Abstract: A method for enhancing the thermal quenching of a metal surface comprises treating the metal surface with a complex phosphate acid ester. The metal surface is simultaneously or subsequently treated with a thermal quenching fluid. The method is particularly adapted for use in thermal quenching of aluminum and aluminum alloy surfaces.

Abstract: This invention provides a method for production of reproducible heat treated parts with improved mechanical properties. More specifically, the invention provides a process which comprises the steps of preparing, for example, a copper beryllium alloy melt, casting the alloy melt by a continuous process which uses rapid solidification process techniques or hot working a cast alloy and solution annealing the hot worked alloy, passing the alloy through one or more cold-working steps, applying mechanical and thermal treatments to decrease the residual lattice strains created by cold working the alloy, and then subjecting the alloy to a heat treatment, at temperatures ranging between 250.degree. F. and 800.degree. F., in a heat treating media that gives a rate of heat flow from the interface into the alloy that is fast enough to create those (.alpha.

Abstract: A process for producing a titanium material with excellent corrosion resistance, which comprises first applying a degree of cold working of 10% or more of the total working reduction while causing an oil to exist on the surface of the titanium material during cold working thereof and then subjecting the titanium material to in-situ heat treatment at a temperature of 300.degree. C. or higher, thereby forming a layer with excellent corrosion resistance containing at least one of Ti.sub.2 N, TiC and Ti(CN) on the titanium material surface.

Abstract: A method of manufacturing a titanium alloy, wherein a melted and possibly preformed part is annealed to set the starting grain structure, wherewith a first grain structure transformation is accomplished by a first cooling step, whereafter high dislocation densities are produced in the course of a hot forming step, whereupon heat treatment involving a recrystallization is carried out, wherewith in the course of a subsequent cooling a predominantly or substantially martensitic breakdown is achieved, wherewith a grain structure transformation is carried out in a subsequent annealing process, and wherewith in the course of a subsequent chilling a fine grain structure is set. At least the first cooling step is accomplished by spraying the preformed part with water and/or water-air mixtures. A spray device may be used for carrying out the method.

Abstract: Disclosed is a method of heat treatment of a low melting-point metal for production of spheroidal bodies formed of a low melting-point metal or alloy or heat treatment of the low-melting point metal coated on the surface of an electrode of a chip part.

Abstract: A method of quenching metal components utilizing a water based quenching composition which includes a polyvinylpyrrolidone polymer of high molecular weight and in relatively high concentrations and thereafter power washing the parts to remove the polymeric film. Another preferred embodiment uses the same high molecular weight polyvinylpyrrolidone in combination with two rust inhibiting agents which greatly extend the time during which the quenchant film left on the quenched parts remains water soluble, while still providing an excellent approximation of the cooling curve characteristic of an oil quenchant.

Abstract: A heat treating method comprising providing metal with a polymeric barrier coating, which acts as a barrier against diffusion of reactive species and which, upon thermal decomposition, acts as an oxygen getter or reducing agent, thus extending its protection past its point of thermal stability.

Abstract: A method of quenching metal components utilizing a water based quenching composition which includes a polyvinylpyrrolidone polymer of high molecular weight and in relatively high concentrations and thereafter power washing the parts to remove the polymeric film. Another preferred embodiment uses the same high molecular weight polyvinylpyrrolidone in combination with two rust inhibiting agents which greatly extend the time during which the quenchant film left on the quenched parts remains water soluable, while still providing an excellent approximation of the cooling curve characteristic of an oil quenchant.

Abstract: Methods of doping Hg.sub.1-x Cd.sub.x Te (50) with fast diffusing dopants by immersion in a mercury reservoir (32) doped with the desired dopants are disclosed. Also, methods of core annihilation of Hg.sub.1-x Cd.sub.x Te slices or ingots by immersion in a heated mercury reservoir are disclosed. Preferred embodiments include dopants such as copper in a mercury reservoir (32) that is heated to 270.degree. C. for a Hg.sub.1-x Cd.sub.x Te slice, and a reservoir (32) that is heated to 150.degree. C. for a thin film of Hg.sub.1-x Cd.sub.xn Te on a CdTe substrate.

Abstract: A process is disclosed for the preparation of metallic products from metal salts admixed with solvent wherein at least one of the metal salt and the solvent is easily reducible. The admixture is heated under hypercritical conditions of temperature and pressure to produce metallic products and a hypercritical fluid. The hypercritical fluid is subsequently removed from the reaction zone and the metallic product is collected. The metallic product includes pure metals selected from the group of silver, gold, platinum, palladium, ruthenium, rhodium, mercury, arsenic, rhenium, tellurium, iridium, osmium, and copper, and alloys and mixtures thereof. The metallic product ordinarily exists as finely divided powders which may be highly porous.

Abstract: A metal quenchant fluid which is a mixture of water and a polyalkylene glycol and a inhibitor is substantially nitrite free. The inhibitor is a soluble product obtained by mixing a carboxylic acid having 4 to 12 carbon atoms in the molecule, an amine such as an alkanolamine boiling above 150.degree. C. at atmospheric pressure and a copper chelating agent such as NN diethanol methylene benzotriazole.

Abstract: An organic polymer containing composition suitable for use as a quenchant having incorporated therein a non-nitrite inhibitor system, which comprises an aromatic compound having at least one substituent nitro group and/or the water soluble organic or inorganic salt thereof and a hydroxy substituted mono aromatic carboxylic acid and/or the water soluble organic or inorganic salt thereof. In another embodiment a pH adjustment agent capable of providing an initial pH of at least 7.5 is also present.

Abstract: A method of quenching which comprises the steps of (a) immersing a metal heated to an elevated temperature in a quenchant composition comprising an aqueous-solution of a sufficiently hydrophilic water-soluble or water-dispersible organic polymer of the formula:Y[AR].sub.xto provide a solution containing 15.

Abstract: A process for quenching metals, particularly steel, using as the quenching bath an aqueous composition containing (a) a substituted oxazoline polymer and (b) an N-vinyl heterocyclic polymer or copolymer in which the heterocyclic group is composed of carbon, nitrogen and hydrogen. The quenching bath provides reduced cooling rates through the martensite temperature ranges.

Abstract: Metal, such as steel, is quenched in a quenching bath comprising an aqueous solution of a substituted oxazoline polymer, one example of which is polyethyloxazoline having a molecular weight of 50,000 to 500,000. The bath is capable of providing quenching effects similar to those produced by oil quenchants, as well as quenching times between those provided by oil and water.

Abstract: A three-step thermal aging method for improving the strength and corrosion resistance of an article comprising a solution heat treated aluminum alloy containing zinc, magnesium, copper and at least one element selected from the group consisting of chromium, manganese and zirconium. The article is precipitation hardened at about 175.degree. to 325.degree. F., heat treated for from several minutes to a few hours at a temperature of about 360.degree. to 390.degree. F. and again precipitation hardened at about 175.degree. to 325.degree. F. In a preferred embodiment the article treated comprises aluminum alloy 7075 in the T6 condition. The method of the invention is easier to control and is suitable for treating articles of greater thickness than other comparable methods.

Abstract: A process for annealing steel strip comprising dipping the strip in a molten glass bath maintained 950.degree. C. or higher to anneal it, taking the strip out of the bath to form coagulated glass coatings on the surfaces of the strip and cooling the strip to destroy and peel off the coatings. The bath comprises 38.0 to 62.0% of B.sub.2 O.sub.3, 18.0 to 32.0% of SiO.sub.2, 18.0 to 32.0% of Na.sub.2 O partly replaceable with K.sub.2 O, up to 10.0% of CaO partly replaceable with MgO, BaO, ZnO and/or SrO, up to 6.0% of Li.sub.2 O, up to 10.0% of Al.sub.2 O.sub.3 and 0.5 to 4.0% of NaF, and has a viscosity not exceeding 200 poises as measured at 950.degree. C. The strip is preferably not exposed to air while above 400.degree. C.

Abstract: A method of quenching metals is described, comprising immersing said metals in a quenching oil composition comprising: (a) a base oil, and (b) a compound represented by the general formula (1) or (2) as described below. ##STR1## (wherein all the symbols are the same as defined in the claims). The use of the quenching oil composition results in the formation of a black coating layer on the metal, producing those metallic articles having improved characteristics, such as good lubricity and rust preventive properties.

Abstract: Bath for the quenching of ferrous and nonferrous metals and their alloys, comprising a hydrogenated starch hydrolysate having, expressed with respect to the dry matter, a percentage of products of degree of polymerization 1 and 2 comprised between 1 and 90, the complement to 100 being constituted by products of degree of polymerization equal to or higher than 3.

Abstract: Aqueous quenching baths containing as an essential constituent a water-soluble salt of a copolymer of maleic, citraconic, or itaconic anhydride and a long chain alpha olefin are useful in quenching metal at cooling rates which are slower than that of water, and may be as slow as or slower than those obtained using a hydrocarbon oil as the quenching medium.

Abstract: High Temperature Oxidation (HTO) of aluminum subjected to heat treatment is controlled by exposing the aluminum surface to a metal chloride prior to heat treatment. Transition metal chlorides are preferred for such treatment.

Abstract: There is presented gold based contact materials fabricated by internal carization and method therefor. Carburizable refractory elements are carburized by internal carburization by exposing a gold based solid solution containing the refractory element to an atmosphere of a gaseous oxide of carbon at an elevated temperature. The elevated temperature is chosen to be below the melting point of the solid solution and high enough to cause gaseous decomposition of a carbon material packed with the solid solution within an enclosing container. The carburizable refractory element with the solid solution is preferentially carburized by the gaseous oxide of carbon to form hard, refractory second phase carbide particles within the gold matrix.

Abstract: A process of quenching metal using as the quenching medium an aqueous solution containing from about 0.5% to 50% by weight of a liquid, water-soluble, capped polyether polyol obtained by reacting ethylene oxide and at least one lower alkylene oxide having 3 to 4 carbon atoms, e.g. propylene oxide, with an active hydrogen compound, such as a lower glycol, to prepare a heteric or block copolymer, and further reacting the copolymer with an alpha olefin oxide, the polyol having a molecular weight of from about 7000 to 15,000.

Abstract: On degrease annealing of thin strip and foil made of aluminum and aluminum alloys in an annealing furnace ozone is introduced into the furnace atmosphere.As a result of this the annealing time can be shortened or the annealing temperature lowered. Likewise the tendency for the foil to stick together when in coiled form is markedly reduced.

Abstract: The subject invention provides a method and apparatus for the control and or rectification of molecular weight distribution of polymeric quenchants. In general this is accomplished by selective filtration and elimination of lower molecular weight constituents and the resulting restoration of the molecular weight balance which is necessary to maintain the quench of the desired severity.

Abstract: A method for purification of Group II-VI crystals by contacting with a zinc melt.

Abstract: The invention concerns a new process for quenching metallic pieces and intended to limit the stresses engendered by quenching without essentially affecting the characteristics.This process consists of quenching the pieces by immersion in a binder of the clay type suspended in water and with a mineral component such as magnetite, ferrosilicon, baryte. Products to inhibit corrosion, antifoam, or antiflocculant agents can be added to this suspension.The invention is applied to metallic pieces, but particularly to high resistance aluminum alloy pieces which are made subject to faults caused by the stresses of excessive quenching because of their form or their dimensions.

Abstract: A method of depositing a hard, fine grained metal or semi-metal alloy is described wherein a volatile halide of the metal or semi-metal is partially reduced and then deposited as a liquid phase intermediate compound onto a substrate in the presence of an alloying gas. The liquid phase deposited on the substrate is then thermochemically reacted to produce the hard, fine grained alloy. Also described are products which may be produced by the above method.

Abstract: The invention provides a method for reducing the incidence of thermal decomposition products of metal-treating compositions on the surface of metal heat-treated in the presence of such compositions. The compositions are modified with certain acetylenic alcohols to improve their clean-burning characteristics; the resulting decrease in residual decomposition product on the metal surface facilitates subsequent processing.

Abstract: Aluminium or silicon is diffused into iron (including silicon-iron) by applying to the iron an aqueous paste containing powdered aluminium/silicon, sodium silicate, and optionally magnesium oxide and colloidal silica, and firing it.

Abstract: An ingot as descending from a mold for continuous casting is cooled by several revolving spray jets.

Abstract: A cooling method and apparatus wherein in the process of continuously hardening a metal pipe by heating the metal pipe as it passes through a heating unit and then cooling the inner surface of the metal pipe, an annular cooling nozzle having a large number of nozzle openings is placed in the metal pipe, and the spray direction of jets of cooling medium from the nozzle openings is selected so as to maintain a dip angle of between 30.degree. and 70.degree. and a transversal angle of between 30.degree. and 90.degree. and either cooling water or a mixture of cooling water and compressed air is sprayed with a jet velocity of greater than 5 meters per second onto a large number of points on the circumference of the inner wall of the metal pipe.

Abstract: A surface of molten metal is covered with a polyphase mixture of a cryogenic fluid and at least one additional constituent in the form of particles, the particles having a size less than 50 microns and forming a homogeneous and stable suspension in the boiling liquefied gas. The particles may be metal or metal oxide or glass or carbon or vegetable or mineral oil, and serve to reduce radiative heat losses from the metal by reflection and/or to serve as a lubricant of the metal in a mold.

Abstract: Austenitized ferrous metal, such as carbon steel, is quenched by means of an aqueous solution of a salt of polyacrylic acid which develops an extremely stable and uniform water vapor envelope surrounding the steel. Rate of cooling is controlled by (1) the molecular weight of the salt, (2) concentration of the salt in the solution, (3) solution temperature, and (4) the degree of agitation of the quenchant solution. In the case of carbon steel, by proper selection of the above variables, the austenitic structure of the hot steel may be directly transformed into non-martensitic structures of improved ductility, machinability and cold working properties, such as fine striped pearlite, without the necessity of further heat treatments, such as tempering, following quenching.The quenching solution may also be used to quench parts formed of alloy steel to obtain a martensitic structure without unwanted cracking and distortion. Non-ferrous metals may also be quenched using the polyacrylate quenching solution.

Abstract: A method for thermally treating metal components. The metal components which are in a partially finished condition are annealed by being placed within a liquid bath which is at a temperature between 200.degree. and 300.degree. C. The liquid bath is a mineral oil and is situated within an enclosure into and out of which the metal components are moved by way of an inlet and outlet of the enclosure which themselves contain liquid for sealing off the interior of the enclosure from the outer atmosphere. The liquid at the inlet and outlet is also a mineral oil and is at a temperature of approximately 190.degree. C, in all cases less than 200.degree. C. The interior atmosphere in the enclosure is an inert atmosphere. The extent of contact between the liquid at the inlet and outlet and outer atmosphere is maintained at a minimum.

Abstract: An aluminum-based alloy containing, wt %:Zinc 6.5-7.6Magnesium 1.6-2.2.Copper 0.8-1.2Cobalt 0.05-0.2.Zirconium 0.05-0.3With admixtures of iron up to 0.3 wt %, silicon up to 0.3 wt %, chromium up to 0.05 wt %, manganese up to 0.05 wt %, the balance being aluminum.The alloy may most effectively be used for manufacturing bulky parts of loaded units.

Abstract: A technique is described for stabilizing gold plated electrical contacts wherein the contacts are treated with an oxidizing agent at elevated temperatures, so resulting in a contact structure which does not evidence resistance drift during subsequent thermal aging. Additionally, the technique may be used to reduce the contact resistance of thermally aged contacts which were not subjected to the foregoing preparative process.

Abstract: An aluminum alloy consising essentially of 0.65 to 0.75% by weight of magnesium and 0.50 to 0.60% by weight of silicon or 0.47 to 0.57% by weight of magnesium and 0.75 to 0.85% by weight of silicon, 0.15% to 0.25% by weight of iron, less than 0.05% of an impurity selected from the group consisting of copper, manganese, zinc, chromium, and titanium and the balance aluminum, the aluminum alloy being subjected to aging treatment at a temperature below 200.degree. C for 20 to 50 minutes to obtain 0.2% proof stress larger than 11 kg/mm.sup.2, ultimate tensile strength larger than 20 kg/mm.sup.2 and elongation more than 8%. Aluminum alloy shapes are formed of the above aluminum alloy by extrusion forming of the aluminum alloy to obtain an extrusion, coating a film on the surface of the extrusion with a water-soluble paint after forming thereon a ground film, heating the extrusion at a temperature below 200.degree.

Abstract: A method for the inhibition of metal scale formation in a hydrocarbon processing unit prior to catalyst loading and start-up comprising the steps: circulating a gas comprising a sulfiding component; heating the hydrocarbon conversion zone to at least hydrocarbon conversion temperature; and, collecting loosely bound metal scale until scale production abates. The recurring problem of catalyst bed inlet plugging is solved by removing indigenous metal scale, dust and debris and by passivating the virgin metallic surfaces before the initial start-up of a hydrocarbon processing unit.

Abstract: A process is provided for treating 7000 series aluminum alloys whereby their stress-corrosion resistance is greatly increased. In accordance with the process, the alloy is pre-aged, deformed at room temperature, and then subjected to two aging steps. The alloy so treated has a high resistance to stress corrosion while retaining satisfactory strength properties.

Abstract: A process for the bright-annealing and recrystallization of copper-zinc alloy articles consists of coating the articles with a solution of a synthetic resin and introducing the thus coated articles into an annealing furnace wherein the articles are subjected to recrystallization temperature.