Abstract: Color filter arrays for color imaging devices are disclosed. The arrays are formed in a single layer of a transparent binder containing at least one cationic photo-bleachable dye. The layer has a thickness less than 10 microns, and the dye is present in the layer in an amount sufficient to impart a density to the layer of at least about 0.5 in that portion of the spectrum in which it selectively absorbs. A method of making the arrays is also disclosed which includes the steps of (1) forming a layer of a transparent binder containing the photo-bleachable dye or dyes and a sensitizer; (2) exposing the layer to a pattern which represents a set of filter elements so as to photo-bleach the photo-bleachable dye; and (3) fixing the layer by leaching the sensitizer from the layer. In particularly preferred embodiments, the dyes are chosen so that those which absorb at longer wavelengths have a lower bleaching efficiency than those which absorb at shorter wavelengths.
Abstract: Compositions containing a polymerizable, curable or crosslinkable component, a photoinitiator, a fluoran colorformer and a latent activator that releases or promotes the release of a Lewis acid, will become insoluble and change color under the influence of actinic radiation. These compositions are particularly useful to make dry film photoresists, which are widely used in the electronics industry to manufacture printed circuits.
Abstract: An imaged element containing a polymeric relief or stencil image, in which the polymer contains crosslinkable moieties, is subjected to an image enlargement process by contacting the image with a solution containing a swelling agent for the image, and a crosslinking agent. The process is particularly useful in enlarging the half-tone image dot area of photopolymer litho masks wherein the half-tone image areas consist of hardened upper skins which rest on softer undervolumes having a lesser degree of polymerization or hardening.
Abstract: A method for forming an image includes the step of desensitizing a radiation sensitive imaging system comprising a dye and a tetra (hydrocarbyl) borate in a binder by converting the tetra (hydrocarbyl) borate to a compound having fewer than four carbon-to-boron bonds.
Type:
Grant
Filed:
May 23, 1980
Date of Patent:
August 10, 1982
Assignee:
Minnesota Mining and Manufacturing Company
Inventors:
Steven M. Aasen, Rex J. Dalzell, Edward J. Goettert, Brian N. Holmes, George V. D. Tiers
Abstract: A mask for structuring surface areas and a method for manufacture thereof. The mask includes at least one metal layer with throughgoing apertures which define the mask pattern and a semiconductor substrate for carrying the metal layer. The semiconductor substrate has throughholes that correspond to the mask pattern. The throughholes in the semiconductor substrate extend from the metal layer-covered surface on the front to at least one tub-shaped recess which extends from the other back surface into the semiconductor substrate. Holes are provided in a surface layer in the semiconductor substrate. The surface layer differs in its doping from the rest of the substrate and the holes which are provided in the surface layer have lateral dimensions larger than the apertures in the metal layer so that the metal layer protrudes over the surface layer.
Type:
Grant
Filed:
March 3, 1980
Date of Patent:
August 3, 1982
Assignee:
International Business Machines Corporation
Inventors:
Harald Bohlen, Helmut Engelke, Johann Greschner, Peter Nehmiz
Abstract: Direct-positive photographic emulsions and elements which include internal-image silver halide grains, a nucleating amount of a hydrazine compound and a redox dye releaser are improved by the incorporation of a nucleation-promoting amount of a quinone oxidizing agent. Diffusion transfer images made from elements using these emulsions exhibit improved image discrimination and improved maximum density.
Abstract: A fluoran compound represented by the formula: ##STR1## wherein R.sub.1 and R.sub.2 each represents an alkyl group containing up to 18 carbon atoms, R.sub.3 represents an alkyl group, a halogenated alkyl group, or an alkoxyalkyl group containing up to 18 carbon atoms, and X represents a halogen atom, a process for preparing such fluoran compound and a pressure-or heat-sensitive recording sheet comprising such fluoran compound as a color former, which are capable of providing black images having excellent stability, e.g., with respect to light.
Abstract: Photoimaging compositions comprising (A) a cyclohexadienone compound as defined, and at least one of (B.sub.1) a leuco dye or (B.sub.2) addition polymerizable ethylenically unsaturated monomer. A polymer binder can be present in the compositions. The new imaging compositions are useful in photoimaging products such as proofing papers, printout papers, overlay films and photopolymerizable elements useful for printing and photoresist purposes. The compositions have improved thermal stability.
Abstract: An optical information storage medium comprising a thin, optically darkenable film containing silver, lead, chlorine and oxygen, produced by vapor-depositing AgCl and PbO in specified proportions on a substrate for the film, is described.
Type:
Grant
Filed:
September 25, 1980
Date of Patent:
July 27, 1982
Assignee:
Corning Glass Works
Inventors:
Nicholas F. Borrelli, Arthur J. Whitman, Peter L. Young
Abstract: This application relates to an imaging composition employing a tellurium compound sensitive to activating radiation. Such imaging compositions have been disclosed in a number of earlier patents, such as U.S. Pat. Nos. 4,142,896, 4,066,460 and 4,106,939. This application discloses improvements in masked reducing agents for such compositions.
Type:
Grant
Filed:
June 26, 1981
Date of Patent:
July 20, 1982
Assignee:
Energy Conversion Devices, Inc.
Inventors:
Stanford R. Ovshinsky, Leon F. Hines, Ronald W. Citkowski, Terry T. Yu
Abstract: Spots due to iron contamination in developed silver halide films are reduced in number by incorporating therein a phosphate and trisodium hydroxyethylethylenediaminetriacetate.
Abstract: A coated film base suitable for coating with a light-sensitive photographic emulsion layer comprises a self-supporting film of a synthetic linear polyester and a continuous subbing layer applied to at least one surface of said self-supporting film comprising a water-insoluble copolymer of (a) styrene or a derivative of styrene, (b) a comonomer selected from acrylic acid, methacrylic acid or a derivative of acrylic acid or methacrylic acid and (c) a copolymerizable sulphonated ethylenically unsaturated comonomer having the general structure: ##STR1## wherein R.sub.1, R.sub.2 and R.sub.3 are the same or different and represent hydrogen, halogen, alkyl, nitrile, amide, amine, ketone, ethyl or vinyl;R.sub.
Type:
Grant
Filed:
February 24, 1981
Date of Patent:
July 13, 1982
Assignee:
Imperial Chemical Industries Limited
Inventors:
Terence D. J. Elmes, Patrick T. McGrail
Abstract: Novel E-beam resists and process for their use are described. These resists are conducting organic charge transfer salts. Films of these materials can be deposited by solvent casting or by sublimation. The deposited film can be made to produce a positive or negative resist image depending on the E-beam energy and exposure time. Exposure of this material to an E-beam produces patterns having differential electrical, optical and solvation properties.
Type:
Grant
Filed:
July 28, 1981
Date of Patent:
July 6, 1982
Assignee:
International Business Machines Corporation
Inventors:
Edward M. Engler, John D. Kuptsis, Robert G. Schad, Yaffa Tomkiewicz
Abstract: Gelatin-containing layers of photographic materials are hardened by adding a compound containing from 2 to 6 sulfonyl ethyl sulfate groups in the form of its salts and activating the compound by adjusting a pH-value in the range from 6.5 to 11.
Type:
Grant
Filed:
December 29, 1980
Date of Patent:
July 6, 1982
Assignee:
Agfa-Gevaert Aktiengesellschaft
Inventors:
Wolfgang Himmelmann, Peter Bergthaller, Johannes Sobel
Abstract: In a silver halide photographic material, at least one mercapto complexing agent for silver salt is contained in at least one photographic constituting layer and at least one anion or betaine type cyanine sensitizing dye is contained in silver halide emulsion layer to improve photographic defects such as reduction of sensitivity, softening in tone, etc.
Abstract: A silver halide photosensitive material is stabilized against overdevelopment fogging by containing at least one antifoggant thioether represented by the following general formula I in silver halide emulsion layer and/or layer contiguous to said emulsion layer; ##STR1## wherein A represents the heterocyclic group of a mercapto antifoggant; R.sub.1 and R.sub.2, which may jointly form a benzene ring, represent each a halogen atom or an alkyl, aryl or aryloxy group.
Abstract: A silver halide photographic light-sensitive element is described comprising a support having thereon at least one silver halide emulsion layer, wherein at least one compound represented by formula (I) is incorporated in the silver halide emulsion layer or in another hydrophilic colloid layer: ##STR1## wherein X represents a hydroxy group or a group represented by ##STR2## wherein R.sup.2 and R.sup.3 (which may be the same or different) each reprsents hydrogen, an alkyl group, or an aryl group; R.sup.1 represents a sulfur-containing saturated heterocyclic group or a group represented by -A-S-B, wherein A represents an alkylene group and B represents hydrogen, an alkyl group, or an aryl group; and Z represents an atomic group forming a 5-membered or 6-membered unsubstituted or substituted carbocyclic ring.In the silver halide photographic light-sensitive element, the so-called "latent image fading" phenomenon is prevented without accompanying degradation of other photograhic properties.
Abstract: An improved silver halide precipitation process of preparing a dispersion of silver halide grains is disclosed. The process comprises forming a radiation-sensitive silver halide dispersion by reacting silver and halide salts in solution within a dispersing medium to form silver halide grain nuclei within the dispersing medium and allowing silver halide grain growth to occur in a reaction vessel in which the silver halide grain nuclei and the dispersing medium are present. The improvement comprises, while increasing silver halide present in the dispersing medium during silver halide grain growth, reducing the volume of the dispersion by separating a portion of the dispersing medium while retaining the silver halide grains within the remaining dispersion.