Patents Assigned to Nippon Oil Company
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Patent number: 5438090Abstract: A masterbatch composition for thermoplastic resin modification containing a polybutene and an ethylene-.alpha.-olefin copolymer obtained by copolymerizing ethylene with .alpha.-olefin in the presence of specific catalysts and characterized by specific properties, and a method for preparing the composition by kneading and extrusion at a temperature ranging from the maximum peak temperature (Tm) to (Tm-45).degree. C. in accordance with differential scanning calorimetry of the copolymer are disclosed.Masterbatch pellets for thermoplastic resin modification having low surface tackiness can be obtained from the composition.Type: GrantFiled: March 27, 1990Date of Patent: August 1, 1995Assignee: Nippon Oil Company, Ltd.Inventors: Saburo Matsubara, Yoshihiro Goushi
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Patent number: 5433937Abstract: A simple manufacturing process for obtaining a carbon/carbon composite of superior performance is provided without using a carbon fiber fabric which is expensive and without going through the step of fixing fibers together using a binder.A precursor fiber for a carbon fiber which precursor fiber has been rendered infusible is subjected to uniaxial pressing at a temperature lower than the temperature adopted in the infusiblizing treatment, and then a carbonization treatment is performed.According to the present invention, a primary-pressed carbon material can be produced without using a binder, thus resulting in that not only the carbon material but also a carbon/carbon composite can be produced in a simple manner.Type: GrantFiled: December 6, 1993Date of Patent: July 18, 1995Assignee: Nippon Oil Company, Ltd.Inventors: Yoshio Sohda, Yutaka Sonokawa, Takefumi Kohno
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Patent number: 5432249Abstract: The present invention provides a novel liquid crystalline polyester comprising structural units represented by the following general formulae A, B, C and D: ##STR1## where X and Y are each independently H, Cl, Br or an alkyl group having 1 to 4 carbon atoms, the molar ratio of A/B is in the range from 49/1 to 20/30 and that of C/D is in the range from 10/40 to 45/5.Type: GrantFiled: December 21, 1994Date of Patent: July 11, 1995Assignee: Nippon Oil Company, LimitedInventors: Yoshihiro Kumagai, Takuya Matsumoto, Iwane Shiozaki, Shigeki Takikawa
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Patent number: 5432236Abstract: According to the present invention, in a vapor phase polymerization of olefins, there is provided an efficient polyolefin manufacturing process capable of preventing the formation of a sheet-like polymer and allowing an olefin polymerization reaction to be started stably.Type: GrantFiled: February 18, 1994Date of Patent: July 11, 1995Assignee: Nippon Oil Company, LimitedInventors: Akira Sano, Kunimichi Kubo, Kazuo Matsuura
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Patent number: 5413657Abstract: A compensator for a liquid crystal display device is made by applying a solution containing a liquid crystalline polymer onto an orientation substrate, then allowing the liquid crystalline polymer to be oriented, and thereafter transferring the resulting layer of the liquid crystalline polymer on the orientation substrate onto a light transmitting substrate, said solution containing the liquid crystalline polymer having incorporated therein 0.01% to 10% by weight of a surface active agent relative to the liquid crystalline polymer.Type: GrantFiled: June 3, 1993Date of Patent: May 9, 1995Assignee: Nippon Oil Company, LimitedInventors: Teruaki Yamanashi, Shinichirou Suzuki, Yoshio Tsujimoto, Toshikazu Kiyohara
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Patent number: 5411558Abstract: An oil-in-water type heavy oil emulsion fuel having a specific and broad particle size distribution which has a viscosity close to that of water, can be sufficiently atomized at a temperature of room temperature to 90.degree. C., is excellent in the handleability and fluidity, despite a very high heavy oil concentration, and has a very excellent stability such that neither precipitation nor increase in the viscosity occurs even after storage for a long period of time is prepared according to the present invention. Oil-in-water type heavy oil emulsion fuel according to the present invention can be used as a substitute fuel for heavy fuel oil without modification of the boilers. Further, the combustion efficiency of the heavy oil emulsion fuel according to the present invention is high and it is possible to reduce the amount of nitrogen oxides and sulfur oxides after combustion.Type: GrantFiled: August 26, 1993Date of Patent: May 2, 1995Assignees: Kao Corporation, Nippon Oil Company, LimitedInventors: Takao Taniguchi, Masanori Iizuka, Kazuo Isobe, Sayuri Tamaki, Shinichi Satake, Tadakazu Yamashita
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Patent number: 5391660Abstract: Polyolefins having a high molecular weight, an appropriate molecular weight distribution and a relatively narrow composition distribution are prepared in high activity.The polymerization of an olefin or olefins is performed in the presence of a catalyst comprising a catalyst component and a modified organoaluminum compound, the catalyst component being prepared by mutually contacting (1) a compound of the general formula Me.sup.1 R.sup.1.sub.n X.sup.1.sub.4-n and (2) an alkali metal salt of cyclopentadiene or indene and optionally (3) a compound of the general formula Me.sup.2 R.sup.2.sub.m X.sup.2.sub.3-m, and the modified organoaluminum compound and water and containing Al--O--Al bond(s).Type: GrantFiled: January 12, 1993Date of Patent: February 21, 1995Assignee: Nippon Oil Company, LimitedInventors: Yosuke Numao, Yoshio Tajima
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Patent number: 5391688Abstract: It is intended to provide a liquid crystalline polyester whose orientation in the state of liquid crystal can be easily immobilized as glass phase and which is suitable for application to optical elements.A liquid crystalline polyester comprising repeating units a, b, c and d represented by the following general formulae: ##STR1## where X and Y are each independently a hydrogen atom, Cl, Br or an alkyl group having 1 to 4 carbon atoms, the repeating units a, b, c and d being in mole ratios such that (a+b)/(c+d) is approximately 1, a/b is in the range from 98/2 to 50/50 and c/d is in the range from 70/30 to 10/90.Type: GrantFiled: January 18, 1994Date of Patent: February 21, 1995Assignee: Nippon Oil Company, LimitedInventors: Hitoshi Mazaki, Takehiro Toyooka, Iwane Shiozaki
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Patent number: 5382482Abstract: According to the present invention there is provided a negative zinc electrode for an alkaline storage battery, comprising an electrode using zinc as an active material and a polymer layer which is substantially in direct contact with the electrode, the polymer layer containing at least a polymer having a crosslinked structure. There is also provided an alkaline storage battery using such negative zinc electrode and in which the occurrence of dendrites and shape change is suppressed.Type: GrantFiled: July 29, 1993Date of Patent: January 17, 1995Assignee: Nippon Oil Company, LimitedInventors: Masanobu Suga, Seiichi Akita, Nobuyuki Kuroda
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Patent number: 5372614Abstract: A sludge dispersing agent for fuel oils includes a polymer having at least one >C.dbd.N.sup.+ < bond in its molecule and at least one compound selected from the group consisting of long-chain alkyl phosphates and alkyl sulfosuccinates and salts thereof.Type: GrantFiled: March 29, 1993Date of Patent: December 13, 1994Assignees: Nippon Zeon Co., Ltd., Nippon Oil CompanyInventors: Shizuo Kitahara, Kazuhisa Kanefuji, Akio Oda, Hiromoto Inoura, Shigeru Kinomoto
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Patent number: 5369193Abstract: Polyolefins exhibiting better particle properties are prepared by polymerizing an olefin or olefins in the presence of a catalyst comprising a solid catalyst component and an organometallic compound, the solid catalyst component being prepared by reacting the following components [I] and [II] at first and then reacting the reaction product thus obtained with the following component [III]:[I] a reaction product obtained by reacting:(1) a silicon oxide and/or an aluminum oxide, and(2) a titanium compound, or a titanium compound and a vanadium compound,[II] a reaction product obtained by the reaction of:(1) a magnesium halide,(2) a compound represented by the general formula Me(OR).sub.n X.sub.z-n wherein Me represents an element of J Groups I to IV in the Periodic Table, z represents the valence of the element Me, n is 0<n.ltoreq.Type: GrantFiled: October 27, 1992Date of Patent: November 29, 1994Assignee: Nippon Oil Company, LimitedInventors: Akira Sano, Takeichi Shiraishi, Kunihiro Suzuki, Mitsuo Okamoto, Kazuo Matsuura
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Patent number: 5359036Abstract: Disclosed herein are methods and means of producing novel growth hormone-like proteins derived from the pituitary gland of fishes belonging to the order Pleuronectina, the family Paralichthydae, which are useful in the growth promotion for fishes, by genetic engineering using cloned genes.Type: GrantFiled: February 15, 1991Date of Patent: October 25, 1994Assignee: Nippon Oil Company, LimitedInventors: Shusaku Sakata, Hiroshi Kawauchi, Masao Ono
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Patent number: 5359443Abstract: A process for producing an optical element using a liquid crystalline polymer and superior in heat resistance is provided. In a process for producing an optical element comprising a light transmitting substrate, an alignment film formed on the substrate and a layer of a liquid crystalline polymer formed on the alignment film, or in a process for producing an optical element, involving transferring a layer of a liquid crystalline polymer formed on an orientating substrate onto a light transmitting substrate, the said liquid crystalline polymer being a heat-polymerizable polymer which exhibits a nematic orientation or a twisted nematic orientation in the state of liquid crystal and which assumes a glassy state at a temperature below the liquid crystal transition point thereof, the liquid crystalline polymer layer is heat-treated during an orientating treatment, or after fixing of the orientation obtained, or after the transfer.Type: GrantFiled: November 23, 1992Date of Patent: October 25, 1994Assignee: Nippon Oil Company, LimitedInventors: Takehiro Toyooka, Hiroyuki Itoh
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Patent number: 5358661Abstract: It is intended to provide a novel polyester which is optically active, can be prepared easily and inexpensively and is superior in stability and solubility in solvents.A liquid crystalline polyester consisting essentially of repeating units represented by the following formulae (a), (b), or (b') and (c): ##STR1## where the repeating unit c contains an optically active carbon and X is an alkyl group having 1 to 4 carbon atoms or a halogen atom, the repeating units a, b or b' and c being in mole ratios such that a/b is in the range from 95/5 to 5/95, a/b' is range from 95/5 to 50/50 and (a+b)/c or (a+b')/c is approximately 1.Type: GrantFiled: January 26, 1994Date of Patent: October 25, 1994Assignee: Nippon Oil Company, LimitedInventors: Hitoshi Mazaki, Takuya Matsumoto
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Patent number: 5348820Abstract: A negative zinc electrode for an alkaline storage battery capable of suppressing the occurrence of dendrite and shape change is provided. The negative zinc electrode comprises an electrode using zinc as an active material and a polymer layer formed substantially in direct contact with the electrode, the polymer layer comprising a polymer having an oxygen permeability constant of not less than 1.times.10.sup.-10 cm.sup.3 (STP) cm.sup.-1 s.sup.-1 cmHg.sup.-1.Type: GrantFiled: July 9, 1993Date of Patent: September 20, 1994Assignee: Nippon Oil Company, LimitedInventors: Masanobu Suga, Seiichi Akita, Nobuyuki Kuroda
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Patent number: 5346724Abstract: An oil and fat composition for food processing machines comprises polyglycerides of medium chain saturated fatty acids and/or mixed polyglycerides of medium chain saturated fatty acids and long chain saturated fatty acids and, optionally, triglycerides of medium chain saturated fatty acids. The composition is safe for food sanitation, has excellent oxidation stability and lubricating property and a suitable degree of viscosity and cloud point as well as a high viscosity and a low temperature fluidity which cannot be attained by MCT and is favorably utilized as lubricating oil for food processing machines and tools and agricultural machines and tools.Type: GrantFiled: January 5, 1993Date of Patent: September 13, 1994Assignee: Nippon Oil Company, Ltd.Inventors: Ryoji Ohgake, Mitsuo Okada, Hiroyuki Takashima, Teruo Shimizu, Narihito Yamamoto
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Patent number: 5342532Abstract: A lubricating oil composition comprises an alkylnaphthalene which has one or two alkyl groups each having from 8 to 30 carbon atoms, and at least one member selected from benzo(b)thiophene and derivatives thereof, and naphthalenethiol and derivatives thereof. The composition has good oxidative stability.Type: GrantFiled: September 23, 1992Date of Patent: August 30, 1994Assignee: Nippon Oil Company, Ltd.Inventors: Mitsuhiko Takei, Toshio Yoshida, Yoshiaki Nagai, Koji Masamizu
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Patent number: 5342982Abstract: Silicon-containing organic compounds useful as starting materials of functional polymer materials, as well as a process for preparing the same, are provided. The silicon-containing organic compounds are represented by the following general formula: ##STR1## where R.sup.1 is a .pi. conjugated type divalent organic group having 2 to 30 carbon atoms, R.sup.2 is a hydrocarbon group having 1 to 30 carbon atoms, X.sup.1 is a halogen atom, m and n satisfy the conditions of 1.ltoreq.m.ltoreq.2 and n.gtoreq.2, respectively. A compound of the above general formula is prepared by reacting an organometallic compound of the following general formula:M.sup.1 -R.sup.1 -M.sup.2where M.sup.1 and M.sup.2 are each a metal selected from Group 1, 2 and 12 metals in the Periodic Table, with a silane compound of the following general formula: ##STR2## where R.sup.2 is a hydrocarbon group having 1 to 30 carbon atoms, X.sup.1, X.sup.2 and X.sup.3 are each a halogen atom.Type: GrantFiled: June 24, 1993Date of Patent: August 30, 1994Assignee: Nippon Oil Company, LimitedInventors: Masaki Minami, Keizo Ikai, Mitsuo Matsuno
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Patent number: 5340869Abstract: A binder composition comprising a petroleum resin, an aromatic heavy mineral oil, a thermoplastic elastomer, an ethylene copolymer and a waxy substance has a high viscosity at 60.degree. C. and a low viscosity at high temperatures, and can provide a mixture together with aggregate having remarkably high compressive strength.Type: GrantFiled: April 23, 1993Date of Patent: August 23, 1994Assignee: Nippon Oil Company, Ltd.Inventors: Masao Isobe, Yoshio Aizawa, Kenichi Kogo, Chuzo Yoshida
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Patent number: 5336605Abstract: A process for the preparation of an adventive embryo of a plant belonging to the genus Podophyllum, comprising the steps of preparing cells of a plant belonging to the genus Podophyllum, incubating the cells in a sugar free medium or a medium containing up to 2% by weight sugar, and then incubating the cells in a medium containing more than 2% by weight of sugar to generate an adventive embryo; a process for the production of a podophyllotoxin compound comprising the steps of preparing an adventive embryo of a plant belonging to the genus Podophyllum, culturing the adventive embryo to generate an adventitious organ, culturing the adventitious organ to produce a podophyllotoxin compound, and recovering the podophyllotoxin compound; and a process for the production of a podophyllotoxin compound, comprising the steps of preparing de-differentiated cells or tissue of a plant belonging to the genus Podophyllum culturing the de-differentiated cells or tissue in a liquid medium to generate a differentiated organ, cuType: GrantFiled: February 1, 1993Date of Patent: August 9, 1994Assignee: Nippon Oil Company, Ltd.Inventors: Ko Sakata, Eitaroh Morita, Tetsuya Takezono