Patents Assigned to Nippon Oil Company
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Patent number: 5756660Abstract: A polyethylene article such as film or fiber having high strength and high elastic modulus is produced by orienting an ultra-high molecular weight polyethylene having an intrinsic viscosity at 135.degree. C. in decalin of 5 to 50 dl/g, said ultra-high molecular weight polyethylene being prepared by homo- or copolymerizing ethylene in the presence of a catalyst system and hydrogen, said catalyst system comprising (1) a solid catalyst component containing at least magnesium, titanium and/or vanadium, (2) an organometallic compound and (3) a compound represented by the following general formula ?I!: ##STR1## where R.sup.1, R.sup.2, R.sup.3 and R.sup.4 are each hydrogen or a hydrocarbon residue, with the proviso that any two of R.sup.1, R.sup.2, R.sup.3 and R.sup.4 may conjointly form a cyclic hydrocarbon residue.Type: GrantFiled: October 2, 1996Date of Patent: May 26, 1998Assignee: Nippon Oil Company, LimitedInventors: Takeichi Shiraishi, Yoshiyuki Shimo, Seizo Kobayashi
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Patent number: 5750457Abstract: A solid acid catalyst for paraffin conversion which consists of an acid salt of a heteropoly acid being represented by the following general formula:A.sub.x H.sub.(3-x) PY.sub.12 O.sub.40wherein A represents one ion selected from the group consisting of alkali metal ion and ammonium ion; Y represents at least one atom selected from the group consisting of W and Mo; x represents a number of 2.2 to 2.8, and a metal Group VIII, wherein the acid salt of heteroply acid has been impregnated in the metal of Group VIII, and paraffin conversion process using the same.Type: GrantFiled: July 31, 1995Date of Patent: May 12, 1998Assignee: Nippon Oil Company, Ltd.Inventors: Kyutae Na, Toshio Okuhara, Makoto Misono
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Patent number: 5728641Abstract: According to the present invention there are provided a catalyst component, a catalyst using the catalyst component and a process using the catalyst, for the preparation of olefin polymers high in molecular weight and relatively wide in molecular weight distribution, using an extremely small amount of a modified organoaluminum compound such as methylaluminoxane and in high yield. The catalyst component is prepared by contacting at least the following constituents (1), (2), (3) and (4) with one another:(1) a compound represented by the general formula Me.sup.1 R.sup.1.sub.p (OR.sup.2).sub.q X.sub.4-p-q where R.sup.1 and R.sup.2 are each independently a hydrocarbon group having 1 to 24 carbon atoms, X is a halogen atom, Me is Zr, Ti or Hf, p and q are each an integer in the ranges of 0.ltoreq.p.ltoreq.4 and 0.ltoreq.q.ltoreq.4, provided 0.ltoreq.p+q.ltoreq.4;(2) at least one compound selected from the group consisting of compounds represented by the following general formulas 1 to 4:General formula 1: Me.sup.Type: GrantFiled: June 21, 1995Date of Patent: March 17, 1998Assignee: Nippon Oil Company, LimitedInventors: Fuyuki Aida, Yoshio Tajima, Kazuo Matsuura
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Patent number: 5723417Abstract: An oil-soluble polyester having a weight average molecular weight of 10,000 to 1,000,000, which is a polycondensate prepared by polycondensing the following ingredients (A) and (B): (A) a dicarboxylic acid ingredient, and (B) a diol ingredient comprising (i) a hindered glycol represented by the following formula: HO--CH.sub.2 --CR.sup.1 R.sup.2 --CH.sub.2 --OH wherein R.sup.1 and R.sup.2 independently represent a linear or branched alkyl group, and (ii) an alkylene glycol having at least 4 carbon atoms in the main chain. This oil-soluble polyester is useful as an additive for a lubricating oil.Type: GrantFiled: February 12, 1996Date of Patent: March 3, 1998Assignees: Nippon Zeon Co., Ltd., Harima Chemicals, Inc., Nippon Oil Company, Ltd.Inventors: Shizuo Kitahara, Yutaka Shikatani, Junichi Igarashi, Yoshihide Ishikawa, Shinsuke Hasegawa, Michio Miyamoto
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Patent number: 5705088Abstract: An electrorheological fluid comprising an electrically insulating liquid and acid, iodine or alcohol-treated, or iodine-treated and subsequently electrically insulating film-coated, dispersible carbonaceous particles dispersed therein has a high electrorheological effect even without lowering in a high temperature region, though it is a water-free system.Type: GrantFiled: February 14, 1996Date of Patent: January 6, 1998Assignee: Nippon Oil Company, Ltd.Inventors: Makoto Sasaki, Yukio Kobayashi, Katsuhiko Haji
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Patent number: 5702630Abstract: A fluid having both magnetic and electrorheological characteristics, which comprises composite particles of ferromagnetic particles and a metallic oxide prepared by a sol-gel reaction of a metal alkoxide in the presence of the ferromagnetic particles and a solvent and a process for producing the same.Type: GrantFiled: March 19, 1997Date of Patent: December 30, 1997Assignee: Nippon Oil Company, Ltd.Inventors: Makoto Sasaki, Hisatake Sato
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Patent number: 5701862Abstract: A method and apparatus for replenishing the lubricating oil of an internal combustion engine involving, during operation of the engine, continuously supplying a predetermined quantity of new oil from a reserve tank in which lubricating oil is stored to a holding region for lubricating oil circulated to the engine. As a result, an adequate effective extension of the life of the lubricating oil can be achieved, so that maintenance of the engine lubricating oil can be greatly reduced.Type: GrantFiled: May 16, 1995Date of Patent: December 30, 1997Assignee: Nippon Oil Company LimitedInventors: Kiyoshi Inoue, Masakuni Hirata
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Patent number: 5644008Abstract: Olefin is polymerized using a catalyst comprising a solid catalyst component and an organometallic compound, the solid catalyst component being prepared by reacting 1 a reaction product obtained by reacting the reaction product of Si oxide and/or Al oxide and Ti compound or both Ti compound and V compound (Ti.V component) with organic Al compound, with 2 a reaction product obtained by the reaction of Mg halide, a compound of the general formula Me(OR).sub.n X.sub.z-n and Ti.V component (optional component), and further reacting the reaction product of the above 1 and 2 with 3 a compound of the general formula R.sub.p Si(OR).sub.q X.sub.4-p-q.Type: GrantFiled: October 23, 1995Date of Patent: July 1, 1997Assignee: Nippon Oil Company, LimitedInventors: Akira Sano, Takeichi Shiraishi, Hiroyuki Shimizu, Kunihiro Suzuki, Kazuo Matsuura
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Patent number: 5624890Abstract: A lubricating oil composition for two-stroke cycle cylinder injection engines contains as essential ingredients: (A): a base oil containing (1) 10-30% by mass of polybutene with number-average molecular weight 250-350 on the basis of a total amount of the base oil, (2) 30-60% by mass of polybutene with number-average molecular weight 450-550 on the basis of the total amount of the base oil, and (3) 15-40% by mass of mineral oil and/or a synthetic oil, which is other than polybutene, with kinematic viscosity 2-35 mm.sup.2 /s at 100.degree. C., on the basis of the total amount of the base oil; and (B): 2-15 parts by mass of alkylaminophenol having an alkyl group with 8-400 carbon atoms relative to 100 parts by mass of the base oil.Type: GrantFiled: November 27, 1995Date of Patent: April 29, 1997Assignees: Nippon Oil Company, Ltd, Yamaha Hatsudoki Kabushiki KaishaInventors: Mineo Kagaya, Kazuo Miyazawa
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Patent number: 5622660Abstract: A process for producing a process for producing a two- or three-dimensional carbon fabric, which process includes melt-spinning (a) an optically anisotropic carbonaceous pitch having an optically anisotropic phase content of 60 to 100%, subjecting the thus- infusibilized fibers to a primary heat treatment at a temperature greater than 1000.degree. and not higher than 2500.degree. C. to produce primary heat treated fibers having a tensile strength not lower than 300 kg/mm.sup.2 and a breaking elongation in the range of 0.4% to 10%, preparing a two- or three-dimensional fabric from the primary heat treated fibers and then subjecting the two- or three-dimensional fabric to a secondary heat treatment at a temperature which is at least 50.degree. higher than the temperature used in the primary heat treatment, the temperature in the secondary heat treatment being higher than 1050.degree. C. and no higher than 3300.degree. C.Type: GrantFiled: January 9, 1995Date of Patent: April 22, 1997Assignee: Nippon Oil Company, LimitedInventors: Seiichi Uemura, Yoshio Sohda, Yasuzi Ido
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Patent number: 5614134Abstract: A carbon/carbon composite is prepared without using any expensive carbon fiber fabric and without performing any complicated molding step prior to a densifying step. More specifically, a pitch-based infusiblized fiber alone, or optionally in the form of a mixture thereof with a pitch-based carbonized fiber, is subjected to carbonization and molding under uniaxial pressing to obtain a carbon/carbon composite preform. The preform is then densified using a carbonaceous matrix.Type: GrantFiled: May 22, 1995Date of Patent: March 25, 1997Assignee: Nippon Oil Company, LimitedInventors: Yoshio Sohda, Takefumi Kohno, Yutaka Sanokawa
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Patent number: 5607839Abstract: Bacterium belonging to a new genus, and a process for production of carotenoid pigment selected from the group consisting of astaxanthin, adonixanthin, .beta.-carotene, echinenone, canthaxanthin and zeaxanthin, comprising the steps of culturing a bacterium capable of producing at least one of the carotenoid pigments, and recovering an individual carotenoid pigments.The producer bacterium belongs to new genus.According to the present process various carotenoids can be produced in an industrial scale. By the present process (3S, 3'S)-astaxanthin can be produced in an almost 100% purity.Type: GrantFiled: July 19, 1994Date of Patent: March 4, 1997Assignee: Nippon Oil Company, Ltd.Inventors: Akira Tsubokura, Hisashi Yoneda, Mikihiro Takaki, Takashi Kiyota
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Patent number: 5604170Abstract: An effective catalyst carrier for use in the polymerization of olefins is provided.Said carrier comprises particles of silicon oxide or aluminum oxide satisfying the following characteristics (A) to (E):(A) An average particle diameter as measured by the sieving method is in the range of 20 to 150 .mu.m.(B) A specific surface area as measured by the BET method is in the range of 150 to 600 m.sup.2 /g.(C) The volume of pores ranging in pore radius from 18 to 1,000 Angstroms as measured by the mercury penetration method is in the range of 0.3 to 2.0 cm.sup.3 /g.(D) An apparent specific gravity as measured according to JIS K6220-6.8 is not lower than 0.32.(E) After the particles classified in the range of between 53 .mu.m and 75 .mu.m by the sieving method have been subjected to an ultrasonic disintegration treatment at 40 KHz, 35 W, for 20 minutes, the proportion of 50 .mu.m or smaller particles, i.e., degree of ultrasonic disintegration, is not more than 30%.Type: GrantFiled: February 22, 1994Date of Patent: February 18, 1997Assignee: Nippon Oil Company, LimitedInventors: Akira Sano, Kunimichi Kubo, Kazuo Matsuura, Yoshio Tajima
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Patent number: 5599478Abstract: According to the present invention there is provided a compensator for a liquid crystal display superior in the color compensating performance, capable of making color compensation of a high-speed STN-LCD and capable of freely changing the value of wavelength dispersion. The compensator is obtained by using a liquid crystalline polyester which contains 4-hydroxycinnamic acid units and catechol units as constituent units.Type: GrantFiled: August 14, 1995Date of Patent: February 4, 1997Assignee: Nippon Oil Company, LimitedInventors: Takuya Matumoto, Tadahiro Kaminade, Nishimura Suzushi, Shigeki Takigawa
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Patent number: 5578243Abstract: A liquid crystalline polymer film useful as a high functional optical element is provided. Said liquid crystalline polymer film is formed on a substrate and having at least a tilt orientation fixed, and said tilt orientation is such that the angle between a director of said liquid crystalline polymer and a flat surface of said substrate is in the range of 5 to 85 degrees in terms of an average value.Type: GrantFiled: June 7, 1995Date of Patent: November 26, 1996Assignee: Nippon Oil Company, LimitedInventors: Hitoshi Mazaki, Takuya Matsumoto, Iwane Shiozaki, Shigeki Takikawa
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Patent number: 5561221Abstract: Disclosed are 1) compositions comprising isolated monomeric subunits of chaperonin-60 or truncated fragments thereof that promote the folding of a polypeptide chain in vitro, 2) monomeric subunits of chaperonin-60 or truncated fragments thereof, immobilized on a solid surface, that promote also the folding of a polypeptide chain in vitro, 3) methods for preparing and/or immobilizing the monomeric subunits of chaperonin-60 or truncated fragments thereof, and 4) methods for folding polypeptide chains, specifically polypeptide chains expressed in a heterologous expression system, in vitro using the monomeric subunits of chaperonin-60 or truncated fragments thereof.Type: GrantFiled: August 3, 1994Date of Patent: October 1, 1996Assignee: Nippon Oil Company LimitedInventors: Masasuke Yoshida, Hideki Taguchi, Jin Konishi
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Patent number: 5556821Abstract: According to the present invention there is provide a catalyst capable of affording an olefin homopolymer or copolymer having a high molecular weight and a relatively wide molecular weight distribution, in high yield, using an extremely small amount of a modified organoaluminum compound (particularly methylaluminoxane).The catalyst comprises the modified organoaluminum compound and a catalyst component comprising the following compounds (1) and (2): (1) a compound represented by the general formula R.sub.p MX.sub.4-p where M is a transition metal of Group IVa in the Periodic Table, R is cyclopentadienyl, substituted cyclopentadienyl, indenyl, substituted indenyl, or an aralkyl group having 7 to 24 carbon atoms, provided Rs may be bonded together through an alkylene groups having 2 to 8 carbon atoms and/or silylene group, X is a halogen atom, a hydrogen atom or a hydrocarbon residue having 1 to 24 carbon atoms, and p is a number satisfying the condition of 1.ltoreq.p.ltoreq.Type: GrantFiled: July 19, 1994Date of Patent: September 17, 1996Assignee: Nippon Oil Company, LimitedInventors: Fuyuki Aida, Yoshio Tajima, Kazuo Matsuura
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Patent number: 5543041Abstract: The present invention relates to a supply system for pre-treating a petroleum distillation residual oil to be fed to a hydrogenation apparatus. In order to remove iron fine particles having a particle size of less than 25.mu. in the feed oil which could be not removed in the prior art, by constituting a system comprising a heater for heating the feed oil to a given temperature by heat exchange with a high temperature bottom oil of a fractionating tower after hydrogenation treatment of the feed oil, a filter equipped with a back washing mechanism for filtering solid materials in the feed oil after heating, and a high gradient magnetic separator for magnetically separating magnetic iron fine particles having a particle size of less than 25.mu. contained in the feed oil.Type: GrantFiled: July 6, 1994Date of Patent: August 6, 1996Assignees: Nippon Oil Company, Ltd., Nippon Petroleum Refining Company, Ltd.Inventors: Hajime Okazaki, Manabu Kazato, Masaoki Ouchi, Haruki Nagano, Masaru Ushio, Kozo Kamiya
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Patent number: 5541271Abstract: A polyolefin having superior particle properties such as an extremely high bulk density, a large average particle diameter and a narrow particle size distribution, and having a narrow molecular weight distribution, is obtained in high yield, by polymerizing an olefin, using a catalyst comprising a solid catalyst component and an organometallic compound, the solid catalyst component being obtained by reacting a) a silicon oxide and/or an aluminum oxide, the reaction product of an organomagnesium compound and a compound of the general formula Me(OR).sub.n X.sub.Z-n, and a titanium compound, in the presence of ROH, and further reacting the resulting reaction product with a compound of the general formula AlR.sub.q X.sub.3-q.Type: GrantFiled: January 30, 1995Date of Patent: July 30, 1996Assignee: Nippon Oil Company, LimitedInventors: Akira Sano, Shiraishi Takeichi, Kunihiro Suzuki, Mitsuo Okamoto, Katsumi Usui, Hiroyuki Shimizu, Kazuo Matsuura
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Patent number: 5536426Abstract: An electrorheological fluid comprising an electrically insulating liquid and acid, iodine or alcohol-treated, or iodine-treated and subsequently electrically insulating film-coated, dispersible carbonaceous particles dispersed therein has a high electrorheological effect even without lowering in a high temperature region, though it is a water-free system.Type: GrantFiled: May 18, 1994Date of Patent: July 16, 1996Assignee: Nippon Oil Company, Ltd.Inventors: Makoto Sasaki, Yukio Kobayashi, Katsuhiko Haji