Abstract: Improved hydraulic cement compositions and methods for cementing wells drilled through low temperature earth formations wherein the cement is subjected to freeze-thaw cycling are provided. The compositions are comprised of a hydraulic cement, gypsum cement, fly ash, an alkali metal halide, water, and an alcohol freezing point depressant.

Abstract: A method of, and compositions for, the making of a fire-resistant door core assembly. Doors produced from the door core assemblies. In the making of a door core assembly, an aqueous slurry containing gypsum cement and diatomaceous earth is prepared. The slurry may also include expanded mineral ore material and Portland cement. The slurry preliminarily hardens during a green cure stage.

Abstract: A process is disclosed for producing a hydraulic cement binder for both general and special applications, consisting of water, cementitious materials, boric acid, borax, citric acid, an alkali metal activator, and with or without ground silica. This cement making process with sequences for mixing the composition, is particularly useful because it provides: time to mix all components adequately, unrestricted transporting time that can be terminated, at will, followed by alterable placement and finishing times. The process provides the means for creating a hydraulic cement binder that can be used as a neat cement or it can be extended with fillers, such as sand and gravel, to make mortar or concrete, that rapidly gains very high structural strengths.

Abstract: The present invention provides fly ash cementing compositions and methods which are useful in any cementing application, and are particularly suitable for cementing in subterranean zones penetrated by well bores. The cementing compositions can include a portion of the drilling fluid used to drill a well bore as a component thereof. Also, drilling fluid can be disposed of by combining it with the fly ash cementing composition whereby it solidifies in a disposal location.

Abstract: A cement composition for temporary, environmentally sound structures, including berms for erosion and flood control, comprising portland cement, flyash, sodium silicate, water and aggregate in predetermined amounts to obtain a pumpable cement composition having less than 2 inches of slump and a 28 day compressive strength of between about 100 and about 400 psi.

Abstract: A blended, hydraulic cement binder, is disclosed, consisting of water, fly ash, Type III portland cement, Type I portland cement, slag cement, ground silica, boric acid, borax, citric acid and an alkali metal activator. The cement binder and sequences for mixing the composition, is particularly useful because it provides: time to mix all components adequately, unrestricted transporting time that can be terminated, at will, followed by alterable placement and finishing times. The cement binder can be used as a neat cement or it can be extended with fillers, such as sand and gravel, to make mortar or concrete, that rapidly gains very high structural strengths.

Abstract: A tectoaluminosilicate cement which consists of K, Ca and aluminosilicates plus, optionally, Li, Na and Mg, contains: a phyllosilicate dehydroxylated at a temperature between 500.degree. and 900.degree. C., reactive amorphous silica, reactive calcium silicate glass or reactive calcium aluminosilicate glass with a Ca:Si ratio of .gtoreq.1 and alkali silicate with the total formula: a(M.sub.2 O) * x(SiO.sub.2) * y(H.sub.2 O) in which M=Li, Na or K, a=0-4, x=0-5 and y=3-20, the overall Si:Al ratio being .gtoreq.1. The tectoaluminosilicate cement preferably alkali hydroxide. The dehydroxylated phyllosilicate is a metakaolin giving tectosilicate structures. The reactive amorphous silica is a dealuminated phyllosilicate, a fly ash dealuminated with mineral acids, where applicable, a fine-grained crystalline form of SiO.sub.

Abstract: The invention provides a novel, environmentally stabilized formed product and to a method of producing a hard, dry, e.g., agglomerated or formed, environmentally stabilized product useful as a construction material, e.g., as pellets, panels, bricks, etc. comprising: a) ash such as RDF or coal ash (typically stack scrubber solids or bottom ash obtained from the burning of coal), b) an oxidizer and c) water. The amount of water present is selected to render the product plastic so that it can be molded to the desired shape. The oxidizer is provided in a sufficient amount to oxidize unstable compounds and to convert potassium, calcium or magnesium bisulfite to the sulfate form. Following the addition of the oxidizer, the admixture is exposed to electromagnetic energy, preferably ultraviolet light, to help drive the oxidation reaction to completion.

Abstract: Cement admixture compositions formed from alkenyl ether/maleic anhydride copolymers having specific molecular structures have been found to impart a high degree of slump loss over a sustained period of time while not causing any significant set retardation of the treated cement based composition.

Abstract: A polymer modified cement, low shrinkage mortar patching and/or coating compound that can be sanded after drying and has the consistency of drywall compound for coating, patching or taping drywall, plaster, stucco, concrete or wood surfaces.

Abstract: Improved hydraulic cement compositions and methods for cementing wells drilled through low temperature earth formations wherein the cement is subjected to freeze-thaw cycling are provided. The compositions are comprised of a hydraulic cement, gypsum cement, fly ash, an alkali metal halide, water, and an alcohol freezing point depressant.

Abstract: The invention provides a novel formed product and method of producing a hard, dry, e.g., agglomerated or formed, product useful as a construction material comprising: a) papermill sludge made up of paper fiber, clay and calcium carbonate, b) ash such as coal ash (typically stack scrubber solids obtained from the burning of coal), and c) water. The amount of water present is selected to render the product plastic so that it can be molded to the desired shape. An oxidizer is provided in a sufficient amount to oxidize unstable compounds and to convert potassium, calcium or magnesium bisulfite to the sulfate form. Following the addition of the oxidizer, the admixture is exposed to electromagnetic energy, preferably ultraviolet light, to help drive the oxidation reaction to completion. In an optional form of the invention, a minor amount of a cation exchange resin is added to the mixture to sequester heavy metals.

Abstract: A stucco coating for interior and exterior walls of buildings that provides increased bonding strength over the prior art.

Abstract: Residue produced by incineration of commercial, industrial or municipal waste is treated to remove oversize material and ferrous materials. The moisture content of the untreated residue is adjusted, and the residue is mixed with Portland cement to partially aggregate the residue into a free-flowing, granular material containing no more than about five percent by weight fines and having a hydraulic conductivity of at least about 0.001 cm/sec after curing for 24 hours. The treated residue can be used to form a gas-venting layer for a landfill, and retains its good hydraulic conductivity as it cures into a cohesive mass, such that leaching of hazardous materials is reduced.

Abstract: A process for solidifying organic waste in cement for transport and storage in solid form by mixing organic waste, water, and a cationic amine to form an emulsion, mixing the emulsion with cement to form a mixture without breaking the emulsion, casting the mixture in a form, and curing the mixture to a solidified form. In a preferred embodiment of the process, a particulate material with a negative surface charge is included in the mixture to neutralize positive charges on the cationic amine and the cement. An alcohol or glycol may be included in the emulsion to enhance the holding power and integrity of the emulsion by controlling size and uniformity of emulsion particle size. The process is applicable to organic wastes such as waste oils, halogenated solvents, non-halogenated solvents, pesticides, herbicides, liquids and sludges containing heavy metals, radioactive mixed wastes and mixtures thereof.

Abstract: In general purpose concrete compositions, from about 10% but less than about 25% by wt of the usual amount of portland cement for such compositions is replaced with Class F fly ash and cement kiln dust, both abundant and inexpensive waste products, in the weight ratio of such fly ash to cement kiln dust of about 3:1-1:1 with a minimum of about 5% of the replaced portland cement being cement kiln dust. General purpose concrete prepared from these mix compositions exhibit early strength characteristics, especially from day 1 to day 3, generally equal to or better than those exhibited by comparable all portland cement mix compositions.

Abstract: Improved cementitious compositions having increased flexural, tensile and shear-bond strength, increased wear resistance, decreased water permeability and enhanced workability than previous cement compositions, which are prepared with water treated with an emulsified tar component, and preferably a residual amount of sodium tripolyphosphate, are provided. Methods of forming shaped articles therefrom are also provided.

Abstract: An unground, fine pozzolan having a sulphur content determined as wt. % SO.sub.3 of 5 to 25 wt. % is employed in admixture with Portland cement to provide a blended hydraulic cement which has increased compressive strength characteristics as well as extended retardation time without the need for separate addition of gypsum; the pozzolan may also be admixed with fly ash to provide a pozzolan blend for use with Portland cement with reduced Portland cement content and use of Class C fly ash; the pozzolan is derived by reaction of coal flue gases with an atomized vapor of slaked lime.

Abstract: System and method for low temperature treatment of organic wastes containing potentially toxic concentrations of metals is described which comprises forming the waste material into pellets of preselected size, mixing the pellets with inert material, incrementally heating the mixture in air from about 200.degree. C. to about 600.degree. C. in order to oxidize the pellets to the corresponding ash containing the metals, collecting the ash, and combining the ash with inert material and binder to form a solidified compact for disposal.

Abstract: Described is the process for forming a hardenable mixture of a coal ash comprising free CaO and free CaSO.sub.4.0 H.sub.2 O.In order to remove all free CaO the coal ash is mixed with a fly-ash comprising essentially no free CaO and no free CaSO.sub.4.0 H.sub.2 O and water and subsequently subjected to a heat treatment.By removal of free CaO it is found that the strength of hardened granules formed from such ash mixture does not deteriorate as is the case from granules formed with a coal ash comprising free CaO.Also a process for forming hardened granules and a building component formed with use of a hardenable mixture according to the invention are described.

Abstract: There is disclosed a softy mud solidifying agent which comprises cement, and at least two members selected from the group consisting of pozzolanic substances, inorganic compounds and organic compounds. The solidifying agent is capable of solidifying dredged earth, sand, softy mud, etc. in such a manner that their mixture can be re-cast into water to form submerged banks, artificial fish-gathering places, etc., without causing water pollution.

Abstract: Improved cementitious compositions having increased flexural, tensile and shear-bond strength, increased wear resistance, decreased water permeability and enhanced workability than previous cement compositions, which are prepared with water treated with an emulsified tar component, and preferably a residual amount of sodium tripolyphosphate, are provided. Methods of forming shaped articles therefrom are also provided.

Abstract: An admixture for ultra-dry-mix concrete is disclosed containing one or more varieties of cement dispersing agents (A) selected from a group consisting of lignosulfonates, oxycarboxylates and polycarboxylates, and in addition, containing one or more varieties of nonionic surface-active agents (B) selected from a group consisting of polyoxyalkylene alkylaryl and alkyl ethers with a hydrophilic-lipophilic balance (HLB-value) of 8 to 17.

Abstract: A cement based on blast-furnace slag and fly ash, characterized in that the cement is a homogeneous dry particulate mixture in ready-to-use form, which comprises blast-furnace slag having a specific surface area of 500-650 m.sup.2 /kg and fly ash in a weight ratio in the range of 20/80-60/40, and further comprises the following components in the amounts indicated, calculated on the total mixture: at least 2% by weight of portland cement clinker and 2-12% by weight of sodium silicate (calculated as Na.sub.2 O+SiO.sub.2).

Abstract: A composition, suitable for use as a base in the construction of roads, parking lots, and other areas, is formulated from an ash aggregate comprising municipal solid waste incinerator ash, MSWIA, mixed with an aggregate material; upon addition of cement, compaction and curing, a volumetrically stable solid is formed. The incinator ash is combined with an aggregate material, crushed, and sifted to remove particles having a size greater than three eighths (3/8") inch prior to the addition of cement. The moisture content of the ash aggregate mixture and ash aggregate/cement mixtures are carefully adjusted to achieve maximum compressive strength. When ash aggregates containing less than 50 percent MSWIA are combined with at least 5 percent cement by dry weight, volumetrically stable solids are formed within seven days that have compressive strengths in excess of 300 psi.

Abstract: In the treatment of solid residues containing heavy metals from combustion plants, the heavy-metal compounds dissolved after washing-out and subsequently precipitated are separated from the solvent, usually water or slightly acid aqueous solutions by cross-current diaphragm filtration. The sludge obtained during filtration and comprising precipitated insoluble heavy-metal compounds is dewatered together with the remaining solid residues and made suitable for dumping, e.g. by using binders. The cross-current diaphragm filter improves the washing of heavy metals out of the washing or waste water, and the method and the associated plant are simplified by the joint processing of the sludges containing solids.

Abstract: Residue produced by incineration of commercial, industrial or municipal waste is treated on-site at the point of generation or storage. Moist residue, such as incinerator bottom ash, is mixed in a multi-segment rotary drum with a heavy metals treatment agent in a first section of the drum. An aggregation agent is added to the mixture, and the mixture separates under the shearing force imposed by the rotating drum into individual pieces which are rolled into balls. A cementitious coating material is added to coat the balls, and the coated balls are classified by size. The classified coated balls are conveyed to a bagging plant, where they are packaged in flexible containers formed from material selected to retard water loss, and tagged with identifying information. Toxic contaminants such as cadmium, lead and mercury are immobilized in the cured balls, which can be used as a construction aggregate. Leaching of heavy metals from the incinerator residue is strongly inhibited by the process.

Abstract: A composition for use as a road base or levee fill. The composition comprises catalytic cracking catalyst particles in the size range of 1 to 200 microns and a binder the type and amount of which depend on the end use. Hydrated lime is employed as the binder in road base construction while hydrated lime, portland cement, fly ash or mixtures of fly ash and portland cement can be used in levee construction. The catalyst particles are present in amounts of 80% to 96% and the binder is present in amounts of 4% to 20%,both percentage ranges being determiend according to the dry weight of the composition.

Abstract: Described is the process for forming a hardenable mixture of a coal ash comprising free CaO and free CaSO.sub.4 .OH.sub.2 O.In order to remove all free CaO the coal ash is mixed with a fly-ash comprising essentially no free CaO and no free CaSO.sub.4.OH.sub.2 O and water and subsequently subjected to a heat treatment.by removal of free CaO it is found that the strength of hardened granules formed from such as mixture does not deteriorate as is the case form granules formed with a coal ash comprising free CaO.Also a process for forming hardened granules and a building component formed with use of a hardenable mixture according to the invention are described.

Abstract: The invention concerns a method for producing a hardened mineral product, especially concrete. The method utilizes a hydration reaction with water for at least 1 hour, preferably for 4 to 40 hours, by producing a water/binding agent paste containing components for retardation of binding agent crystallization together with other possible admixtures, e.g., accelerators. When the binding agent reaches an appropriate degree of hydration, preferably 10 to 90%, the unset paste is complemented with fillers for producing the desired mineral mix, after which the end product is shaped as desired and hardened. The water/binding agent paste is agitaged in order to promote the hydration reaction, and when required, admixed with an additional amount of the retarding component of the binding agent crystallization. Furthermore, the invention includes an apparatus for hydrating the binding agent with a facility for subjecting the paste to compacting pressurization in order to improve hydration.

Abstract: A method and composition for solidification or semicolidification of single or multi-phased waste including mixing the waste with a composition including having as its major component a cement, and, as lesser components, a fixative, an absorbant, and optionally an emulsifier. The composition of the invention is mixed with the waste and dried.

Abstract: Improved cement compositions having greater strength, density, and lesser porosity, than concretes previously known are provided, which are prepared with water which been treated so as to comprise a residual amount of sodium tripolyphosphate. Methods of forming high-strength shaped articles are also provided.