Abstract: Multilayer Films have a first skin layer that is prepared from a high density polyethylene and a second skin layer (also referred to as the sealant layer) that is prepared from a linear low density polyethylene (LLDPE) having a density of from 0.90 to 0.92 g/cc and a Dilution Index, Yd, of greater than 0°. Seals can be prepared by placing two pieces of this film against each other such that the sealant layers are in contact with each other, then applying heat to at least one high density skin layer such that heat is transmitted/conducted through the multilayer film in a sufficient amount to melt the sealant layer and form a seal. The use of LLDPE having a Dilution Index of greater than 0° has been found to improve the sealing performance of multilayer films in comparison to multilayer films where the sealant layer is a conventional LLDPE having a Dilution Index of less than 0°.

Abstract: This disclosure relates to ethylene interpolymer products comprising a Melt Flow-Intrinsic Viscosity Index value, MFIVI, of from ? 0.05 to ? 0.80; a first derivative of a melt flow distribution function, formula (I) at a loading of 4000 g, of from ? -1.85 to ?-1.51; a sum of unsaturation, SUMU, from ? 0.047 to ? 0.100 unsaturations per 100 carbon atoms; and a residual catalytic metal of from ? 0.03 to ? 5 ppm of hafnium. Ethylene interpolymer products comprise at least two ethylene interpolymers. Ethylene interpolymer products are characterized by a melt index (I2) from 0.3 to 500 dg/minute, a density from 0.855 to 0.975 g/cc and from 0 to 25 mole percent of one or more a-olefins. Ethylene interpolymer products have polydispersity, Mw/Mn, from 1.7 to 25; and CDBI50 values from 1% to 98%. These ethylene interpolymer products have utility in flexible as well as rigid applications.

Abstract: Provided in this disclosure are titanium complexes that contain 1) a cyclopentadienyl ligand; 2) an adamantyl-phosphinimine ligand; and 3) at least one activatable ligand. The use of such a complex, in combination with an activator, as an olefin polymerization catalyst is demonstrated. The catalysts are effective for the copolymerization of ethylene with an alpha olefin (such as 1-butene, 1-hexene or 1-octene) and enable the production of high molecular weight copolymers (Mw greater than 25,000) at high productivity under solution polymerization conditions.

Abstract: High density polyethylene compositions having a high flow index and a bimodal composition provides an outstanding combination of processability, stiffness and ductility in rotomolded articles. The compositions have a low relative elasticity (G?/G?, measured at 0.05 rad/sec) of less than 0.03.

Abstract: Mixed metal oxide catalysts having an amorphous content of not less than 40 wt. % are prepared by calcining the catalyst precursor fully or partially enclosed by a porous material having a melting temperature greater than 600° C. in an inert container including heating the catalyst precursor at a rate from 0.5 to 10° C. per minute from room temperature to a temperature from 370° C. to 540° C. under a stream of pre heated gas chosen from steam and inert gas and mixtures thereof at a pressure of greater than or equal to 1 psig having a temperature from 300° C. to 540° C. and holding the catalyst precursor at that temperature for at least 2 hours and cooling the catalyst precursor to room temperature.

Abstract: An ethylene interpolymer product comprises from 40 to 80 weight % of a first ethylene interpolymer having a molecular weight distribution index of Formula (I), and, from 20 to 60 weight % of a second ethylene interpolymer having a molecular weight distribution index of Formula (II), wherein said ethylene interpolymer product is characterized by a dilution Index, Yd, greater than 0, and, a solid-to-liquid transition temperature not greater than 112° C. The ethylene interpolymer product may be further characterized as having a weighted Rheological Adhesion Parameter, Rhadh, greater than 1.5. Films made from the ethylene interpolymer product composition have a hot tack seal onset temperature less than 90° C. and a hot tack window at 2.5N measured on a 2 mil blown film no less than 30° C.

Abstract: A new olefin polymerization catalyst is ligated with a tetradentate ligand having a phenoxy/amino/ether/phenoxy (O/N/O/O) atom donor set. The new polymerization catalyst which is based on zirconium or hafnium produces an ethylene copolymer with high molecular weight and high comonomer incorporation levels.

Abstract: A thermoformable film comprises a polyethylene composition. The polyethylene composition comprises a first polyethylene which is an ethylene copolymer having a weight average molecular weight of from 70,000 to 250,000 and a molecular weight distribution Mw/Mn of <2.3, a second polyethylene which is an ethylene copolymer or homopolymer having a weight average molecular weight of from 15,000 to 100,000 and a molecular weight distribution Mw/Mn of <2.3, and a third polyethylene which is an ethylene copolymer or homopolymer having a weight average molecular weight of from 70,000 to 250,000 and a molecular weight distribution Mw/Mn of >2.3, where the first polyethylene has more short chain branching than the second polyethylene or the third polyethylene. The polyethylene composition has a melt flow ratio (I21/I2) of ?50 and an area Dimensional Thermoformability Index (aDTI) at 105° C. of less than 15.

Abstract: A composition comprising a high molecular weight, chromium catalyzed ethylene copolymer (also referred to as a polyethylene resin), a nucleating agent and zinc oxide.

Abstract: Oxidative dehydrogenation catalysts comprising MoVNbTeO having improved consistency of composition and a 25% conversion of ethylene at less than 420° C. and a selectivity to ethylene above 95% are prepared by treating the catalyst precursor with H2O2 in an amount equivalent to 0.30-2.8 mL H2O2 of a 30% solution per gram of catalyst precursor prior to calcining and treating the resulting catalyst with the equivalent amount of peroxide after calcining.

Abstract: An all polyethylene multilayer film structure having alternating layers of (A) a linear low density polyethylene and (B) a high density polyethylene has improved performance properties relative to a film structure in which the (A) and (B) layers are arranged in a block like or random manner.

Abstract: A rotomolding composition comprises a blend of two polyethylenes: 1) a well stabilized polyethylene; and 2) a poorly stabilized polyethylene having a very low flow rate. The poorly stabilized polyethylene is further characterized by having a large particle size (from 500 to 3000 microns). Rotomolded parts prepared from the composition have a rough inner surface. Polyurethane foam adheres well to this rough surface.

Abstract: A polyethylene composition suitable for rotomolding and comprising a blend of a stabilized polyethylene, and optionally a substantially non-stabilized polyethylene, with a recycled polymer (PCR), is described. By using a PCR with a higher density and lower melt flow as compared to the stabilized polyethylene, a higher portion of the recycled polymer is present on the interior surface f the rotomolded part. Oxidation of the recycled polymer results in formation of oxidized species, such as carbonyl groups, on the interior surface of the part, which along with higher surface roughness enhances adhesion between the interior surface and coatings or fillings, such as polyurethane, used to provide a layer of insulation or improve structural strength or buoyancy.

Abstract: This disclosure relates to ethylene interpolymer compositions and films prepared therefrom. Specifically: ethylene interpolymer products having: a dimensionless nonlinear rheology network parameter, ?int., greater than or equal to 0.01, satisfying 0.01×(Z?50)0.78??int.?0.01×(Z?60)0.78 inequality wherein Z is a normalized molecular weight defined by Z = M w M e where Mw and Me are the weight average and entanglement molecular weights, and; a residual catalytic metal of from ?0.03 to ?5 ppm of hafnium. The disclosed ethylene interpolymer products have a melt index from about 0.3 to about 500 dg/minute, a density from about 0.855 to about 0.975 g/cc, a polydispersity, M w M n , from about 1.7 to about 25 and a Composition Distribution Breadth Index (CDBI50) from about 1% to about 98%.

Abstract: A polymer suitable for use in a thin film hinge (living hinge) comprising from about 0.1 to about 5 weight % of a C4-8 comonomer and the balance ethylene, said composition having a density as determined according to ASTM D 792 from about 0.945 to about 0.965 g/cm3; a melt index as determined according to ASTM D1238 (2.16 kg/190° C.) from about 10 to about 20 g/10 min; a weight average molecular weight (Mw) from about 45,000 to about 55,000 g/mol; a polydispersity from about 2.5 to about 3.1 and when molded into a strip having a length of about 13 cm and gross thickness from about 50 to about 70 mil (about 1 to about 2 mm) and completely bent over end to end four times to create a thinned region or crease having a thickness from about 15 to about 30 mil (about 0.3 to about 0.7 mm) tested by bending and releasing the deformed thinned region of the strip through a radius of curvature from about 180 to about 190° about a rounded plate goes through not less than 500 cycles without breaking.

Abstract: Disclosed herein are polymerization processes where recycled polymeric material is fed to polymerization process to produce a blend of virgin polymer with recycled polymeric content.

Abstract: Disclosed herein are processes for producing blends of recycled polymeric material and virgin polyethylene. Post-consumer recycled plastic (PCR) can vary widely with respect to composition which includes mixtures of variable amounts of different polar and non-polar polymers such as polyethylene, polypropylene, ethylene vinyl alcohol, and polyamide. Mixing PCR and virgin polyethylene is inconsistent, partially due to variability, and frequently results in a final product with poor mechanical and optical properties. The process described herein of adding PCR to a solution polymerization process provides another option for blending PCR and virgin polyethylene that offers an ability to exert greater control on the properties of the final product, independent of the composition of the PCR.

Abstract: A process, a system, and an apparatus are provided for converting a lower alkane to an alkene. Oxygen and the lower alkane are provided to an ODH reactor to convert at least a portion of the lower alkane to an alkene. An ODH stream comprising the alkene, an oxygenate, steam, and a carbon-based oxide is produced. The bulk of the oxygenate is removed from the ODH outlet stream by non-dilutive cooling, with residual oxygenate being removed using dilutive quenching with a carbonate. Subsequently, separation of the carbon-based oxide from the alkene is achieved using a caustic tower, which also produces spent caustic in the form of a carbonate, which is then used as the carbonate for dilutive quenching. Dilutive quenching using a carbonate allows conversion of the oxygenate to an acetate, which can then be used to simplify separation of the oxygenate from water.

Abstract: Multilayer Films have a first skin layer that is prepared from a high density polyethylene and a second skin layer (also referred to as the sealant layer) that is prepared from a linear low density polyethylene (LLDPE) having a density of from 0.90 to 0.92 g/cc and a Dilution Index, Yd, of greater than 0°. Seals can be prepared by placing two pieces of this film against each other such that the sealant layers are in contact with each other, then applying heat to at least one high density skin layer such that heat is transmitted/conducted through the multilayer film in a sufficient amount to melt the sealant layer and form a seal. The use of LLDPE having a Dilution Index of greater than 0° has been found to improve the sealing performance of multilayer films in comparison to multilayer films where the sealant layer is a conventional LLDPE having a Dilution Index of less than 0°.

Abstract: A thermoformable film including a polyethylene composition. The polyethylene composition includes a first polyethylene which is an ethylene copolymer having a weight average molecular weight of from 70,000 to 250,000 and a molecular weight distribution Mw/Mn of <2.3, a second polyethylene which is an ethylene copolymer or homopolymer having a weight average molecular weight of less than 75,000 and a molecular weight distribution Mw/Mn of <2.3, a third polyethylene which is an ethylene copolymer or homopolymer having a weight average molecular weight of less than 75,000 and a molecular weight distribution Mw/Mn of <2.3, and a fourth polyethylene which is an ethylene copolymer or homopolymer having a weight average molecular weight of from 100,000 to 250,000 and a molecular weight distribution Mw/Mn of >2.3, where the first polyethylene has more short chain branching than the second polyethylene or the third polyethylene.