Abstract: A catalyst coating for use in a hydrolysis catalyst (H-catalyst) for the reduction of nitrogen oxides, a manufacturing method for such a coating, a catalyst structure and its use are described. The H-catalyst includes alkaline compounds, which are capable of adsorbing HNCO and/or nitrogen oxides and which include alkali and alkaline earth metals, lanthanum and/or yttrium and/or hafnium and/or prasedium and/or gallium, and/or zirconium for promoting reduction, such as for promoting the hydrolysis of urea and the formation of ammonia and/or the selective reduction of nitrogen oxides.
Abstract: In making frangible objects, including lead-free bullets and other projectiles, powdered metal primary and powdered ceramic secondary phases are mixed and densified at an elevated temperature such that the ceramic phase forms a brittle network. Different combinations of metal and ceramic phases may be used to achieve desired chemical and physical properties. Any appropriate mixing, forming, and/or thermal processing methods and equipment may be used. Degrees of frangibility, strength, and toughness can be adjusted to suit a given application by precursor selection, degree of mixing, relative amounts of metal and ceramic phases, forming method, and thermal and mechanical processing parameters.
Abstract: A method for phlegmatizing an explosive in an aqueous suspension including a dispersed phlegmatizing agent. The phlegmatizing agent is deposited on a surface of the explosive at low temperature utilizing opposite electric charges of the phlegmatizing agent and the explosive. Also a device and a phlegmatized explosive.
Abstract: One embodiment of the invention provides an alloy with a density greater than 10 g/cm3, the alloy comprising a single phase solution of tungsten, nickel, and iron. Also provided is a cone liner for use in shaped charges, the liner comprised of a tungsten, nickel, iron alloy having a single phase microstructure. Substantially no precipitates or second phases exist in the alloy.
Abstract: This invention relates to detonator-sensitive assembled booster charges for use in blasting engineering. The booster charge comprises nitroalkane and a cavity-forming agent.
Abstract: Disclosed herein are energetic compositions and methods of making thereof. A composition includes particles of a nitrogen-containing oxidizer dispersed in a polymeric binder and a bonding agent bonded to a surface of at least a portion the particles. The bonding agent disclosed is a Lewis acid.
Type:
Grant
Filed:
May 2, 2014
Date of Patent:
March 12, 2019
Assignee:
RAYTHEON COMPANY
Inventors:
Thomas M. Deppert, Carl Shanholtz, David R. Smith
Abstract: This invention relates to a thermal hydrogen generator and a process and system for generating hydrogen gas, more specifically to a process and system for generating hydrogen gas by thermally decomposing a metal hydride.
Abstract: A reduced toxicity pyrotechnic strobe composition and method includes creating a mixture of strontium nitrate, magnalium, sulfur, and no more than 10 parts by weight of a nitrocellulose binder. The strontium nitrate may comprise 27 percent of the mixture. The magnalium may comprise a 50:50 blend of magnesium and aluminum. The magnalium may comprise 18 percent of the mixture. The sulfur may comprise 55 percent of the mixture. The mixture may include a pulse rate of approximately one pulse per minute. The method may further include modifying the pulse rate of the mixture. The method may further include using a reduced particle size of the magnalium. The method may further include substituting no more than 12.5% of the strontium nitrate with potassium nitrate.
Type:
Grant
Filed:
March 12, 2015
Date of Patent:
February 19, 2019
Assignee:
The United States of America as Represented by the Secretary of The Army
Abstract: Systems and methods for releasing a material into an environment. The material may be encapsulated in a receptacle or otherwise packaged for movement into the environment. The receptacle with the material inside is introduced into the environment. A triggering causes release of the material from the receptacle into the environment.
Type:
Grant
Filed:
January 29, 2016
Date of Patent:
February 19, 2019
Assignee:
Lawrence Livermore National Security, LLC
Inventors:
William C. Floyd, III, Roger D. Aines, Eric B. Duoss, John J. Vericella
Abstract: Disclosed herein are energetic compositions and methods of making thereof. A composition includes perchlorate or nitrate containing oxidizer particles, a polymeric binder, and a borylated ferrocene derivative bonding agent bonded to a surface of at least a portion the perchlorate or nitrate containing oxidizer particles to form a Lewis complex.
Abstract: A method of deploying an apparatus in a wellbore comprises positioning a device at a predetermined location; wherein the device comprises a composition that contains an expandable graphite, and a metallic binder, and wherein the composition has a first shape; and exposing the composition to a microwave energy to cause the composition to attain a second shape different from the first shape. Alternatively, the composition further comprises an activation material comprising a thermite, a mixture of Al and Ni, or a combination comprising at least one of the foregoing and a method of deploying an apparatus comprising such a composition includes exposing the composition to a selected form of energy.
Type:
Grant
Filed:
September 30, 2014
Date of Patent:
February 5, 2019
Assignee:
BAKER HUGHES, A GE COMPANY, LLC
Inventors:
Lei Zhao, Caleb R. Newman, Edward T. Wood, Zhiyue Xu
Abstract: An explosive assembly includes a first explosive unit having a first longitudinal end portion having a first mechanical coupling feature, a second explosive unit having a second longitudinal end portion having a second mechanical coupling feature, and a tubular connector having a first end portion mechanically coupled to the first mechanical coupling feature and a second end portion mechanically coupled to the second mechanical coupling feature, such that the first explosive unit, the connector, and the second explosive unit are connected together end-to-end along a common longitudinal axis. Each explosive unit can contain a high explosive material and a detonator, and the connector can comprise a detonation control module electrically coupled to the detonators and configured to detonate the explosive units.
Abstract: A shape memory article comprises a shape memory material that transitions to a first shape from a second shape when a temperature of the shape memory material exceeds a threshold temperature. A plurality of microcapsules is in thermal contact with the shape memory material. Each microcapsule in the plurality of microcapsules has a first compartment, a second compartment, and an isolating structure separating the first and second compartments. The isolating structure is rupturable in response to a stimulus. The first compartments each contain a first component, and the second compartments each contain a second component that reacts with the first component to produce heat.
Type:
Grant
Filed:
July 28, 2016
Date of Patent:
January 1, 2019
Assignee:
International Business Machines Corporation
Inventors:
Daniel J. Buvid, Eric J. Campbell, Sarah K. Czaplewski, Christopher W. Steffen
Abstract: For production of a propellant charge powder, especially for medium and large calibers, in a process in which the solid is incorporated together with a liquid in a mixing and drying process into the channels of a granular green material and compacted therein to form a plug, the solid, under otherwise identical process conditions, is set within a setting range of >0-0.5% by weight based on the weight of the granular green material. For more significant lowering of the maximum pressure within an upper temperature range and for more significant raising of the maximum pressure within a lower temperature range of the application temperature range, an increased amount of solid is used. The solid is a substance whose melting point is at least 10° C., especially 20° C., above a maximum use temperature of the propellant charge powder and which is inert toward the granular green material. Since the plug consists virtually exclusively of inert material, a high ballistic stability is achieved.
Type:
Grant
Filed:
March 28, 2012
Date of Patent:
November 13, 2018
Assignee:
NITROCHEMIE ASCHAU GMBH
Inventors:
Beat Vogelsanger, Bruno Ossola, Alexander Huber, Christian Wagner, Oliver Hampel
Abstract: An encapsulated, particulate energetic composition includes one of explosive particles of a known size, oxidizer particles of a known size, and a mixture of explosive particles and oxidizer particles of known sizes, in which particles of one of the explosive particles, the oxidizer particles, and the mixture of the explosive and the oxidizer particles, are encapsulated by a combustible fuel of a known thickness to enhance the energy output. A method of making the encapsulated, particulate energetic composition includes placing one of explosive particles, oxidizer particles, and a mixture of explosive particles and oxidizer particles within a deposition chamber, mixing one of the explosive particles, the oxidizer particles, and the mixture of explosive particles and the oxidizer particles, and depositing, to a known encapsulating thickness, a combustible fuel onto the one of the explosive particles, the oxidizer particles, and the mixture of explosive particles and oxidizer.
Type:
Grant
Filed:
September 24, 2009
Date of Patent:
November 13, 2018
Assignee:
The United States of America as Represented by the Secretary of the Navy
Abstract: The invention relates to ignition sets comprising initial explosive substances selected from the group consisting of compounds, in particular compounds of lead, which are derived from trinitropolyphenols, such as trinitrophenol, trinitroresorcinol or hydrazoic acid, for example, in mixture with oxygen-generating substances, wherein further included are initial explosive substances made of alkali metal and/or alkaline-earth metal salts of dinitrobenzofuroxanes and oxygen-generating substances made from nitrates of ammonium, guanidine, aminoguanidine, triaminoguanidine, dicyanodiamidine and from the elements of sodium, potassium, magnesium, calcium, cerium and/or from multivalent metal oxides.
Abstract: A shaped charge includes a casing, a liner disposed within an opening of the casing and an explosive disposed between the casing and the liner. The liner is made of a metal powder blend that includes a spheroidized metal powder. The spheroidized metal powder includes a spheroidized tungsten powder. The metal powder blend may further include a binder and a lubricant. The binder includes copper or lead. The lubricant includes graphite.
Abstract: The present disclosure generally pertains to a device for separating two or more components of an explosive device. The elongated hollow device has an interior space for holding the components as well as two open ends. A separator is positioned within the device, thus creating at least two non-communicating compartments. The separator prevents the premature mixing of the components. Application of compressive force onto the circumference of the separator will cause the separator to fracture, thus mixing the components. The device increases safety and lowers costs associated with shipping explosive materials by keeping the components separated until immediately before use.
Abstract: Disclosed are hypergolic salts with borane cluster anions that ignite spontaneously upon contact with nitric acid (from 70% to 100% in water) with short ignition delay. The salts, when added as trigger additive to combustible solvent or ionic liquids, make the resulting formulation hypergolic. The salts with borane cluster anions also shorten ignition delay in hypergols, such as RP-1, and additionally allow nitric acid to be used to replace liquid oxygen as an oxidizer. In some examples, the borane salts are formed in situ in an ionic liquid.
Type:
Grant
Filed:
June 20, 2014
Date of Patent:
October 16, 2018
Assignee:
The Board of Trustees of The University of Alabama
Abstract: A combustible element includes regions of fuel material interspersed with regions of oxidizer material. The element may be made by additive manufacturing processes, such as three-dimensional printing, with the fuel material regions and the oxidizer material regions placed in appropriate locations in layer of the combustible element. For example, different extruders may be used to extrude and deposit portions of a fuel filament and an oxidizer filament at different locations in each layer of the combustible element. The combustible element may define a combustion chamber within the element, where combustion occurs when the combustible element is ignited. The fuel material and the oxidizer material may be selected, and their relative amounts may be controlled, such that desired relative amounts of fuel and oxidizer are present for combustion with desired characteristics, such as combustion rate.
Type:
Grant
Filed:
June 3, 2015
Date of Patent:
October 9, 2018
Assignee:
Raytheon Company
Inventors:
Jeremy C. Danforth, Mark T. Langhenry, Matt H. Summers, Teresa Perdue