Abstract: The invention relates to a regulation method for regulating the temperature in a reactor utilized in the polymerization of olefines. A circulating gas is led to the reactor along a circulating gas flow line, and the circulating gas is cooled by leading part of the circulating gas flowing along a circulating gas flow line along a by-pass flow line through a cooler. A regulating device for the circulating gas inlet-flow temperature controls the amount of the circulating gas by-pass flow along a circulating gas by-pass flow line through the cooler such that the sum of the openings of a valve in the circulating gas flow line and a valve in the circulating gas by-pass flow line is maintained substantially constant in the range from about 90 to about 120%.

Abstract: When asymmetric olefins or a monomer mixture containing asymmetric monomers is polymerized by a catalyst composition containing esters of carboxylic acid e.g. as a so-called donor, and alcohol the ester group can be transesterified with the alcohol to an ester containing another alkyl group during the preparation and/or polymerization of the catalyst. This is advantageous particularly when an adduct of a so-called spray-crystallized Mg-halide and alcohol is used as the catalyst carrier, because the alkoxy group of the alcohol of the carrier and the alkoxy group of the ester of the donor can be transesterified and thus obtain the preferable effects of both esters on the run of the polymerization reaction. Hereby, a solvent having a high boiling point should be used as the intermediate agent, so that the transesterification reaction can take place. Most preferable have been found hydrocarbons having high boiling points, especially nonane and decane.

Abstract: The invention relates to a conductive polymer composite wherein the internally conductive polymer component consists of a polymer of a 3-substituted thiophene, the polymer being doped with a suitable electron acceptor or electron emitter compound. The polymer composite is prepared by processing in molten state by various methods such as extrusion molding, injection molding, compression molding, or sheet blowing, together with a suitable polymer matrix, to form a homogenous composite.

Abstract: In conventional spraying methods the problem in the preparation of small carrier particles aimed for the polymerization is that the drops constituting the prestages of the particles agglomerate or form otherwise in different sizes, whereby the size distribution of the carrier particles becomes too broad. This leads due to the so-called replica phenomenon to a polymer product having also a too broad particle size distribution. In the present invention the carrier is prepared by spraying a liquid containing a carrier through a nozzle into inert gas so that its first forms small droplets, which then solidify to small carrier particles. The desired narrow particle size distribution is provided by feeding a liquid containing a carrier through a nozzle, in which or in connection with which the liquid drops by means of the standing sonic waves in the ultrasonic range into small droplets of uniform size. The droplets of uniform size solidify then into small carrier particles of equally uniform size.

Abstract: The invention relates to a method for the preparation of electronic and electro-optical components and circuits based on conducting polymers. One or more boundary surfaces in the component between a conducting polymer and another material are formed by melting of the conducting polymer.

Abstract: A plastic storage and transportation container for loose cartridges, in which container static electricity arising inside the container may be conducted outside the container by a conductive fiber material disposed on the inner surface. The shell of the container is a thermoplastic tube structure. The conductive fiber material is preferably carbon fibers fixed to the inner surface of the tube structure in connection with its preparation. The cover and/or the bottom portion of the container is formed by a plug part made of a conductive plastic.

Abstract: The invention relates to polyethylene co- or ter-polymers that are cross-linkable. The polymers contain unsaturated acrylate bonds as a result of which the polymer can be efficiently cross-linked by ionizing radiation or chemically by means of peroxides.

Abstract: The invention relates to a method for the preparation of a supported procatalyst intended for the polymerization of olefines, in which particles are formed of magnesium dihalide and alcohol, the particles are reacted with an organic compound of a metal from the groups I-III, the thus obtained particulate product is activated by means of a titanium and/or vanadium compound and optionally a donor, and optionally a prepolymerization is carried out for the activated particles. A problem of such a method is how to form particles of magnesium dihalogenide and alcohol having a structure advantageous for the polymerization of olefins. The problem has in the present invention been solved so that the particles are formed by spray crystallizing (spray freezing) a mixture of magnesium dihalide and alcohol to complex particles of magnesium dihalide and alcohol. The hydroxyl content of the particles so obtained is much greater than earlier, which results in a much more active procatalyst than the preceding ones.

Abstract: This invention relates to a butene-1 copolymer composition suitable as a wire coating material which is superior in flame retardance and even if it burns, no toxic gas is generated and superior in mechanical strengths, chacterized by comprising 20-55% by weight of a butene-1 copolymer containing 80-99 mol % of butene-1 unit and 1-20% of .alpha.-olefin unit having at least 5 carbon atoms and having an intrinsic viscosity [.eta.] of 1.0-7.0 dl/g measured in decalin at 135.degree. C. and a maximum melting point of 80.degree.-120.degree. C. measured by differential scanning calorimetric analysis and 80-45% by weight of an inorganic metal hydroxide and/or an inorganic metal hydrate which have an average particle size of 0.05-6 m.

Abstract: The present invention relates to N acyl and O acyl derivatives of N,N-bis(2,2-dimethyl-3-hydroxypropyl)amine which are produced as follows: ammonium halide, sulphate or aldehyde, and isobutyl aldehyde are subjected to condensation reaction and the obtained product is reduced to the corresponding amino alcohol. The hydrogen atoms linked to the nitrogen atom and the oxygen atom are thereafter substituted by acyl groups. The N-acylation and esterification of hydroxyl groups can be performed simultaneously using a carboxyl acid, carboxyl acid halide, or carboxyl acid anhydride. The N,N-bis(2,2-dimethyl-3-hydroxypropyl)amine derivatives can be used as polymer stabilizers, PCV plasticizers, emulsifiers, corrosion resistance agents, and metal complexing agents.

Abstract: The invention relates to a method and device for feeding a mud-like catalyst mixture into a polymerization reactor. The catalyst mixture is fed from a container into a batching space of a feeder connected thereto, from which channel the catalyst mixture is further fed by batches into the polymerization reactor by the use of the pressure of a medium fed into the feeder. In accordance with the invention, after each catalyst batch fed into the polymerization reactor, the medium is substantially removed from the batching space of the feeder by leading the medium via an outlet channel into a space between two on/off valves before filling the batching space with a new catalyst batch.

Abstract: The invention relates to a new bis(trialkylsilyl) chromate of the formula ##STR1## where n is approximately 1-2. Such a compound can be prepared by causing a corresponding silyl halide to react with silver chromate. The product is especially suitable for the polymerization and copolymerization of ethylene, the formed polymer having a high molar mass and a wide molar mass distribution.

Abstract: The present invention concerns a heterogenic catalyst suited to the metathesis reactions of hydrocarbons in particular. Such a catalyst includes an inorganic oxide support, typically consisting of .gamma.-alumina, having rhenium oxide absorbed onto its surface. The catalyst in accordance with the invention is prepared by vapourizing a precursor of rhenium, preferably rhenium heptoxide, preferably at a temperature of at least 160.degree. C., and routing the vapour into a reaction chamber where they are brought to interaction with the support material. The temperature of the support material is kept above the condensation temperature of the vapour and simultaneously sufficiently high so as to attain the thermal activation energy level necessary for the generation of bonds between the rhenium oxide and the support material. According to the invention, the process is carried out preferredly within a temperature range of approx. 160.degree. . . . 500.degree. C.

Abstract: The present invention concerns a catalyst for the polymerization of olefins, and a method for preparing the same said catalyst constituting an inorganic support material with catalytically active chromium and titanium compounds bound on its surface. The catalyst is prepared according to the invention by bringing the catalytically active metal compounds sequentially in vapor phase onto the support material surface in excess amounts in relation to the binding sites available on the support material surface. The support material temperature is maintained above the condensation temperature of the vapor, preferably above 160.degree. C., and simultaneously sufficiently high so as to achieve the thermal activation energy necessary for the generation of bonds between the support material and the catalytically active material or its compound. To avoid desorption of the chemisorbed compounds, the temperature is kept below approx. 500.degree. C.

Abstract: The invention relates to a method for manufacturing a joint, in which method around the sections (14, 15) to be joined to each other sections of a sealing element (12, 13) are placed and the joint (16) is heated by a form (10). A reinforced plastic is used for the joining compound (12, 13), and sections (11a, 11b) of the form (10) are pressed, in a manner known per se, around the members (14, 15) surrounded by the reinforced plastic sealing member sections and to be joined to each other in the joint (16). The invention also relates to a joint manufactured by the aforementioned method.

Abstract: The invention relates to a method and an apparatus for continuously taking a sample from a discharge system of a polymerization reactor having a discontinuously opening discharge valve connecting the polymerization reactor to a product tube leading into a solid-constituent separation system. A sampling means having a closing valve of an on/off type is connected to the product tube. The closing valve closes for the period of a pressure wave occurring when the discharge valve opens, and opens after the pressure wave. A buffer container connected to an analyzer is provided with a sufficient volume to maintain the continuity of the sample flow when the closing valve is closed.

Abstract: A metathesis process of the conversion of olefines, in which at least one olefine is brought into contact with a solid catalyst system comprising on a solid silica carrier 0.1-40% by weight of a tungsten compound under reaction conditions such that the catalyst system converts the olefine into olefines having a different molecular weight. In the process a magnesium oxide or titanium oxide containing co-gel prepared by means of a co-gelling system is used as the silica carrier.

Abstract: Polyolefin-vinyl polymer composites are produced by impregnating polyolefin particles with vinyl monomer and free radical polymerization initiator in the ratio of about 10-200 parts by weight of vinyl monomer and 0.01-4.0 parts by weight free radical polymerization initiator per 100 parts by weight polyolefin, the impregnation being effected by slowly mixing the components at room temperature or at an elevated temperature below the decomposition temperature of the free radical polymerization initiator. After the impregnation is completed, an aqueous suspension of the mixture is formed by adding the same to water in a ratio of about 100 parts by weight of mixture per 80-1000 parts by weight of water, after which the aqueous suspension is heated to a temperature sufficiently high to polymerize the vinyl monomer.

Abstract: The invention relates to the homogenization of mixtures of internally conductive polymers like 3-substituted polythiophene and matrix polymers. With an efficient homogenization the conductivity is improved when the portion of the conductive polymer is low. An efficient homogenization is achieved in the invention by mixing the internally conductive polymer with a monomer or by dissolving it into it, after which the monomer is polymerized. The plastic composites so obtained are used for several purposes in which conductivity is needed, such as EMI and ESD shielding.

Abstract: A method for impregnating fibre bundles with molten or liquid resin in manufacturing a fibre-reinforced material, which material comprises one or more fibre bundles, wherein each fibre is surrounded by matrix resin, by impregnating a continuous web (10;10a) of one or more fibre bundles with molten or liquid resin (32, 33) and solidifying the resin by cooling or chemical reaction. During the impregnation the molten or liquid resin (35) material is made subject to shear forces by bringing it between two closely nearby surfaces (10;10a, 36;37) which are in moving relationship to each other.