Abstract: It is to provide a cathode active material for a lithium ion secondary battery, which has high safety, a high discharge voltage, a large capacity and excellent cyclic durability, and a process for producing it. A cathode active material for a lithium secondary battery, characterized by comprising a particulate lithium cobalt composite oxide represented by the formula LiaCobAlcMgdAeOfFg??(1) (wherein A is Ti, Nb or Ta, O.90?a?1.10, 0.97?b?1.00, 0.000l?c?0.02, 0.000l?d?0.02, 0.000l?e?0.01, 1.98?f?2.02, 0?g?0.02, and 0.0003?c+d+e?0.03).

Abstract: A composite oxide suitable for an active material of a positive electrode for a lithium secondary cell which can be used in a wide range of voltage, has a large electric capacity and excellent low temperature performance and is excellent in the durability for charge-discharge cycles and highly safe, a process for its production, and a positive electrode and a cell employing it, are presented. The composite oxide is a lithium-cobalt composite oxide which is represented by the formula LiCo1-xMxO2, (wherein 0?x?0.02 and M is at least one member selected from the group consisting of Ta, Ti, Nb, Zr and Hf), and which has a half-width of the diffraction peak for (110) face at 2?=66.5±1°, of from 0.070 to 0.180°, as measured by the X-ray diffraction using CuK? as a ray source.

Abstract: It is to provide a cathode active material powder for a positive electrode for a lithium secondary battery, which has a large volume capacity density, high safety and excellent durability for charge and discharge cycles. A cathode active material powder for a lithium secondary battery characterized by comprising a first composite oxide powder represented by the formula (1) LipQxMyOzFa (wherein Q is Co or Mn, M is aluminum or an alkaline earth metal element or a transition metal element other than Q, provided that when Q is Co, 0.9?p?1.1, 0.980?x?1.000, 0?y?0.02, 1.9?z?2.1, x+y=1, and 0?a?0.02, and when Q is Mn, 1?p?1.3, x=2?y, 0?y?0.05, z=4, and a=0), having an average particle size D50 of from 5 to 30 ?m, and having a compression breaking strength of at least 40 MPa; and a second composite oxide powder represented by the formula (2) LipNixCoyMnzNqOrFa (wherein N is aluminum or an alkaline earth metal element or a transition metal element other than Ni, Co and Mn, 0.9?p?1.1, 0.2?x?0.8, 0?y?0.4, 0?z?0.

Abstract: To provide a process for producing a lithium-cobalt composite oxide for a positive electrode of a lithium secondary battery, which has a large volume capacity density, high safety, high charge and discharge cycle durability, high press density and high productivity. A process for producing a lithium-cobalt composite oxide represented by the formula LipCoxMyOzFa (wherein M is a transition metal element other than Co, or an alkaline earth metal element, 0.9?p?1.1, 0.980?x?1.000, 0?y?0.02, 1.9?z?2.1, x+y=1, and 0?a?0.02), characterized in that as a cobalt source, a mixture is used which comprises cobalt hydroxide in the form of substantially spherical secondary particles with an average particle size of from 8 to 20 ?m formed by agglomeration of primary particles and tricobalt tetroxide in the form of secondary particles with an average particle size of from 2 to 10 ?m formed by agglomeration of primary particles, in a cobalt atomic ratio of from 5:1 to 1:5, and firing is carried out at from 700 to 1,050° C.

Abstract: It is to provide a positive electrode active material for a lithium secondary battery, which has a large volume capacity density, high safety, excellent properties for uniform coating, excellent durability for charge and discharge cycles and low temperature characteristics even at a high charge voltage. A process for producing a lithium-containing composite oxide represented by the formula LipNxMmOzFa (wherein N is at least one element selected from the group consisting of Co, Mn and Ni, M is at least one element selected from the group consisting of Al, alkaline earth metal elements and transition metal elements other than N, 0.9?p?1.2, 0.9?x<1.00, 0<m?0.03, 1.9?z?2.2, x+m=1 and 0?a?0.02), which comprises using a solution comprising a complex containing the M element (M element-containing complex) dissolved in an organic solvent, an N source and a lithium source, and if necessary, a fluorine source, by means of a mixing step, an organic solvent removal step and a firing step.

Abstract: A positive electrode active material for a lithium secondary battery containing a lithium-cobalt composite oxide, which has a large volume capacity density, has a high safety and is excellent in charge and discharge cyclic durability, and its production process, are provided. A lithium-cobalt composite oxide represented by the formula LipCoxMyOzFa (wherein M is a transition metal element other than Co or an alkaline earth metal element, 0.9?p?1.1, 0.980?x?1.000, 0?y?0.02, 1.9?z?2.1, x+y=1 and 0?a?0.

Abstract: A positive electrode material for a lithium secondary battery for high voltage high capacity use exhibiting high cycle durability and high safety. The positive electrode material is composed of particles having a composition represented by the general formula: LiaCObMgcAdOeFf (A is the group 6 transition element or the group 14 element, 0.90?a?1.10, 0.97?b?1.00, 0.0001?c>0.03, 0.0001?d?0.03, 1.98?e?2.02, 0?f?0.02 and 0.0001?c+d?0.03), and magnesium, the element A and fluorine exist uniformly in the vicinity of the surfaces of the particles.

Abstract: A lithium-containing composite oxide for a positive electrode for a lithium secondary battery is prepared by formulating a powder mixture by impregnating an N element source powder having an average particle size (D50) ranging from 2 to 20 ?m with an aqueous solution of a carboxylic acid having a total of two or more carboxylic acid groups or carboxylic acid groups and hydroxyl groups in its molecule, and optionally, containing an M element, or its salt, and then drying the material obtained; and firing the N element powder material in admixture with a lithium source, optionally, an M element source and a fluorine source, at a temperature ranging from 700° C. to 1050° C.

Abstract: It is to provide a positive electrode active material for a lithium secondary battery, which has a large volume capacity density and high safety, is excellent in uniform coating properties and is excellent in the charge and discharge cyclic durability and low temperature characteristics even at a high charge voltage. A process for producing a lithium-containing composite oxide represented by the formula LipQqNxMyOzFa (wherein Q is at least one element selected from the group consisting of titanium, zirconium, niobium and tantalum, N is at least one element selected from the group consisting of Co, Mn and Ni, M is at least one element selected from the group consisting of Al, alkaline earth metal elements and transition metal elements other than the Q element and the N element, 0.9?p?1.1, 0<q?0.03, 0.97?x<1.00, 0?y<0.03, 1.9?z?2.1, q+x+y=1 and 0?a?0.

Abstract: Coagulated particles of nickel-cobalt-manganese hydroxide wherein primary particles are coagulated to form secondary particles are synthesized by allowing an aqueous solution of a nickel-cobalt-manganese salt, an aqueous solution of an alkali-metal hydroxide, and an ammonium-ion donor to react under specific conditions; and a lithium-nickel-cobalt-manganese-containing composite oxide represented by a general formula, LipNixMn1-x-yCoyO2-qFq (where 0.98?p?1.07, 0.3?x?0.5, 0.1?y?0.38, and 0?q?0.05), which is a positive electrode active material for a lithium secondary cell having a wide usable voltage range, a charge-discharge cycle durability, a high capacity and high safety, is obtained by dry-blending coagulated particles of nickel-cobalt-manganese composite oxyhydroxide formed by making an oxidant to act on the coagulated particles with a lithium salt, and firing the mixture in an oxygen-containing atmosphere.

Abstract: A particulate positive electrode active material for a lithium secondary cell which satisfies high charge and discharge cyclic durability, high safety, high temperature storage properties, a high discharge average voltage, large current discharge properties, a high weight capacity density, a high volume capacity density, etc. in a well-balanced manner is provided. A particulate positive electrode active material for a lithium secondary cell, which is represented by the formula LipCoxMyOzFa (wherein M is at least one element selected from Groups 2 to 8, 13 and 14 of the Periodic Table, 0.9?p?1.1, 0.980?x?0.9999, 0.0001?y?0.02, 1.9?z?2.1, 0.9?x+y?1 and 0.0001?a?0.02), wherein fluorine atoms and element M are unevenly distributed on the particle surface, the atomic ratio of fluorine atoms to cobalt atoms (a/x) is from 0.0001 to 0.02, and in powder X-ray diffraction using CuK?-ray, the half value width of the angle of diffraction on (110) plane is from 0.06 to 0.

Abstract: There is obtained an active material for a lithium secondary battery that has a wide usable voltage range, a high charge-discharge cycle durability, a high capacity and high safety and availability. The particles of a lithium-nickel-cobalt-manganese-fluorine-containing composite oxide having an R-3m rhombohedral structure represented by a general formula LipNixMn1-x-yCoyO2-qFq (where 0.98?p?1.07, 0.3?x?0.5, 0.1?y?0.38, and 0?q?0.05), and the particles of the lithium-nickel-cobalt-manganese-fluorine-containing composite oxide characterized in that the half-width of the diffraction peak of a (110) plane whose 2? is 65±0.5° in the X-ray diffraction using a Cu—K? line is, 0.12 to 0.25° are used as an active substance for a positive electrode.

Abstract: To provide a lithium-nickel-cobalt-manganese composite oxide powder for a positive electrode of a lithium secondary battery, which has a large volume capacity density and high safety and is excellent in the charge and discharge cyclic durability. A positive electrode active material powder for a lithium secondary battery characterized by comprising a first granular powder having a compression breaking strength of at least 50 MPa and a second granular powder having a compression breaking strength of less than 40 MPa, formed by agglomeration of many fine particles of a lithium composite oxide represented by the formula LipNixCoyMnzMqO2-aFa (wherein M is a transition metal element other than Ni, Co and Mn, Al or an alkaline earth metal element, 0.9?p?1.1, 0.2?x?0.8, 0?x?0.4, 0?z?0.5, y+z>0, 0?q?0.05, 1.9?2?a?2.1, x+y+z+q=1, and 0?a?0.02) to have an average particle size D50 of from 3 to 15 ?m, in a weight ratio of the first granular powder/the second granular powder being from 50/50 to 90/10.

Abstract: There is obtained a material of a positive electrode for a secondary lithium-ion cell having high cycle durability and high safety in high-voltage and high-capacity applications, which is a particulate positive electrode active material for a secondary lithium-ion cell represented by a general formula, LiaCObAcBdOeFf (A is Al or Mg, B is a group-IV transition element, 0.90?a?1.10, 0.97?b?1.00, 0.0001?c?0.03, 0.0001?d?0.03, 1.98?e?2.02, 0?f?0.02, and 0.0001?c+d?0.03), where element A, element B and fluorine are evenly present in the vicinity of the particle surfaces.

Abstract: To provide a process for producing a lithium-cobalt composite oxide for a positive electrode of a lithium secondary battery excellent in volume capacity density, safety, charge and discharge cyclic durability, press density and productivity, by using in expensive cobalt hydroxide and lithium carbonate. A mixture having a cobalt hydroxide powder and a lithium carbonate powder mixed so that the atomic ratio of lithium/cobalt would be from 0.98 to 1.01, is fired in an oxygen-containing atmosphere at from 250 to 700° C., and the fired product is further fired in an oxygen-containing atmosphere at from 850 to 1,050° C., or such a mixture is heated at a temperature-raising rate of at most 4° C./min in a range from 250 to 600° C. and fired in an oxygen-containing atmosphere at from 850 to 1,050° C.

Abstract: A lithium-nickel-cobalt-manganese composite oxide powder for a positive electrode of a lithium secondary battery, which has a large volume capacity density and high safety and is excellent in the charge and discharge cyclic durability, is presented. It is a lithium-nickel-cobalt-manganese composite oxide powder for a lithium secondary battery, represented by the formula LipNixCoyMnzMqO2-aFa (wherein M is a transition metal element other than Ni, Co or Mn, or an alkaline earth metal element, 0.9?p?1.1, 0.2?x?0.5, 0.1?y?0.4, 0.2?z?0.5, 0?q?0.05, 1.9?2-a?2.1, x+y+z+q=1, and 0?a?0.02). The lithium-nickel-cobalt-manganese composite oxide is an agglomerated granular composite oxide powder having an average particle size D50 of from 3 to 15 ?m, formed by agglomeration of many fine particles, and the compression breaking strength of the powder is at least 50 MPa.

Abstract: To provide a process for producing a lithium-cobalt composite oxide for a positive electrode of a lithium secondary battery, which has a large volume capacity density, high safety, high charge and discharge cycle durability, high press density and high productivity. A process for producing a lithium-cobalt composite oxide represented by the formula LipCoxMyOzFa (wherein M is a transition metal element other than Co, or an alkaline earth metal element, O.9?p?1.1, 0.980?x?1.000, 0?y?0.02, 1.9?z?2.1, x+y=1, and 0?a?0.02), characterized in that as a cobalt source, a mixture is used which comprises cobalt hydroxide in the form of substantially spherical secondary particles with an average particle size of from 8 to 20 ?m formed by agglomeration of primary particles and tricobalt tetroxide in the form of secondary particles with an average particle size of from 2 to 10 ?m formed by agglomeration of primary particles, in a cobalt atomic ratio of from 5:1 to 1:5, and firing is carried out at from 700 to 1,050° C.

Abstract: The present invention provides a lithium-transition metal composite oxide having a large volume capacity density, high safety, excellent coating uniformity, excellent charge/discharge cycle durability and excellent low temperature characteristics, and suitable as a positive electrode active material for a lithium secondary cell. A lithium-transition metal composite oxide which is represented by the formula LixM1?yNyO2 (wherein 0.2?x?1.2, 0?y?0.7, M is a transition metal element, and N is a transition metal element other than M or an alkaline earth metal element), wherein in the distribution curve of the cumulative volume particle size of said lithium composite oxide, the inclination of the curve at a cumulative volume fraction of 20% and 80% are at most 9%/?m and at least 3%/?m, respectively, and the average particle size is from 3 to 20 ?m.

Abstract: An electric double layer capacitor which has a low internal resistance and a large capacitance per unit volume and which is excellent in the voltage retention property, is provided. In a non-aqueous type electric double layer capacitor having a separator disposed between a positive electrode and a negative electrode made of carbonaceous electrodes, the separator comprises a sheet having a thickness of from 10 to 100 ?m and a porosity of from 50 to 90% and a netted spacer having a thickness of from 10 to 100 mm, a numerical aperture of from 30 to 85% and an opening of from 50 to 350 mesh, laminated one on the other.

Abstract: The present invention provides a composite oxide for a high performance solid oxide fuel cell which can be fired at a relatively low temperature, and which has little heterogeneous phases of impurities other than the desired composition. The composite oxide is the one having a perovskite type crystal structure containing rare earth elements, and having constituent elements homogeneously dispersed therein. A homogeneous composite oxide having an abundance ratio of heterogeneous phases of at most 0.3% by average area ratio, and a melting point of at least 1470° C., is obtained by using metal carbonates, oxides or hydroxides, and reacting them with citric acid in an aqueous system.