Patents by Inventor Shintaro Kikuchi

Shintaro Kikuchi has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).

  • Patent number: 8802273
    Abstract: A microporous polyethylene membrane made of a polyethylene resin having a ratio (mass-average molecular weight/number-average molecular weight) of 5 to 300 and comprising 1% or more by mass of ultra-high-molecular-weight polyethylene having a mass-average molecular weight of 7×105 or more, the microporous polyethylene membrane comprising (a) a coarse-structure layer having an average pore diameter of more than 0.04 ?m, which is formed on at least one surface, and (b) a dense-structure layer having an average pore diameter of 0.04 ?m or less, an area ratio of the coarse-structure layer to the dense-structure layer in a membrane cross section being 0.1 to 0.8.
    Type: Grant
    Filed: September 14, 2006
    Date of Patent: August 12, 2014
    Assignee: Toray Battery Separator Film Co., Ltd
    Inventors: Kotaro Takita, Shintaro Kikuchi, Kazuhiro Yamada, Teiji Nakamura, Koichi Kono
  • Patent number: 8778525
    Abstract: A multi-layer, microporous polyethylene membrane comprising (a) a first microporous layer made of a polyethylene resin, and (b) a second microporous layer comprising a polyethylene resin, and a heat-resistant polymer having a melting point or a glass transition temperature of 170° C. or higher, the heat-resistant polymer being dispersed in the form of fine particles in the polyethylene resin, and the second microporous layer having pores containing fine particles of the heat-resistant polymer as nuclei from which the cleavage of polyethylene resin fibrils starts, the multi-layer microporous polyethylene membrane having well-balanced shutdown properties, meltdown properties, permeability, mechanical strength, heat shrinkage resistance and compression resistance.
    Type: Grant
    Filed: August 24, 2006
    Date of Patent: July 15, 2014
    Assignee: Toray Battery Separator Film Co., Ltd
    Inventors: Shintaro Kikuchi, Kotaro Takita
  • Patent number: 8748028
    Abstract: The invention relates to a particular multi-layer microporous membrane having a good balance of important properties, including excellent electrochemical stability and low heat shrinkage, while maintaining high permeability and heat resistance, with good mechanical strength, compression resistance and electrolytic solution absorption. Of particular importance when used as a battery separator, the present multi-layer microporous membrane exhibits excellent heat shrinkage, melt down temperature and thermal mechanical properties, i.e. low maximum shrinkage in the molten state. The multi-layer microporous membrane of the present invention is manufactured by layering, such as for example by coextrusion, one or more microporous membrane first layers and one or more microporous membrane second layers, such as on one or both sides of a first layer. The invention further relates to battery separators comprising the multi-layer microporous membrane and batteries utilizing the battery separators.
    Type: Grant
    Filed: November 2, 2007
    Date of Patent: June 10, 2014
    Assignee: Toray Battery Separator Film Co. Ltd.
    Inventors: Kotaro Takita, Shintaro Kikuchi
  • Publication number: 20140134357
    Abstract: An image transfer sheet includes an image-receiving layer, a substrate, and a rear outermost layer containing an alkali metal salt of an aliphatic carboxylic acid. The image-receiving layer, the substrate, and the rear outermost layer are arranged in that order.
    Type: Application
    Filed: April 16, 2013
    Publication date: May 15, 2014
    Applicant: FUJI XEROX CO., LTD.
    Inventors: Tomoo KOBAYASHI, Tetsuro KODERA, Naoyuki EGUSA, Kaoru TORIKOSHI, Shintaro KIKUCHI
  • Patent number: 8715849
    Abstract: The invention relates to a microporous membrane which comprises polyethylene, the microporous membrane having a differential pore volume curve with an area under the curve over the range of pore diameters of from about 100 nm to about 1,000 nm that is 25% or more of a total area under the curve over the range of pore diameters of from about 10 nm to about 1,000 nm.
    Type: Grant
    Filed: October 5, 2007
    Date of Patent: May 6, 2014
    Assignee: Toray Battery Separator Film Co., Ltd.
    Inventors: Kotaro Takita, Shintaro Kikuchi
  • Patent number: 8709640
    Abstract: The invention relates to polyolefin membranes and membrane precursors comprising polyethylene and polypropylene. The polyolefin membrane can be a microporous polyolefin membrane comprising a first microporous layer and at least one second microporous layers where the first and second layers contain polypropylene and polyethylene, and the amount of polyethylene in the first layer is at least about 80 wt. % and the amount of polyethylene in the second layer is at least about 50 wt. %. The amount of polyethylene is higher in the first microporous layer than in the second microporous layer, and the total amount of the polyethylene in the first and second microporous layers is at least about 61 wt. %, based on the weight of the multi-layer, microporous polyolefin membrane.
    Type: Grant
    Filed: August 29, 2008
    Date of Patent: April 29, 2014
    Assignee: Toray Battery Separator Film Co., Ltd
    Inventors: Shintaro Kikuchi, Junko Takita
  • Patent number: 8710110
    Abstract: A process of producing a membrane includes extruding diluent and polymer to form an extrudate, the polymer includes a first polyethylene having an Mw<1.0×106, a second polyethylene having an Mw?1.0×106, and a polypropylene having an Mw?5.0×105 and a ?Hm?80.0 J/g; wherein the sum of the polypropylene having an Mw?5.0×105 and a ?Hm?80.0 J/g and the second polyethylene is ?15.0 wt. % and processing the extrudate into a membrane having a thickness ?12.0 ?m by stretching the extrudate in at least one planar direction at about 108.0 to 116.0° C. after removing the solvent to a magnification factor of ?1.1 and excludes any stretching of the extrudate after removing the solvent at a magnification factor or >1.1 and removing at least a portion of the diluent from the extrudate.
    Type: Grant
    Filed: June 7, 2013
    Date of Patent: April 29, 2014
    Assignee: Toray Battery Separator Film Co. Ltd.
    Inventors: Shintaro Kikuchi, Kotaro Takita, Kazuhiro Yamada
  • Publication number: 20130273434
    Abstract: A process of producing a membrane includes extruding diluent and polymer to form an extrudate, the polymer includes a first polyethylene having an Mw<1.0×106, a second polyethylene having an Mw?1.0×106, and a polypropylene having an Mw?5.0×105 and a ?Hm?80.0 J/g; wherein the sum of the polypropylene having an Mw?5.0×105 and a ?Hm?80.0 J/g and the second polyethylene is ?15.0 wt. % and processing the extrudate into a membrane having a thickness ?12.0 ?m by stretching the extrudate in at least one planar direction at about 108.0 to 116.0° C. after removing the solvent to a magnification factor of ?1.1 and excludes any stretching of the extrudate after removing the solvent at a magnification factor or >1.1 and removing at least a portion of the diluent from the extrudate.
    Type: Application
    Filed: June 7, 2013
    Publication date: October 17, 2013
    Inventors: Shintaro Kikuchi, Kotaro Takita, Junko Takita, Kazuhiro Yamada
  • Publication number: 20130256933
    Abstract: A microporous polyethylene membrane made of a polyethylene resin comprising 15% or less by mass of ultra-high-molecular-weight polyethylene having a mass-average molecular weight of 1×106 or more, which is constituted by a dense-structure layer having an average pore diameter of 0.01 to 0.05 ?m, and a coarse-structure layer formed on at least one surface and having an average pore diameter 1.2-fold to 5.0-fold of that of the dense-structure layer, has a high electrolytic solution absorption speed with thickness and air permeability little changing when compressed. Such a microporous polyethylene membrane is produced by extruding a melt blend of the above polyethylene resin and a membrane-forming solvent through a die, cooling the resultant extrudate with a temperature distribution in a thickness direction to provide a gel-like sheet, stretching the gel-like sheet at a temperature from the crystal dispersion temperature of the polyethylene resin +10° C. to the crystal dispersion temperature +30° C.
    Type: Application
    Filed: May 24, 2013
    Publication date: October 3, 2013
    Inventors: Kotaro TAKITA, Shintaro KIKUCHI, Kazuhiro YAMADA, Teiji NAKAMURA, Koichi KONO
  • Publication number: 20130189587
    Abstract: The invention relates to microporous membranes having a thickness 19.0 micrometer or less, the membranes having a relatively high porosity, air permeability and puncture strength. Such membranes can be produced by extrusion and are suitable for use as battery separator film.
    Type: Application
    Filed: March 7, 2011
    Publication date: July 25, 2013
    Applicant: TORAY BATTERY SEPARATOR FILM CO., LTD.
    Inventors: Shintaro Kikuchi, Kazuhiro Yamada, Junko Takita
  • Patent number: 8420403
    Abstract: A method for evaluating the caking property of sodium hydrogencarbonate crystal particles, characterized in that sodium hydrogencarbonate crystal particles are hermetically sealed in a packaging material having a water vapor transmission rate of at least 3 g/(m2·24 h) (at 40° C. with a relative humidity difference of 90%) as stipulated in JIS K7129 and left at rest at a temperature of from 17 to 35° C. at a carbon dioxide gas concentration of from 0.03 to 0.05 vol % at a relative humidity of from 40 to 95% for from 2 weeks to 3 months, and the proportion of agglomerated sodium hydrogencarbonate crystal particles is determined to evaluate the caking tendency. A novel test method for evaluating the caking property of sodium hydrogencarbonate crystal particles, capable of providing results of the caking property test with high reproducibility, quantitatively with high versatility, can be provided.
    Type: Grant
    Filed: January 3, 2007
    Date of Patent: April 16, 2013
    Assignee: Asahi Glass Company, Limited
    Inventors: Shintaro Kikuchi, Fumiaki Nakashima, Hisakazu Arima, Shigeru Sakurai, Takako Hirano
  • Publication number: 20130045412
    Abstract: The invention relates to microporous polymeric membranes suitable for use as battery separator film. The invention also relates to a method for producing such a membrane, batteries containing such membranes as battery separators, methods for making such batteries, and methods for using such batteries.
    Type: Application
    Filed: December 15, 2010
    Publication date: February 21, 2013
    Inventors: Kazuhiro Yamada, Shintaro Kikuchi, Junko Takita
  • Patent number: 8338017
    Abstract: A microporous membrane comprising (a) from 40 to 60% of a first polyethylene resin having a weight average molecular weight of from 3×105 to 3.5×105 and a molecular weight distribution of from 5 to 50, (b) from 20 to 40% of a first polypropylene having a weight average molecular weight of from 0.9×106 to 1.1×106, a molecular weight distribution of from 1 to 50, and a heat of fusion of from to 120 J/g, (c) from 10 to 25% of a second polypropylene having a weight average molecular weight of from 5.7 to 105 to 6.6×105, a molecular weight distribution of from 5 to 50, and a heat of fusion of from 80 to 120 J/g, and (d) from 0 to 10% of a second polyethylene resin having a weight average molecular weight of from 1×106 to 3×106 and a molecular weight distribution of from 5 to 50, percentages based on the mass of the membrane.
    Type: Grant
    Filed: October 12, 2007
    Date of Patent: December 25, 2012
    Assignee: Toray Battery Separator Film Co., Ltd.
    Inventors: Shintaro Kikuchi, Kotaro Takita
  • Patent number: 8323821
    Abstract: The present invention relates to a particular multi-layer microporous membrane having a good balance of important properties, including excellent electrochemical stability and low heat shrinkage, while maintaining high permeability and heat resistance, with good mechanical strength, compression resistance and electrolytic solution absorption. Of particular importance when used as a battery separator, the present multi-layer microporous membrane exhibits excellent heat shrinkage, melt down temperature and thermal mechanical properties, i.e. low maximum shrinkage in the molten state. The multi-layer microporous membrane of the present invention can be produced (or manufactured) by layering, such as for example by coextrusion, one or more microporous membrane second layers and one or more microporous membrane first layers, such as on one or both sides of a second layer.
    Type: Grant
    Filed: November 9, 2007
    Date of Patent: December 4, 2012
    Assignee: Toray Battery Separator Film Co., Ltd.
    Inventors: Kotaro Takita, Shintaro Kikuchi
  • Patent number: 8304114
    Abstract: A microporous polyolefin membrane having a structure in which its pore size distribution curve obtained by mercury intrusion porosimetry has at least two peaks, which is produced by extruding a melt-blend of a polyolefin composition comprising (a) high density polyethylene resin having a weight average molecular weight of from about 2.5×105 to about 5×105 and a molecular weight distribution of from about 5 to about 100, (b) polypropylene resin having a weight average molecular weight of from about 3×105 to about 1.
    Type: Grant
    Filed: September 20, 2007
    Date of Patent: November 6, 2012
    Assignee: Toray Battery Separator Film Co., Ltd.
    Inventors: Kotaro Takita, Shintaro Kikuchi
  • Publication number: 20120273114
    Abstract: A multi-layer, microporous polyolefin membrane comprising first microporous layers constituting at least both surface layers, and at least one second microporous layer disposed between both surface layers, the first microporous layer comprising a first polyethylene resin containing 8% or more by mass of ultra-high-molecular-weight polyethylene having a weight-average molecular weight of 1×106 or more, the second microporous layer comprising a second polyethylene resin containing 7% or less by mass of the ultra-high-molecular-weight polyethylene, and having a structure in which a pore diameter distribution curve obtained by mercury intrusion porosimetry has at least two peaks, and the total thickness of the first microporous layers being 15-60% per 100% of the total thickness of the first and second microporous layers.
    Type: Application
    Filed: July 12, 2012
    Publication date: November 1, 2012
    Applicant: TORAY TONEN SPECIALTY SEPARATOR GODO KAISHA
    Inventors: Kotaro TAKITA TAKITA, Shintaro KIKUCHI, Junko TAKITA
  • Patent number: 8273279
    Abstract: A microporous membrane having a structure in which its pore size distribution curve obtained by mercury intrusion porosimetry has at least two peaks, which is produced by extruding a combination of a diluent or solvent and a polyolefin resin composition comprising from about 75 to about 99% of a polyethylene resin having a weight average molecular weight of from about 2.
    Type: Grant
    Filed: September 28, 2007
    Date of Patent: September 25, 2012
    Assignee: Toray Battery Separator Film Co., Ltd.
    Inventors: Kotaro Takita, Shintaro Kikuchi
  • Patent number: 8252450
    Abstract: A multi-layer, microporous polyolefin membrane comprising first microporous layers constituting at least both surface layers, and at least one second microporous layer disposed between both surface layers, the first microporous layer comprising a first polyethylene resin containing 8% or more by mass of ultra-high-molecular-weight polyethylene having a weight-average molecular weight of 1×106 or more, the second microporous layer comprising a second polyethylene resin containing 7% or less by mass of the ultra-high-molecular-weight polyethylene, and having a structure in which a pore diameter distribution curve obtained by mercury intrusion porosimetry has at least two peaks, and the total thickness of the first microporous layers being 15-60% per 100% of the total thickness of the first and second microporous layers.
    Type: Grant
    Filed: April 9, 2007
    Date of Patent: August 28, 2012
    Assignee: Toray Tonen Specialty Separator Godo Kaisha
    Inventors: Kotaro Takita, Junko Takita, legal representative, Shintaro Kikuchi
  • Patent number: 8236268
    Abstract: A process for producing sodium hydrogencarbonate crystal particles having a low caking property, which entails subjecting sodium hydrogencarbonate crystal particles having an average particle size of from 50 to 500 ?m based on the mass to heat treatment at a temperature of from 70 to 95° C. by a heating gas having a carbon dioxide gas concentration of at most the concentration calculated by the formula: Carbon dioxide gas concentration=0.071×e(0.1×T)×R(?0.0005×T?0.9574), where T (° C.) is the temperature of sodium hydrogencarbonate crystals, and R (%) is the relative humidity around the crystals at the temperature of the crystals, provided that the upper limit of the carbon dioxide gas concentration is 100 vol % to form anhydrous sodium carbonate on the surface of the sodium hydrogencarbonate crystal particles with a content of anhydrous sodium carbonate of from 0.03 to 0.4 mass % in the sodium hydrogencarbonate crystals.
    Type: Grant
    Filed: December 27, 2006
    Date of Patent: August 7, 2012
    Assignee: Asahi Glass Company, Limited
    Inventors: Hachirou Hirano, Takako Hirano, legal representative, Shintaro Kikuchi, Fumiaki Nakashima, Hisakazu Arima, Shigeru Sakurai
  • Patent number: 8026005
    Abstract: A microporous polyolefin membrane having a structure in which its pore size distribution curve obtained by mercury intrusion porosimetry has at least two peaks, which is produced by (1) extruding a melt-blend of (a) (i) a polyethylene resin containing 7% or less by mass of ultra-high-molecular-weight polyethylene having a weight-average molecular weight of 1×106 or more, or (ii) a mixture of 75% by mass or more of said polyethylene resin and 25% or less by mass of polypropylene, and (b) a membrane-forming solvent, (2) stretching a gel-like sheet obtained by cooling an extrudate, (3) washing it, (4) stretching the resultant microporous membrane to 1.1-1.8 fold in at least one direction, and (5) heat-setting it at a temperature in a range of the stretching temperature of the microporous membrane plus or minus 5 degrees centigrade.
    Type: Grant
    Filed: April 9, 2007
    Date of Patent: September 27, 2011
    Assignee: Tonen Chemical Corporation
    Inventors: Kotaro Takita, Shintaro Kikuchi