The Nitrogen Is A Ring Member Of A Heterocyclic Ring Patents (Class 106/31.46)
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Patent number: 6827771Abstract: An ink composition for inkjet recording comprising: an azo dye having an aromatic nitrogen-containing 6-membered heterocycle as a coupling component; a compound represented by the following formula (I); and an aqueous medium wherein the azo dye is dissolved or dispersed in the aqueous medium:Type: GrantFiled: April 11, 2002Date of Patent: December 7, 2004Assignee: Fuji Photo Film Co., Ltd.Inventors: Tadashi Omatsu, Masaki Noro, Toshiki Fujiwara
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Publication number: 20040237837Abstract: A lightfast additive and an ink composition including the same include a benzophenone moiety for lightfastness and a moiety for wettability and the ability to stabilize a colorant, wherein the two moieties are covalently bonded. The lightfast additive may exhibit effective ultraviolet (UV) light absorption capacity, effective wettability, and an ability to stabilize a colorant. The ink composition utilizing the light fast additive thus has an improved lightfastness and long-term storage stability.Type: ApplicationFiled: May 24, 2004Publication date: December 2, 2004Applicant: Samsung Electronics Co., Ltd.Inventors: Kyung-hoon Lee, Seung-min Ryu, Yeon-kyoung Jung
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Patent number: 6821585Abstract: There are disclosed an ink-jet recording material comprising a support, and an ink-receptive layer provided on the support, wherein the ink-jet recording material contains at least one compound selected from a carbohydrazide compound in which at least one nitrogen atom at 1-position and 5-position is substituted by two substituents other than a hydrogen atom and a compound having a 4-oxysemicarbazide structure, and ink for ink-jet recording comprising at least one of the above-mentioned compound.Type: GrantFiled: April 23, 2002Date of Patent: November 23, 2004Assignee: Mitsubishi Paper Mills LimitedInventors: Koichi Sumioka, Kozo Haino
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Patent number: 6811597Abstract: An ink composition and/or a recording medium are made to contain a compound expressed by general formula (1) and a hydrazide compound. An ink composition thereby obtained does not clog and the ink composition and recording medium thus obtained can offer high quality images that hardly cause yellowing of the resulting recording with superior light resistance. Recording and an inkjet recording method pertaining thereto are also provided.Type: GrantFiled: March 21, 2002Date of Patent: November 2, 2004Assignee: Seiko Epson CorporationInventors: Yasuhiro Oki, Kazuhiko Kitamura, Tetsuya Aoyama, Kyoichi Oka, Nobuo Uotani, Hiroshi Takahashi, Yuji Ito
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Publication number: 20040187736Abstract: An ink set where constituent inks all are an ink containing at least one dye having an oxidation potential more positive than 1.0 V (vs SCE), particularly where the ratio k1/k2 of the fading rate constant (k1) of an image drawn by using the ink alone to the fading rate constant (k2) of a mixed color image drawn by using all constituent inks constituting the ink set in equivalent amounts with the same density measurement light as in the measurement of k1 is 0.7 to 1.3 in all inks. According the present invention, an inkjet ink set capable of giving an image having good image quality and excellent image fastness regardless of the color of image, such as aging stability, light fastness and water resistance, and an inkjet image recording method using the ink set are provided.Type: ApplicationFiled: March 25, 2004Publication date: September 30, 2004Applicant: FUJI PHOTO FILM CO., LTD.Inventors: Toshiki Taguchi, Manabu Ogawa
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Publication number: 20040170779Abstract: The present invention relates to an ink jet ink, an ink jet recording material or an ink jet system comprising at least one compound selected from the group consisting of a) the dialkyl hydroxylamine stabilizers, b) the nitrone stabilizers and c) the amine oxide stabilizers. The present stabilizer compounds provide ink jet prints with outstanding light stability, gas fade stability and dark storage stability. The hydroxylamines are for example N,N-dihydrocarbylhydroxylamines of the formula R1R2N—OH, wherein R1 and R2 are independently benzyl, methyl, ethyl, octyl, lauryl, dodecyl, tetradecyl, hexadecyl, heptadecyl or octadecyl, or wherein R1 and R2 are each the alkyl mixture found in hydrogenated tallow amine. The nitrone and amine oxide stabilizers are for example nitrone and amine oxide analogues of the dialkylhydroxylamine stabilizers.Type: ApplicationFiled: January 21, 2004Publication date: September 2, 2004Inventors: Mervin G. Wood, Joseph Suhadolnik, Ramanathan Ravichandran, Sai P. Shum
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Publication number: 20040128775Abstract: The invention relates to a dye mixture essentially consisting of one dye of formula (4) and a dye of formula (5). The black dye mixture is advantageously used for ink jet printing and provides high light-resisting and neutral black ink formulations.Type: ApplicationFiled: November 21, 2003Publication date: July 8, 2004Inventors: Andreas Wuzik, Josef Geisenberger, Heidemarie Menzel
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Publication number: 20040129172Abstract: An ink, which contains at least one dye of formula (1):Type: ApplicationFiled: August 1, 2003Publication date: July 8, 2004Applicant: FUJI PHOTO FILM CO., LTD.Inventors: Toru Harada, Naotaka Wachi
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Publication number: 20040099180Abstract: An aqueous ink composition which comprises a compound represented by the formula (1) or the salt thereof: (1) wherein R1 and R2 independently represent a hydrogen atom, an alkyl group, an alkoxy group, an alkanoylamino group, an alkoxyalkoxy group, a sulfonic acid group, a carboxyl group or an ureido group, m and n independently represent 1 or 2, and M1 represents a cation from a hydrogen atom, an alkali metal, an alkaline earth metal or an organic amine, or an ammonium ion. The composition has a hue and clarity suitable for the ink-jet recording, and can provide a recorded matter which is excellent in light resistance, water resistance and moisture resistance and can be controlled with respect to the degree of the discoloration or fading by the action of ozone.Type: ApplicationFiled: December 17, 2003Publication date: May 27, 2004Inventors: Hirokazu Kitayama, Yasuo Shirasaki, Toru Tabei
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Patent number: 6736888Abstract: A compound comprising a disazo chromophore and an optionally substituted heterocyclic group linked together through a —SO2—NH— group, inks comprising these compounds, ink jet printer cartridges containing these inks and their use in ink jet printing.Type: GrantFiled: March 18, 2002Date of Patent: May 18, 2004Assignee: Avecia LimitedInventor: Mark Robert James
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Publication number: 20040089198Abstract: A process for coloration of a substrate comprising applying thereto by means of an ink jet printer a composition comprising a medium and a compound of Formula (1): 1Type: ApplicationFiled: September 11, 2003Publication date: May 13, 2004Inventors: Christine Millard, Clive Edwin Foster, Peter Gregory
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Publication number: 20040074018Abstract: The invention relates to a colorant composition that substantially comprises a colorant of formula (1) and a colorant formula (2) or (3). The magenta colorant mixture is advantageously used in ink-jet printing and yields storage-stable and water-proof ink formulations.Type: ApplicationFiled: August 11, 2003Publication date: April 22, 2004Inventors: Andreas Wuzik, Josef Geisenberger, Heidemarie Menzel
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Publication number: 20040065227Abstract: Disclosed is a phase change ink composition comprising an ink vehicle, a colorant, and a nonpolymeric organic gelator selected from the group consisting of anthracene-based compounds, steroid compounds, partially fluorinated high molecular weight alkanes, high molecular weight alkanes with exactly one hetero atom, chiral tartrate compounds, chiral butenolide-based compounds, bis-urea compounds, guanines, barbiturates, oxamide compounds, ureidopyrimidone compounds, and mixtures thereof, said organic gelator being present in the ink in an amount of no more than about 20 percent by weight of the ink, said ink having a melting point at or below which the ink is a solid, said ink having a gel point at or above which the ink is a liquid, and said ink exhibiting a gel state between the melting point and the gel point, said ink exhibiting reversible transitions between the solid state and the gel state upon heating and cooling, said ink exhibiting reversible transitions between the gel state and the liquid state uponType: ApplicationFiled: September 4, 2002Publication date: April 8, 2004Applicant: Xerox CorporationInventors: Marcel P. Breton, Danielle C. Boils-Boissier, Donald R. Titterington, Jule W. Thomas, Jeffrey H. Banning, Christine E. Bedford, James D. Wuest
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Patent number: 6685767Abstract: A recording liquid for ink jet containing a solid fine particle dispersion obtained by dispersing in a medium a compound represented by the following general formula (I) or (II), and an ink jet recording method of recording using the recording liquid for ink jet containing the solid fine particle dispersion obtained by dispersing in a medium a compound represented by the following general formula (I) or (II):Type: GrantFiled: April 3, 2001Date of Patent: February 3, 2004Assignee: Fuji Photo Film Co., Ltd.Inventors: Masaki Noro, Yoshiharu Yabuki, Makoto Yamada
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Patent number: 6683151Abstract: The invention relates to a compound comprising a reaction product of (A) an isocyanate functional compound of which at least 40 wt. %, relative to the total amount of (A), has a molecular weight of at least about 500, and (B) a nitrogen-containing compound capable of reacting with said isocyanate functional compound (A). The reaction product has a molecular weight of less then about 20,000 and comprises an effective amount of groups that are able to form reversible intermolecular physical interactions such that a resulting compound shows polymeric mechanical properties at a temperature below a transition temperature. The nitrogen-containing compound is, for instance, melamine, urea, acetoguanamine, benzoguanamine, cyanamide, dicyanamide, thiourea, isocytosine, pyrimidone or aminopyridine. The supramolecular compound comprising a suitable amount of the reaction products exhibits a relatively high elongation at break.Type: GrantFiled: February 24, 2000Date of Patent: January 27, 2004Assignee: DSM N.V.Inventors: Jacobus A. Loontjens, Johan E. G. A. Jansen, Bartholomeus J. M. Plum
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Publication number: 20040011249Abstract: An ink composition and/or a recording medium are made to contain a compound expressed by general formula (1) and a hydrazide compound. An ink composition thereby obtained does not clog and the ink composition and recording medium thus obtained can offer high quality images that hardly cause yellowing of the resulting recording with superior light resistance. Recording and an inkjet recording method pertaining thereto are also provided.Type: ApplicationFiled: June 24, 2003Publication date: January 22, 2004Applicant: SEIKO EPSON CORPORATIONInventors: Yasuhiro Oki, Kazuhiko Kitamura, Tetsuya Aoyama, Kyoichi Oka, Nobuo Uotani, Hiroshi Takahashi, Yuji Ito
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Publication number: 20040011247Abstract: Ink for inkjet recording comprises a dye, water, a water-miscible organic solvent and a precursor of acids, and thereby is rendered resistant to image blur even under a high humidity condition, an ink set including such ink, and an inkjet recording method, in which such ink or such an ink set is used.Type: ApplicationFiled: July 14, 2003Publication date: January 22, 2004Applicant: FUJI PHOTO FILM CO., LTD.Inventor: Toshiki Taguchi
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Patent number: 6676735Abstract: An aqueous ink comprising at least a colorant, a water-soluble organic solvent and a compound represented by general formula (I) shown below, wherein said water-soluble organic solvent stays liquid at a temperature of not higher than 40° C., exhibits a water solubility of not lower than 1% by weight at a temperature of 20° C. and a saturated vapor pressure of not higher than 1.7 Pa at a temperature of 20° C. and is contained in an amount of from 5 to 35% by weight: wherein Y represents a nonmetallic atom group required to form a 5- to 7-membered ring with C and N; X represents a hydrogen atom, oxyradical group, hydroxyl group, alkyl group, alkenyl group, alkinyl group, aryl group, acyl group, sulfonyl group, sulfinyl group, alkoxy group, aryloxy group or acyloxy group; and R1 to R4 may be the same or different and each represent a hydrogen atom or alkyl group, with the proviso that any two of R1 to R4 and Y may be connected to each other to form a 5- to 7-membered ring.Type: GrantFiled: June 21, 2001Date of Patent: January 13, 2004Assignee: Seiko Epson CorporationInventors: Yasuhiro Oki, Kazuhiko Kitamura, Tetsuya Aoyama, Nobuo Uotani, Hiroshi Takahashi, Yuji Ito
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Publication number: 20030164114Abstract: The present invention relates to a cyan dye mixture, an ink composition containing the mixture and a method of ink-jet recording with the ink composition. The print obtained by the method is characterized by discoloring or fading little even when allowed to stand in a well ventilated shade or in an ozone gas. The cyan dye mixture comprises compounds which are obtained by chlorosulfonating, as a starting material, copper phthalocyanine or a sulfonated copper phthalocyanine and then aminating the chlorosulfonation product with an aminating agent used in an amount of at least 2.Type: ApplicationFiled: January 17, 2003Publication date: September 4, 2003Inventors: Hirokazu Kitayama, Shinichi Namba, Takafumi Fujii, Junji Otani, Junko Yoshioka, Yasuo Shirasaki
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Patent number: 6582501Abstract: An ink composition for ink-jet printers is provided which includes a chromophore, a solvent, a co-solvent, a humectant, a surfactant, a viscosity adjuster and an additive. The additive is a nitrogen-containing heterocyclic compound. This nitrogen-containing heterocyclic compound has the hydroxy groups which improve miscibility with water, thereby preventing clogging of nozzles during use. The present invention increases the affinity for dye used as a chromophore and for the hydroxy groups of paper after discharging of ink, which allows the chromophore to easily fix on the paper, thus enhancing smearfastness of the ink composition after printing.Type: GrantFiled: February 26, 2001Date of Patent: June 24, 2003Assignee: Samsung Electronics Co., Ltd.Inventors: Seung-min Ryu, Seung-soon Jang, Jun-hoe Cha
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Publication number: 20030097959Abstract: An ink composition for inkjet recording comprising: an azo dye having an aromatic nitrogen-containing 6-membered heterocycle as a coupling component; a compound represented by the following formula (I); and an aqueous medium wherein the azo dye is dissolved or dispersed in the aqueous medium: 1Type: ApplicationFiled: April 11, 2002Publication date: May 29, 2003Inventors: Tadashi Omatsu, Masaki Noro, Toshiki Fujiwara
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Publication number: 20030070582Abstract: A compound expressed by General Formula 1, whose weight reduction after 1 hour at 60° C. is no more than 1%, is contained in an ink composition and/or a recording medium. This makes it possible to provide an ink composition, a recording medium, printed matter, and an ink jet recording method with which the light resistance of the printed matter is excellent, there is no ink clogging, and a high-quality image with almost no yellowing of the printed matter can be obtained.Type: ApplicationFiled: March 21, 2002Publication date: April 17, 2003Applicant: SEIKO EPSON CORPORATIONInventors: Kazuhiko Kitamura, Yasuhiro Oki, Tetsuya Aoyama, Kyoichi Oka, Nobuo Uotani, Hiroshi Takahashi, Yuji Ito
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Patent number: 6521031Abstract: An ink-jet ink which includes a coloring composition which contains an oil-soluble dye represented in the following formula (I). In the formula (I), R1 and R2 represent respectively independently a hydrogen atom, a halogen atom, an aliphatic group, an aromatic group, or the like. A represents —NR5R6 or a hydroxyl group. R5 and R6 represent respectively independently a hydrogen atom, an aliphatic group, or the like. B1 represents ═C(R7)— or ═N—, and B2represents —C (R8)═ or —N═. R3, R4, R7, and R8 represent respectively independently a hydrogen atom, a halogen atom, an aliphatic group, an aromatic group, or the like. Q includes at least one nitrogen atom and, together with a carbon atom to be combined, represents an atom group which is required to form a nitrogen-containing heterocyclic ring having a five-membered ring or more.Type: GrantFiled: March 8, 2001Date of Patent: February 18, 2003Assignee: Fuji Photo Film Co., Ltd.Inventors: Keizo Kimura, Takayuki Ito
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Publication number: 20020185036Abstract: An ink composition and/or a recording medium are made to contain a compound expressed by general formula (1) and a hydrazide compound. An ink composition thereby obtained does not clog and the ink composition and recording medium thus obtained can offer high quality images that hardly cause yellowing of the resulting recording with superior light resistance. Recording and an inkjet recording method pertaining thereto are also provided.Type: ApplicationFiled: March 21, 2002Publication date: December 12, 2002Applicant: SEIKO EPSON CORPORATIONInventors: Yasuhiro Oki, Kazuhiko Kitamura, Tetsuya Aoyama, Kyoichi Oka, Nobuo Uotani, Hiroshi Takahashi, Yuji Ito
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Patent number: 6444020Abstract: Disclosed are an azo dye having the following formula (1), an ink-jet ink comprising the aforesaid azo dye, an ink-jet recording method using the aforesaid ink-jet ink, and a thermal transfer recording material comprising the aforesaid azo dye: wherein Z represents an atomic group which forms, together with a nitrogen atom, a five-, six- or seven-membered ring, R1 represents a hydrogen atom, an oxy radical, an aliphatic group, an aliphatic oxy group, an acyl group, an aliphatic oxycarbonyl group, an aryloxycarbonyl group or an acyloxy group, R2, R3, R4 and R5, which may be the same or different, each represents an alkyl group, or R2 and R3 and/or R4 and R5 may be combined with each other to form a ring, and Dye represents a dye moiety group necessary for forming an azo dye.Type: GrantFiled: April 17, 2000Date of Patent: September 3, 2002Assignee: Fuji Photo Film Co., Ltd.Inventors: Nobuo Seto, Takayoshi Kamio
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Patent number: 6436178Abstract: An ink, such as an inkjet ink composition is described which contains at least one colorant, at least one liquid vehicle, at least one humectant, and at least one cyclic amide. Methods to improve the resistance to highlighter smear, minimize banding of a printed image, improve the dry or wet rub resistance of a printed image, and/or improve the waterfastness of a printed image using the ink compositions of the present invention are further described.Type: GrantFiled: December 20, 2000Date of Patent: August 20, 2002Assignee: Cabot CorporationInventor: Jason D. Hosmer
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Publication number: 20020059884Abstract: An ink composition for ink-jet printers is provided which includes a chromophore, a solvent, a co-solvent, a humectant, a surfactant, a viscosity adjuster and an additive, wherein the additive is a nitrogen-containing heterocyclic compound having formula: 1Type: ApplicationFiled: February 26, 2001Publication date: May 23, 2002Inventors: Seung-min Ryu, Seung-soon Jang
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Publication number: 20020050226Abstract: An aqueous ink comprising at least a colorant, a water-soluble organic solvent and a compound represented by general formula (I) shown below, wherein said water-soluble organic solvent stays liquid at a temperature of not higher than 40° C., exhibits a water solubility of not lower than 1% by weight at a temperature of 20° C. and a saturated vapor pressure of not higher than 1.7 Pa at a temperature of 20° C.Type: ApplicationFiled: June 21, 2001Publication date: May 2, 2002Applicant: SEIKO EPSON CORPORATIONInventors: Yasuhiro Oki, Kazuhiko Kitamura, Tetsuya Aoyama, Nobuo Uotani, Hiroshi Takahashi, Yuji Ito
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Publication number: 20020046680Abstract: A recording liquid for ink jet containing a solid fine particle dispersion obtained by dispersing in a medium a compound represented by the following general formula (I) or (II), and an ink jet recording method of recording using the recording liquid for ink jet containing the solid fine particle dispersion obtained by dispersing in a medium a compound represented by the following general formula (I) or (II): 1Type: ApplicationFiled: April 3, 2001Publication date: April 25, 2002Inventors: Masaki Noro, Yoshiharu Yabuki, Makoto Yamada
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Patent number: 6281270Abstract: Color images with high fixation comparable to that of silver salt photographic images are formed on printing papers, using aqueous ink compositions by ink jet recording. Color images thus formed have high saturation and high resolution. An intercalated compound capable of fixing water-soluble dyes to a printing paper due to the intercalation based on ion-exchanging between them is incorporated into the dye-receiving layer 2 of the paper, on which color images are formed by ink jet recording using an aqueous ink composition containing a water-soluble dye. The content of the intercalated compound in the layer 2 is from 10 to 90% by weight. As the intercalated compound, montmorillonoids are preferred when water-soluble cationic dyes are used while hydrotalcite-group minerals are preferred when water-soluble anionic dyes are used. FIG. 1 is selected.Type: GrantFiled: November 12, 1997Date of Patent: August 28, 2001Assignee: Sony CorporationInventors: Kengo Ito, Yoshio Fujiwara
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Patent number: 6251177Abstract: Solid preparations of metal-containing or metal-free phthalocyanine dyes, a) which have an average particle size of greater than 100 &mgr;m, and b) which have a pH of greater than or equal to 10 when dissolved in 10 times the amount of water, are particularly suitable for the dyeing and printing of paper, after dissolution in water.Type: GrantFiled: December 8, 1999Date of Patent: June 26, 2001Assignee: Bayer AktiengesellschaftInventor: Josef-Walter Stawitz
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Patent number: 6235096Abstract: 1. An ink comprising water, a water-dissipatable polymer and a dye, wherein the dye carries a group of the Formula (1): wherein: R1 is optionally substituted branched chain alkyl; and R2 is H, optionally substituted alkyl or optionally substituted aryl. The inks are useful in ink jet printers.Type: GrantFiled: March 30, 1999Date of Patent: May 22, 2001Assignee: Zeneca LimitedInventors: Barry Huston Meyrick, Mark Holbrook, Roy Bradbury