Patents by Inventor Mark L. Hlavinka

Mark L. Hlavinka has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).

  • Publication number: 20170096512
    Abstract: Disclosed herein are ethylene-based polymers having a density greater than 0.945 g/cm3, a high load melt index less than 25 g/10 min, a peak molecular weight ranging from 52,000 to 132,000 g/mol, and an environmental stress crack resistance of at least 250 hours. These polymers have the processability of chromium-based resins, but with improved impact strength and stress crack resistance, and can be used in large-part blow molding applications.
    Type: Application
    Filed: December 15, 2016
    Publication date: April 6, 2017
    Inventors: Mark L. Hlavinka, Qing Yang, Yongwoo Inn, William M. Whitte, John R. Rathman, Steven J. Secora, Daniel G. Hert
  • Patent number: 9611188
    Abstract: The present invention discloses processes for alkylating an aromatic compound, such as benzene or toluene, using a chemically-treated solid oxide. Suitable chemically-treated solid oxides include fluorided silica-coated alumina and fluorided-chlorided silica-coated alumina.
    Type: Grant
    Filed: February 17, 2016
    Date of Patent: April 4, 2017
    Assignee: Chevron Phillips Chemical Company LP
    Inventors: Qing Yang, Max P. McDaniel, Uriah J. Kilgore, Mark L. Hlavinka
  • Patent number: 9605100
    Abstract: Disclosed herein are polymerization processes for the production of olefin polymers. These polymerization processes can employ a catalyst system containing two or three metallocene components, resulting in ethylene-based copolymers that can have a medium density and improved stress crack resistance.
    Type: Grant
    Filed: June 27, 2016
    Date of Patent: March 28, 2017
    Assignee: Chevron Phillips Chemical Company LP
    Inventors: Mark L. Hlavinka, Errun Ding, Paul DesLauriers, Yongwoo Inn, Lili Cui, Qing Yang, Ashish M. Sukhadia, Guylaine St. Jean, Richard M. Buck
  • Publication number: 20170066857
    Abstract: Methods for controlling the die swell of an olefin polymer produced using a dual catalyst system are disclosed. The die swell of the olefin polymer can be increased or decreased as a function of the catalyst weight ratio and the reactant molar ratio used during the olefin polymerization process.
    Type: Application
    Filed: September 9, 2015
    Publication date: March 9, 2017
    Inventors: Jeff F. Greco, Qing Yang, Vivek Rohatgi, Mark L. Hlavinka, Jim B. Askew
  • Patent number: 9550849
    Abstract: Disclosed herein are ethylene-based polymers having a density greater than 0.945 g/cm3, a high load melt index less than 25 g/10 min, a peak molecular weight ranging from 52,000 to 132,000 g/mol, and an environmental stress crack resistance of at least 250 hours. These polymers have the processability of chromium-based resins, but with improved impact strength and stress crack resistance, and can be used in large-part blow molding applications.
    Type: Grant
    Filed: January 14, 2016
    Date of Patent: January 24, 2017
    Assignee: Chevron Phillips Chemical Company LP
    Inventors: Mark L. Hlavinka, Qing Yang, Yongwoo Inn, William M. Whitte, John R. Rathman, Steven J. Secora, Daniel G. Hert
  • Patent number: 9493589
    Abstract: Disclosed herein are ethylene-based polymers generally characterized by a density greater than 0.954 g/cm3, high load melt index ranging from 10 to 45 g/10 min, a ratio of high load melt index to melt index ranging from 175 to 600, a rheological slope parameter ranging from 0.15 to 0.30, and an ESCR in 10% igepal exceeding 800 hours. These polymers have the beneficial processability and die swell features of chromium-based resins, but with improved stiffness and stress crack resistance, and can be used in blow molding and other end-use applications.
    Type: Grant
    Filed: September 9, 2015
    Date of Patent: November 15, 2016
    Assignee: Chevron Phillips Chemical Company LP
    Inventors: Jeff F Greco, Qing Yang, Vivek Rohatgi, Mark L. Hlavinka, Jim B Askew
  • Publication number: 20160311745
    Abstract: Processes for producing an ?,?-unsaturated carboxylic acid, such as acrylic acid, or a salt thereof, using solid promoters are disclosed. The solid promoters can be certain solid oxides, mixed oxides, and clays, illustrative examples of which can include alumina, zirconia, magnesia, magnesium aluminate, sepiolite, and similar materials.
    Type: Application
    Filed: July 7, 2016
    Publication date: October 27, 2016
    Inventors: Mark L. Hlavinka, Max P. McDaniel
  • Publication number: 20160304644
    Abstract: Disclosed herein are polymerization processes for the production of olefin polymers. These polymerization processes can employ a catalyst system containing two or three metallocene components, resulting in ethylene-based copolymers that can have a medium density and improved stress crack resistance.
    Type: Application
    Filed: June 27, 2016
    Publication date: October 20, 2016
    Inventors: Mark L. Hlavinka, Errun Ding, Paul DesLauriers, Yongwoo Inn, Lili Cui, Qing Yang, Ashish M. Sukhadia, Guylaine St. Jean, Richard M. Buck
  • Publication number: 20160289351
    Abstract: Disclosed herein are methods of making bis(phenol) ligand compounds and transition metal bis(phenolate) compounds. The transition metal bis(phenolate) compounds can be used as components in catalyst systems for the polymerization of olefins.
    Type: Application
    Filed: June 8, 2016
    Publication date: October 6, 2016
    Inventor: Mark L. Hlavinka
  • Patent number: 9441000
    Abstract: Metallocene compounds and pharmaceutical compositions containing these metallocene compounds are disclosed and described. Methods of treating cancer employing such metallocene compounds and pharmaceutical compositions also are provided.
    Type: Grant
    Filed: July 10, 2014
    Date of Patent: September 13, 2016
    Assignee: Chevron Philips Chemical Company, LP
    Inventors: Mark L. Hlavinka, Qing Yang, Mandi Michelle Murph
  • Patent number: 9416087
    Abstract: Processes for producing an ?,?-unsaturated carboxylic acid, such as acrylic acid, or a salt thereof, using solid promoters are disclosed. The solid promoters can be certain solid oxides, mixed oxides, and clays, illustrative examples of which can include alumina, zirconia, magnesia, magnesium aluminate, sepiolite, and similar materials.
    Type: Grant
    Filed: October 8, 2014
    Date of Patent: August 16, 2016
    Assignee: Chevron Phillips Chemical Company LP
    Inventors: Mark L. Hlavinka, Max P. McDaniel
  • Publication number: 20160229782
    Abstract: Processes for producing an ?,?-unsaturated carboxylic acid, such as acrylic acid, or a salt thereof, using treated solid oxides are disclosed. The treated solid oxides can be calcined solid oxides, metal-treated solid oxides, or metal-treated chemically-modified solid oxides, illustrative examples of which can include sodium-treated alumina, calcium-treated alumina, zinc-treated alumina, sodium-treated sulfated alumina, sodium-treated fluorided silica-coated alumina, and similar materials.
    Type: Application
    Filed: April 6, 2016
    Publication date: August 11, 2016
    Inventors: Mark L. Hlavinka, Max P. McDaniel, Pasquale Iacono
  • Patent number: 9394387
    Abstract: Disclosed herein are methods of making bis(phenol) ligand compounds and transition metal bis(phenolate) compounds. The transition metal bis(phenolate) compounds can be used as components in catalyst systems for the polymerization of olefins.
    Type: Grant
    Filed: May 15, 2014
    Date of Patent: July 19, 2016
    Assignee: Chevron Phillips Chemical Company LP
    Inventor: Mark L. Hlavinka
  • Patent number: 9394393
    Abstract: Disclosed herein are polymerization processes for the production of olefin polymers. These polymerization processes can employ a catalyst system containing two or three metallocene components, resulting in ethylene-based copolymers that can have a medium density and improved stress crack resistance.
    Type: Grant
    Filed: September 2, 2015
    Date of Patent: July 19, 2016
    Assignee: Chevron Phillips Chemical Company LP
    Inventors: Mark L. Hlavinka, Errun Ding, Paul DesLauriers, Yongwoo Inn, Lili Cui, Qing Yang, Ashish Sukhadia, Guylaine St. Jean, Richard M. Buck
  • Patent number: 9394385
    Abstract: A polymer reactor-blend comprising at least a first component having a polydispersity index of greater than about 20 and is present in an amount of from about 1 wt. % to about 99 wt. % based on the total weight of the polymer and a second component having a polydispersity index of less than about 20 and is present in an amount of from about 1 wt. % to about 99 wt. % based on the total weight of the polymer wherein a molecular weight distribution of the second component lies within a molecular weight distribution of the first component.
    Type: Grant
    Filed: April 13, 2015
    Date of Patent: July 19, 2016
    Assignee: Chevron Phillips Chemical Company LP
    Inventors: Mark L. Hlavinka, Qing Yang, William B. Beaulieu, Paul J. Deslauriers
  • Publication number: 20160168290
    Abstract: A polymer reactor-blend comprising at least a first component having a polydispersity index of greater than about 20 and is present in an amount of from about 1 wt. % to about 99 wt. % based on the total weight of the polymer and a second component having a polydispersity index of less than about 20 and is present in an amount of from about 1 wt. % to about 99 wt. % based on the total weight of the polymer wherein a molecular weight distribution of the second component lies within a molecular weight distribution of the first component.
    Type: Application
    Filed: February 23, 2016
    Publication date: June 16, 2016
    Inventors: Mark L. Hlavinka, Qing Yang, William B. Beaulieu, Paul J. Deslauriers
  • Publication number: 20160122454
    Abstract: Disclosed herein are ethylene-based polymers having a density greater than 0.945 g/cm3, a high load melt index less than 25 g/10 min, a peak molecular weight ranging from 52,000 to 132,000 g/mol, and an environmental stress crack resistance of at least 250 hours. These polymers have the processability of chromium-based resins, but with improved impact strength and stress crack resistance, and can be used in large-part blow molding applications.
    Type: Application
    Filed: January 14, 2016
    Publication date: May 5, 2016
    Inventors: Mark L. Hlavinka, Qing Yang, Yongwoo Inn, William M. Whitte, John R. Rathman, Steven J. Secora, Daniel G. Hert
  • Publication number: 20160102039
    Abstract: Processes for producing an ?,?-unsaturated carboxylic acid, such as acrylic acid, or a salt thereof, using solid promoters are disclosed. The solid promoters can be certain solid oxides, mixed oxides, and clays, illustrative examples of which can include alumina, zirconia, magnesia, magnesium aluminate, sepiolite, and similar materials.
    Type: Application
    Filed: October 8, 2014
    Publication date: April 14, 2016
    Inventors: Mark L. Hlavinka, Max P. McDaniel
  • Patent number: 9284391
    Abstract: A polymer having a melt index of from about 0.5 g/10 min to about 4.0 g/10 min and a density of equal to or greater than 0.96 g/cc which when formed into a 1-mil film displays a moisture vapor transmission rate ranging from equal to or greater than about 0 to equal to or about 20% greater than X where X=k1{?61.95377+39.52785(Mz/Mw)?8.16974(Mz/Mw)2+0.55114(Mz/Mw)3}+k2{?114.01555(?)+37.68575(Mz/Mw)(?)?2.89177(Mz/Mw)2(?)}+k3{120.37572(?)2?25.91177(Mz/Mw)(?)2}+k4{18.03254(?)3} when Mw is from about 100 kg/mol to about 180 kg/moL; Mz is from about 300 kg/mol to about 1000 kg/mol; ? is from about 0.01 S to about 0.35 s; k1 is 1 g/100 in2·day; k2 is 1 g/100 in2·day·s; k3 is 1 g/100 in2·day·s2; and k4 is 1 g/100 in2·day·s3.
    Type: Grant
    Filed: November 29, 2011
    Date of Patent: March 15, 2016
    Assignee: Chevron Phillips Chemical Company LP
    Inventors: Mark L. Hlavinka, Qing Yang, Guylaine St. Jean, Brooke A. Gill, Deloris R. Gagan
  • Patent number: 9273170
    Abstract: Disclosed herein are ethylene-based polymers having a density greater than 0.945 g/cm3, a high load melt index less than 25 g/10 min, a peak molecular weight ranging from 52,000 to 132,000 g/mol, and an environmental stress crack resistance of at least 250 hours. These polymers have the processability of chromium-based resins, but with improved impact strength and stress crack resistance, and can be used in large-part blow molding applications.
    Type: Grant
    Filed: March 12, 2014
    Date of Patent: March 1, 2016
    Assignee: Chevron Phillips Chemical Company LP
    Inventors: Mark L. Hlavinka, Qing Yang, Yongwoo Inn, William M. Whitte, John R. Rathman, Steven J. Secora, Daniel G. Hert