Abstract: An apparatus, system and method for suppression of fires are provided. In accordance with one embodiment of the invention, a housing is provided with a first opening (or set of openings), a second opening (or set of openings) and a flow path defined between the first and second openings. A fire-suppressing gas is produced, such as from a solid propellant composition, and is introduced into the flow path in such a way that a volume of ambient air is drawn from a location external to the housing, through the first opening and into the flow path. The volume of ambient air may be subjected to an oxygen-reducing process and mixed with the fire-suppressing gas to form a gas mixture. The gas mixture is discharged from the flow path through the second opening and into an associated environment for suppression of a fire located therein.

Abstract: In this method for making a sintered reactive material, fuel particles are blended with a polymer matrix comprising at least one fluoropolymer in an inert organic media to disperse the fuel particles in the polymer matrix and form a reactive material. The reactive material is dried and pressed to obtain a shaped preform, which is sintered in an inert atmosphere to form the sintered reactive material. By sintering in an inert atmosphere, the sintered reactive material may include reactive metals and/or metalloids in a nonoxidized state. The resulting sintered reactive material preferably has a tensile strength in excess of 1800 psi and an elongation at break in excess of 30%.

Abstract: A method of forming ?-alane. The method includes reacting aluminum trichloride and an alkali metal hydride to form an alane-ether complex solution. An aqueous diethyl ether solution is optionally added to the alane-ether complex solution to form a partially hydrolyzed ether/alane-ether complex solution. A solution of a first crystallization additive is added to the alane-ether complex solution or to the aqueous ether/alane-ether complex solution to form a crystallization solution. The first crystallization additive is selected from the group consisting of polystyrene, polybutadiene, polystyrene-co-polybutadiene, polyisoprene, poly-alpha-methylstyrene, polystyrene-co-polyindene, poly-alpha-pinene, and mixtures thereof. Optionally, a second crystallization additive is added to the crystallization solution.

Abstract: A method of forming ?-alane. The method includes reacting aluminum trichloride and an alkali metal hydride to form an alane-ether complex solution. An aqueous ether solution is optionally added to the alane-ether complex solution to form a partially hydrolyzed ether/alane-ether complex solution. A solution of a crystallization additive is added to the alane-ether complex solution or to the aqueous ether/alane-ether complex solution to form a crystallization solution. The crystallization additive is selected from the group consisting of squalene, cyclododecatriene, norbornylene, norbornadiene, a phenyl terminated polybutadiene, 2,4-dimethyl anisole, 3,5-dimethyl anisole, 2,6-dimethyl anisole, polydimethyl siloxane, and mixtures thereof. Ether is removed from the crystallization solution to crystallize the ?-alane.

Abstract: Gas generating compositions and methods for their use are provided. Metal complexes are used as gas-generating compositions. These complexes are comprised of a metal cation template, a neutral ligand containing hydrogen and nitrogen, and sufficient oxidizing anion to balance the charge of the complex. The complexes are formulated such that when the complex combusts, nitrogen gas and water vapor is produced. Specific examples of such complexes include metal nitrite ammine, metal nitrate ammine, and metal perchlorate ammine complexes, as well as hydrazine complexes. A binder and co-oxidizer can be combined with the metal complexes to improve crush strength of the gas-generating compositions and to permit efficient combustion of the binder. Such gas-generating compositions are adaptable for use in gas-generating devices, such as automobile air bags.

Abstract: A melt-cast explosive which shares comparable explosive properties to those of COMP B explosives and is melt-pourable and castable under conditions comparable to those of COMP B explosives, but experiences less impact, shock, and thermal sensitivity and avoids the issues of toxicity associated with COMP B. A fundamental and well-accepted component of COMP B, i.e., trinitrotoluene (TNT), is replaced with one or more mononitro-substituted or dinitro-substituted melt-cast binders, such as dinitroanisole, which can be melt-cast without presenting the toxicity drawbacks experienced with the use of TNT. The melt-cast binder can also be combined with a processing aid selected from the group consisting of alkylnitroanilines and arylnitroanilines. Preferably, the composition also includes coarse oxidizer particles and energetic filler in fine particulate form.

Abstract: In this method for making a sintered reactive material, fuel particles are blended with a polymer matrix comprising at least one fluoropolymer in an inert organic media to disperse the fuel particles in the polymer matrix and form a reactive material. The reactive material is dried and pressed to obtain a shaped preform, which is sintered in an inert atmosphere to form the sintered reactive material. By sintering in an inert atmosphere, the sintered reactive material may include reactive metals and/or metalloids in a nonoxidized state. The resulting sintered reactive material preferably has a tensile strength in excess of 1800 psi and an elongation at break in excess of 30%.

Abstract: In this method for making multi-base propellants, pelletized nitrocellulose is coated with an electrostatically insensitive liquid elastomer precursor or non-plasticizer while wetted in a non-solvent diluent, preferably in the absence of plasticizers. The non-solvent diluent is then substantially, if not completely, removed from the coated nitrocellulose. Then, the coated pelletized nitrocellulose is mixed with a plasticizer and optionally other ingredients and fillers, including energetic fuels such as nitroguanidine. The propellant formulation is then cast, and optionally cured with an acceptable curative, such as a diisocyanate or polyisocyanate. The resulting material may be visually (i.e., to the naked eye) homogeneous. Also, the coated nitrocellulose pellets present during processing have reduced sensitivity to electrostatic discharge.

Abstract: This melt-cast explosive shares comparable explosive properties to those of COMP B explosives and is melt-pourable and castable under conditions comparable to those of COMP B explosives, but experiences less impact, shock, and thermal sensitivity and avoids the issues of toxicity associated with COMP B. A fundamental and well-accepted component of COMP B, i.e., trinitrotoluene (TNT), is replaced with one or more mononitro-substituted or dinitro-substituted melt-cast binders, such as dinitroanisole, which can be melt cast without presenting the toxicity drawbacks experienced with the use of TNT. The melt-cast binder can also be combined with a processing aid selected from the group consisting of alkylnitroanilines and arylnitroanilines. Preferably, the composition also includes coarse oxidizer particles and energetic filler in fine particulate form.

Abstract: In this method for making a sintered reactive material, fuel particles are blended with a polymer matrix comprising at least one fluoropolymer in an inert organic media to disperse the fuel particles in the polymer matrix and form a reactive material. The reactive material is dried and pressed to obtain a shaped pre-form, which is sintered in an inert atmosphere to form the sintered reactive material. By sintering in an inert atmosphere, the sintered reactive material may include reactive metals and/or metalloids in a non-oxidized state. The resulting sintered reactive material preferably has a tensile strength in excess of 1800 psi and an elongation at break in excess of 30%.

Abstract: In this method for making a sintered reactive material, fuel particles are blended with a polymer matrix comprising at least one fluoropolymer in an inert organic media to disperse the fuel particles in the polymer matrix and form a reactive material. The reactive material is dried and pressed to obtain a shaped pre-form, which is sintered in an inert atmosphere to form the sintered reactive material. By sintering in an inert atmosphere, the sintered reactive material may include reactive metals and/or metalloids in a non-oxidized state. The resulting sintered reactive material preferably has a tensile strength in excess of 1800 psi and an elongation at break in excess of 30%.

Abstract: Gas generating compositions and methods for their use are provided. Metal complexes are used as gas generating compositions. These complexes are comprised of a metal cation template, a neutral ligand containing hydrogen and nitrogen, and sufficient oxidizing anion to balance the charge of the complex. The complexes are formulated such that when the complex combusts, nitrogen gas and water vapor is produced. Specific examples of such complexes include metal nitrite ammine, metal nitrate ammine, and metal perchlorate ammine complexes, as well as hydrazine complexes. A binder and co-oxidizer can be combined with the metal complexes to improve crush strength of the gas generating compositions and to permit efficient combustion of the binder. Such gas generating compositions are adaptable for use in gas generating devices such as automobile air bags.

Abstract: This melt-cast explosive shares comparable explosive properties to those of COMP B explosives and is melt-pourable and castable under conditions comparable to those of COMP B explosives, but experiences less impact, shock, and thermal sensitivity and avoids the issues of toxicity associated with COMP B. A fundamental and well-accepted component of COMP B, i.e., trinitrotoluene (TNT), is replaced with one or more mononitro-substituted or dinitro-substituted melt-cast binders, such as dinitroanisole, which can be melt cast without presenting the toxicity drawbacks experienced with the use of TNT. The melt-cast binder can also be combined with a processing aid selected from the group consisting of alkylnitroanilines and arylnitroanilines. Preferably, the composition also includes coarse oxidizer particles and energetic filler in fine particulate form.

Abstract: A gas generating eject motor includes a case containing an ignitable low temperature gas generant material that does not produce toxic gases upon the combustion thereof. The gas generant material is generally contained with a screen enclosure housed within the case. An igniter is disposed within the gas generant material for selectively igniting the gas generant to thereby generate combustion gases. A nozzle is disposed within an open aft end of the case for focusing and directing the combustion gases generated by the ignited gas generant material. The case is constructed and arranged to be separably attached to the aft end of a rocket to be launched from a launch platform, so that, upon ignition of the gas generant, the combustion gases focused by the nozzle will apply a thrust to the rocket and thereby propel, or eject, the rocket from the launch platform, at which time the combustible propellant of the rocket motor will ignite and the eject motor will be separated from the rocket.

Abstract: An air bag igniter including a foamed material, and an air bag assembly containing the same are disclosed. The foamed material is formed from a composition including, as ingredients, a polyfunctional isocyanate, a polymeric binder having a plurality of hydroxyl groups which are reactive with the polyfunctional isocyanate, a fuel source, an oxidizer, and a foaming agent which may or may not be retained in the foamed material.

Abstract: This substantially water-free method for preparing high density igniter granules involves uniformly coating fuel and oxidizer particulates dispersed in a non-solvent with a thermoplastic elastomer solution to produce coated igniter granules exhibiting substantially uniform size and shape distributions. The coated igniter granules are especially useful for waterless extrusion into igniters for automobile gas generating inflation devices, solid propellant rocket motors, and thrust decoys.

Abstract: Gas generating compositions and methods for their use are provided. Metal complexes are used as gas generating compositions. These complexes are comprised of a metal cation template, a neutral ligand containing hydrogen and nitrogen, sufficient oxidizing anion to balance the charge of the complex, and at least one cool burning organic nitrogen-containing compound. The complexes are formulated such that when the complex combusts, nitrogen gas and water vapor is produced. Specific examples of such complexes include metal nitrite ammine, metal nitrate ammine, and metal perchlorate ammine complexes, as well as hydrazine complexes. A binder and co-oxidizer can be combined with the metal complexes to improve crush strength of the gas generating compositions and to permit efficient combustion of the binder. Such gas generating compositions are adaptable for use in gas generating devices such as automobile air bags.

Abstract: The present invention relates to an igniter composition which is capable of being extruded to yield a robust igniter extrudate. The composition is particularly useful in the form of an igniter stick or other selected geometry for use in supplemental safety restraint systems designed for use such as in vehicles, ground or airborne, having such systems.

Abstract: The present invention relates to flares and other solid propellant devices, rockets or the like, equipped with an igniter or igniter system which is based in whole in part on an extruded igniter stick.

Abstract: An ignition enhanced gas generant grain and method of making an ignition enhanced gas generant involving the application of a dry blend igniter composition to a gas generant particle having a wet adhesive surface.