces than throughout its thickness.
    Type: Grant
    Filed: August 17, 2005
    Date of Patent: May 20, 2014
    Assignee: Monosol LLC
    Inventors: Andrew P. Verrall, Steven G. Friedrich
  • Publication number: 20130273277
    Abstract: Disclosed herein are water-soluble films and resulting packets including a water-soluble film coated by a powder, wherein the powder includes a mixture of a powdered lubricant and an active agent. Optionally, the active agent may be encapsulated, e.g. microencapsulated, for release of the active agent through mechanisms including, but not limited to, mechanical rupture, melt, ablation, dissolution, diffusion, biodegradation, or pH-controlled release. Active ingredients described include enzymes, oils, flavors, colorants, odor absorbers, fragrances, pesticides, fertilizers, activators, acid catalysts, metal catalysts, ion scavengers, bleaches, bleach components, fabric softeners and combinations thereof. Examples of packet fills include laundry detergents, bleach and laundry additives, fabric care, dishwashing, hard surface cleaning, beauty care, skin care, other personal care, and foodstuffs.
    Type: Application
    Filed: March 14, 2013
    Publication date: October 17, 2013
    Applicant: Monosol, LLC.
    Inventors: David M. Lee, Yashodhan S. Parulekar
  • Patent number: 8268914
    Abstract: A film-forming composition made from a mixture of PVOH, chitosan, an alkali metal or ammonium bisulfite or metabi sulfite, and optional ingredients such as plasticizers, antioxidants, UV stabilizers, surfactants, crosslinking agents, lubricants, and extenders, is disclosed. Also disclosed are a method of making a film from the composition, a resulting film, and a packet made from the film and containing a cleaning composition such as a rinse additive. The composition can be formulated to yield an article such as a film which is soluble only below a predetermined pH threshold.
    Type: Grant
    Filed: November 13, 2007
    Date of Patent: September 18, 2012
    Assignee: Monosol, LLC
    Inventors: Andrew P. Verrall, Solomon E. Brown, Dennis A. Beckholt
  • Publication number: 20110186467
    Abstract: Disclosed is a pouch having at least one sealed compartment containing a first composition. At least one wall of the at least one sealed compartment is made from a water-soluble film having any suitable thickness. The water-soluble film comprises PVOH polymer such that when the film has a thickness of about 76 microns the film is characterized by a Dissolution Index of about 620 to about 920, or of about 665 to about 920, or about 710 to about 920; and a Stress Index of about 145 to about 626, or about 155 to about 480, or about 165 to about 325.
    Type: Application
    Filed: January 28, 2011
    Publication date: August 4, 2011
    Applicant: MONOSOL, LLC
    Inventors: Frank W. Denome, Steven G. Friedrich, Regine Labeque, David M. Lee, Roxane Rosmaninho, Jichun Shi, Andrew P. Verrall
  • Publication number: 20110189413
    Abstract: Disclosed are plasticized, water-soluble films having favorable cold-water solubility, wet handling, and thermoforming characteristics, and which can include a PVOH resin made up of blend of two or more PVOH polymers each having a monomodal molecular weight distribution, and the PVOH resin characterized by a viscosity in a range of about 13.5 cP to about 20 cP (or a corresponding weight average molecular weight), a degree of hydrolysis of about 84% to about 92%, a polydispersity index value in a range of about 1 to about 5, a residual water content of about 4 wt. % to about 10 wt. %, and a Resin Selection Index value in a range of 0.255 to 0.315; methods of making the films; compositions including PVOH resins for making the films; and pouch and packet articles made from the films.
    Type: Application
    Filed: January 28, 2011
    Publication date: August 4, 2011
    Applicant: MONOSOL, LLC
    Inventors: Frank W. Denome, Steven G. Friedrich, Regine Labeque, David M. Lee, Roxane Rosmaninho, Jichun Shi, Andrew P. Verrall
  • Patent number: 7803872
    Abstract: A water-soluble, halogen-resistant film-forming composition useful for packaging water treatment products is disclosed. The film can include an acid-stable, water-soluble polyvinyl alcohol polymer, an oxidizable organic material, a chelating agent, a free radical scavenger, and secondary additives such as plasticizers, lubricants, and surfactants. The resulting film has favorable solubility properties after having been exposed to halogenated (e.g., chlorinated and brominated) compositions such as water treatment and agricultural products for prolonged periods of time.
    Type: Grant
    Filed: April 24, 2007
    Date of Patent: September 28, 2010
    Assignee: Monosol, LLC
    Inventors: Andrew P. Verrall, Stephen D. Goodrich
  • Publication number: 20100105821
    Abstract: A film-forming composition made from a mixture of PVOH, chitosan, an alkali metal or ammonium bisulfite or metabi sulfite, and optional ingredients such as plasticizers, antioxidants, UV stabilizers, surfactants, crosslinking agents, lubricants, and extenders, is disclosed. Also disclosed are a method of making a film from the composition, a resulting film, and a packet made from the film and containing a cleaning composition such as a rinse additive. The composition can be formulated to yield an article such as a film which is soluble only below a predetermined pH threshold.
    Type: Application
    Filed: November 13, 2007
    Publication date: April 29, 2010
    Applicant: MONOSOL, LLC
    Inventors: Andrew P. Verrall, Solomon E. Brown, Dennis Allen Beckholt
  • Patent number: 7642226
    Abstract: Generally speaking, the present invention is a water-soluble copolymer film comprising a hydrolyzed copolymer of vinyl acetate and a second monomer, the resultant polyvinyl alcohol copolymer having a degree of hydrolysis, expressed as a percentage of vinyl acetate units converted to vinyl alcohol units, of from about 90% to 100%. The second monomer is preferably selected from the group of monomers having carboxylate functionality or sulfonate functionality. The resulting water-soluble copolymer film is disclosed for use in making pouches to contain a unit dose of liquid detergent, such as a liquid laundry detergent. However, it is an aspect of the copolymer film that film solubility is not significantly affected adversely by the detergent. Such film produces pouches having a greater storage shelf-life over prior art water-soluble film.
    Type: Grant
    Filed: March 2, 2006
    Date of Patent: January 5, 2010
    Assignee: Monosol, LLC
    Inventors: Andrew P. Verrall, P. Scott Bening, Karen A. Kugler
  • Publication number: 20080255290
    Abstract: A method of dust abatement, including applying and reapplying to a surface having particulate material a single-phase solution including a water-soluble polymer selected from the group consisting of polyvinyl alcohol, derivatives thereof, and combinations thereof, at a rate of 0.1 g/m to 6 g/m2, on a dry basis, and suitable solutions for the method optionally including surfactants, plasticizers, tackifying agents, and nanoclays, are disclosed.
    Type: Application
    Filed: December 5, 2006
    Publication date: October 16, 2008
    Applicant: MONOSOL, LLC
    Inventors: Christian Rath, Andrew P. Verrall
  • Publication number: 20070231441
    Abstract: An edible film useful for packaging food additives is disclosed. The film generally includes an edible film-forming resin, a plasticizer, a compatibilizer, and optional secondary additives. The resulting edible film has favorable heat seal properties, being able to form an acceptable heat seal over temperature ranges of at least about 10° C.
    Type: Application
    Filed: March 29, 2006
    Publication date: October 4, 2007
    Applicant: MONOSOL, LLC
    Inventors: Andrew Verrall, Stephen Goodrich, Solomon Brown
  • Patent number: 7022656
    Abstract: Generally speaking, the present invention is a water-soluble copolymer film comprising a hydrolyzed copolymer of vinyl acetate and a second monomer, the resultant polyvinyl alcohol copolymer having a degree of hydrolysis, expressed as a percentage of vinyl acetate units converted to vinyl alcohol units, of from about 90% to 100%. The second monomer is preferably selected from the group of monomers having carboxylate functionality or sulfonate functionality. The resulting water-soluble copolymer film is disclosed for use in making pouches to contain a unit dose of liquid detergent, such as a liquid laundry detergent. However, it is an aspect of the copolymer film that film solubility is not significantly affected adversely by the detergent. Such film produces pouches having a greater storage shelf-life over prior art water-soluble film.
    Type: Grant
    Filed: March 19, 2003
    Date of Patent: April 4, 2006
    Assignee: Monosol, LLC.
    Inventors: Andrew P. Verrall, P. Scott Bening, Karen A. Kugler
  • Patent number: 6821590
    Abstract: A water-soluble film for packaging a non-liquid product is disclosed. The film is made from a hydrolyzed copolymer of vinyl acetate and methyl acrylate in the range of from about 30 to about 95 percent by weight, modified starch in the range of from about 8 to about 30 percent by weight, plasticizer in the range of from about 5 to about 30 percent by weight, lubricant/release agent in the range of from about 0.0 to about 1.5 percent by weight, and surfactant in the range of from about 0.01 to about 1.5 percent by weight. The increased starch content of the resultant film lowers production cost, but creates physical incompatibilities for use with liquid products.
    Type: Grant
    Filed: February 14, 2003
    Date of Patent: November 23, 2004
    Assignee: MonoSol, LLC
    Inventors: Andrew P. Verrall, P. Scott Bening, Karen A. Kugler
  • Patent number: 6787512
    Abstract: Generally speaking, the present invention is a water-soluble copolymer film comprising a hydrolyzed copolymer of vinyl acetate and a second monomer, the resultant polyvinyl alcohol copolymer having a degree of hydrolysis, expressed as a percentage of vinyl acetate units converted to vinyl alcohol units, of from about 90% to 100%. The second monomer is preferably selected from the group of monomers having carboxylate functionality or sulfonate functionality. The resulting water-soluble copolymer film is disclosed for use in making pouches to contain a unit dose of liquid detergent, such as a liquid laundry detergent. However, it is an aspect of the copolymer film that film solubility is not significantly affected adversely by the detergent. Such film produces pouches having a greater storage shelf-life over prior art water-soluble film.
    Type: Grant
    Filed: November 26, 2003
    Date of Patent: September 7, 2004
    Assignee: MonoSol, LLC
    Inventors: Andrew P. Verrall, P. Scott Bening, Karen A. Kugler
  • Patent number: 6484879
    Abstract: The present invention relates to a bag packaging system composed of a bag sealable to contain a liquid, in which the bag is composed of a continuous outer water soluble film and an inner continuous protective film layer that allows storage therein of a liquid that would chemically or physically react with the water soluble film but is prevented from doing so by the presence of the continuous protective film layer on the inner portion of the bag.
    Type: Grant
    Filed: April 7, 1997
    Date of Patent: November 26, 2002
    Assignees: Syngenta Crop Protection, Inc., MonoSol, LLC
    Inventors: Armand J. Desmarais, Henry E. Knoop, Lawrence C. Dull, Jean A. Raymond