Abstract: A negative electrode material for a lithium ion battery, in which a fine particle (A) containing an element selected from Si, Sn, Ge and In and a carbon particle (B) obtained by heat-treating a petroleum-based coke and/or a coal-based coke at a temperature of 2,500° C. or more are connected through a chemical bond such as urethane bond, urea bond, siloxane bond and ester bond. Also disclosed are a negative electrode sheet obtained by coating a current collector with a paste containing the negative electrode material, a binder and a solvent, and then drying and pressure-forming the paste; and a lithium ion battery incorporating the negative electrode sheet.

Abstract: A method for producing a graphie material for an electrode material for lithium ion batteries, including a step for exothermically graphitizing a carbon material by directly passing an electric current therethrough. The carbon material has an compact powder resistivity of 0.4 ?·cm or less when compressed to a density of 1.4 g/cm3, has an angle of repose in the range of 20° to 50° inclusive, and has a particle size (D90) in the volume-based particle size distribution measured using laser diffraction of 120 ?m or less. The average surface interval (d002) of a surface (002) of the carbon material after graphitization, measured using x-ray diffraction, is in the range of 0.3354 nm-0.3450 nm inclusive.

Abstract: The invention relates to an anode for lithium secondary battery comprising vapor grown carbon fiber uniformly dispersed without forming an agglomerate of 10 ?m or larger in an anode active material using natural graphite or artificial graphite, which anode is excellent in long cycle life and large current characteristics. Composition used for production for the anode can be produced, for example, by mixing a thickening agent solution containing an anode active material, a thickening agent aqueous solution and styrene butadiene rubber as binder with a composition containing carbon fiber dispersed in a thickening agent with a predetermined viscosity or by mixing an anode active material with vapor grown carbon fiber in dry state and then adding polyvinylidene difluoride thereto.

Abstract: The invention relates to a composite material comprising carbon fibers and complex oxide particles, wherein the carbon fibers and the complex oxide particles have a carbon coating on at least part of their surface, said carbon coating being a non powdery coating The material is prepared by a method comprising mixing a complex oxide or precursors thereof, an organic carbon precursor and carbon fibers, and subjecting the mixture to a heat treatment in an inert or reducing atmosphere for the decomposition of the precursors The material is useful as the cathode material in a battery.

Abstract: A negative electrode material for use in a lithium-ion battery is obtained by a method comprising subjecting a carbon particle (B) comprising a graphite material or the like to surface treatment with an oxidizing agent and then removing a residue of the oxidizing agent, modifying the carbon particle (B) from which the residue of the oxidizing agent has been removed with a silane coupling agent, modifying a particle (A) comprising an element capable of occluding and releasing a lithium ion, such as a Si particle, with a silane coupling agent, linking the modified carbon particle (B) and the modified particle (A) via a chemical bond, and coating a composite particle comprising the particle (A) and the carbon particle (B) linked to the particle (A) via a chemical bond with carbon.

Abstract: A negative electrode material for lithium ion batteries is obtained by a method which includes: mixing carbon particles (B) such as graphite particles, particles (A), such as Si particles, containing an element capable of occluding and releasing lithium ions, a carbon precursor such as sucrose, a carboxylic acid compound such as acetic acid, and a liquid medium such as water or isopropyl alcohol to prepare a slurry; drying and solidifying the slurry; and heat-treating the resulting solidified material to carbonize the carbon precursor. A lithium ion battery is obtained using this negative electrode material.

Abstract: A composite carbon particle for use in a negative electrode of a lithium-ion secondary battery, the composite carbon particle including a core particle composed of a carbon material obtained by heating, at not higher than 2500° C., petroleum coke having a Hardgrove grindability index (HGI value) of 30 to 60 (defined by ASTM D409), and a covering layer composed of a carbonaceous material obtained by heating an organic compound at 1000° C. to 2000° C. The composite carbon particle has a 50% particle diameter (D50) of 1 ?m to 30 ?m in a volume-based cumulative particle size distribution as measured by a laser diffraction method.

Abstract: A method for producing a graphite material for lithium ion batteries, including a step for exothermically graphitizing a carbon material by directly applying an electric current therethrough. The carbon material is obtained by heating at a temperature in the range of 800° C.-1500° C. inclusive and subsequently pulverizing an organic carbon starting material, has a compact powder resistivity of 0.3 ? cm or less when compressed to a density of 1.4 g/cm3, has an angle of repose in the range of 20° to 50° inclusive, and has a particle size (D90) in the volume-based particle size distribution measured using laser diffraction of 120 ?m or less. The average surface interval (d002) of a surface (002) of the carbon material after graphitization, measured using x-ray diffraction, is in the range of 0.3354 nm-0.3450 nm inclusive.

Abstract: The invention provides composite graphite particles, comprising a core material consisting of graphite having a interlayer distance d(002) of 0.337 nm or less and a surface layer consisting of graphite in which the intensity ratio ID/IG (R value) between the peak intensities (ID) in a range of 1300 to 1400 cm?1 and ( IG) in a range of 1580 to 1620 cm?1 as measured by Raman scattering spectroscopy is 0.3 or higher, wherein the peak intensity ratio I110/I004 between the peak intensities (I110)of face (110) and (I004)of face (004) obtained by XRD measurement on the graphite crystal is 0.15 or higher when the graphite has been mixed with a binder and pressure-molded to a density of 1.55 to 1.

Abstract: A graphite material having pores which, when 200 rectangular regions of 6 ?m×8 ?m are randomly selected in a surface image of the graphite material observed by a scanning electron microscope, in the surface of the graphite material appearing in the regions, a pore appearing on the surface and having an aperture in a shape having a diameter of 15 nm to 200 nm, a circularity degree of 0.75 to 1.0 and a major axis/minor axis ratio of 1.0 to 1.5 is visible in two regions or more. Also disclosed is a carbon material for battery electrodes, a paste for electrodes, an electrode and a lithium ion secondary battery including the graphite material.

Abstract: Disclosed are a negative electrode for lithium secondary batteries, containing an active material (A) capable of absorbing/desorbing lithium ions and a binder (B), wherein the active material (A) is a carbon-based material obtained from at least one starting material selected from a group consisting of petroleum cokes and coal cokes and having a mean particle size of from 1 to 30 and a true density of from 1.90 to 2.00 g/cm3 and its use; and a method for producing a carbon-based negative electrode active material having a mean particle size of from 1 to 30 ?m and a true density of from 1.90 to 2.00 g/cm3, the method comprising (a) a step of grinding at least one selected from a group consisting of petroleum cokes and coal cokes, (b) a step of controlling the particle size, and (c) a step of heat-treating in an inert gas atmosphere at 900 to 1900° C.

Abstract: A method for producing a graphite material for lithium ion batteries, including a step for exothermically graphitizing a carbon material by directly applying an electric current therethrough. The carbon material is obtained by heating at a temperature in the range of 800° C.-1500° C. inclusive and subsequently pulverizing an organic carbon starting material, has a compact powder resistivity of 0.3 ?cm or less when compressed to a density of 1.4 g/cm3, has an angle of repose in the range of 20° to 50° inclusive, and has a particle size (D90) in the volume-based particle size distribution measured using laser diffraction of 120 ?m or less. The average surface interval (d002) of a surface (002) of the carbon material after graphitization, measured using x-ray diffraction, is in the range of 0.3354 nm-0.3450 nm inclusive.

Abstract: Particles (A) including an element capable of intercalating and deintercalating lithium ions, carbon particles (B) capable of intercalating and deintercalating lithium ions, multi-walled carbon nanotubes (C), carbon nanofibers (D) and optionally electrically conductive carbon particles (E) are mixed in the presence of shear force to obtain a composite electrode material. A lithium ion secondary battery is obtained using the above composite electrode material.

Abstract: A method for producing a graphie material for an electrode material for lithium ion batteries, including a step for exothermically graphitizing a carbon material by directly passing an electric current therethrough. The carbon material has an compact powder resistivity of 0.4 ?·cm or less when compressed to a density of 1.4 g/cm3, has an angle of repose in the range of 20° to 50° inclusive, and has a particle size (D90) in the volume-based particle size distribution measured using laser diffraction of 120 ?m or less. The average surface interval (d002) of a surface (002) of the carbon material after graphitization, measured using x-ray diffraction, is in the range of 0.3354 nm-0.3450 nm inclusive.

Abstract: The invention relates to an anode for lithium secondary battery comprising vapor grown carbon fiber uniformly dispersed without forming an agglomerate of 10 ?m or larger in an anode active material using natural graphite or artificial graphite, which anode is excellent in long cycle life and large current characteristics. Composition used for production for the anode can be produced, for example, by mixing a thickening agent solution containing an anode active material, a thickening agent aqueous solution and styrene butadiene rubber as binder with a composition containing carbon fiber dispersed in a thickening agent with a predetermined viscosity or by mixing an anode active material with vapor grown carbon fiber in dry state and then adding polyvinylidene difluoride thereto.

Abstract: A carbon raw material such as a green coke in which loss on heat when it is heated from 300 to 1200° C. under an inert atmosphere is no less than 5% by mass and no more than 20% by mass is pulverized and then the pulverized carbon raw material is graphitized to obtain a graphite material suitable for a carbon material for anode in a lithium-ion secondary battery or the like that enables to make electrodes having a high-energy density and a large-current load characteristic since it has a small specific surface area and a small average particle diameter while maintaining high beginning efficiency and a high discharge capacity in the first round of charging and discharging. And an electrode for batteries are obtained using the graphite material.

Abstract: A composite electrode material consisting of a carbon coated complex oxide, fibrous carbon and a binder. Said material is prepared by a method which includes co-grinding an active electrode material and fibrous carbon, and adding a binder to the co-grinded mixture to lower the viscosity of the mixture. The fibrous carbon is preferably vapor grown carbon fibers.

Abstract: The invention relates to an anode for lithium secondary battery comprising vapor grown carbon fiber uniformly dispersed without forming an agglomerate of 10 ?m or larger in an anode active material using natural graphite or artificial graphite, which anode is excellent in long cycle life and large current characteristics. Composition used for production for the anode can be produced, for example, by mixing a thickening agent solution containing an anode active material, a thickening agent aqueous solution and styrene butadiene rubber as binder with a composition containing carbon fiber dispersed in a thickening agent with a predetermined viscosity or by mixing an anode active material with vapor grown carbon fiber in dry state and then adding polyvinylidene difluoride thereto.

Abstract: The invention relates to a composite electrode material consisting of a carbon coated complex oxide, fibrous carbon and a binder. Said material is prepared by a method which comprises co-grinding an active electrode material and fibrous carbon, and adding a binder to the co-grinded mixture to lower the viscosity of the mixture. The fibrous carbon is preferably vapor grown carbon fibers.

Abstract: A negative electrode material for a lithium ion battery, in which a fine particle (A) containing an element selected from Si, Sn, Ge and In and a carbon particle (B) obtained by heat-treating a petroleum-based coke and/or a coal-based coke at a temperature of 2,500° C. or more are connected through a chemical bond such as urethane bond, urea bond, siloxane bond and ester bond. Also disclosed are a negative electrode sheet obtained by coating a current collector with a paste containing the negative electrode material, a binder and a solvent, and then drying and pressure-forming the paste; and a lithium ion battery incorporating the negative electrode sheet.