Patent number: 9279085
Abstract: The invention relates to a method for producing monofunctionalized dialkylphosphinic acids, esters, and salts, characterized in that a phosphinic acid source (I) is reacted with olefins (IV) in the presence of a catalyst A to obtain an alkylphosphonous acid, the salt or ester thereof, whereupon said alkylphosphonous acid, the salt or ester (II) thereof is reacted with compounds containing C?C, C?O, or C?N double bonds to obtain compounds of type (III), wherein R1, R2, R3, R4, R5, R6 are identical or different from each other and independently represent, inter alia, H, C1-C18-alkyl, C6-C18-aryl, C6-C18-aralkyl, X represents, inter alia, H, C1-C18-alkyl, C6-C18-aryl, and/or Mg, Ca, Al, Sb, Sn, Ge, Ti, Fe, Zr, Zn, Ce, Bi, Sr, Mn, Cu, Ni, Li, Na, K, H, and wherein A represents OH, NH2, NHR, NR2, or O—CO—R8, and W represents a mineral acid, carboxylic acid, Lewis acid, or organic acid, wherein n is a whole or a fractional number from 0 to 4, and catalyst A represents transition metals and/or transition metal compo
Type:
Grant
Filed:
October 6, 2009
Date of Patent:
March 8, 2016
Assignee:
Clariant Finance (BVI) Limited
Inventors:
Michael Hill, Harald Bauer, Werner Krause, Martin Sicken
Publication number: 20160009918
Abstract: The invention relates to a flame-retardant polyamide composition, containing as component A 1 to 96% by weight of one or more thermoplastic polyamides, as component B 2 to 25% by weight of dialkylphosphinic salt of the formula (I) and/or a diphosphinic salt of the formula (II) and/or the polymers thereof, wherein R1, R2 are the same or different C1-C6 alkyl, linear or branched or H: R3 C1-C10 alkylene, linear or branched, C6-C10 arylene, C7-C20 alkylarylene or C7-C20 arylalkylene; M Mg, Ca, Al, Sb, Sn, Ge, Ti, Zn, Fe, Zr, Ce, Bi, Sr, Mn, Li, Na, K and/or a protonized nitrogen base; m is 1 to 4; n is 1 to 4; x is 1 to 4, as component C 1 to 20% by weight salt of the phosphorous acid, as component D 1 to 50% by weight of filler or reinforcing material, as component E 0 to 2% by weight of a carboxyl ester amide, as component F 0 to 1% of a phosphonite or a mixture of a phosphonite and a phosphate, and as component G 0 to 1% by weight of an ester or salt of long-chain aliphatic carboxylic acids (fatty acids), whi
Type:
Application
Filed:
February 27, 2014
Publication date:
January 14, 2016
Inventors:
Sebastian HOEROLD, Harald BAUER, Martin SICKEN
Patent number: 9150710
Abstract: The invention relates to a flameproof agent stabilizer combination containing, as component A 40-99 wt. % of a phosphinic acid salt of formula (I) and/or a diphosphinic acid salt of formula (II) and/or polymers thereof, wherein R1, R2 are the same or different and represent C1-C18-alkyl linear, branched or cyclic, C6-C18-aryl, C7-C18-arylalkyl and/or C7-C18-alkylaryl; R3 represents C1-C10-alkylene, linear or branched, C6-C10-arylene, C7-C18-alkylarylene or C7-C18-arylalkylene; M represents Mg, Ca, Al, Sb, Sn, Ge, Ti, Zn, Fe, Zr, Ce, Bi, Sr, Mn, Li, Na, K and/or a protoned nitrogen base; m represents 1-4; n represents 1-4; x represents 1-4, as component B 1-60 wt. % of a phosphinic acid salt of general formula (III) wherein R4 represents C1-C18-alkyl linear, branched or cyclic, C6-C18-aryl, C7-C18-arylalkyl or C7-C18-alkylaryl and M represents Mg, Ca, Al, Sb, Sn, Ge, Ti, Zn, Fe, Zr, Ce, Bi, Sr, Mn, Li, Na, K and/or a protonated nitrogen base, as component C 0-50 wt.
Type:
Grant
Filed:
April 20, 2011
Date of Patent:
October 6, 2015
Assignee:
Clariant Finance (BVI) Limited
Inventors:
Sebastian Hoerold, Harald Bauer
Patent number: 9068061
Abstract: The invention relates to a novel flameproof agent stabiliser combination for thermoplastic and duroplastic polymers, containing, as component A 25-97.7 wt % of a dialkylphosphinic acid salt of formula (I) and/or a diphosphinic acid salt of formula (II) and/or polymers thereof, wherein R1, R2 are the same or different and represent C1-C6-alkyl, linear or branched and/or aryl; R3 represents C1-C10-alkylene, linear or branched, C6-C10-arylene, C7-C20-alkylarylene or C7-C20-arylalkylene; M represents Mg, Ca, Al, Sb, Sn, Ge, Ti, Zn, Fe, Zr, Ce, Bi, Sr, Mn, Li, Na, K and/or a protonated nitrogen base; m represents 1-4; n represents 1-4; x represents 1-4, as component B 2-45 wt. % of a monoalkylphosphinic acid salt of general formula (Ill), wherein R4 represents C1-C6-alkyl, linear or branched; M represents Mg, Ca, Al, Sb, Sn, Ge, Ti, Zn, Fe, Zr, Ce, Bi, Sr, Mn, Li, Na, K and/or a protonated nitrogen base; representing, as component C 0.3-30 wt.
Type:
Grant
Filed:
April 20, 2011
Date of Patent:
June 30, 2015
Assignee:
Clariant Finance (BVI) Limited
Inventors:
Sebastian Hoerold, Harald Bauer, Michael Hill