The Nitrogen Is A Ring Member Of A Heterocyclic Ring Patents (Class 106/31.46)
  • Patent number: 7407540
    Abstract: A coloring liquid can form an image showing a high color developability and a high vividness as well as an excellent water fastness when used as recording material with a recording technique such as ink-jet printing. An ink tank, a recording unit, a recording apparatus and a recording method are adapted to use such a coloring liquid. Such a coloring liquid contains at least one colorant compound having a structure represented by the general formula (1) below and an ink tank, a recording unit, a recording apparatus and a recording method are adapted to use such a coloring liquid.
    Type: Grant
    Filed: February 14, 2006
    Date of Patent: August 5, 2008
    Assignee: Canon Kabushiki Kaisha
    Inventors: Yuko Yamagishi, Yasuaki Murai, Takeshi Miyazaki
  • Patent number: 7402201
    Abstract: To provide an ink stock solution excellent in handleability, a method for producing the same, an ink composition using the ink stock solution, particularly suitable for an ink for inkjet recording, and a method for producing the same, the ink stock solution includes a dye and a viscosity reducing agent, wherein the ink stock solution has a solid concentration of the dye of 7% or more by weight; the method for producing the ink stock solution includes adding a dye to a water and dissolving the dye in the water, and then, adding a viscosity reducing agent to control the viscosity; the method for producing the ink stock solution includes dissolving a dye, a water and a viscosity reducing agent all together; and the ink composition includes the ink stock solution and has a viscosity of 1 to 30 mPa·s.
    Type: Grant
    Filed: March 22, 2005
    Date of Patent: July 22, 2008
    Assignee: FUJIFILM Corporation
    Inventors: Naotaka Wachi, Takashi Ozawa, Toshiki Fujiwara, Keiichi Tateishi
  • Patent number: 7399349
    Abstract: An ink for ink jet recording, which hardly causes blotting of an image even under high humidity conditions while maintaining the advantages as water-based ink (handling properties, stability, producing properties, hue), is provided. Also provided is a method of manufacturing ink for ink jet recording, an ink set for ink jet recording, and an ink jet recording method.
    Type: Grant
    Filed: September 12, 2005
    Date of Patent: July 15, 2008
    Assignee: FUJIFILM Corporation
    Inventors: Toshiki Taguchi, Toshiaki Aono, Masanobu Takashima, Manabu Ogawa
  • Patent number: 7396398
    Abstract: An ink composition is provided including an amide compound represented by formula I, a coloring agent and a solvent. The amide compound and the polyhydric alcohol in the ink composition decrease the mobility of coloring agents and increase the adhesion to media, thereby minimizing the bleeding between colors of printed images, and improving the water fastness and dry and wet rub fastness to provide good color fastness on papers. The ink composition also improves the quality of the printed image, and also has good long-term storage stability. Thus, the ink composition can be widely used as ink-jet inks for ink-jet printers, printing inks, paints, textile printing, paper manufacturing, cosmetics manufacturing, ceramic industry, etc.
    Type: Grant
    Filed: October 15, 2004
    Date of Patent: July 8, 2008
    Assignee: Samsung Electronics Co., Ltd.
    Inventors: Jong-in Lee, Seung-min Ryu, Su-aa Jung
  • Patent number: 7393403
    Abstract: A self-dispersible coloring agent represented by formula (II) below is prepared by incorporating a hydrophilic group into a coloring agent through a reaction of a hydrophilic group-containing halide represented by formula (I) below and the coloring agent in the presence of a Lewis acid catalyst: X-L-R1??(I) (the coloring agent)-L-R1??(II) wherein L represents a single bond or —C(?O)—; R1 is selected from the group consisting of a substituted or unsubstituted C1-C20 alkyl group containing a hydrophilic group, a substituted or unsubstituted C6-C20 aryl group containing a hydrophilic group a substituted or unsubstituted C2-C20 heteroaryl group containing a hydrophilic group and a substituted or unsubstituted C7-C20 arylalkyl group containing a hydrophilic group; and X is one of: —F, —Br, —I and —Cl. may be obtained conveniently through a one-step process.
    Type: Grant
    Filed: August 27, 2004
    Date of Patent: July 1, 2008
    Assignee: Samsung Eletronics Co., Ltd.
    Inventors: Jong-in Lee, Seung-min Ryu, Su-aa Jung
  • Patent number: 7384464
    Abstract: The present invention relates to an ink-jet ink, an ink-jet recording material or an ink-jet system containing at least one water-soluble hindered amine compound of the general formula (I): wherein G1 and G2 are independently alkyl 1 to 4 carbon atoms or are together pentamethylene; Z1 and Z2 are each methyl, or Z1 and Z2 together form an unsubstituted linking moiety or a linking moiety substituted by one or more groups selected from an ester, ether, hydroxy, oxo, cyanohydrin, amide, amino, carboxy or an urethane group; E is alkoxy of 1 to 18 carbon atoms, cycloalkoxy of 5 to 12 carbon atoms or aralkoxy of 7 to 15 carbon atoms, or E is —O-T-(OH)b; T is a straight or branched chain alkylene of 1 to 18 carbon atoms, cycloalkylene of 5 to 18 carbon atoms, cycloalkenylene of 5 to 18 carbon atoms, a straight or branched chain alkylene of 1 to 4 carbon atoms substituted by phenyl or by phenyl substituted by one or two alkyl groups of 1 to 4 carbon atoms; b is 1, 2 or 3 with the proviso that b cannot exceed the
    Type: Grant
    Filed: March 22, 2005
    Date of Patent: June 10, 2008
    Assignee: Ciba Specialty Chemicals Corporation
    Inventors: Mervin G. Wood, Robert E. Detlefsen, Joseph Suhadolnik, Walter Renz
  • Patent number: 7377972
    Abstract: An aqueous printing fluid, comprising a cosolvent, the cosolvent or mixture of compounds comprising at least one inner salt compound having a sp3-hybridized nitrogen cation and an associated anionic charge either isolated on an N-substituted oxygen anion bound directly to the sp3-hybridized nitrogen cation or isolated among the oxygens of a carboxylate group; a method of avoiding paper curl in printed paper by using the above-described aqueous printing fluid; and a printer system for avoiding paper curl in printed paper through using the above-described aqueous printing fluid.
    Type: Grant
    Filed: September 27, 2004
    Date of Patent: May 27, 2008
    Assignee: Hewlett-Packard Development Company, L.P.
    Inventors: Gary W Byers, Richard Anderson, Mark L. Choy
  • Publication number: 20080036838
    Abstract: An ink composition for inkjet recording, and more particularly, an ink composition for inkjet recording in which bleeding between colors of a printed image is reduced, and dry and wet rub fastness of a printed image are improved. The ink composition includes an oxylate-based compound and an amide compound.
    Type: Application
    Filed: November 30, 2006
    Publication date: February 14, 2008
    Inventors: In-hye Kim, Jong-in Lee
  • Publication number: 20080006177
    Abstract: There is provided an aqueous formulation comprising an IR-absorbing naphthalocyanine dye of formula (II): or a salt form thereof, wherein: M is Ga(A1); A1 is an axial ligand selected from —OH, halogen, —OR3, —OC(O)R4 or —O(CH2CH2O)eRe wherein e is an integer from 2 to 10 and Re is H, C1-8 alkyl or C(O)C1-8 alkyl; R1 and R2 may be the same or different and are selected from hydrogen or C1-12 alkoxy; R3 is selected from C1-12 alkyl, C5-12 aryl, C5-12 arylalkyl or Si(Rx)(Ry)(Rz); R4 is selected from C1-12 alkyl, C5-12 aryl or C5-12 arylalkyl; and Rx, Ry and Rz may be the same or different and are selected from C1-12 alkyl, C5-12 aryl, C5-12 arylalkyl, C1-12 alkoxy, C5-12 aryloxy or C5-12 arylalkoxy; The formulation has a pH in the range of 3.5 to 7 and is particularly suitable for use as an IR-absorbing inkjet ink, providing compatibility with known CMYK inks together with an optimally red-shifted ?max.
    Type: Application
    Filed: July 10, 2006
    Publication date: January 10, 2008
    Inventors: Sutharsiny Indusegaram, Graciel Gonzaga, Simone Charlotte Vonwiller, Scott Matthew Starling, Lachlan Everett Hall, Damon Donald Ridley, Kia Silverbrook
  • Patent number: 7303615
    Abstract: There is provided a colorant material comprising a compound represented by at least one of the following general formulas (1) and (2) as a first colorant compound and at least one of a water insoluble triphenylmethane compound and a water insoluble xanthene compound as a second colorant compound
    Type: Grant
    Filed: February 24, 2005
    Date of Patent: December 4, 2007
    Assignee: Canon Kabushiki Kaisha
    Inventors: Yuko Yamagishi, Yasuaki Murai, Takeshi Miyazaki
  • Patent number: 7303272
    Abstract: A black ink for inkjet recording having an aqueous medium containing a dye in which ?max of the absorption spectrum in an aqueous solution is in the region from 500 and 700 nm and the half-value width in the absorption spectrum of a dilute solution standardized to an absorbance of 1.0 is 100 nm or more. An object of the present invention is to provide an inkjet recording ink ensuring excellent discharge stability even after aging of the ink and also exhibiting excellent weather resistance.
    Type: Grant
    Filed: July 1, 2003
    Date of Patent: December 4, 2007
    Assignee: FUJIFILM Corporation
    Inventors: Toshiki Taguchi, Takashi Ozawa, Toshiaki Aono, Yoshiharu Yabuki, Tomohiro Chino
  • Patent number: 7291212
    Abstract: An inkjet recording ink composition comprising an aqueous medium having dissolved and/or dispersed therein at least one dye, wherein at least one betaine-type surfactant is contained in the ink composition. The dye is preferably a magenta dye having an azo structure or a cyanine dye having a phthalocyanine structure. The inkjet recording ink composition is excellent in ejection property, light fastness, heat fastness and oxidation resistance and causing less dye bleeding.
    Type: Grant
    Filed: February 6, 2003
    Date of Patent: November 6, 2007
    Assignee: Fujifilm Corporation
    Inventor: Toshiki Taguchi
  • Patent number: 7291213
    Abstract: An ink composition comprising: a coloring agent having an oxidation potential of more electropositive than 1.0V (vs SCE); a water; a guanidine compound; and a surfactant, the ink composition to be used in inkjet recording and an inkjet recording method with the use of the ink composition.
    Type: Grant
    Filed: August 23, 2005
    Date of Patent: November 6, 2007
    Assignee: Fujifilm Corporation
    Inventors: Manabu Ogawa, Keiichi Tateishi
  • Patent number: 7279034
    Abstract: It is an object of the present invention to provide an ink composition with which the indoor storage stability (gas resistance) of an image produced with an ink composition featuring a phthalocyanine-based cyan dye can be increased without causing any additive precipitation or bronzing. The present invention provides an ink composition containing at least water, a phthalocyanine-based cyan dye, and a lithium salt of an aromatic compound having a sulfo group and expressed by General Formulas 1 and/or 2 in the claims. The present invention also provides an ink composition containing at least water, a phthalocyanine-based cyan dye, and a lithium salt of an aromatic compound having a sulfo group and expressed by General Formulas 5 and/or 6 in the claims.
    Type: Grant
    Filed: December 19, 2005
    Date of Patent: October 9, 2007
    Assignee: Seiko Epson Corporation
    Inventors: Yasuhiro Oki, Kazuhiko Kitamura
  • Patent number: 7276111
    Abstract: An object of the present invention is to provide an ink composition that can improve the preservation characteristics (gas fastness) of an image produced by an ink composition which uses phthalocyanine group cyan dye. The present invention provides an ink composition wherein at least water, the phthalocyanine group cyan dye indicated by the general formula (I), and an aromatic compound having a sulfone group and/or the salt thereof represented by the general formulae (a) and/or (b) are contained; and an ink composition wherein at least water, the phthalocyanine group cyan dye indicated by the general formula (VIII), and an aromatic compound having a sulfone group and/or the salt thereof represented by the general formulae (a) and/or (b) are contained.
    Type: Grant
    Filed: January 25, 2005
    Date of Patent: October 2, 2007
    Assignee: Seiko Epson Corporation
    Inventors: Yasuhiro Oki, Kazuhiko Kitamura
  • Patent number: 7273519
    Abstract: An ink set where constituent inks all are an ink containing at least one dye having an oxidation potential more positive than 1.0 V (vs SCE), particularly where the ratio k1/k2 of the fading rate constant (k1) of an image drawn by using the ink alone to the fading rate constant (k2) of a mixed color image drawn by using all constituent inks constituting the ink set in equivalent amounts with the same density measurement light as in the measurement of k1 is 0.7 to 1.3 in all inks. According the present invention, an inkjet ink set capable of giving an image having good image quality and excellent image fastness regardless of the color of image, such as aging stability, light fastness and water resistance, and an inkjet image recording method using the ink set are provided.
    Type: Grant
    Filed: March 25, 2004
    Date of Patent: September 25, 2007
    Assignee: Fujifilm Corporation
    Inventors: Toshiki Taguchi, Manabu Ogawa
  • Patent number: 7270699
    Abstract: The invention provides an ink set for ink-jet recording that is able to form an image having a sufficient optical density and causing no feathering and intercolor bleed within a short period of time while being excellent in reliability of the maintenance unit. The ink set comprises at least a liquid (a) containing a colorant, water soluble solvent and water; a liquid (b) containing a pH adjusting agent, water soluble solvent and water; and a liquid (c). The ink set satisfies any one of the conditions in the first embodiment: (i) the colorant is anionic, (ii) the liquid (b) has a pH of not higher than 6.5, (iii) the liquid (c) has a pH of not lower than 8.0, and (iv) the mixed liquid of the liquid (b) and the liquid (c) in a mass ratio of 1:1 has a pH of not lower than 7; or the second embodiment: (i) the colorant is cationic, (ii) the liquid (b) has a pH of not lower than 8.5, (iii) the liquid (c) has a pH of not higher than 6.
    Type: Grant
    Filed: September 1, 2004
    Date of Patent: September 18, 2007
    Assignee: Fuji Xerox Co., Ltd.
    Inventor: Takatsugu Doi
  • Patent number: 7256222
    Abstract: To provide a radiation-curable ink composition that can form a high-quality image on not only liquid absorbing materials to be recorded but also non-liquid absorbing materials to be recorded, is superior in curing properties in air, and is superior in storage stability, color tone, light fastness and water resistance of ink, and also to provide an image recording method. The radiation-curable ink composition comprises a monomer having a polymerizable group selected from the group consisting of an acryloyl group, a methacryloyl group, an allyl group, and a vinyl group, an oil-soluble dye, and from 0.005 to 1% by weight of a storage stabilizer, wherein the oil-soluble dye is dissolved in the ink.
    Type: Grant
    Filed: January 29, 2003
    Date of Patent: August 14, 2007
    Assignee: Fujifilm Corporation
    Inventors: Takahiro Ishizuka, Kazue Sano, Junichi Yamanouchi, Keiichi Tateishi
  • Patent number: 7250079
    Abstract: The invention provides a water-soluble ink capable of forming an image having good color hue and high fastness in various use and environmental conditions, which comprises a coloring composition comprising a disazo dye represented by the following formula 1: A1-N?N-A2-N?N-A3 and at least one other dye having a specific structure; in formula 1, A1, A2 and A3 each independently represents an aromatic group which may be substituted or a heterocyclic group which may be substituted, and A1 and A3 each is a monovalent group and A2 is a divalent group.
    Type: Grant
    Filed: January 7, 2004
    Date of Patent: July 31, 2007
    Assignee: Fujifilm Corporation
    Inventors: Tomohiro Chino, Toshiki Fujiwara, Masaru Takasaki
  • Patent number: 7238228
    Abstract: A metal chelate of Formula (1) or salt thereof. Formula (1) wherein: R1 and R2 are each independently H or an organic group; M is a metal; p is 1 to 4; Y is an optionally substituted heterocyclic ring with a nitrogen ortho to the azo bridge; G is a substituent; and n is 0 to 5.
    Type: Grant
    Filed: March 15, 2004
    Date of Patent: July 3, 2007
    Assignee: Fujifilm Imaging Colorants Limited
    Inventors: Gavin Wright, Peter Gregory
  • Patent number: 7220302
    Abstract: Provided are an inkjet ink prepared by dissolving or dispersing a specific dye in an aqueous medium and containing one of at least one alkylene diol where one alkylene group has at least 3 carbon atoms or homologue thereof and at least one polymer compound; and an ink set containing an ink including a specific dye and an ink including one compound capable of interacting with the dye; thereby being able to provide an ink and the like having a good jet-out stability, and forming images of good quality with neither beading nor bronzing, and the images formed of the inks have good fastness to heat, light and ozone.
    Type: Grant
    Filed: March 29, 2004
    Date of Patent: May 22, 2007
    Assignee: Fujifilm Corporation
    Inventor: Toshiki Taguchi
  • Patent number: 7214260
    Abstract: The present invention provides an ink set for ink jet recording using at least two kinds of liquids. The first liquid contains at least a colorant, a water soluble solvent and water, and the second liquid contains at least a compound represented by the following general formula (1), a water soluble solvent and water.
    Type: Grant
    Filed: June 4, 2004
    Date of Patent: May 8, 2007
    Assignee: Fuji Xerox Co., Ltd.
    Inventors: Takatsugu Doi, Chizuru Koga, Takashi Ogino, Kiyoshi Hosoi, Tsukasa Matsuda
  • Patent number: 7211132
    Abstract: To provide an ink set capable of recording images with good ozone fastness on a recording medium, an ink set of the present invention comprises at least a yellow ink composition, a magenta ink composition, and a cyan ink composition. The cyan ink composition contains at least one of the compounds expressed by formula (1) below as a cyan dye: and the magenta ink composition contains, as a colorant, at least one substance selected from the group consisting of compounds expressed by formula (2) below: and salts thereof (in formula (2), A represents an alkylene group, an alkylene group containing a phenylene group, or a group expressed by formula (3) below: and X represents a group selected from the group consisting of NH2, OH, and Cl).
    Type: Grant
    Filed: September 28, 2004
    Date of Patent: May 1, 2007
    Assignee: Seiko Epson Corporation
    Inventors: Yasuhiro Oki, Kazuhiko Kitamura, Tetsuya Aoyama, Masahiro Hanmura, Hiroshi Fukumoto
  • Patent number: 7150782
    Abstract: A metal chelate compound obtainable from contacting a transition metal salt with a compound of the Formula (1): wherein: x represents plural atoms required to form at least one optionally substituted 5- to 7-membered heterocyclic ring; and Ar is an optionally substituted stilbene, acenaphthylene, phenanthrene or anthracene group carrying a hydroxy, amino or carboxy group adjacent to the —N?N— group shown in Formula (1) or 6-hydroxyquinoline where the hydroxy group is adjacent to the —N?N— group shown in Formula (1); provided that when the compound of Formula (1) is of Formula: that, p, the level of sulfonation, is not in the range 1 to 2. Also compositions, inks, printed substrates and inkjet cartridges.
    Type: Grant
    Filed: May 20, 2004
    Date of Patent: December 19, 2006
    Assignee: Fujifilm Imaging Colorants Limited
    Inventors: Clive Edwin Foster, John Mayall, Mark Kenworthy
  • Patent number: 7135504
    Abstract: An ink composition for ultraviolet curable ink-jet recording including carbon black, a photopolymerizable compound and a photopolymerization initiator, comprising at least one selected from the group consisting of non-metallic phthalocyanine sulfonic acids, metal phthalocyanine sulfonic acids in which the central metal is Cu, Fe, Ni, Co, or Ti, and metal salts thereof, and a polymer dispersant containing a basic functional group. The photopolymerizable compound may dissolve the polymer dispersant.
    Type: Grant
    Filed: April 25, 2003
    Date of Patent: November 14, 2006
    Assignee: Dainippon Ink and Chemicals, Inc.
    Inventors: Yutaka Yamada, Hisao Yamaguchi, Osamu Oshima
  • Patent number: 7132012
    Abstract: An ink comprising a compound represented by formula (I) as defined in the specification
    Type: Grant
    Filed: July 15, 2005
    Date of Patent: November 7, 2006
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Keiichi Tateishi, Yoshiharu Yabuki
  • Patent number: 7125444
    Abstract: An inkjet ink comprising at least one dye having a heterocyclic ring and a metal ion in an aqueous medium, wherein the ink jet ink further comprises a compound capable of accelerating aggregation of the dye in the aqueous medium.
    Type: Grant
    Filed: March 24, 2004
    Date of Patent: October 24, 2006
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Toshiki Taguchi, Naotaka Wachi
  • Patent number: 7097700
    Abstract: A water-soluble complex dye capable of forming an image having light resistance, ozone resistance and high saturation; a water-based recording fluid, particularly an ink jet recording fluid, employing such a dye; and an ink jet recording method, are presented.
    Type: Grant
    Filed: December 29, 2004
    Date of Patent: August 29, 2006
    Assignee: Mitsubishi Chemical Corporation
    Inventor: Wataru Shimizu
  • Patent number: 7097701
    Abstract: An ink containing a phthalocyanine compound represented by the formula (I): wherein X1 to X4, Y1 to Y4, A1 to A4, and M are defined herein.
    Type: Grant
    Filed: December 29, 2003
    Date of Patent: August 29, 2006
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Keiichi Tateishi, Yoshiharu Yabuki, Shigeaki Tanaka
  • Patent number: 7094281
    Abstract: The present invention provides a black ink composition obtained by mixing at least one colorant selected from the group consisting of a compound represented by the following formula (1) and a salt thereof, one or more organic acids and one or more organic bases: wherein R1 represents a phenyl group having a substituent group or a naphthyl group having a substituent group, R2 represent a phenylene group having a substituent group or a naphthylene group having a substituent group, R3 represents a 5- to 7-membered heterocyclic ring having at least one double bond and substituent group, and further, the above-mentioned substituent groups in the above-mentioned R1 to R3 are each independently selected from the group consisting of OH, SO3H, PO3H2, CO2H, NO2, NH2, a C1–4 alkyl group, a C1–4 alkyl group having a substituent group, a C1–4 alkoxyl group, a C1–4 alkoxyl group having a substituent group, an amino group, an amino group having a substituent group and a phenyl group having a substituent group.
    Type: Grant
    Filed: August 6, 2004
    Date of Patent: August 22, 2006
    Assignee: Seiko Epson Corporation
    Inventors: Masahiro Hanmura, Tetsuya Aoyama
  • Patent number: 7094279
    Abstract: The present invention provides a black water-based ink composition that has excellent resistance to light and ozone, has an excellent hue as a black ink, and also has excellent storage stability. A black water-based ink composition is prepared by combining at least one type of black dye selected from the group consisting of compounds expressed by the following formula (1) and salts thereof: and at least one type of dye other than a black dye, and the hue is adjusted by adding the dye other than a black dye. It is preferable if the dye other than the black dye is a compound that has at least one type of group selected from the group consisting of an —SO3H group, —COOH group, —SO3M group, and —COOM group (where M in these groups is an alkali metal atom), and is not an ammonium salt or a salt with an organic cation. It is also preferable for the dye other than the black dye to be a dye selected from the group consisting of yellow dyes and magenta dyes.
    Type: Grant
    Filed: November 22, 2004
    Date of Patent: August 22, 2006
    Assignee: Seiko Epson Corporation
    Inventors: Masahiro Hanmura, Tetsuya Aoyama, Kazuhiko Kitamura
  • Patent number: 7094280
    Abstract: A water-soluble complex dye capable of forming an image having light resistance, ozone resistance and high saturation; a water-based recording fluid, particularly an ink jet recording fluid, employing such a dye; and an ink jet recording method, are presented.
    Type: Grant
    Filed: December 20, 2004
    Date of Patent: August 22, 2006
    Assignee: Mitsubishi Chemical Corporation
    Inventors: Wataru Shimizu, Masahiro Yamada
  • Patent number: 7083668
    Abstract: The ink set of the present invention provides a high ejection stability, gives an image having an excellent hue, light-resistance and waterproofness and improves the image preservability under severe conditions in ink jet recording, in which the ink set comprising a plurality of inks different in hues, wherein the plurality of inks includes a yellow ink containing a coloring agent that is a dye having: a ?max of from 390 nm to 470 nm; an I(?max+70 nm)/I(?max) ratio of not greater than 0.4, in which I(?max) is the absorbance at ?max and I(?max+70 nm) is the absorbance at (?max+70 nm); and a forced fading rate constant of not greater than 5.0×10?2 [hour?1], an ink cartridge having the ink set received therein, an ink jet printer comprising the ink cartridge mounted therein and an image recording method.
    Type: Grant
    Filed: August 22, 2003
    Date of Patent: August 1, 2006
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Toshiki Taguchi, Yoshiharu Yabuki, Toru Harada, Naotaka Wachi
  • Patent number: 7066993
    Abstract: The invention relates to a colorant composition that substantially comprises a colorant of formula (1) and a colorant formula (2) or (3). The magenta colorant mixture is advantageously used in ink-jet printing and yields storage-stable and water-proof ink formulations.
    Type: Grant
    Filed: February 12, 2002
    Date of Patent: June 27, 2006
    Assignee: Clariant GmbH
    Inventors: Andreas Wuzik, Josef Geisenberger, Heidemarie Menzel
  • Patent number: 7066990
    Abstract: The present invention relates to an ink jet ink, an ink jet recording material or an ink jet system comprising at least one compound selected from the group consisting of a) the dialkyl hydroxylamine stabilizers, b) the nitrone stabilizers and c) the amine oxide stabilizers. The present stabilizer compounds provide ink jet prints with outstanding light stability, gas fade stability and dark storage stability. The hydroxylamines are for example N,N-dihydrocarbylhydroxylamines of the formula R1R2N—OH, wherein R1 and R2 are independently benzyl, methyl, ethyl, octyl, lauryl, dodecyl, tetradecyl, hexadecyl, heptadecyl or octadecyl, or wherein R1 and R2 are each the alkyl mixture found in hydrogenated tallow amine. The nitrone and amine oxide stabilizers are for example nitrone and amine oxide analogues of the dialkylhydroxylamine stabilizers.
    Type: Grant
    Filed: January 21, 2004
    Date of Patent: June 27, 2006
    Assignee: Ciba Specialty Chemicals Corporation
    Inventors: Mervin G. Wood, Joseph Suhadolnik, Ramanathan Ravichandran, Sai P. Shum
  • Patent number: 7060124
    Abstract: The invention relates to a dye mixture consisting essentially of one dye of formula (4) and a dye of formula (5).
    Type: Grant
    Filed: July 5, 2002
    Date of Patent: June 13, 2006
    Assignee: Clariant GmbH
    Inventors: Andreas Wuzik, Josef Geisenberger, Heidemarie Menzel
  • Patent number: 7056374
    Abstract: An aqueous ink composition which comprises a compound represented by the formula (1) or the salt thereof: (1) wherein R1 and R2 independently represent a hydrogen atom, an alkyl group, an alkoxy group, an alkanoylamino group, an alkoxyalkoxy group, a sulfonic acid group, a carboxyl group or an ureido group, m and n independently represent 1 or 2, and M1 represents a cation from a hydrogen atom, an alkali metal, an alkaline earth metal or an organic amine, or an ammonium ion. The composition has a hue and clarity suitable for the ink-jet recording, and can provide a recorded matter which is excellent in light resistance, water resistance and moisture resistance and can be controlled with respect to the degree of the discoloration or fading by the action of ozone.
    Type: Grant
    Filed: April 1, 2002
    Date of Patent: June 6, 2006
    Assignee: Nippon Kayaku Kabushiki Kaisha
    Inventors: Hirokazu Kitayama, Yasuo Shirasaki, Toru Tabei
  • Patent number: 7052534
    Abstract: Ink for inkjet recording comprises a dye, water, a water-miscible organic solvent and a precursor of acids, and thereby is rendered resistant to image blur even under a high humidity condition, an ink set including such ink, and an inkjet recording method, in which such ink or such an ink set is used.
    Type: Grant
    Filed: July 14, 2003
    Date of Patent: May 30, 2006
    Assignee: Fuji Photo Film Co., Ltd.
    Inventor: Toshiki Taguchi
  • Patent number: 7048790
    Abstract: Provided is a black ink for inkjet recording obtained by dissolving and/or dispersing, in an aqueous medium, at least one black azo dye having a specific property or structure and further containing at least one metal chelating agent, which is excellent in durability of image including image quality and discharge property even after the ink is filled in an ink cassette and stored for a long period of time while being set in a printer.
    Type: Grant
    Filed: September 29, 2003
    Date of Patent: May 23, 2006
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Toshiki Taguchi, Toshiaki Aono
  • Patent number: 7037365
    Abstract: The present invention provides an ink set, in which in ink jet recording, an ejection stability is enhanced, hues, light resistance and water resistance of an image obtained are made excellent, and image keeping quality under severe conditions is improved, wherein the color ink set comprising a plurality of inks different in hues in order to record on a recording medium, the ink set comprising as a black ink at least a specified coloring agent, which has a ?max of 500 nm to 700 nm and a half value width in an absorption spectrum of a dilute solution normalized to an absorbance of 100 nm or more, an ink cartridge containing the same, an ink jet printer carrying them, and an image recording method.
    Type: Grant
    Filed: August 22, 2003
    Date of Patent: May 2, 2006
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Toshiki Taguchi, Yoshiharu Yabuki, Tomohiro Chino, Naotaka Wachi
  • Patent number: 7029523
    Abstract: A black ink for ink-jet recording, which is excellent in durability of image (including durability of image quality) and discharging property, obtained by dissolving and/or dispersing at least one black azo dye having a particular property or structure in an aqueous medium, wherein a transition metal ion content of the black ink is 0.1 mmol/l or less.
    Type: Grant
    Filed: September 29, 2003
    Date of Patent: April 18, 2006
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Toshiki Taguchi, Naotaka Wachi
  • Patent number: 7025815
    Abstract: A water-soluble complex dye capable of forming an image having light resistance, ozone resistance and high saturation; a water-based recording fluid, particularly an ink jet recording fluid, employing such a dye; an ink set employing such a recording fluid; and an ink jet recording method, are presented.
    Type: Grant
    Filed: December 7, 2004
    Date of Patent: April 11, 2006
    Assignee: Mitsubishi Chemical Corporation
    Inventors: Wataru Shimizu, Mio Ishida, Hideo Sano, Yukichi Murata
  • Patent number: 7025814
    Abstract: The present invention relates to an ink-jet ink, an ink-jet recording material or an ink-jet system containing at least one water-soluble hindered amine compounds of the general formula (I) or (II): wherein G1 and G2 are independently alkyl of (1) to (4) carbon atoms or are together pentamethylene; Z1 and Z2 are each methyl, or Z1 and Z2 ?together form an unsubstituted linking moiety or a linking moiety substituted by one or more groups selected from an ester, ether, hydroxy, oxo, cyanohydrin, amide, amino, carboxy or an urethane group; E is oxyl; X is an inorganic or organic anion; and wherein the local charge of cations h is equal to the total charge of anions j.
    Type: Grant
    Filed: January 8, 2002
    Date of Patent: April 11, 2006
    Assignee: Ciba Specialty Chemicals Corp.
    Inventor: Stéphane Biry
  • Patent number: 7022170
    Abstract: An ink for ink jet recording which provides high-quality images excellent in weather fastnesses is provides, which is an ink for ink jet recording, comprising a yellow dye having a specific characteristic wherein the total amount of a cation other than a monovalent metal ion, a hydrogen ion, an ammonium ion, an organic quaternary nitrogen ion and an ion formed by proton addition to the nitrogen atom in basic organic material is not more than 0.5 wt % based on the amount of the ink.
    Type: Grant
    Filed: September 29, 2003
    Date of Patent: April 4, 2006
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Toshiki Taguchi, Naotaka Wachi
  • Patent number: 7018455
    Abstract: An ink composition, a recording medium or printed matter containing a compound expressed by General Formula 1 The compound has a weight reduction after 1 hour at 60°C. of no more than 1%. This makes it possible to provide the ink composition, a recording medium, printed matter, and an ink jet recording method wherein a light resistance of the printed matter is excellent, there is no ink clogging, and a high-quality image with almost no yellowing of the printed matter can be obtained.
    Type: Grant
    Filed: March 21, 2002
    Date of Patent: March 28, 2006
    Assignee: Seiko Epson Corporation
    Inventors: Kazuhiko Kitamura, Yasuhiro Oki, Tetsuya Aoyama, Kyoichi Oka, Nobuo Uotani, Hiroshi Takahashi, Yuji Ito
  • Patent number: 7011699
    Abstract: The invention provides an inkjet ink which exhibits, at the printing particularly on paper, excellent ink permeability to eliminate the problem of soiling immediately after printing, can be polymerized in higher sensitivity after printing and enables the recording of an image excellent in water resistance and light fastness through polymerization curing, the inkjet ink comprising a coloring fine particle dispersion containing coloring fine particles and at least one oil-soluble dye, a polymerizable hydrophobic ethylenic unsaturated monomer and a polymerization initiator, the at least one oil-soluble dye having an oxidation potential of 1.0 V or more.
    Type: Grant
    Filed: November 26, 2003
    Date of Patent: March 14, 2006
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Junichi Yamanouchi, Takahiro Ishizuka, Yoshiharu Yabuki
  • Patent number: 6923855
    Abstract: An ink, which contains at least one dye of formula (1): A—N?N—BX1n1B?—N?N—A???Formula (1) wherein A and A? each independently represent an aryl group or a monovalent heterocyclic group; B and B? each independently represent an arylene group or a divalent heterocyclic group; X1 represents a divalent linking group; n1 is 0 or 1; and at least one of A, B, A?, and B? is a heterocyclic group.
    Type: Grant
    Filed: August 1, 2003
    Date of Patent: August 2, 2005
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Toru Harada, Naotaka Wachi
  • Patent number: 6872243
    Abstract: Disclosed is a phase change ink composition comprising an ink vehicle, a colorant, and a nonpolymeric organic gelator selected from the group consisting of anthracene-based compounds, steroid compounds, partially fluorinated high molecular weight alkanes, high molecular weight alkanes with exactly one hetero atom, chiral tartrate compounds, chiral butenolide-based compounds, bis-urea compounds, guanines, barbiturates, oxamide compounds, ureidopyrimidone compounds, and mixtures thereof, said organic gelator being present in the ink in an amount of no more than about 20 percent by weight of the ink, said ink having a melting point at or below which the ink is a solid, said ink having a gel point at or above which the ink is a liquid, and said ink exhibiting a gel state between the melting point and the gel point, said ink exhibiting reversible transitions between the solid state and the gel state upon heating and cooling, said ink exhibiting reversible transitions between the gel state and the liquid state upon
    Type: Grant
    Filed: September 4, 2002
    Date of Patent: March 29, 2005
    Assignee: Xerox Corporation
    Inventors: Marcel P. Breton, Danielle C. Boils-Boissier, Donald R. Titterington, Jule W. Thomas, Jr., Jeffrey H. Banning, Christine E. Bedford, James D. Wuest
  • Publication number: 20040244645
    Abstract: The present invention provides an ink set for ink jet recording using at least two kinds of liquids. The first liquid contains at least a colorant, a water soluble solvent and water, and the second liquid contains at least a compound represented by the following general formula (1), a water soluble solvent and water. The present invention also provides an ink jet recording apparatus comprising a recording head from which the ink set for ink jet recording is ejected, and an ink jet recording method by which an image is formed by applying the first and second liquids on a recording medium so as to contact each other.
    Type: Application
    Filed: June 4, 2004
    Publication date: December 9, 2004
    Applicant: FUJI XEROX CO., LTD.
    Inventors: Takatsugu Doi, Chizuru Koga, Takashi Ogino, Kiyoshi Hosoi, Tsukasa Matsuda
  • Patent number: 6827770
    Abstract: A metal chelated dyestuff for inkjet recording comprising a water soluble azo metal chelated compound formed by an azo-based compound represented by the following general formula (1) having one or more hydrophilic group per molecule and a metal element; an aqueous inkjet recording liquid comprising an aqueous medium and the aforementioned metal chelated dyestuff; and an inkjet recording method using the aforementioned recording liquid are described, wherein the heterocyclic ring containing X1 is a triazole ring or the like; and Ar1 represents naphthyl group having a chelated group.
    Type: Grant
    Filed: June 18, 2002
    Date of Patent: December 7, 2004
    Assignee: Mitsubishi Chemical Corporation
    Inventors: Tomohiro Chino, Masahiro Yamada, Hideo Sano, Wataru Shimizu, Yuukichi Murata