Additive Materials For Inorganic Cements Which Contain A Hydraulic Settable Material Patents (Class 106/819)
Organic material containing additive (e.g., carbohydrate, bituminous material, etc.) (Class 106/823)
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Patent number: 5685903Abstract: A cementitious composition useful for water-resistant construction materials, including floor underlayments, backing boards, self-leveling floor materials, road patching materials, fiberboard, fire-proofing sprays, and fire-stopping materials includes about 20 wt. % to about 75 wt. % calcium sulfate beta-hemihydrate, about 10 wt. % to about 50 wt. % Portland cement, about 4 wt. % to about 20 wt. % silica fume and about 1 wt. % to about 50 wt. % pozzolanic aggregate. The Portland cement component may also be a blend of Portland cement with fly ash and/or ground blast slag.Type: GrantFiled: September 13, 1996Date of Patent: November 11, 1997Assignee: National Gypsum CompanyInventors: Elisha Stav, Edward A. Burkard, Ronald S. Finkelstein
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Patent number: 5683503Abstract: A composition for and a method of promoting the flow of a concrete slurry through a pump and a conduit is provided. The composition is a dry particulate mixture comprised of a water soluble, inorganic material and a solvatable, organic polymer. The composition, when mixed with a suitable quantity of water, is useful in a method of priming a pump used to pump a concrete slurry. The composition, when mixed with a concrete slurry, is useful to improve the flow of the slurry through a conduit.Type: GrantFiled: September 17, 1996Date of Patent: November 4, 1997Assignee: Fritz Industries, Inc.Inventor: Daniel P. Montgomery
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Method for blending of admixtures in a sprayed concrete mass and agent for application of the method
Patent number: 5681386Abstract: In a method for blending of admixtures in a concrete mass which is transported through pipes/hoses to a casting site and in which the mass shall have a consistency which is suitable for casting of the mass on wall or roof surfaces there are used admixtures consisting of two components which react with each other. The two components are mixed into the mass at different points in time, possibly in combination with normally used additional admixtures for the mass.Type: GrantFiled: June 6, 1995Date of Patent: October 28, 1997Assignee: MBT Holding AGInventor: Odd Tjugum -
Patent number: 5667581Abstract: The present invention relates to a quick-hardening hydraulic bonding agent consisting of calcium silicate cement, particularly Portland cement, as well as additives and/or common admixtures which is characterized by a content of: 94.70 to 99.79% in weight of calcium silicate cement; 0.01 to 2.0% in weight of an organic and/or inorganic accelerator for the hydration of the calcium silicates; 0.1 to 3.0% in weight of an organic and/or inorganic retarding agent which inhibits the hydration of the calcium silicates, possibly having a liquefying effect; 0.01 to 0.30% in weight of an inhibiting agent with respect to the formation of the calcium aluminate sulfate hydrates.Type: GrantFiled: June 10, 1996Date of Patent: September 16, 1997Assignee: Heidelberger Zement AGInventors: Joachim Unsin, Hans Peter Braunbach, Manfred Tax
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Patent number: 5660625Abstract: Improved set accelerating mixtures and their use are disclosed to shorten the period after mixing hydraulically setting building materials, for example cement, up to the transition into the solid phase. The improved set accelerating mixtures comprise basic aluminum sulphates of the formula: Al(OH).sub.a (SO.sub.4).sub.b, in which the subscripts satisfy the conditions:a=3-2b and b=0.05 to 0.4.These basic aluminum sulphates are produced by parallel precipitation from solutions containing aluminum at temperatures usually less than 60.degree. C. by mixing dilute acid solutions and alkaline solutions containing sulphates in the pH range from 5.0 to 8.0 to produce an amorphous, basic aluminum sulphate.Type: GrantFiled: January 24, 1996Date of Patent: August 26, 1997Assignee: Giulini Chemie GmbHInventors: Otto Helmboldt, Istvan Potencsik, Johannes Breker, Reinhold Sedelies, Detlev Roggenkamp
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Patent number: 5660624Abstract: Self-repairing, fiber reinforced matrix materials include a matrix material including inorganic as well as organic matrices. Disposed within the matrix are hollow fibers having a selectively releasable modifying agent contained therein. The hollow fibers may be inorganic or organic and of any desired length, wall thickness or cross-sectional configuration. The modifying agent is selected from materials capable of beneficially modifying the matrix fiber composite after curing. The modifying agents are selectively released into the surrounding matrix in use in response to a predetermined stimulus be it internal or externally applied. The hollow fibers may be closed off or even coated to provide a way to keep the modifying agent in the fibers until the appropriate time for selective release occurs.Type: GrantFiled: September 29, 1995Date of Patent: August 26, 1997Inventor: Carolyn M. Dry
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Patent number: 5658380Abstract: An oil and gas well cementing composition and method are shown utilizing hydraulic cement, water a cement hydration retarder and an additive which is effective over a selected time period degrade the retarder. The additive is a controlled release oxidizer which releases nascent oxygen over time to gradually oxidize the cement hydration retarder, thereby providing a single cement slurry design for cementing pipes for oil and gas wells where wide temperature differentials exist between the two ends of the pipe.Type: GrantFiled: February 13, 1996Date of Patent: August 19, 1997Inventor: Robert Lee Dillenbeck, III
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Patent number: 5656075Abstract: A cement composition including spodumene which has been heated to at least 1000.degree. C. which is capable of inhibiting expansion of the concrete due to the alkali-silica reaction. The present invention also provides a method of reducing expansion in cement compositions.Type: GrantFiled: May 10, 1995Date of Patent: August 12, 1997Assignee: W. R. Grace & Co.-Conn.Inventors: James Michael Gaidis, Ellis Martin Gartner
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Patent number: 5653796Abstract: An admixture for cement comprises phosphorous acid and/or a salt thereof or a waste fluid originated from an electroless nickel-plating process which contains phosphorous acid and/or a salt thereof. The admixture is used as a setting accelerator, a rust proofing agent for reinforcing steel or a frost resistive agent for concrete and mortar as hydraulic cement blends. The admixture not only permits improvement of the resulting concrete in the setting-accelerating effect, but also can maintain the compressive strength at a high level while maintaining the bleeding rate at a low level.Type: GrantFiled: March 29, 1996Date of Patent: August 5, 1997Assignee: Dipsol Chemicals Co., Ltd.Inventors: Masaru Kawai, Shuji Igarashi
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Patent number: 5650004Abstract: There is disclosed a cement plaster composition wherein an additive having from about 10% to about 75% of a silicone treated powder and from about 90% to about 25% of a pozzalanic filler is combined with a type I Portland cement and a crushed aggregate to form a water repellent coating for plastering a swimming pool surface. The additive may also include rheology modifiers, water reducing agents, or set time modifiers.Type: GrantFiled: June 20, 1995Date of Patent: July 22, 1997Inventor: Michael D. Yon
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Patent number: 5641348Abstract: A mixture producing a slurry for coating metallic vehicle exhaust conduits utilizing a refractory cement and a caustic or alkaline salt binder. Sufficient amounts of water are also employed in the slurry resulting in a flowable material. The slurry flows over and hardens as a thin uniform coating on the interior surface of an exhaust conduit. The coating exhibits excellent adhesion to the metallic material, does not crack or chip under impact forces, and possesses a coefficient of thermal expansion similar to the underlying metallic structure.Type: GrantFiled: August 7, 1995Date of Patent: June 24, 1997Inventors: Richard N. Miller, Noble Thomas Pessano
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Patent number: 5641352Abstract: An early strength-enhancing admixture and cement composition is disclosed. The admixtures incorporate strength-enhancing components selected from the group consisting ofa. a nitrogenous compound of the formula ##STR1## wherein R.sub.1 =R.sub.5 A;R.sub.2 =R.sub.5 A, R.sub.5 OH, --OR.sub.6, --R.sub.6, --H, or Z;R.sub.3 =R.sub.5 A, R.sub.5 OH, --OR.sub.6, --R.sub.6, --H, or Z;A=--COOH or --SO.sub.3 H (or salts thereof)Z= ##STR2## R.sub.4 =an alkylene linking group; R.sub.5 =C.sub.1 -C.sub.10 alkylene;R.sub.6 =C.sub.1 -C.sub.10 alkyl;and at least one of R.sub.2 or R.sub.3 is R.sub.5 A, andb. a nitrogenous compound of the formula ##STR3## wherein R.sub.7 =R.sub.5 OH;R.sub.8 =R.sub.5, --R.sub.5 OH;R.sub.9 =--H, R.sub.5 OH.Type: GrantFiled: October 25, 1995Date of Patent: June 24, 1997Assignee: W.R. Grace & Co.-Conn.Inventors: Ara A. Jeknavorian, Leslie Jardine
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Patent number: 5637144Abstract: An asbestos replacement is disclosed which includes water retention agents and finely divided mineral clays with high moisture retention capabilities. Combining the aforementioned ingredients in the correct proportions yields properties as those of asbestos when used in cementitious mortar compositions.Type: GrantFiled: June 5, 1995Date of Patent: June 10, 1997Inventors: Burton K. Whatcott, Lynn G. Bigelow
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Patent number: 5634972Abstract: A method of controlling the hydration of a cementitious composition comprising the steps of:i) providing a cementitious composition containing an amount of a neutralized salt of an alpha-monohydroxy carboxylic acid effective to retard the cementitious composition, said carboxylic acid containing two or more carboxylic acid groups, and subsequently,ii) adding an additional amount of said neutralized salt of an alpha monohydroxy carboxylic acid or a second neutralized salt of an alpha monohydroxy carboxylic acid in an amount sufficient to activate hydration of the retarded cementitious composition, said cementitious composition comprising hydraulic binder and water.Type: GrantFiled: March 13, 1996Date of Patent: June 3, 1997Assignee: Sandoz Ltd.Inventors: John T. Pacanovsky, Lan Huang, Frank T. Gay, Samy M. Shendy
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Patent number: 5629048Abstract: A method of rapidly forming in place a cementitious structure comprising mixing a cement composition with an amount of a water soluble citrate effective to accelerate the setting of the cement in the presence of sufficient water for hydraulic setting of the cement, and delivering the resulting composition while fluid to the place for forming the cementitious structure.Type: GrantFiled: May 17, 1996Date of Patent: May 13, 1997Assignee: Sandoz Ltd.Inventor: Frederick D. Kinney
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Patent number: 5622558Abstract: A cement admixture composition composed of a mixture of alkylene glycol and fume silica to provide a means of inhibiting drying shrinkage and enhancing compressive strength.Type: GrantFiled: September 18, 1995Date of Patent: April 22, 1997Assignee: W.R. Grace & Co.-ConnInventors: Neal S. Berke, Michael P. Dallaire
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Patent number: 5622557Abstract: Binder compositions are provided which include a mineral binder and a silicon-containing carbon black. The silicon-containing carbon black can have attached an ionic or ionizable organic group or can be oxidized. Silicon-containing carbon blacks may be prepared by a furnace method. The binder compositions of the present invention have improved coloring and weathering properties in comparison to binder compositions prepared with conventional carbon blacks. Furthermore, the binder compositions that incorporate silicon-containing carbon blacks having ionic or ionizable organic groups attached exhibit excellent dispersibility, even in pelletized form. Articles such as roofing tiles can be prepared from the binder compositions. Also contemplated is a method of improving the color stability of a mineral binder composition. Silicon-containing carbon blacks as described above are added to the mineral binder composition.Type: GrantFiled: May 22, 1995Date of Patent: April 22, 1997Assignee: Cabot CorporationInventors: Khaled Mahmud, Jameel Menashi, James A. Belmont, Ralph U. Boes
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Patent number: 5622556Abstract: An improved lightweight cementitious product made up of an aqueous cementious mixture that can incorporate fly ash, portland cement, sand, lime, and the weight saving component, which is micronized polystyrene particles having particle sizes in the range of 50 to 2000 microns, and characterized by having very low water contents, in the range of from about 0.5% to 5% v/v. The ultra low water compositions can be extruded and can be molded under high pressure.Type: GrantFiled: October 2, 1995Date of Patent: April 22, 1997Inventor: David M. Shulman
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Patent number: 5609681Abstract: A process for modifying the slump of a concrete or mortar by the addition at different times of a water-soluble poly(alkylene oxide) and a .beta.-naphthalene sulphonate-formaldehyde condensate, a plasticizer or superplasticizer which is selected from lignosulphonates, melamine sulphonate formaldehyde condensates, carboxylates and selected styrene-maleic anhydride copolymers. The poly(alkylene oxide) is preferably partially replaced by a (hydroxy)alkyl cellulose. The process is advantageously used in shotcreting.Type: GrantFiled: June 6, 1995Date of Patent: March 11, 1997Assignee: Sandoz Ltd.Inventors: Josef F. Drs, Tom Melbye, Odd M. Tjugum, Salvatore Valenti
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Patent number: 5603758Abstract: Compositions useful for making lightweight roof tiles. The compositions comprise in percent by weight: between about 2.0 to 4.1 latex (solids basis), between about 20.0 to 28.0 cement, between about 28.0 to 55.0 lightweight aggregate, between about 9.0 to 15.0 water, between about 5.0 to 35.0 standard weight aggregate such as sand, between about 0.0 to 8.0 filler such as limestone, and between 0.0 to 1.5 accelerating additive such as calcium chloride. Methods for making the compositions e.g. into lightweight roof tiles, are also disclosed.Type: GrantFiled: October 6, 1995Date of Patent: February 18, 1997Assignee: Boral Concrete Products, Inc.Inventors: Walter A. Schreifels, Jr., Alfonso V. Alvarez, Luciano Lopez, Joseph E. Smith
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Patent number: 5597514Abstract: A corrosion inhibitor formulation for use in reinforced concrete structures, the inhibitor reducing the rate of corrosion in metallic reinforcing rods placed within the structures. The formulation comprises a mixture of benzoic acid, aldonic acid, and a triazole such as benzotriazole or tolyltriazole.Type: GrantFiled: January 24, 1995Date of Patent: January 28, 1997Assignee: Cortec CorporationInventors: Boris A. Miksic, Christophe Chandler, Margarita Kharshan, Alla Furman, Barry Rudman, Larry Gelner
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Patent number: 5595597Abstract: Phosphomagnesia compositions settable into improvedly water-insensitive cements that retain their mechanical properties comprise an intimate admixture of (i) a binder phase including (a) at least one phosphorous compound (P.sub.2 O.sub.5 or derivative/precursor thereof) and (b) at least one magnesium compound reactive therewith in the presence of water, (ii) an effective amount of cementitious aggregate, and (iii) a water sensitivity-reducing amount of at least one silicone homogeneously distributed therethrough.Type: GrantFiled: March 6, 1996Date of Patent: January 21, 1997Assignee: Rhone-Poulenc ChimieInventors: William Fogel, Eric Garcin
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Patent number: 5593493Abstract: A method of making concrete from base metal smelter slag includes grinding the slag to a size within the range of from about -250 to about 425 mesh to produce ground slag cement, mixing the ground slag cement with Type 3 high early strength Portland cement in a ratio of at least about 0.5:1 by weight, and adding sand and stone to produce a concrete.Type: GrantFiled: June 26, 1995Date of Patent: January 14, 1997Inventor: David Krofchak
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Patent number: 5591259Abstract: Rapid setting cementitious compositions comprise hydraulic cement and at least 4% by weight based on the weight of the cement of a water-soluble malate or citramalate such as an alkali metal malate or alkali metal citramalate.Type: GrantFiled: June 6, 1995Date of Patent: January 7, 1997Assignee: Sandoz Ltd.Inventors: Lan Huang, Stephen A. Farrington
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Patent number: 5588990Abstract: Blended cement compositions for mixture with aggregate and water to prepare cementitious products. Such blended cement compositions contain cement, calcined diatomaceous earth, calcined kaolin, and about 0.5% to about 4% (w/w) of potassium, with or without talc and/or bentonite or their functional equivalents. Admixtures for blending into cement to create such blended cements or their read-mix equivalents contain calcined kaolin, calcined diatomaceous earth, and potassium, with or without talc and/or bentonite or their functional equivalents.Type: GrantFiled: November 3, 1995Date of Patent: December 31, 1996Assignee: Universal Cement & Concrete Products, Inc.Inventor: Jonathan E. Dongell
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Patent number: 5584927Abstract: The hydraulic substance according to the present invention comprises a certain amount of solid particles A (such as portland cement and mixed cement comprising portland cement), an average diameter thereof is 5 to 50 .mu.m, and solid particles B (such as silica fume comprising amorphous silica), an average diameter thereof is less than 1/5 of the particles A, and the particles B have such characteristic that they cohere to the surfaces of the particles A in water, and the quantity of the particles B is arranged such that they cover at least to make a single layer over the whole or part of surfaces of the particles A to cover whole or part of surfaces of particles A with particles B at least with a single layer, and the quantity of the water is arranged such that it is less than 60% of the total amount of the particles A and particles B.Type: GrantFiled: July 27, 1994Date of Patent: December 17, 1996Assignees: Takenaka Corporation, Mitsubishi Materials Corporation, Keihin Ryoko Concrete Industry Corporation, Takemoto Oil and Fat CorporationInventors: Toshio Yonezawa, Kenrou Mitsui, Kunio Yanagibashi, Yousaku Ikeo, Tooru Okuno, Etsurou Asakura, Hisatsugu Yoshida, Mitsuo Sato, Mitsuo Kinoshita
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Patent number: 5584926Abstract: A cement composition consists essentially of (a) from 50% to 97% by weight (calculated on the total composition) of a Portland cement clinker, the sulfur content of which is from 0.5% to 10% by weight expressed as SO.sub.3 and the fluorine content of which is from 0.13% to 1.00% by weight expressed as F, and (b) from 3% to 50% by weight (calculated on the total composition) of an extender containing a carbonate selected from calcium carbonate, magnesium carbonate, calcium magnesium carbonate and mixtures thereof as its main constituent and having a median particle size (d.sub.50) of below 14 .mu.m. Preferably, the total content of C.sub.3 S and C.sub.2 S in the Portland cement clinker is at least 65%. A preferred carbonate is electrostatic precipitator dust extracted from cement kiln exhaust gases. The cement composition may be mixed with further components such as other extenders, retarding agents and aggregate.Type: GrantFiled: January 4, 1995Date of Patent: December 17, 1996Assignee: Aalborg Portland A/SInventors: Hans E. Borgholm, Jesper Damtoft
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Patent number: 5582695Abstract: The structural part is used in an electolytic cell for production of aluminum and comes into contact with the gas atmosphere in the electrolytic reduction cell. The structural part is made completely from, or is a metal part which is coated with, a concrete composition of 15-30% by weight of a hydraulic cement, 5-10% by weight of microsilica and 65-85% by weight of a refractory filler material.Type: GrantFiled: July 17, 1995Date of Patent: December 10, 1996Assignee: Elkem Aluminium ANSInventor: Odd Olsen
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Patent number: 5577865Abstract: Method of admixing and placing a substantially non-flowable cementitious material into an underground space, such as a mine shaft or the like. In a preferred embodiment, a cement slurry including about 95% Class F fly ash and about 5% hydraulic cement is admixed with an activator using a high intensity mixer to form a substantially non-flowable cementitious material, wherein the substantially non-flowable material is pumped through a conduit and placed into the underground space. The cementitious material does not flow away from the area of placement.Type: GrantFiled: July 28, 1995Date of Patent: November 26, 1996Assignee: Halliburton CompanyInventors: Jorge E. Manrique, Rodney L. Paugh, Richard L. Moody
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Patent number: 5575846Abstract: The mortar composition for fixing an anchoring element in a drilled hole in a substrate consists of a water component and a mineral mortar paste held separately from the water component in a crushable container. The mineral mortar paste includes a mixture of mineral mortar and a liquid solvent chemically inert towards the mineral mortar and the mineral mortar paste is hardenable with the water component to form a hardened mortar compound. The water component consists of water and a thixotropic agent so that the water component acts like a paste when not subject to shear forces but flows when subject to shear forces such as those created by the anchoring element advancing in the drilled hole. The thixotropic agent is advantageously amorphous pyrogenic silicic acid.Type: GrantFiled: September 15, 1995Date of Patent: November 19, 1996Assignee: fischerwere, Artur Fischer GmbH & Co KGInventors: Norbert Arnold, Willi Haug
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Patent number: 5575841Abstract: A cementitious material, such as concrete, contains carriers having within them an agent for improving the physical properties of the cementitious material. The agent is released from the carriers into the cementitious material at a desired time after setting by the action of an external stimulus.Type: GrantFiled: December 29, 1993Date of Patent: November 19, 1996Assignee: Carolyn M. DryInventor: Carolyn M. Dry
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Patent number: 5571319Abstract: A fluid, stable aqueous dispersion of silica fume and alkali or alkaline earth metal nitrite salt. The dispersion contains a water soluble alkylene glycol.Type: GrantFiled: September 18, 1995Date of Patent: November 5, 1996Assignee: W. R. Grace & Co.-Conn.Inventors: Neal S. Berke, Michael P. Dallaire
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Patent number: 5571318Abstract: The present invention provides well cementing methods and compositions for use in cold environments which are particularly suitable for cementing conductor strings in deep water offshore wells. The cement compositions are basically comprised of a relatively coarse particulate hydraulic cement mixed with an ultra fine particulate hydraulic cement, sufficient water to form a pumpable slurry and a fluid loss control additive.Type: GrantFiled: August 31, 1995Date of Patent: November 5, 1996Assignee: Halliburton CompanyInventors: James E. Griffith, Patty L. Totten, Bobby L. King, Jiten Chatterji
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Patent number: 5565026Abstract: A 2-component composition is disclosed which contains an inorganic binder as well as a curing agent composed of water or an aqueous solution. The composition also contains substances which regulate solidification and curing, as well as, if necessary, conventional amounts of slag powders, fillers and blowing agents. The composition is distinguished by the fact that it cures rapidly even at low temperatures and can be used in small amounts. As a result, the composition is particularly suitable as a dowelling composition for fastening anchor rods in boreholes.Type: GrantFiled: June 6, 1995Date of Patent: October 15, 1996Assignee: Hilti AktiengesellschaftInventors: Ulrich Hense, Peter Mauthe, Rudolf Hinterwaldner
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Patent number: 5560774Abstract: In a process for accelerating the setting and hardening of a material which contains a hydraulic binder or which consists of a hydraulic binder there is used a setting accelerator mixture which is free of alkali metals and free of chlorides. Said setting accelerating mixture contains at least one water soluble sulfate of a polyvalent cation and a further constituent which is selected from the group consisting of calcium aluminate, calcium sulfoaluminate, basic aluminum salts, mixtures thereof or mixtures containing at least one of said constituents and a further component. If the water soluble sulfate of the polyvalent cation is aluminum sulfate, then said compound has to contain crystal water in order to provide the water solubility of said product.Type: GrantFiled: December 6, 1994Date of Patent: October 1, 1996Assignee: Sika AG, vorm. Kaspar Winkler & Co.Inventors: Theodor A. B urge, Klemens B osch, Dieter Mai
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Patent number: 5558708Abstract: A system and method for dispersing pigment in cement based compositions comprising a predetermined and prepackaged amount of a cement based component and a predetermined and prepackaged amount of an aqueous dispersion of a pigment containing component.Type: GrantFiled: May 11, 1995Date of Patent: September 24, 1996Assignee: C-Cure CorporationInventors: Charles J. Johansen, Jr., Ernest D. Hollas, Robert L. Vecchio, Hani Zoumut
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Patent number: 5556457Abstract: A method of recovering steel plant waste revert materials including blast furnace flue dust and sludges involves mixing the revert materials with water to provide a total moisture content of about 14-20% by weight, then adding Portland cement as a sole binder, mixing, and, when the water content is limited to about 18 to 20%, casting the mixture onto the ground in the form of a slab or, when the water content is limited to about 14 to 16% and an accelerator for curing the cement is used, casting the mixture onto a conveyor in the form of preformed streams, curing the cast mixture and breaking it up to provide 1/2 inch to 5 inch agglomerate particles that can be recycled to the blast furnace.Type: GrantFiled: April 21, 1995Date of Patent: September 17, 1996Assignee: USX CorporationInventors: Raymond R. Terza, Eugene A. Bogdan
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Patent number: 5554218Abstract: This invention relates generally to the field of cement, especially cement for underwater application. The invention provides a composition for preparing cement that solidifies underwater comprising exothermic micro particles and base cement. Exothermic micro particles are less than about two thousand two hundred and fifty micrometers in diameter and can be, for example, calcium chloride. The invention further provides a kit for preparing cement that solidifies underwater comprising exothermic micro particles in a container and base cement. The invention provides a method of underwater construction or repair comprising mixing a composition comprising exothermic micro particles and base cement with water and applying the composition to an underwater structure where the composition solidifies. The composition, kit and method are particularly well suited for swimming pool repair.Type: GrantFiled: April 3, 1995Date of Patent: September 10, 1996Inventors: Shawn Evans, Kevin Wallace
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Patent number: 5547504Abstract: A non-shrink grout including Portland cement, sand and an additive which is a polymer incorporating at least one of a calcium compound and aluminum metal so as to be reactive with the cement. The grout when fresh expands during curing by gas formation and by hydration and expands when hardened. The grout is useful in construction.Type: GrantFiled: August 23, 1995Date of Patent: August 20, 1996Assignee: Board of Trustees operating Michigan State UniversityInventor: Parviz Soroushian
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Patent number: 5534058Abstract: A structural product fabricated from waste materials and a method for making the product. The product includes fly ash, cellulose-based material and an adhesive binder. The product advantageously has good strength with light weight, can be sawed or hammered like wood and is substantially resistant to fire. The composition is particularly useful for forming structural products such as bricks, panels, roof shingles, studs and the like.Type: GrantFiled: January 27, 1995Date of Patent: July 9, 1996Assignee: Midway Environmental Associates, Inc.Inventor: William M. Strabala
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Patent number: 5531825Abstract: Hydraulic cement set-accelerating admixture compositions; cement compositions containing such admixtures; and methods for preparing said cement compositions. The admixture compositions comprise one or more nitroalcohols present in an amount effective to increase the set acceleration of a hydraulic cement composition. The invention further relates to a method of making a hydraulic cement composition comprising adding to a cement composition comprising a hydraulic cement binder, a nitroalcohol component in an amount effective to increase the set-acceleration of the binder, and to a cement composition comprising a hydraulic cement binder and a nitroalcohol set-accelerating agent.Type: GrantFiled: June 7, 1995Date of Patent: July 2, 1996Assignee: W. R. Grace & Co.-Conn.Inventors: Ellis M. Gartner, Joseph A. Cogliano, Ahmad Arfaei, Leslie A. Jardine, Paul Scheiner, Heyman C. Duecker
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Patent number: 5531824Abstract: High-strength, high-hardness concrete, mortar, or grout is prepared by blending portland cement, water, and aggregate with a source of reactive silica, pouring the concrete mixture into a form, allowing the concrete to cure until it reaches its conventional 28-day strength, and immersing the cured concrete in a solution of alkali metal hydroxide and aluminum nitrate at 60.degree.-110.degree. C. for 3-14 days. Alternatively, the cured concrete may be sprayed with the solution and maintained at 60.degree.-110.degree. C. for 3-14 days. A dense, hard surface layer of alkali metal aluminum silicate is formed, the compressive strength and surface hardness of the concrete is increased, and the water infiltration rate into the concrete is decreased.Type: GrantFiled: May 25, 1995Date of Patent: July 2, 1996Inventors: J. Pate Burkes, Philip G. Malone, Lillian D. Wakeley
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Patent number: 5527388Abstract: An admixture for cement compositions is provided which contributes both anodic and cathodic corrosion inhibition, and the cement compositions containing such additives. The cement additive is a combination of an anodic corrosion inhibitor such as calcium nitrite, and a cathodic corrosion inhibitor such as calcium stearate or other fatty acid. The mixed inhibitors in accordance with the invention provide as good or better corrosion inhibition than does calcium nitrite when used alone.Type: GrantFiled: January 25, 1995Date of Patent: June 18, 1996Assignee: W. R. Grace & Co.-Conn.Inventors: Neal S. Berke, Ding F. Shen, Maria C. Hicks, Ellis M. Gartner
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Patent number: 5518541Abstract: Phosphomagnesia compositions settable into improvedly water-insensitive cements that retain their mechanical properties comprise an intimate admixture of (i) a binder phase including (a) at least one phosphorous compound (P.sub.2 O.sub.5 or derivative/precursor thereof) and (b) at least one magnesium compound reactive therewith in the presence of water, (ii) an effective amount of cementitious aggregate, and (iii) a water sensitivity-reducing amount of at least one silicone homogeneously distributed therethrough.Type: GrantFiled: December 29, 1994Date of Patent: May 21, 1996Assignee: Rhone-Poulenc ChimieInventors: William Fogel, Eric Garcin
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Patent number: 5503672Abstract: The invention relates to the cementing of high temperature wells. The retarder consists of a methylene phosphonic acid derivative and of a boric acid or a borate at least as acid as borax in an aqueous solution, in particular, Na pentaborate, in a preferred ratio of 0.08 to 0.92 parts by weight. A long setting time and a very swift compressive strength development are obtained at the same time.Type: GrantFiled: March 8, 1994Date of Patent: April 2, 1996Assignee: Dowell, a division of Schlumberger Technology CorporationInventors: Veronique Barlet-Gouedard, Hugo Hendriks, Pierre Maroy
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Patent number: 5503671Abstract: The invention relates to the cementing of high temperature wells. A cement retarder comprises a phosphonic acid derivative combined with borax in a weight ratio of phosphonic acid derivative to borax of about 0.025 to about 0.2. A long pumping time is realized with rapid compressive strength development following placement.Type: GrantFiled: May 10, 1995Date of Patent: April 2, 1996Assignee: Dowell, a division of Schlumberger Technology CorporationInventors: Jean-Michel Casabonne, Marc Jouve, Erik Nelson
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Patent number: 5494516Abstract: A process for modifying the slump of a concrete or mortar by the addition at different times of a water-soluble poly(alkylene oxide) and a .beta.-naphthalene sulphonate-formaldehyde condensate, a plasticizer or superplasticizer which is selected from lignosulphonates, melamine sulphonate formaldehyde condensates, carboxylates and selected styrene-maleic anhydride copolymers. The poly(alkylene oxide) is preferably partially replaced by a (hydroxy)alkyl cellulose. The process is advantageously used in shotcreting.Type: GrantFiled: July 20, 1993Date of Patent: February 27, 1996Assignee: Sandoz Ltd.Inventors: Josef F. Drs, Tom Melbye, Odd M. Tjugum, Salvatore Valenti
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Patent number: 5494513Abstract: Lightweight concrete products, useful for example in blocks, wall panels, floor and roof slabs, in which zeolite is a major component, its content in the cementing material of the products exceeding 50 wt. %. Depending on application, zeolite may be non-treated or calcined at a temperature enabling the surface activation of the zeolite and resulting high surface energy. Zeolite thus treated will work as both pozzolanic material and bubble-generating agent. Strengthening agents are used to improve compressive strength of the products. Also, a binding material, useful for hazardous waste stabilization, comprising zeolite as a major component, is proposed.Type: GrantFiled: July 7, 1995Date of Patent: February 27, 1996Assignee: National Research Council of CanadaInventors: Yan Fu, Jian Ding, James J. Beaudoin
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Patent number: 5490889Abstract: A blended hydraulic cement binder, is disclosed, consisting of water, fly ash, Type III portland cement, Type I portland cement, slag cement, ground silica, boric acid, borax, citric acid and an alkali metal activator. The cement binder and sequences for mixing the composition, is particularly useful because it provides: time to mix all components adequately, unrestricted transporting time that can be terminated, at will, followed by alterable placement and finishing times. The cement binder can be used as a neat cement or it can be extended with fillers, such as sand and gravel, to make mortar or concrete, that rapidly gains very high structural strengths.Type: GrantFiled: January 20, 1995Date of Patent: February 13, 1996Inventors: William D. Kirkpatrick, Carole W. Kirkpatrick
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Patent number: RE35194Abstract: The present invention is a specific combination of components having unique properties both in composition and benefits. Such a combination has been found in alkali or alkaline earth metal nitrates, alkanolamines and alkali or alkaline earth metal thiocyanates. In such combinations it has also been found that alkaline and alkali earth thiosulfates and chlorides below the concentration level where corrosion is promoted may advantageously be substituted for all or part of the thiocyanates and that diethanolamine, N,N-di(hydroxyethyl)glycine (bicine) and N,N-di(hydroxyethyl)-.beta.-aminopropionic acid (DAPA) and certain alkanolamines and alkanolamino acids and derivatives may advantageously be substituted for all or part of the triethanolamine.Type: GrantFiled: January 12, 1994Date of Patent: April 2, 1996Assignee: Sandoz Ltd.Inventor: Arthur H. Gerber