Patents Assigned to Monosol, LLC.
  • Patent number: 10696460
    Abstract: Disclosed herein are water-soluble films and resulting packets including a water-soluble film coated by a powder, wherein the powder includes a mixture of a powdered lubricant and an active agent. Optionally, the active agent may be encapsulated, e.g. microencapsulated, for release of the active agent through mechanisms including, but not limited to, mechanical rupture, melt, ablation, dissolution, diffusion, biodegradation, or pH-controlled release. Active ingredients described include enzymes, oils, flavors, colorants, odor absorbers, fragrances, pesticides, fertilizers, activators, acid catalysts, metal catalysts, ion scavengers, bleaches, bleach components, fabric softeners and combinations thereof. Examples of packet fills include laundry detergents, bleach and laundry additives, fabric care, dishwashing, hard surface cleaning, beauty care, skin care, other personal care, and foodstuffs.
    Type: Grant
    Filed: December 29, 2017
    Date of Patent: June 30, 2020
    Assignee: MONOSOL, LLC
    Inventors: David M. Lee, Yashodhan S. Parulekar
  • Patent number: 10611555
    Abstract: A method of making a web of multi-dose cleaning products may include forming first and second pluralities of internal holders in a first film, forming a first plurality of external holders in a carrier sheet corresponding with the first plurality of internal holders, and forming a second plurality of external holders in the carrier sheet corresponding with the second plurality of internal holders. The method may also include filling each of the first plurality of internal holders with a first cleaning composition, and filling each of the second plurality of internal holders with a second cleaning composition. Furthermore, the method may include sealing a second film to the first film to define first and second pluralities of pouches, folding the carrier sheet so that each of the first plurality of pouches overlaps a corresponding one of the second plurality of pouches, and sealing together overlapping portions of the carrier sheet.
    Type: Grant
    Filed: January 10, 2018
    Date of Patent: April 7, 2020
    Assignee: MONOSOL, LLC
    Inventor: David Brian Edwards
  • Patent number: 10604318
    Abstract: Disclosed herein are sealing solutions for sealing water-soluble films, in particular aqueous mixtures including one or more polymeric solvents such as polyols. Aqueous sealing solutions including a relatively dilute solvent for one or more polymeric components of the water-soluble film (e.g., water-soluble polymeric components thereof, such as polyvinyl alcohol (PVOH)) can exhibit one or more benefits, including a reduction in dissolution of the film by the sealing solution and an increase in seal strength. Also disclosed are sealed articles formed with the sealing solutions, for example water-soluble packets containing various liquid or solid compositions.
    Type: Grant
    Filed: October 26, 2017
    Date of Patent: March 31, 2020
    Assignee: MONOSOL, LLC
    Inventors: Sumeet Kumar, Percy Bromby, II, David M. Lee
  • Patent number: 10562701
    Abstract: A web (8) of cleaning products (10) and a method of manufacturing the same is disclosed. The web includes first (20) and second carrier (30) sheets and a plurality of pouches (50) containing a cleaning composition. Each of the pouches is disposed in a respective depression (26) formed in an upper surface (28) of the first carrier sheet. A first internal atmosphere (80) is enclosed within each of the pouches. The first carrier sheet is sealed to the second carrier sheet such that a second internal atmosphere (82) exists between the second carrier sheet and the plurality of pouches. The second internal atmosphere has a greater absolute pressure (P) than the first internal atmosphere so that the plurality of pouches and at least a portion of the cleaning composition in the plurality of pouches are compressed into the plurality of depressions in the first carrier sheet by the second internal atmosphere.
    Type: Grant
    Filed: January 13, 2016
    Date of Patent: February 18, 2020
    Assignee: MONOSOL, LLC
    Inventors: David M. Lee, David Brian Edwards
  • Patent number: 10526479
    Abstract: Disclosed herein are water-soluble films including a polyvinyl alcohol (PVOH) resin blend and optionally one or more additional components such as plasticizers, fillers, surfactants, and other additives. The PVOH resin blend includes a PVOH copolymer including one or more types of anionic monomer units such as a PVOH terpolymer and a PVOH polymer such as another PVOH anionic copolymer or a partially or completely hydrolyzed PVOH homopolymer. When the PVOH copolymer and PVOH polymer are blended in particular proportions and/or selected with regard to various criteria related to physical and chemical film properties, the resulting water-soluble film formed from the PVOH resin blend exhibits substantially improved aqueous dissolution properties, tensile strength properties, and/or tensile modulus properties.
    Type: Grant
    Filed: October 13, 2015
    Date of Patent: January 7, 2020
    Assignee: MONOSOL, LLC
    Inventors: Steven G. Friedrich, David M. Lee, Thomas J. Yogan, Regine Labeque, Florence Catherine Courchay, Robby Renilde Francois Keuleers
  • Publication number: 20200002226
    Abstract: Cement, concrete, stucco, and plaster that are have black ceramic polymer derived pigment included as an encapsulated water soluble sacket added to the powered or wet materials. A ceramic black SiOC additive encapsulated in a water soluble sacket and having a particle size of about 0.1 ?m to 3 ?m.
    Type: Application
    Filed: April 25, 2019
    Publication date: January 2, 2020
    Applicants: Melior Innovations, Inc., MonoSol, LLC.
    Inventors: P. Scott Bening, JR., P Scott Bening, David Bening
  • Patent number: 10513588
    Abstract: Disclosed herein are water-soluble films including a polyvinyl alcohol (PVOH) polymer and a combination of at least three plasticizers. The combination of plasticizers includes dipropylene glycol as a first plasticizer, a sugar alcohol such as sorbitol as a second plasticizer, and a polyol such as glycerin as a third plasticizer. When the PVOH polymer and plasticizers are blended in particular proportions and/or selected with regard to various criteria related to physical and chemical film properties, the resulting water-soluble film formed from the PVOH resin blend exhibits beneficial combinations four) of aged tensile strength, aged melting transition delta elevation, aged adhesion value, and/or resistance to seal peeling, which provide strong film seals that retain their water-solubility characteristics.
    Type: Grant
    Filed: October 13, 2015
    Date of Patent: December 24, 2019
    Assignee: MONOSOL, LLC
    Inventors: Steven G. Friedrich, David M. Lee, Regine Labeque, Florence Catherine Courchay
  • Patent number: 10472476
    Abstract: Disclosed herein are water-soluble films including a polyvinyl alcohol (PVOH) resin blend and optionally one or more additional components such as plasticizers, fillers, surfactants, and other additives. Also disclosed herein are articles including the water-soluble film and containing a composition such as a household care composition. The PVOH resin blend includes a PVOH copolymer including one or more types of anionic monomer units such as a PVOH terpolymer and a PVOH polymer such as a partially or completely hydrolyzed PVOH homopolymer. When the PVOH copolymer and PVOH polymer are blended in particular proportions and/or selected with regard to various criteria related to the 4% solution viscosity of one or both of the PVOH polymer(s) and PVOH copolymer(s), the resulting water-soluble film formed from the PVOH resin blend exhibits substantially improved aqueous dissolution properties.
    Type: Grant
    Filed: October 13, 2015
    Date of Patent: November 12, 2019
    Assignee: MONOSOL, LLC
    Inventors: Steven G. Friedrich, David M. Lee, Thomas J. Yogan, Regine Labeque
  • Patent number: 10457920
    Abstract: The invention relates to a lipase containing water-soluble film, and a detergent pouch formed by the water-soluble film.
    Type: Grant
    Filed: May 14, 2014
    Date of Patent: October 29, 2019
    Assignees: MONOSOL LLC, Novozymes A/S
    Inventors: Victor Casella, Thomas Hoenger Callisen, Tue Rasmussen, Lise Munch Mikkelsen, Ole Simonsen
  • Patent number: 10443024
    Abstract: The present disclosure relates to pouches made from a combination of chemically different water-soluble films and optionally containing a composition (e.g. a household care composition or non-household care composition) that is at least partially enclosed by the water-soluble films in at least one compartment.
    Type: Grant
    Filed: June 12, 2017
    Date of Patent: October 15, 2019
    Assignee: MONOSOL, LLC
    Inventors: Philip Frank Souter, Robby Renilde Francois Keuleers, Regine Labeque, Florence Catherine Courchay, Marc Rene Bert Renmans, David M. Lee, Steven G. Friedrich, Lee K. Yeung, Shinsuke Nii
  • Patent number: 10428297
    Abstract: The present disclosure relates to water-soluble unit dose articles made from a combination of chemically different water-soluble films and optionally containing compositions that are at least partially enclosed by the water-soluble films in at least one compartment.
    Type: Grant
    Filed: June 12, 2017
    Date of Patent: October 1, 2019
    Assignee: MONOSOL, LLC
    Inventors: Philip Frank Souter, Robby Renilde Francois Keuleers, Regine Labeque, Florence Catherine Courchay, Marc Rene Bert Renmans, David M. Lee, Steven G. Friedrich, Lee K. Yeung, Shinsuke Nii
  • Patent number: 10208422
    Abstract: A stain removal device adapted to at least partially surround a stain located on a fabric to activate in a targeted manner includes a shell comprising a wall with an inner surface, an outer surface, a rim defining an aperture in the shell, the rim being defined by the inner and outer surfaces and the inner surface defining a shell cavity, at least one opening extending through the wall of the shell between the inner and outer surfaces of the shell, a dispensable cleaning agent at least partially disposed within the shell cavity, and an attachment portion at least partly coupled to the shell. The attachment portion is configured to removably couple the stain removal device to a fabric or article of clothing such that the rim of the shell contacts the fabric and at least partially surrounds a stain located on the fabric. So configured, the dispensable cleaning agent may activate in a targeted manner relative to the stain during a wash cycle.
    Type: Grant
    Filed: June 15, 2015
    Date of Patent: February 19, 2019
    Assignee: MONOSOL, LLC
    Inventors: David Brian Edwards, Tara Sophia Edwards
  • Patent number: 10202227
    Abstract: Disclosed herein are water-soluble films comprising a mixture of a water-soluble polyvinyl alcohol copolymer including an anionic monomer having a pendant carboxyl group, and a plasticizer blend comprising a first plasticizer comprising sorbitol and a secondary plasticizer selected from the group consisting of glycerol, trimethylolpropane, diglycerol, glycerol propylene oxide polymers, glycerol diacetate, 2-methyl-1,3-propanediol and a combination thereof, wherein (i) when the total plasticizer in the film is less than 12 PHR, then the plasticizer blend comprises sorbitol, glycerol, and at least one additional secondary plasticizer; (ii) when the total plasticizer in the film is at least 12 PHR and less than 20 PHR, then the plasticizer blend comprises sorbitol, glycerol, and at least one additional secondary plasticizer selected from diglycerol, trimethylolpropane and a combination thereof; and (iii) when the total plasticizer in the film is 20 PHR or greater, then sorbitol comprises at least ? of the total
    Type: Grant
    Filed: August 1, 2017
    Date of Patent: February 12, 2019
    Assignee: MONOSOL, LLC
    Inventors: Shinsuke Nii, Nathanael R. Miranda
  • Patent number: 10183794
    Abstract: The present invention relates to the use of water-soluble unit dose article to improve the user dosing experience.
    Type: Grant
    Filed: June 12, 2017
    Date of Patent: January 22, 2019
    Assignee: MONOSOL, LLC
    Inventors: Philip Frank Souter, Robby Renilde Francois Keuleers, Regine Labeque, Florence Catherine Courchay, Marc Rene Bert Renmans
  • Patent number: 10087401
    Abstract: Disclosed herein are water soluble compositions, such as films, including a mixture of a first water-soluble resin, an enzyme, and an enzyme stabilizer which comprises a functional substrate for the enzyme, methods of making such compositions, and methods of using such compositions, e.g. to make packets containing functional ingredients. The enzymes can include proteases and mixtures of proteases with other enzymes, and the compositions provide good retention of enzyme function following film processing and storage.
    Type: Grant
    Filed: March 16, 2012
    Date of Patent: October 2, 2018
    Assignee: MONOSOL, LLC
    Inventors: David M. Lee, Jennifer L. Sims
  • Publication number: 20180186534
    Abstract: Disclosed herein are water-soluble films and resulting packets including a water-soluble film coated by a powder, wherein the powder includes a mixture of a powdered lubricant and an active agent. Optionally, the active agent may be encapsulated, e.g. microencapsulated, for release of the active agent through mechanisms including, but not limited to, mechanical rupture, melt, ablation, dissolution, diffusion, biodegradation, or pH-controlled release. Active ingredients described include enzymes, oils, flavors, colorants, odor absorbers, fragrances, pesticides, fertilizers, activators, acid catalysts, metal catalysts, ion scavengers, bleaches, bleach components, fabric softeners and combinations thereof. Examples of packet fills include laundry detergents, bleach and laundry additives, fabric care, dishwashing, hard surface cleaning, beauty care, skin care, other personal care, and foodstuffs.
    Type: Application
    Filed: December 29, 2017
    Publication date: July 5, 2018
    Applicant: MONOSOL, LLC
    Inventors: David M. Lee, Yashodhan S. Parulekar
  • Publication number: 20180118906
    Abstract: The disclosure provides a water-soluble film, including a mixture of a water-soluble polyvinyl alcohol, a plasticizer, and a starch, wherein (a) the starch includes a hydroxypropylated starch in an amount of about 5 phr to about 30 phr; (b) the starch includes a modified starch having a degree of modification greater than about 2%, in an amount of about 2.5 phr to about 30 phr; (c) the starch is an unmodified starch having an amylose content of about 20% to about 80%; or (d) the starch includes a hydroxypropylated starch having an amylose content of about 23% to about 95% and the polyvinyl alcohol includes unmodified polyvinyl alcohol or anionic modified polyvinyl alcohol with the proviso that the anionic modifier is not acrylate. The disclosure further provides a sealed article including a water-soluble film in the form of a pouch defining an interior pouch volume.
    Type: Application
    Filed: October 27, 2017
    Publication date: May 3, 2018
    Applicant: MONOSOL, LLC
    Inventors: David M. Lee, Percy Bromby, II
  • Patent number: 9908675
    Abstract: Disclosed herein are water-soluble films and resulting packets including a water-soluble film coated by a powder, wherein the powder includes a mixture of a powdered lubricant and an active agent. Optionally, the active agent may be encapsulated, e.g. microencapsulated, for release of the active agent through mechanisms including, but not limited to, mechanical rupture, melt, ablation, dissolution, diffusion, biodegradation, or pH-controlled release. Active ingredients described include enzymes, oils, flavors, colorants, odor absorbers, fragrances, pesticides, fertilizers, activators, acid catalysts, metal catalysts, ion scavengers, bleaches, bleach components, fabric softeners and combinations thereof. Examples of packet fills include laundry detergents, bleach and laundry additives, fabric care, dishwashing, hard surface cleaning, beauty care, skin care, other personal care, and foodstuffs.
    Type: Grant
    Filed: July 19, 2016
    Date of Patent: March 6, 2018
    Assignee: MONOSOL, LLC
    Inventors: David M. Lee, Yashodhan S. Parulekar
  • Publication number: 20180029763
    Abstract: Disclosed herein are water-soluble films comprising a mixture of a water-soluble polyvinyl alcohol copolymer including an anionic monomer having a pendant carboxyl group, and a plasticizer blend comprising a first plasticizer comprising sorbitol and a secondary plasticizer selected from the group consisting of glycerol, trimethylolpropane, diglycerol, glycerol propylene oxide polymers, glycerol diacetate, 2-methyl-1,3-propanediol and a combination thereof, wherein (i) when the total plasticizer in the film is less than 12 PHR, then the plasticizer blend comprises sorbitol, glycerol, and at least one additional secondary plasticizer; (ii) when the total plasticizer in the film is at least 12 PHR and less than 20 PHR, then the plasticizer blend comprises sorbitol, glycerol, and at least one additional secondary plasticizer selected from diglycerol, trimethylolpropane and a combination thereof; and (iii) when the total plasticizer in the film is 20 PHR or greater, then sorbitol comprises at least ? of the total
    Type: Application
    Filed: August 1, 2017
    Publication date: February 1, 2018
    Applicant: MONOSOL, LLC
    Inventors: Shinsuke Nii, Nathanael R. Miranda
  • Patent number: 9873558
    Abstract: A web of multi-dose cleaning products and method of manufacturing the same is disclosed. The web includes a carrier sheet including first and second pluralities of depressions, a first plurality of pouches, and a second plurality of pouches. Each of the pouches is positioned in a respective depression in the carrier sheet. The first plurality of pouches contain a first cleaning composition, and the second plurality of pouches contain a second cleaning composition. A first end of the carrier sheet is folded over a second end of the carrier sheet so that each multi-dose cleaning product is defined by at least an overlapping pair of the first and second pouches and an overlapping pair of the first and second depressions.
    Type: Grant
    Filed: February 26, 2015
    Date of Patent: January 23, 2018
    Assignee: MONOSOL, LLC
    Inventor: David Brian Edwards