Abstract: A fire suppression system for producing an inert gas mixture having a minimal amount of carbon monoxide, particulates, or smoke. The inert gas mixture may be generated by combusting a gas generant. The gas generant may be a composition that includes hexa(ammine)-cobalt(III)-nitrate. The fire suppression system also includes a heat management system to reduce a temperature of the inert gas mixture. In one embodiment, the system includes multiple gas generators and is configured to ignite the respective gas generant of each gas generator in a predetermined, time based sequential order. For example, the gas generant of each gas generator may be ignited in a sequential order at specified time intervals. Methods of extinguishing fires are also disclosed.

Abstract: A gas generating pyrotechnic composition that in addition to a primary fuel component and a primary oxidizer component includes critical relative amounts of elemental carbon and cupric oxide. Also provided are associated methods for producing an inflation gas for an occupant restraint system of a motor vehicle.

Abstract: The disclosure provides an inflator device for a passive restraint device, like an airbag. In certain aspects, a fuel-rich gas generant grain is located in actuating proximity to an initiator device. The grain has at least one flow channel through which a shock wave generated by the initiator device passes. The shock wave opens a burst disc between the inflator housing and downstream airbag to permit gases to flow into the airbag. A chamber storing pressurized gas (having at least one oxidant, e.g., O2) is also disposed within the inflator. Upon initiator actuation, the oxidant can react with combustion products of the initiator and the fuel-rich gas generant and flow into the airbag for rapid inflation. Methods of inflating airbags and improving airbag deployment reliability are provided. Such inflators are particularly suitable for large volume (greater than 60 liter) airbags.

Abstract: An inflator assembly having an inflator body that forms a chamber wherein a quantity of a gas generating solid reacts to form gas. A quantity of gas treatment material is included to treat the formed gas to form a treated gas. At least one assembly exit opening permits the treated gas to exit the inflator assembly. The required gas generating solid has a flame temperature of no more than 1670 K with the inflator assembly having significant weight and volume reductions as compared to an otherwise identical performing inflator assembly that utilizes gas generating composition having higher flame temperatures.

Abstract: Methods of making and resultant compositions thereof, which include a gas generant having a coating including an inorganic combustion inhibitor. Such coated gas generants are useful in pyrotechnic compositions and ignition materials, and may be employed, for example, in inflatable restraint systems. The ratio of coated and uncoated gas generant bodies within an airbag inflator may be tailored to provide S-curve inflation performance. Spray application of aqueous mixture including the combustion inhibitor onto the gas generant body provides a rapid way to achieve a thin but robust coating.

Abstract: An ionic liquid is disclosed. A precursor composition that comprises at least one ionic liquid and at least one energetic material is also disclosed, as is a method of synthesizing an ionic liquid and a method of desensitizing an explosive composition.

Abstract: A quaternary salt is added at low concentrations to a solid propellant, thereby increasing the conductivity of the polymeric binder to provide for safe discharge of static electricity at relatively low potentials.

Abstract: A fire suppression system for producing an inert gas mixture having a minimal amount of carbon monoxide, particulates, or smoke. The inert gas mixture may be generated by combusting a gas generant. The gas generant may be a composition that includes hexa(ammine)-cobalt(III)-nitrate. The fire suppression system also includes a heat management system to reduce a temperature of the inert gas mixture. In one embodiment, the system includes multiple gas generators and is configured to ignite the respective gas generant of each gas generator in a predetermined, time based sequential order. For example, the gas generant of each gas generator may be ignited in a sequential order at specified time intervals. Methods of extinguishing fires are also disclosed.

Abstract: An inflator that includes a quantity of gas generant housed within a chamber. A liquid including at least one of a fuel soluble in the liquid or an oxidizer soluble in the liquid and a piston are housed within another chamber of the inflator. This chamber is sealed. Upon actuation, movement of the piston hydraulically expels the liquid through an opening in the piston such that the liquid contacts the gas formed by combustion of the gas generant and cools the same. The fuel and/or oxidizer in the liquid can react to form additional gas.

Abstract: An ionic liquid is disclosed A precursor composition that comprises at least one ionic liquid and at least one energetic material is also disclosed, as is a method of synthesizing an ionic liquid and a method of desensitizing an explosive composition.

Abstract: An inflator that includes a quantity of gas generant housed within a chamber. A liquid including at least one of a fuel soluble in the liquid or an oxidizer soluble in the liquid and a piston are housed within another chamber of the inflator. This chamber is sealed. Upon actuation, movement of the piston hydraulically expels the liquid through an opening in the piston such that the liquid contacts the gas formed by combustion of the gas generant and cools the same. The fuel and/or oxidizer in the liquid can react to form additional gas.

Abstract: An inflator assembly having an inflator body that forms a chamber wherein a quantity of a gas generating solid reacts to form gas. A quantity of gas treatment material is included to treat the formed gas to form a treated gas. At least one assembly exit opening permits the treated gas to exit the inflator assembly. The required gas generating solid has a flame temperature of no more than 1670 K with the inflator assembly having significant weight and volume reductions as compared to an otherwise identical performing inflator assembly that utilizes gas generating composition having higher flame temperatures.

Abstract: Methods of making and resultant compositions thereof, which include a gas generant having a coating including an inorganic combustion inhibitor. Such coated gas generants are useful in pyrotechnic compositions and ignition materials, and may be employed, for example, in inflatable restraint systems. The ratio of coated and uncoated gas generant bodies within an airbag inflator may be tailored to provide S-curve inflation performance. Spray application of aqueous mixture including the combustion inhibitor onto the gas generant body provides a rapid way to achieve a thin but robust coating.

Abstract: An apparatus, system and method for suppression of fires are provided. In accordance with one embodiment of the invention, a housing is provided with a first opening (or set of openings), a second opening (or set of openings) and a Row path defined between the first and second openings. A fire-suppressing gas is produced, such as from a solid propellant composition, and is introduced into the flow path in such a way that a volume of ambient air is drawn from a location external to the housing, through the first opening and into the flow path. The volume of ambient air may be subjected to an oxygen-reducing process and mixed with the fire-suppressing gas to form a gas mixture. The gas mixture is discharged from the flow path through the second opening and into an associated environment for suppression of a fire located therein.

Abstract: Compositions and methods relate to gas generants used in inflatable restraint systems. The gas generant grains include a fuel mixture having at least one fuel and at least one oxidizer, which have a burn rate that is susceptible to pressure sensitivity during combustion. The gas generant composition further includes a plurality of pressure sensitivity modifying glass fiber particles distributed therein to lessen the pressure sensitivity and/or to increase combustion stability of the gas generant. Such gas generants can be formed via spray drying techniques.

Abstract: Gas-generating compositions and methods for their use are provided. Metal complexes are used as gas-generating compositions. These complexes are comprised of a metal cation template, a neutral ligand containing hydrogen and nitrogen, and sufficient oxidizing anion to balance the charge of the complex. The complexes are formulated such that when the complex combusts, nitrogen gas and water vapor is produced. Specific examples of such complexes include metal nitrite amine, metal nitrate amine, and metal perchlorate amine complexes, as well as hydrazine complexes. A binder and co-oxidizer can be combined with the metal complexes to improve crush strength of the gas-generating compositions and to permit efficient combustion of the binder. Such gas-generating compositions are adaptable for use in gas-generating devices, such as automobile air bags.

Abstract: Methods and systems of providing a source of hydrogen and oxygen with high volumetric energy density, as well as a power systems useful in non-air breathing engines such as those in, for example, submersible vehicles, is disclosed. A hydride reactor may be utilized in forming hydrogen from a metal hydride and a peroxide reactor may be utilized in forming oxygen from hydrogen peroxide. The high temperature hydrogen and oxygen may be converted to water using a solid oxide fuel cell, which serves as a power source. The power generation system may have an increased energy density in comparison to conventional batteries. Heat produced by exothermic reactions in the hydride reactor and the peroxide reactor may be transferred and utilized in other aspects of the power generation system. High temperature water produced during by the peroxide reactor may be used to fuel the hydride reactor.

Abstract: Compositions and methods relating to gas generants used in inflatable restraint systems. The gas generant grains formed via spray drying techniques of the present disclosure provide superior performance, including high burn rates and high gas yields. Further, processing of the gas generant grain products can be streamlined. Such gas generants include by way of non-limiting example, guanidine nitrate, basic copper nitrate, and a secondary oxidizer, such as potassium perchlorate.

Abstract: An ionic liquid is disclosed A precursor composition that comprises at least one ionic liquid and at least one energetic material is also disclosed, as is a method of synthesizing an ionic liquid and a method of desensitizing an explosive composition.

Abstract: An apparatus, system and method for suppression of fires are provided. In accordance with one embodiment of the invention, a housing is provided with a first opening (or set of openings), a second opening (or set of openings) and a Row path defined between the first and second openings. A fire-suppressing gas is produced, such as from a solid propellant composition, and is introduced into the flow path in such a way that a volume of ambient air is drawn from a location external to the housing, through the first opening and into the flow path. The volume of ambient air may be subjected to an oxygen-reducing process and mixed with the fire-suppressing gas to form a gas mixture. The gas mixture is discharged from the flow path through the second opening and into an associated environment for suppression of a fire located therein.