Abstract: A manufactured item for the building industry is disclosed, made mainly of bottom ash and/or debris coming from incineration processes of municipal solid waste or of waste which may be assimilated thereto and/or of RDF and of one or more binders. Such manufactured item may have the shape of small bricks, bricks, blocks, small blocks, kerbs, interlocking paving blocks, panels, tiles, prefabricated slabs, beams, elements for walls, modular building elements, indoor and outdoor cladding elements, blocks, rocks, supports. Moreover, a process for the manufacture of an item for the building industry is disclosed, from bottom ash and/or debris coming from incineration processes of municipal solid waste or of waste which may be assimilated thereto and/or of FDR wherein the ash and/or debris undergo an oxidation process of the amphoteric metals and mixed with a binder.

Abstract: Partial oxidation of crumb rubber derived from environmental hazardous waste tires yields surface treated crumb rubber and a gas condensate which are used as blending stocks for making rubberized concrete with substantially improved mechanical strength as compared to the conventional rubberized concrete. The chemically more active rubber surface becomes hydrophilic, so it interacts with the hydrophilic surface of surrounding cement matrix much stronger. The gas condensate co-produced in the partial oxidation reactor consists of mainly active sulfur oxides (R—SOx—R) and serves as an excellent bonding agent to further enhance the bonding strength between the partially oxidized rubber particles and the cement mixes. The mechanically improved rubberized concrete is more versatile than conventional rubberized concrete.

Abstract: Systems, methods and processes teach by specific examples how the cost of sequestering carbon dioxide (CO2) can be totally offset and turned into profits during coal powered electricity generation from revenue and co-benefits. The process is provided whereby fly ash-carbon mixtures, or de-volatilized coal char, or anthracite coal culm is co-fired in an air-cooled, slagging combustor with limestone or similar slag fluxing materials converts the ash into cementitious slag with properties similar to ground granulated blast furnace slag.

Abstract: The present invention provides a composition and a process for the preparation of chemical activated cold setting fly ash building construction materials. The chemical activator is an alkaline aqueous solution of 11.2 to 13.6 in pH and 1.25 to 1.40 gm/cc in density which contains admixtures of different concentrations of hydroxyl, sulfate, acetate and chloride bearing chemical salts of calcium, magnesium, sodium, potassium and aluminum in water medium. The reaction of chemical activator solution and the mineral constituents of fly ash mix develop binding property. The binding matrix of chemical activated fly ash mix is mostly hydrous silica and silicate group of phases which on setting under atmospheric condition attains strength suitable for building construction application. Utilization of fly ash of any source by weight ranges from 80 to 99% in manufacture of building materials including heat and acid resistance and toxic waste disposal products.

Abstract: It is the object of the invention to provide a cement admixture, and a cement composition that can impart good enough rustproofness to reinforcing bars in hardened cement concrete, and can have resistance to penetration of chloride ions entering from the outside, prevent the hardened cement concrete from getting porous due to reduced leaching of Ca ions and have a self-recovery capability. The invention provides a cement admixture characterized by containing a calcium ferroaluminate compound comprising a CaO—Al2O3—Fe2O3 system, and having a Fe2O3 content of 0.5 to 15% by mass and a CaO.2Al2O3 structure with a CaO/Al2O3 molar ratio ranging from 0.15 to 0.7.

Abstract: A method for producing a reaction product including at least one synthetic formulation that carbonates sufficiently, said method comprising: providing a first raw material, having a first concentration of M; providing a second raw material, having a second concentration of Me; and mixing the first raw material and the second raw material to produce a reaction product that includes at least one synthetic formulation having the general formula MaMebOc, MaMeb(OH)d, MaMebOc(OH)d or MaMebO(OH)d.(H2O)e, wherein M comprises at least one metal that can react to form a carbonate and Me is at least one element that can form an oxide during the carbonation reaction, wherein the at least one synthetic formulation is capable of undergoing a carbonation reaction, and wherein the at least one synthetic formulation is capable of undergoing volume change during the carbonation reaction.

Abstract: A high early strength blended cement composition includes larger sized fly ash and/or natural pozzolan particles blended with smaller sized hydraulic cement particles containing tricalcium silicate and/or dicalcium silicate (e.g., Portland cement and/or ground granulated blast furnace slag). Excess calcium released from the hydraulic cement particles when mixed with water forms calcium hydroxide available for reaction with the fly ash and/or natural pozzolan. The fineness of the hydraulic cement particles is substantially greater than the fineness of the fly ash and/or natural pozzolan particles (e.g., about 1.25 to about 50 times greater). Reducing or eliminating coarse hydraulic cement particles that cannot fully hydrate but include unreacted cores reduces or eliminates wasted cement normally found in concrete.

Abstract: The disclosure concerns cost effective concrete formulations based on an alkali activated binder. The construction material of the concrete type, contains sand, fine aggregates, coarse aggregates, water and a binder comprising: from 55 to 80 wt. % of fly ash containing less than wt. 8% of CaO; from 15 to 40 wt. % of blast furnace slag; a chemical activator containing: from 0.8 to 4 wt. % of alkaline silicates; and from 1.5 to 9 wt. % of alkaline carbonates; wherein the chemical activator has an silica to alkali molar ratio from 0.1 to 0.55; and a booster comprising at least one strong base. The disclosure also concerns a method to produce such a concrete construction material.

Abstract: A zinc-oxide based set retardant additive and admixture for use in Portland cement or other hydraulic cement mixtures. The admixture may comprise silica fume, vitreous calcium aluminosilicate, magnesium aluminum silicate hydrate, a cellulose ether derivative, or their equivalents. The zinc-oxide based set retardant may be interground or pre-blended, pre-packaged, or added on the jobsite, as an admixture, additive, or addition. The zinc-based set retardant may be subsequently added or mixed into a ready mix or wet mixture of portland cement or other hydraulic cement, sand and/or aggregate, with or without fillers, and water, with or without other pozzolans or polymers.

Abstract: A process for reducing the concentration of carbon dioxide in a gas including carbon dioxide and water vapour (for example a flue gas or a cement plant flue gas) which process includes contacting the gas with a particulate solid, which solid includes an alkaline earth metal oxide or hydroxide and a promoter selected from an alkanolamine; an unsubstituted or substituted piperazine; an unsubstituted or substituted morpholine; and a polyethyleneamine oligomer.

Abstract: A method for making a low embodied energy cementitious mixture by blending a variety of post-consumer wastes, post-industrial wastes, as well as renewable, organic and recyclable materials with Portland cement or a material having similar cementitious properties. The primary materials are recycled concrete, coal-fired fly ash waste, silica fume, post-industrial waste, organic or inorganic waste fibers. Glass, brick, ceramics, ground tires and other waste products, as well as virgin aggregate can also be included in the low embodied energy cementitious mixture.

Abstract: A ductile ultra-high performance concrete which includes in relative parts by weight: 100 of Portland cement; 50 to 200 of a sand having a single grading with a D1O to D90 between 0.063 and 5 mm, or a mixture of sands, the finest sand having a D1O to D90 between 0.063 and 1 mm and the coarsest sand having a D1O to D90 between 1 and 5 mm; 0 to 70 of a particulate pozzolanic or non-pozzolanic material or a mixture thereof having a mean particle size less than 15 ?m; 0.1 to 10 of a water-reducing superplasticizer; 10 to 30 of water; and 0.5 to 5% by volume relative to the volume of the hardened composition of glass fibers having an aspect ratio of 6 to 120.

Abstract: The present invention relates to the field of settable compositions for general purpose concrete mixes, and more particularly to settable compositions containing pulverized fly ash and/or bottom ash for improved final and early strength. The fly ash and/or bottom ash is pulverized to a Blaine fineness of 4000 cm2/g or more.

Abstract: A cement product incorporating nanocrystalline cellulose and cellulose fiber throughout the product and a method of making the product.

Abstract: A manufactured item for the building industry is disclosed, made mainly of bottom ash and/or debris coming from incineration processes of municipal solid waste or of waste which may be assimilated thereto and/or of RDF and of one or more binders. Such manufactured item may have the shape of small bricks, bricks, blocks, small blocks, kerbs, interlocking paving blocks, panels, tiles, prefabricated slabs, beams, elements for walls, modular building elements, indoor and outdoor cladding elements, blocks, rocks, supports. Moreover, a process for the manufacture of an item for the building industry is disclosed, from bottom ash and/or debris coming from incineration processes of municipal solid waste or of waste which may be assimilated thereto and/or of FDR wherein the ash and/or debris undergo an oxidation process of the amphoteric metals and mixed with a binder.

Abstract: A low-pressure method for producing construction materials, such as blocks, bricks or slabs, utilizing high percentages of waste cement dust in admixture with additive material capable of effectively neutralizing the high lime content and agglomerating the extremely fine particles of the cement dust upon blending of the admixture with water. The resulting blend may simply be cast in molds of various shapes and sizes and cured under normal atmospheric pressure conditions into a hardened construction material exhibiting high strength, light weight and high thermal insulation.

Abstract: The present disclosure relates to geothermal grout, methods of making geothermal grout, and methods of using geothermal grout. The present disclosure is further directed to an geothermal grout with relative ease of preparation and desirable thermal conductivity while maintaining good sealant properties.

Abstract: A cement product incorporating nanocrystalline cellulose and cellulose fiber throughout the product and a method of making the product.

Abstract: A cementitious compostion for high density, low porosity sheet-form building materials having solid surfaces is comprised of cement, pozzolans, and a high percentage of fine and/or coarse glass aggregate.

Abstract: A cement composition for cementing an oil or gas well includes Portland cement, water and a sulfur component. The cement composition may be used to cement a well bore by creating a cement slurry including the sulfur component, pumping the slurry into the well bore to a selected location and allowing it to solidify.

Abstract: The present invention provides a composition and a process for the preparation of chemical activated cold setting fly ash building construction materials. The chemical activator is an alkaline aqueous solution of 11.2 to 13.6 in pH and 1.25 to 1.40 gm/cc in density which contains admixtures of different concentrations of hydroxyl, sulfate, acetate and chloride bearing chemical salts of calcium, magnesium, sodium, potassium and aluminum in water medium. The reaction of chemical activator solution and the mineral constituents of fly ash mix develop binding property. The binding matrix of chemical activated fly ash mix is mostly hydrous silica and silicate group of phases which on setting under atmospheric condition attains strength suitable for building construction application. Utilization of fly ash of any source by weight ranges from 80 to 99% in manufacture of building materials including heat and acid resistance and toxic waste disposal products.

Abstract: An application for a pre-mixed mortar, stucco or masonry composition includes a approximately 75% sand and 25% of a light-weight cement mix comprising a cement (either Portland cement or hydraulic cement), fly ash, sodium tall oil, sodium stearate, sodium C14-16 Alpha Olefin, linear alkyl benzene; and silicon dioxide.

Abstract: A system and method for treating tailings from a bitumen froth treatment process such as TSRU tailings. The tailings are dewatered and then combusted to convert kaolin in the tailings into metakaolin. Calcined fines and heavy minerals may be recovered from the combustion products, namely from the flue gas and bottom ash.

Abstract: A process for the preparation of a wet concrete composition, including mixing Portland clinker in the form of grains having a Dv97 from 10 to 30 ?m or having a Blaine specific surface greater than or equal to 5300 cm2/g; slag; calcium sulphate; complementary materials, having a Dv90 less than or equal to 200 ?m; from 1500 to 2200 kg/m3 of aggregates; a plasticizer; optionally an accelerator and/or an air-entraining agent and/or a thickening agent and/or a retarder and/or a clay-inerting agent; with 140 to 220 l/m3 of effective water, the total quantity of clinker in the wet concrete being less than or equal to 200 kg/m3.

Abstract: A wellbore servicing method comprises converting a water into an electrochemically activated water, preparing a wellbore servicing composition comprising the electrochemically activated water, and placing the wellbore servicing composition in a wellbore. Also, cement composition comprises a cement and an electrochemically activated water.

Abstract: A composition capable of setting to produce a building material is disclosed. The composition can include from 1% to 30% by weight of an activator, from 1% to 55% by weight of a pozzolan, such as fly ash; from 40% to 90% by weight of an aggregate; and liquid landfill leachate in a sufficient amount such that the composition sets to a building material having a compressive strength of at least 2 MPa, wherein all weight percentages are percent by weight of the total composition. The liquid landfill leachate replaces all or part of the tap water in a conventional composition for forming a building material. The liquid landfill leachate can be recovered after a liquid (typically water) percolates through a landfill and contacts at least one landfilled coal combustion product selected from fly ash, bottom ash, boiler slag, and flue gas desulfurization material. The building material can be a concrete, or a masonry unit.

Abstract: Process for the preparation of a sprayable hydraulic binder composition containing as main components water, aggregates, hydraulic binder, set accelerator, characterized in, that a calcium silicate hydrate (C—S—H) containing component is added before and/or at the spray nozzle.

Abstract: A ready-mix concrete and method for making the ready-mix concrete having mix proportions that include at least 70% coarse recycled aggregate and fly ash is provided. The ready-mix concrete including cement, air, water, sand and a remaining percent of virgin coarse recycled aggregate such that the coarse recycled aggregate combines to 100% of the required coarse aggregate.

Abstract: Sorbent components containing halogen, calcium, alumina, and silica are used in combination during coal combustion to produce environmental benefits. Sorbents such as calcium bromide are added to the coal ahead of combustion and other components are added into the flame or downstream of the flame, preferably at minimum temperatures to assure complete formation of the refractory structures that result in various advantages of the methods. When used together, the components reduce emissions of elemental and oxidized mercury; increase the level of Hg, As, Pb, and/or Cl in the coal ash; decrease the levels of leachable heavy metals (such as Hg) in the ash, preferably to levels below the detectable limits; and make a highly cementitious ash product.

Abstract: Methods of making particulates for use in a subterranean application comprising: providing particulates of a settable composition comprising a cementitious material, a filler material, and an activator of the cementitious material; and pre-curing the particulates until the particulates reach a crush strength of about 50 psi or greater; and curing the pre-cured particulates at a temperature in the range of about 230° F. to about 600° F., so that at least a portion of the particulates comprise a newly formed crystalline phase.

Abstract: A cement manufacturing apparatus capable of increasing quantity of fly ash used in the apparatus while controlling unburned carbon content in cement within a permissible range. The cement manufacturing apparatus comprises a removal means for removing unburned carbon from gypsum, and a grinding means for grinding gypsum from which unburned carbon is removed by the removal means together with clinker to generate cement. With the apparatus, total unburned carbon content in cement can be reduced, and the quantity of fly ash used in the apparatus can be, increased by the reduced amount of unburned carbon. The removal means can remove unburned carbon contained in gypsum as well as unburned carbon contained in fly ash, and the grinding means may grind the fly ash from which unburned carbon is removed together with the gypsum, from which unburned carbon is removed, and clinker.

Abstract: Mixture for use in a three-dimensional printer to make molds suitable for producing ferrous coatings. The mixture includes cement, sand and accelerator. Grain sizes of the cement, sand and accelerator are selected to assure that the three-dimensional printer generates coherent layers.

Abstract: A CO2 control device and method for capturing CO2 from fluid flow, including: a flow-through apparatus and an CO2 absorbing filter treated with an alkaline material which is housed within the flow-through apparatus. The flow-through apparatus receives fluid flow and the CO2 from the fluid flow is absorbed by the CO2 absorbing filter. The absorbed CO2 is converted into CaCO3 which is combined with volcanic ash to form a useful cement material.

Abstract: Cement compositions containing biowaste ash and methods of cementing in subterranean formations using such cement compositions. Examples of suitable biowaste ash include agricultural waste ash, municipal waste ash, waste-water treatment waste ash, animal waste ash, non-human-non-animal industrial waste ash, and combinations thereof.

Abstract: In one example of an embodiment of the invention, a method for producing an aggregate is disclosed comprising mixing sewage sludge from a waste water treatment facility with a non-coal combustion ash silicoaluminous waste material, agglomerating the mixture to form an agglomerate, and pyroprocessing the agglomerate to form an aggregate. The waste material may comprise municipal solid waste incinerator bottom ash, incinerator fly ash, incinerator filter dusts, cement kiln dusts, waste glass, blast furnace slag, kiln dusts, and/or granite sawing residues, for example. The method may further comprise milling the waste material prior to mixing. Preferably, the milling is wet milling. Pyroprocessing of the agglomerate may take place in a rotary kiln. The resulting aggregate may be a lightweight or a normal weight, sintered or vitrified aggregate. Aggregates and methods for making aggregates of high and low calcium silicoaluminous materials are also disclosed.

Abstract: A method for making a sludge aggregate concrete includes the steps of collecting and dehydrating sludge, sintering the sludge at a temperature of about 800˜900° C., grinding and sieving the sludge through a screen to obtain sludge ash, forming the sludge ash into an artificial sludge aggregate by mixing the sludge ash with an inorganic binder and water followed by granularizing, and mixing the artificial sludge aggregate with an inorganic binder and water to form the sludge aggregate concrete product.

Abstract: A geopolymer mortar formed by mixing about 35% to about 45% by weight pozzolanic material, about 35% to about 45% by weight silicon oxide source, about 15% to about 20% by weight alkaline activator solution, and about 0.3% to about 2.5% by weight copper ion source. The pozzolanic material may be fly ash and the silicon oxide source may be sand. The alkaline activator solution may be a sodium hydroxide solution containing sodium silicate. The geopolymer mortar may have a viscosity in the range of about 25,000 to about 50,000 centipoise. The geopolymer mortar may be formed by further mixing one or more additives, such as surfactants, thermal spheres, anti-sagging agents, adhesion primers, or fibers. The geopolymer mortar may be applied as a protective coating on a surface of a structure.

Abstract: A geopolymer composite ultra high performance concrete (GUHPC), and methods of making the same, are provided herein, the GUHPC comprising: (a) a binder comprising one or more selected from the group consisting of reactive aluminosilicate and reactive alkali-earth aluminosilicate; (b) an alkali activator comprising an aqueous solution of metal hydroxide and metal silicate; and (c) one or more aggregate.

Abstract: Geopolymeric cement based on aluminosilicate fly ashes of class F, which, contrary to the prior art, are harmless to use and harden at ambient temperature, favoring their use in common applications in the construction and civil engineering fields. This harmlessness is achieved thanks to a mixture containing: 10 to 15 parts by weight of a non corrosive alkali metal silicate solution in which the M2O:SiO2 molar ratio is less than 0.78, preferably less than 0.69 and the SiO2:M2O ratio greater than 1.28, preferably greater than 1.45, M denoting Na or K; added to this are 10 to 20 parts by weight of water and 5 to 15 parts by weight of blast furnace slag having a specific surface area less than 400 m2/kg preferably less than 380 m2/kg and 50 to 100 parts by weight of class F aluminosilicate fly ash.

Abstract: Cementitious compositions in which the cementitious properties of fly-ash are carefully controlled. The cementitious compositions may be substantially free harsh acids and bases such as citric acids (?pH 2.2) and alkali metal activators including alkali hydroxides (?pH 12-14) and metal carbonates (?pH 11.6). The use of these harsh chemicals creates acid base reactions during use of the products. Instead of these harsh chemicals, a citric salt, for example potassium citrate, may be used as a reaction accelerator. Boric compounds may be used as a retarder in the compositions.

Abstract: This invention relates to a formulation with the addition of low density additives of volcanic ash, hollow ceramic microspheres or a combination of microspheres and volcanic ash or other low density additives into cementitious cellulose fiber reinforced building materials. This formulation is advantageously lightweight or low density compared as compared to current fiber cement products without the increased moisture expansion and freeze-thaw degradation usually associated with the addition of lightweight inorganic materials to fiber cement mixes. The low density additives also give the material improved thermal dimensional stability.

Abstract: A cementitious veneer and laminate composition is provided. The cementitious laminate composition includes a substrate, a primer layer applied to the substrate, the primer layer comprising a mixture of polyvinyl alcohol catalyst, Portland cement, and sand; and a cementitious veneer layer applied to the primer layer, the cementitious veneer layer comprising a mixture of magnesium sulfate, filler, magnesium oxide, gypsum cement or bassanite, cellulose ethers, and polyvinyl alcohol catalyst. The polyvinyl alcohol catalyst comprises a mixture of polyvinyl alcohol fibers dissolved in water and mixed with butylene carbonate. The veneer layer is applied to the substrate and primer layer by means including spraying and manual spreading, and can be ornamentally manipulated either before or after curing of the veneer layer. The veneer composition can be formed into laminated tiles or panels for use in building applications.

Abstract: A process for treating fly ash to render it highly usable as a concrete additive. A quantity of fly ash is obtained that contains carbon and which is considered unusable fly ash for concrete based upon foam index testing. The fly ash is mixed with a quantity of spray dryer ash (SDA) and water to initiate a geopolymerization reaction and form a geopolymerized fly ash. The geopolymerized fly ash is granulated. The geopolymerized fly ash is considered usable fly ash for concrete according to foam index testing. The geopolymerized fly ash may have a foam index less than 40%, and in some cases less than 20%, of the foam index of the untreated fly ash. An optional alkaline activator may be mixed with the fly ash and SDA to facilitate the geopolymerization reaction. The alkaline activator may contain an alkali metal hydroxide, carbonate, silicate, aluminate, or mixtures thereof.

Abstract: A process for treating fly ash to render it highly usable as a concrete additive. A quantity of fly ash is obtained that contains carbon and which is considered unusable fly ash for concrete based upon foam index testing. The fly ash is mixed with an activator solution sufficient to initiate a geopolymerization reaction and for a geopolymerized fly ash. The geopolymerized fly ash is granulated. The geopolymerized fly ash is considered usable fly ash for concrete according to foam index testing. The geopolymerized fly ash may have a foam index less than 35% of the foam index of the untreated fly ash, and in some cases less than 10% of the foam index of the untreated fly ash. The activator solution may contain an alkali metal hydroxide, carbonate, silicate, aluminate, or mixtures thereof.

Abstract: A cementitious slurry and method of making the cementitious slurry comprising mixing a pozzolanic component, a foaming agent of hypochlorite, and a hydroxide solution of soluble hydroxide dissolved in water, whereby the slurry is foamed and hardened into a cellular cementitious composition.

Abstract: A lightweight structural concrete with screw-ability and nail-ability similar to wood is composed of a non-structural and ultra lightweight aggregate such as expanded perlite or a combination of expanded perlite and polystyrene beads of a particular size distribution and volume amount, entrained air cells of another specific size distribution and volume amount, and dense cementitious composition of a cement binder, a fine grade structural filler no larger than concrete sand grade, a pozzolan, and optional micro-fibers for reinforcement. This structural concrete matrix is optimized to hold 13 gauge T-nails and bugle head wood screws with thread ranging from 8 to 11 threads per inch and diameter of 0.10? to 0.137?. The resulting concrete will have consistent screw-ability and nail-ability similar to that of wood.

Abstract: Cementitious compositions and processes for preparing and using the cementitious compositions are provided. The cementitious compositions are characterized by the property of a reduced or an attenuated water vapor emission from a cementitious mix and a concrete formed therefrom.

Abstract: Formed building materials comprising a sequestered CO2 are provided. The building materials of the invention include a composition comprising a carbonate/bicarbonate component. Additional aspects of the invention include methods of making and using the formed building materials.

Abstract: A non-dispersible concrete for underwater and underground construction is disclosed, whose composition primarily comprises: coarse aggregate in a range of from 600 to 1200 kgw/m3; fine aggregate 500 to 1100 kgw/m3, with a fineness modulus (F.M.) in a range of from 2.2 to 3.2; powder 300 to 700 kgw/m3; mixing water 140 to 300 kgw/m3; and cohesion-enhancing admixture (for example, polyacrylamide, PAA) whose solid content is 0.1 to 5.0 wt % of the powder. In addition, a SCC for underwater and underground construction is also developed and has excellent property of self-consolidation (its test value is 400 to 750 mm in slump flow spread test) and an appropriate compressive strength (between 14 to 70 MPa), so as can be widely applied to underwater and underground construction, whose composition further includes superplasticizer with solid content 0.1 to 3.0 wt % of the powder. Also, it covers: water to binder ratio (W/B) of 0.22 to 1.00, paste volume 0.25 to 0.60 m3, and water/powder volume ratio 0.5 to 2.95.

Abstract: Cementitious formulations and their products with enhanced reactivity are provided. Formulations in certain embodiments may include at least one calcium source, a reactant and a filler in a hydrated environment, wherein the reactant, in one form, is crystalline silica that has been modified for reactivity. Enhancement of a reactant may include one or more modifications to its content, grind and/or the cement to silica ratio, as well as addition of one or more additives in the formulation, additives in the form of at least one alumina source, defoamer, catalyst and/or a clay.