Abstract: A dual reactor solution process gives high density polyethylene compositions containing a first ethylene copolymer and a second ethylene copolymer and which have good processability, toughness, and environmental stress crack resistance. The polyethylene compositions are suitable for the preparation of rotomolded parts.

Abstract: A polyethylene composition which when made into a film layer having a thickness of about 1 mil exhibits a machine direction (MD) 1% secant modulus of ?190 MPa and an oxygen transmission rate (OTR) of ?650 cm3 per 100 inch2 per day, and when made into a film layer having a thickness of about 2 mil exhibits a seal initiation temperature (SIT) of ?100° C. and an area of hot tack window (AHTW) of ?160 Newtons·° C.

Abstract: Provided in this disclosure are catalyst compositions. The catalyst compositions include an oxidative dehydrogenation catalyst that includes a mixed metal oxide having the empirical formula: Mo1.0V0.12-0.49Te0.05-0.17Nb0.10-0.20AlcOd wherein c is from 0 to 2.0 and d is a number to satisfy the valence of the oxide. The compositions are at least 40 wt. % amorphous as measured by XRD. The disclosure also provides methods of making the compositions.

Abstract: A polymer suitable for use in a thin film hinge (living hinge) comprising from about 0.1 to about 5 weight % of a C4-8 comonomer and the balance ethylene, said composition having a density as determined according to ASTM D 792 from about 0.945 to about 0.965 g/cm3; a melt index as determined according to ASTM D1238 (2.16 kg/190° C.) from about 10 to about 20 g/10 min; a weight average molecular weight (Mw) from about 45,000 to about 55,000 g/mol; a polydispersity from about 2.5 to about 3.1 and when molded into a strip having a length of about 13 cm and gross thickness from about 50 to about 70 mil (about 1 to about 2 mm) and completely bent over end to end four times to create a thinned region or crease having a thickness from about 15 to about 30 mil (about 0.3 to about 0.7 mm) tested by bending and releasing the deformed thinned region of the strip through a radius of curvature from about 180 to about 190° about a rounded plate goes through not less than 500 cycles without breaking.

Abstract: A polyethylene composition which when made into a film layer having a thickness of about 1 mil has a machine direction (MD) 1% secant modulus of ?200 MPa and an oxygen transmission rate (OTR) of ?600 cm3 per 100 inch2 per day and when made into a film layer having a thickness of about 2 mil has a seal initiation temperature (SIT) of ?90° C. and an area of hot tack window (AHTW) of ?160 Newtons·° C.

Abstract: A multilayer film having Machine Direction Orientation (MDO) is prepared by first co-extruding a multilayer film, then stretching the multilayer film in the machine direction at a temperature lower than the melting point of the polyethylene resin that is used to prepare the film. At least one layer of the film is a first polyethylene composition having a density of from about 0.94 to about 0.97 g/cc and at least one second layer is prepared from a polyethylene composition having a lower density than the first polyethylene composition. This disclosure enables the manufacture of films having outstanding barrier properties (low Water Vapor Transmission Rate, WVTR, and low Oxygen Transmission Rate, OTR) and good physical properties.

Abstract: Barrier films are prepared from a composition comprising 1) a blend of two high density polyethylene HDPE blend components, 2) zinc glycerolate and 3) a dispersion aid/synergist. The two high density polyethylene blend components have substantially different melt indices. It is difficult to properly mix the zinc glycerolate into this HDPE blend. The use of the dispersion aid/synergist improves the water vapor transmission rate (WVTR) of polyethylene film (in comparison to barrier films made with zinc glycerolate, in the absence of the dispersion aid/synergist). The resulting barrier films are suitable for the preparation of packaging for dry foods such as crackers and breakfast cereals.

Abstract: Large volumes of recycled polyethylenes are available for reuse. It would be desirable to prepare films from recycled polyethylene, however, the technical demands for many types of films can make this very difficult. Provided herein are films, for example, stretch films; shrink films; films for vacuum packages and films for dunnage packaging, that may be prepared from a blend of recycled polyethylene with “virgin” polyethylene.

Abstract: A polyethylene composition having a high flow index and a bimodal composition provides an outstanding combination of environmental stress crack resistance (ESCR) and ductility in rotomolded articles. The composition is easy to process/mold.

Abstract: This disclosure relates to ethylene interpolymer compositions and films prepared therefrom. Specifically: ethylene interpolymer products having: a dimensionless nonlinear rheology network parameter, ?int., greater than or equal to 0.01, satisfying 0.01×(Z?50)0.78??int.?0.01×(Z?60)0.78 inequality wherein Z is a normalized molecular weight defined by Z = M w M e where Mw and Me are the weight average and entanglement molecular weights, and; a residual catalytic metal of from ?0.03 to ?5 ppm of hafnium. The disclosed ethylene interpolymer products have a melt index from about 0.3 to about 500 dg/minute, a density from about 0.855 to about 0.975 g/cc, a polydispersity, M w M n , from about 1.7 to about 25 and a Composition Distribution Breadth Index (CDBI50) from about 1% to about 98%.

Abstract: A polyethylene composition includes a first polyethylene which is an ethylene copolymer having a weight average molecular weight of from 70,000 to 250,000 and a molecular weight distribution Mw/Mn of <2.3, a second polyethylene which is an ethylene copolymer or homopolymer having a weight average molecular weight of from 15,000 to 100,000 and a molecular weight distribution Mw/Mn of <2.3, and a third polyethylene which is an ethylene copolymer or homopolymer having a weight average molecular weight of from 70,000 to 250,000 and a molecular weight distribution Mw/Mn of >2.3, where the first polyethylene has more short chain branching than the second polyethylene or the third polyethylene. The polyethylene composition has a soluble fraction in a CEF analysis of at least 10 weight percent. Film made from the polyethylene composition may have a machine direction 1% secant modulus of ?190 MPa (at a film thickness of about 1 mil), a seal initiation temperature (SIT) of ?100° C.

Abstract: A polyethylene composition comprises a first polyethylene which is an ethylene copolymer having a weight average molecular weight of from 70,000 to 250,000 and a molecular weight distribution Mw/Mn of <2.3, a second polyethylene which is an ethylene copolymer or homopolymer having a weight average molecular weight of from 50,000 to 200,000 and a molecular weight distribution Mw/Mn of <2.3, and a third polyethylene which is an ethylene copolymer or homopolymer having a weight average molecular weight of from 70,000 to 200,000 and a molecular weight distribution Mw/Mn of <2.3, where the first polyethylene has more short chain branching than the second polyethylene or the third polyethylene. The polyethylene composition has a composition distribution breadth index, CDBI50 obtained from a crystallization elution fractionation (CEF) analysis of <45 weight %.

Abstract: The devolatilization of plastomer pellets is undertaken using nitrogen that is recycled in the process. Volatile hydrocarbons are removed from the nitrogen in a hydrocarbon extraction vessel (e.g. an adsorbent bed). In an embodiment, the recycled nitrogen contains less than 300 ppm of volatile hydrocarbons after being treated in the adsorbent bed.

Abstract: A phosphinimide catalyst system comprises: i) a phosphinimide pre-polymerization catalyst having two phosphinimide ligands, at least one of which is substituted by a phosphinimide moiety; and ii) a catalyst activator. The catalyst system polymerizes ethylene with an alpha-olefin to give high molecular weight ethylene copolymer.

Abstract: This document relates to oxidative dehydrogenation catalysts that include molybdenum, vanadium, and oxygen.

Abstract: A dual reactor solution process gives high density polyethylene compositions containing a first ethylene copolymer and a second ethylene copolymer and which have good processability, stiffness, and environmental stress crack resistance. The polyethylene compositions are suitable for compression molding or injection molding applications and are particularly useful in the manufacture of caps and closures for bottles.

Abstract: A phosphinimide catalyst system comprises: i) a phosphinimide pre-polymerization catalyst having a cyclopentadienyl ligand and a phosphinimide ligand which is substituted with a guanidinate type group; and ii) a catalyst activator. The catalyst system polymerizes ethylene with an alpha-olefin to give high molecular weight ethylene copolymer.

Abstract: A polyethylene composition includes a first polyethylene which is an ethylene copolymer having a weight average molecular weight of from 70,000 to 250,000 and a molecular weight distribution Mw/Mn of <2.3, a second polyethylene which is an ethylene copolymer or homopolymer having a weight average molecular weight of from 15,000 to 100,000, a molecular weight distribution Mw/Mn of >2.3, and a third polyethylene which is an ethylene copolymer or homopolymer having a weight average molecular weight of from 70,000 to 250,000 and a molecular weight distribution Mw/Mn of >2.3, where the first polyethylene has more short chain branching than the second polyethylene or the third polyethylene. The polyethylene composition has a soluble fraction in a CEF analysis of at least 10 weight percent. Film made from the polyethylene composition may have a machine direction 1% secant modulus of 200 ?MPa (at a film thickness of about 1 mil), a seal initiation temperature (SIT) of ?90° C.

Abstract: Provided in this disclosure are oxidative dehydrogenation catalysts that include a mixed metal oxide having the empirical formula: Mo1.0V0.12-0.49Te0.05-0.17Nb0.10-0.20Od wherein d is a number to satisfy the valence of the oxide. The oxidative dehydrogenation catalyst is characterized by having XRD diffraction peaks (2? degrees) at 22±0.2, 27±0.2, 28.0±0.2, and 28.3±0.1. The disclosure also provides methods of making the catalysts that include wet ball milling.

Abstract: A one pot synthetic method for making a bridged cyclopentadienyl/fluorenyl type ligand and the corresponding ansa metallocene polymerization catalyst. In a key step, a cyclopentadienide/fluorenide dianion is prepared by combining a fluorene compound, a fulvene compound, and at least 2 molar equivalents of KN(SiMe3)2 in any order in the presence of an ether solvent under ambient conditions. Reaction of the cyclopentadienide/fluorenide dianion with a Group IV transition metal chloride, followed by alkylation gives a metallocene polymerization catalyst in good yields.