Liquid Patents (Class 148/28)
  • Patent number: 10865335
    Abstract: The present invention relates to the solar photo-thermal power generation technology. Provided is a quartz sand/graphite composite molten salt heat transfer and heat storage medium and a preparation method thereof. The medium is characterized in that it is prepared by adding quartz sand into an existing common heat transfer and heat storage molten salt system for compounding. Hot stability of the obtained heat transfer and heat storage medium is generally improved, an application temperature range is expanded, causticity is reduced, and a service life of a device is greatly prolonged. In addition, a material cost is low.
    Type: Grant
    Filed: January 21, 2014
    Date of Patent: December 15, 2020
    Assignee: SHENZHEN ENESOON SCIENCE & TECHNOLOGY CO., LTD.
    Inventor: ZhiYong Zeng
  • Patent number: 10842147
    Abstract: A biofilm sealant is provided imparting a residual biocidal property. The biofilm sealant is used to treat a surface to impart a film having a capacity to quickly kill bacteria and other germs for at least 24 hours after deposit of the film on a treated surface. The disinfectant formulation biofilm sealant comprises a polymer binder, wherein the polymer binder is an oxazoline homopolymer or an extended or a modified polymer based on an oxazoline homopolymer, and a biocidal compound.
    Type: Grant
    Filed: May 23, 2016
    Date of Patent: November 24, 2020
    Assignees: Microban Products Company, W.M. Barr & Company, Inc.
    Inventors: Tian Lan, Samuel James Hanna, Gina Parise Sloan, Brian Patrick Aylward, Karen Terry Welch, Dennis Earl Shireman, Kevin Andrew Kavchok, Charles L. Hawes
  • Patent number: 10834922
    Abstract: A disinfectant formulation is provided imparting a residual biocidal property. The disinfectant formulation is used to treat a surface to impart a film having a capacity to quickly kill bacteria and other germs for at least 24 hours after deposit of the film on a treated surface. The disinfectant formulation comprises a polymer binder, wherein the polymer binder is an oxazoline homopolymer or an extended or a modified polymer based on an oxazoline homopolymer, and a biocidal compound. The disinfectant formulation further comprises a carrier. An article having the disinfectant formulation is provided as well as methods of making, using and applying the disinfectant formulation.
    Type: Grant
    Filed: November 23, 2015
    Date of Patent: November 17, 2020
    Assignees: Microban Products Company, W.M. Barr & Company, Inc.
    Inventors: Tian Lan, Samuel James Hanna, Gina Parise Sloan, Brian Patrick Aylward, Karen Terry Welch, Dennis Earl Shireman, Kevin Andrew Kavchok, Charles L. Hawes
  • Patent number: 10233335
    Abstract: The aqueous protective coating composition is provided for easy application to refractory linings and walls. When dried, the protective coating composition provides excellent chemical resistance to molten aluminum alkali metals and vapors. The protective coating composition includes alumina and silica, suitably provided as mullite, calcined alumina, and colloidal silica; and a metallic non-wetting agent.
    Type: Grant
    Filed: February 22, 2017
    Date of Patent: March 19, 2019
    Assignee: Magneco/Metrel, Inc.
    Inventors: Madjid Soofi, Lara Binz, Michael W. Anderson
  • Patent number: 10002684
    Abstract: A copper alloy according to the present invention is a copper alloy rolled to be plate-shaped. The copper alloy contains 8.5 to 9.5 mass % of Ni, 5.5 to 6.5 mass % of Sn with a remainder being Cu and unavoidable impurities. An average diameter of crystal grains in a cross section perpendicular to a rolling direction is less than 6 ?m. A ratio x/y of an average length x of the crystal grains in a plate width direction to an average length y in a plate thickness direction satisfies 1?x/y?2.5. An X-ray diffracted intensity ratio in a plate surface parallel to the rolling direction of the copper alloy includes, when an X-ray diffracted intensity of a (220) plane is standardized as 1, an intensity ratio of a (200) plane being 0.30 or less, an intensity ratio of a (111) plane being 0.45 or less, and an intensity ratio of a (311) plane being 0.60 or less. The intensity ratio of the (111) plane is greater than the intensity ratio of the (200) plane and smaller than the intensity ratio of the (311) plane.
    Type: Grant
    Filed: July 26, 2012
    Date of Patent: June 19, 2018
    Assignee: NGK Insulators, Ltd.
    Inventors: Takefumi Ito, Chisako Maeda, Yuji Yoshida, Kei Saegusa, Takayuki Kemmotsu
  • Patent number: 9803255
    Abstract: Aqueous media for quenching metal substrates are provided and contain (i) a polyvinylpyrrolidone/polyvinylcaprolactam copolymer and (ii) one or more of a second polymer, which is selected from (a) a substituted oxazoline polymer; (b) a poly(oxyethylene-oxyalkylene)glycol; or (c) a polyvinylpyrrolidone polymer. The quenching bath provides reduced cooling rates through the martensite temperature ranges. Also provided are processes for quenching metal substrates using these quenching media.
    Type: Grant
    Filed: May 13, 2014
    Date of Patent: October 31, 2017
    Assignee: Houghton Technical Corporation
    Inventors: Laura Gunsalus, Joseph F. Warchol
  • Patent number: 8999500
    Abstract: The invention comprises semifinished products with a structured surface, the semifinished product comprising an oxidized and subsequently re-reduced surface containing at least one refractory metal, and also a process for their production and their use for producing high-capacitance components.
    Type: Grant
    Filed: August 10, 2007
    Date of Patent: April 7, 2015
    Assignee: H.C. Starck GmbH
    Inventors: Melanie Stenzel, Andreas Scharf, Helmut Haas, Holger Brumm, Timo Langetepe, Christoph Schnitter
  • Publication number: 20140326367
    Abstract: This invention discloses a metal coating method whereby an abrasion resistant and wear resistant coating is first applied to the metal object, the coated metal object is then fused onto the metal object and the resulting coated metal object is more abrasion resistant and wear resistant while retaining the metal object's original shape.
    Type: Application
    Filed: February 5, 2014
    Publication date: November 6, 2014
    Applicant: THE LUND INDUSTRIAL GROUP
    Inventor: Earl E. Hill
  • Publication number: 20140261926
    Abstract: A fluid composition is prepared by esterification of (a) at least one synthetic alcohol and (b) a mixture of fatty acids, including at least oleic and linoleic acids, and at least one of a mixture comprising a Miristic acid, Palmitoleic acid, Margarinic acid, Margaroleic acid, ?-Linoleic acid, Arachidic acid, Eicosenoic Behenic acid, and Erucic acid. The fatty acids can also include at least one of stearic acid and palmitic acid. The composition can be used as, or as part of, a quenching bath for a metal.
    Type: Application
    Filed: December 9, 2013
    Publication date: September 18, 2014
    Applicant: A. & A. Fratelli Parodi S.p.A.
    Inventors: Augusto Parodi, Leandro Marini, Felice Matta, Simone Bianchi
  • Publication number: 20140246132
    Abstract: Aqueous media for quenching metal substrates are provided and contain (i) a polyvinylpyrrolidone/polyvinylcaprolactam copolymer and (ii) one or more of a second polymer, which is selected from (a) a substituted oxazoline polymer; (b) a poly(oxyethylene-oxyalkylene)glycol; or (c) a polyvinylpyrrolidone polymer. The quenching bath provides reduced cooling rates through the martensite temperature ranges. Also provided are processes for quenching metal substrates using these quenching media.
    Type: Application
    Filed: May 13, 2014
    Publication date: September 4, 2014
    Applicant: Houghton Technical Corp.
    Inventors: Laura Gunsalus, Joseph F. Warchol
  • Patent number: 8764914
    Abstract: Aqueous media for quenching metal substrates are provided and contain (i) a polyvinylpyrrolidone/polyvinylcaprolactam copolymer and (ii) one or more of a second polymer, which is selected from (a) a substituted oxazoline polymer; (b) a poly(oxyethylene-oxyalkylene) glycol; or (c) a polyvinylpyrrolidone polymer. The quenching bath provides reduced cooling rates through the martensite temperature ranges. Also provided are processes for quenching metal substrates using these quenching media.
    Type: Grant
    Filed: December 30, 2010
    Date of Patent: July 1, 2014
    Assignee: Houghton Technical Corp.
    Inventors: Laura Gunsalus, Joseph F. Warchol
  • Patent number: 8535455
    Abstract: A treatment solution for an insulation coating for a grain oriented electrical steel sheet includes at least one member selected from phosphates of Mg, Ca, Ba, Sr, Zn, Al, and Mn, and colloidal silica in a proportion of 0.5 to 10 mol in terms of SiO2 and at least one member selected from permanganates of Mg, Sr, Zn, Ba, and Ca in a proportion of 0.02 to 2.5 mol in terms of metal elements in the permanganates, relative to PO4:1 mol in the phosphates.
    Type: Grant
    Filed: August 20, 2008
    Date of Patent: September 17, 2013
    Assignee: JFE Steel Corporation
    Inventors: Minoru Takashima, Mineo Muraki, Makoto Watanabe, Tomofumi Shigekuni
  • Publication number: 20120118446
    Abstract: Aqueous metal quenching media comprising vinyllactam/acrylamide copolymers
    Type: Application
    Filed: November 15, 2011
    Publication date: May 17, 2012
    Applicant: BASF SE
    Inventors: Frank FISCHER, Stephan Bauer, Erik Bohrer, Ludger Wegmann, Antonietta Mauri
  • Patent number: 7909943
    Abstract: A process for hardening a work piece of stainless steel through diffusion of the elements carbon and/or nitrogen into the work piece surfaces. The work piece is submerged into a molten salt bath and subjected to the molten salt bath for a period ranging from 15 minutes to 240 hours at temperatures below 450° C. In addition to potassium chloride and lithium chloride, the molten salt bath contains an activator substance consisting of barium chloride, strontium chloride, magnesium chloride and/or calcium chloride, and a free or complex cyanide as carbon-donating substance.
    Type: Grant
    Filed: June 11, 2007
    Date of Patent: March 22, 2011
    Assignee: Durferrit GmbH
    Inventors: Ulrich Baudis, Michael Niedermeyer
  • Patent number: 7771548
    Abstract: Disclosed is a quenching medium for treating a heated metal part, said medium comprising water and a polyacrylate terpolymer comprising acrylamide and/or methacrylamide monomer units, acrylic acid and/or methacrylic acid monomer units and alkyl alkoxylate allyl ether monomer units where the acid groups are in the form of an alkali metal salt and where the alkyl alkoxylate allyl ether monomers are of the formula where n is an integer from 1 to about 30, R is ethylene, propylene or butylene and G is an alkyl group of 8 to 30 carbon atoms. Also disclosed is a method for quenching a heated metal part, which process comprises immersing said metal part in the quenching medium. Also disclosed are the polyacrylate ternary copolymers.
    Type: Grant
    Filed: November 23, 2009
    Date of Patent: August 10, 2010
    Assignee: Ciba Specialty Chemicals Corp.
    Inventors: Robert Cockcroft, David Petty, Frank J. L. Leroy, Francis Mark Prince, Nils Hoeck, Paul Guedj
  • Patent number: 7727339
    Abstract: A highly basic particle flux for submerged arc welding that produces less than 7 ml/100 gr of diffusible hydrogen in the weld metal, which flux comprises a carbon dioxide containing compound with an effective amount of heat releasable carbon dioxide in the range of 0.5-3.5% by weight of the flux over 10% by weight of a low melting point compound and a binder.
    Type: Grant
    Filed: June 6, 2005
    Date of Patent: June 1, 2010
    Inventors: Ashish Kapoor, Teresa A. Melfi
  • Patent number: 7658995
    Abstract: A nickel powder exhibits superior oxidation behavior, reduction behavior and sintering behavior in a production process for a multilayer ceramic capacitor and is suitable for the capacitor; a production method therefor is also provided. The nickel powder, which may be used as a raw material, is treated with a sulfur-containing compound, and the sulfur-containing compound is coated on the surface thereof, or alternatively, a nickel-sulfur compound layer is formed on the surface thereof.
    Type: Grant
    Filed: June 13, 2005
    Date of Patent: February 9, 2010
    Assignee: Toho Titanium Co., Ltd.
    Inventor: Mitsugu Yoshida
  • Publication number: 20090095384
    Abstract: Aqueous media for quenching metal substrates are provided and contain (i) a polyvinylpyrrolidone/polyvinylcaprolactam copolymer and (ii) one or more of a second polymer, which is selected from (a) a substituted oxazoline polymer; (b) a poly(oxyethylene-oxyalkylene) glycol; or (c) a polyvinylpyrrolidone polymer. The quenching bath provides reduced cooling rates through the martensite temperature ranges. Also provided are processes for quenching metal substrates using these quenching media.
    Type: Application
    Filed: October 11, 2007
    Publication date: April 16, 2009
    Applicant: Houghton Technical Corp.
    Inventors: Laura Gunsalus, Joseph F. Warchol
  • Publication number: 20090065107
    Abstract: A polymeric quenchant. The polymeric quenchant comprises an inorganic nanoparticle, a water-soluble polymer, and water, wherein a weight ratio of the inorganic nanoparticle, water-soluble polymer and water is about 0.05-5:1-5:100. The cooling rate of steel during a quenching process can be adjusted by regulating the components and ratios of the adjusted by regulating the components and ratios of the polymeric quenchant to achieve desirable steel properties.
    Type: Application
    Filed: November 20, 2007
    Publication date: March 12, 2009
    Applicants: INDUSTRIAL TECHNOLOGY RESEARCH INSTITUTE, GELIE CO., LTD.
    Inventors: George Ho, Li Kuei Lin, Wen-Faa Kuo
  • Publication number: 20080099108
    Abstract: A process for hardening a work piece of stainless steel through diffusion of the elements carbon and/or nitrogen into the work piece surfaces. The work piece is submerged into a molten salt bath and subjected to the molten salt bath for a period ranging from 15 minutes to 240 hours at temperatures below 450° C. In addition to potassium chloride and lithium chloride, the molten salt bath contains an activator substance consisting of barium chloride, strontium chloride, magnesium chloride and/or calcium chloride, and a free or complex cyanide as carbon-donating substance.
    Type: Application
    Filed: June 11, 2007
    Publication date: May 1, 2008
    Applicant: Durferrit GmbH
    Inventors: Ulrich Baudis, Michael Niedermeyer
  • Publication number: 20040099340
    Abstract: Methods of providing improved metal coatings or metal deposits on a substrate, improvements in plating solutions that are used to provide such metal deposits and articles of the metal-coated substrates. The solderability of the metal coating is enhanced by incorporating trace amounts of phosphorus in the metal coating to reduce surface oxide formation during subsequent heating and thus enhance long term solderability of the metal coating. The phosphorus is advantageously provided in the metal coating by incorporating a source of phosphorus in a solution that is used to provide the metal coating on the substrate, and the metal coating is then provided on the substrate from the solution.
    Type: Application
    Filed: November 27, 2002
    Publication date: May 27, 2004
    Inventors: Yun Zhang, Robert A. Schetty,, Kilnam Hwang
  • Patent number: 6689227
    Abstract: This invention relates to application of eco-friendly starch solution as a quenching medium for heated metal parts fabricated from steel, alloy steel, aluminum and aluminum alloys. Depending on the material grade, critical temperature and desired cooling rate, various types of starch solution can be used and the composition and concentration of the starch quenchant can be tailored to provide the required cooling characteristics for wide range of materials. In particular the starch solutions have the potential to replace quenching oil. The starch solutions are environmentally friendly, having no toxic fumes and no after usage disposal liabilities as compared to oil fumes.
    Type: Grant
    Filed: January 2, 2002
    Date of Patent: February 10, 2004
    Assignee: Tata Consultancy Services, division of Tata Sons LTD
    Inventor: Satyam Suraj Sahay
  • Publication number: 20020038679
    Abstract: In a surface treatment process for mechanical parts, for conferring on the parts a high resistance to wear and corrosion and a roughness propitious to lubrication, nitriding of the part is followed consecutively by oxidation of the part. The nitriding is applied by immersing the part in a molten salt nitriding bath free of sulfur-containing species at a temperature from approximately 500° C. to approximately 700° C. The oxidation is carried out in an oxidizing aqueous solution at a temperature less than approximately 200° C.
    Type: Application
    Filed: August 6, 2001
    Publication date: April 4, 2002
    Inventors: Stephane Chomer, Stephan Teil
  • Patent number: 5766505
    Abstract: The invention provides a water-soluble quenching medium suitably usable for quenching of metal, which can prevent quenching cracks and quenching ununiformity while having good hardenability. The medium comprises (A) a polyalkylene glycol having a weight average molecular weight of from 10,000 to 100,000 and/or its derivative, (B) a glycol ether having a weight average molecular weight of 1,000 smaller, and optionally (C) an alkylene glycol having a weight average molecular weight of 1,000 or smaller, (D) an alkali metal carboxylate, and (E) an organic amine compound having a weight average molecular weight of 1,000 or smaller.
    Type: Grant
    Filed: February 12, 1997
    Date of Patent: June 16, 1998
    Assignee: Idemitsu Kosan Co., Ltd.
    Inventors: Hideo Kanamori, Hitoshi Uchida, Eiichi Nakamura
  • Patent number: 5685920
    Abstract: Disclosed is an annealing separator for production for grain-oriented electrical steel sheet, containing one or more compound selected from the following general formula;?Mg.sub.1-x M.sup.3+.sub.x !O ?Mg.sub.1-x M.sup.2+.sub.x !O or ?Mg.sub.1-x M.sup.2+.sub.x1 M.sup.3+.sub.x2 !OwhereM.sup.2+ is at least one bivalent element selected from the group consisting of Be, Ca, Ba, Sr, Sn, Mn, Fe, Co, Ni, Cu, Zn;M.sup.3+ is at least one tervalent element selected from the group consisting of Al, Fe, Cr, Co, B, Ti, Sb;0.01.ltoreq.x.ltoreq.0.40; x=x1+x2This annealing separator having a lower melting point and higher degree of reactivity is applied on the decarburization annealed strip, and improves the properties of the glass film, especially uniform film appearance and good sealing effect, and magnetic properties.
    Type: Grant
    Filed: May 12, 1995
    Date of Patent: November 11, 1997
    Assignee: Nippon Steel Corporation
    Inventors: Osamu Tanaka, Maremizu Ishibashi, Tsuyoshi Hamaya, Tsutomu Haratani, Tomoji Kumano, Koji Yamasaki, Akira Sakaida, Chihiro Sakurai, Hotaka Honma
  • Patent number: 5629251
    Abstract: A ceramic coating-forming agent of an Mg-M.sup.3+ -O based two-component oxide solid solution capable of forming a ceramic coating excellent in heat resistance, adhesion to a substrate metal, electric insulation and the properties of low thermal expansion, at a low temperature, the agent containing an Mg-M.sup.3+ -O based two-component oxide solid solution of the formula (1),(Mg.sub.1-x M.sup.2+.sub.x).sub.1-y M.sup.3+.sub.y O (1)wherein M.sup.2+ is at least one divalent metal selected from the group consisting of Ca.sup.2+, Mn.sup.2+, Fe.sup.2+, Co.sup.2+, Ni.sup.2+, Cu.sup.2+ and Zn.sup.2+, M.sup.3+ is at least one trivalent metal selected from the group consisting of Al.sup.3+, Mn.sup.3+, Fe.sup.3+, Co.sup.3+, Ni.sup.3+, Ti.sup.3+, Bi.sup.3+ and Cr.sup.3+, x is a number in the range of 0.ltoreq.x<0.5 and y is a number in the range of 0<y<0.5, or an anionic oxide-dispersed Mg-M.sup.3+ -O based two-component oxide solid solution of the formula (2),(Mg.sub.1-x M.sup.2+.sub.x).sub.1-y M.sup.3+.sub.
    Type: Grant
    Filed: May 23, 1995
    Date of Patent: May 13, 1997
    Assignee: Kabushiki Kaisha Kaisui Kagaku Kankyujo
    Inventor: Shigeo Miyata
  • Patent number: 5525165
    Abstract: A cyaniding process, operating in a molten cyanide salt, and a nitriding process, operating in a Tufftride salt bath, can be utilized to modify the near-surface microstructure of Ti-6Al-4V alloy. The surface-hardened layers have been characterized with respect to their hardness and microstructure. The corrosion and wear performance can be both improved by cyaniding and nitriding.
    Type: Grant
    Filed: June 6, 1994
    Date of Patent: June 11, 1996
    Assignee: National Science Council
    Inventors: Jiann-Kuo Wu, Fu-Der Lai
  • Patent number: 5270374
    Abstract: An anti-nitriding composition comprising a water-based alkyd resin having suspended therein particulate tin and titanium dioxide; a thixotropic agent maintains the particulates in suspension during storage and application; the composition includes surfactant and co-solvent to impart paint-like characteristics. The composition is suitable for use as a local shield during the heat treatment of metals to prevent nitriding or ferritic nitro-carburization at temperatures in the range of about 850.degree. F. to about 1150.degree. F. The water-based formulation is safe to use and to transport, and has an air drying time at normal working temperatures comparable to those drying times previously achievable only with organic-solvent based anti-nitriding compositions.
    Type: Grant
    Filed: January 21, 1992
    Date of Patent: December 14, 1993
    Inventor: Glenn O. Ratliff
  • Patent number: 5234507
    Abstract: An anti-oxidation agent for preventing oxidation of a stainless steel strip during continuous annealing comprising a colloidal inorganic substance which can be crystallized at a temperature not higher than 1300.degree. C. at least one compound having a melting point not higher than 1300.degree. C., selected from the group consisting of silicates, borates and phosphates, a dispersion agent, and the balance substantially water. The anti-oxidation agent is applied to the surface of the stainless steel strip. During the annealing, the anti-oxidation agent enhances the heat absorption so that the stainless steel strip temperature is elevated to the annealing temperature in a short time. The anti-oxidation agent on the strip surface forms a film of a fine structure which keeps the strip surface away from oxidizing components of the annealing atmosphere so as to suppress generation of oxide scale. The film is easily separated due to thermal contraction in the course of the cooling after the annealing.
    Type: Grant
    Filed: July 9, 1991
    Date of Patent: August 10, 1993
    Assignee: Kawasaki Steel Corporation
    Inventors: Kuniaki Sato, Genichi Ishibashi, Yasuhiro Katsuki, Hiroyuki Kaito, Hisatomi Muraki, Yoshiharu Yamaguchi
  • Patent number: 5192373
    Abstract: Decarburized grain oriented silicon steel is provided with an annealing separator which forms a glass film after the final high temperature anneal. The magnesia used as the annealing separator has a total chlorine level of 0.01 to 0.20% by weight based on the weight of magnesia with at least 0.01% metal chloride selected from the group of Mg, Ca, Na and K. The chloride addition acts to seal the coating surface during the final anneal to control diffusion and stabilize the secondary grain growth. The glass film which forms during the anneal may be laser scribed for domain refinement without coating damage. The magnesia may also contain additions of phosphates, TiO.sub.2, SiO.sub.2, Cr and B. The temperature of the magnesia is maintained below 25.degree. C. to control hydration and eliminate the need for other additives in the magnesia slurry to control hydration.
    Type: Grant
    Filed: April 12, 1991
    Date of Patent: March 9, 1993
    Assignee: Armco, Inc.
    Inventors: Wade S. Wright, Robin A. Murphy
  • Patent number: 5110854
    Abstract: An anti-nitriding composition comprising a water-based alkyd resin having suspended therein particulate tin and titanium dioxide; a thixotropic agent maintains the particulates in suspension during storage and application; the composition includes surfactant and co-solvent to impart paint-like characteristics. The composition is suitable for use as a local shield during the heat treatment of metals to prevent nitriding or ferritic nitro-carburization at temperatures in the range of about 850.degree. F. to about 1150.degree. F. The water-based formulation is safe to use and to transport, and has an air drying time at normal working temperatures comparable to those drying times previously achievable only with organic-solvent based anti-nitriding compositions.
    Type: Grant
    Filed: March 8, 1990
    Date of Patent: May 5, 1992
    Inventor: Glenn O. Ratliff
  • Patent number: 5102476
    Abstract: Components made from steel can be nitrocarburized in cyanate- and cyanide-containing salt baths within relatively short times if the process is carried out at 600.degree. to 700.degree. C. in a first stage and at 560.degree. to 590.degree. C. in a second stage. The components exhibit the same or better characteristics as compared to considerably longer processing at 560.degree. to 590.degree. C.
    Type: Grant
    Filed: October 1, 1990
    Date of Patent: April 7, 1992
    Assignee: Degussa Aktiengesellschaft
    Inventor: Georg Wahl
  • Patent number: 5011548
    Abstract: For making a ductile boron-containing grain-oriented silicon steel, there is practiced, at a late stage in the making of the product either during the final texture anneal or a subsequent anneal, a high-temperature anneal in a reducing atmosphere with the use of a separating-agent coating, particularly magnesium oxide, which contains an effective amount of a compound of molybdenum and/or tungsten.
    Type: Grant
    Filed: July 28, 1988
    Date of Patent: April 30, 1991
    Assignee: Allegheny Ludlum Corporation
    Inventor: Douglas C. Dean
  • Patent number: 4969959
    Abstract: A method for enhancing the thermal quenching of a metal surface comprises treating the metal surface with a complex phosphate acid ester. The metal surface is simultaneously or subsequently treated with a thermal quenching fluid. The method is particularly adapted for use in thermal quenching of aluminum and aluminum alloy surfaces.
    Type: Grant
    Filed: July 31, 1989
    Date of Patent: November 13, 1990
    Assignee: Reynolds Metals Company
    Inventors: Joseph M. Marr, Barry L. Riddle
  • Patent number: 4948675
    Abstract: By adding an appropriate amount, 1 to 12 weight percent, based on the amount of magnesium oxide present and Loss On Ignition values of powdered magnesium metal to the magnesium oxide aqueous slurry composition used to make a separating-agent composition in the making of grain-oriented silicon electrical steel, there are obtained composition, an article, and a method characterized principally by a substantial decrease in the rate of rejections of the produce of the final texturizing anneal because of coating defects--such difficulties as bare spots, and metal-overlay pattern. Moreover, the magnetic properties may be improved because of improved control of the propagation of the internally oxidized zone of the steel.
    Type: Grant
    Filed: May 19, 1989
    Date of Patent: August 14, 1990
    Assignee: Allegheny Ludlum Corporation
    Inventors: Nazmi Toker, Leroy R. Price
  • Patent number: 4931108
    Abstract: The present invention provides a method for cooling a rolled steel material, especially a wire rod, which comprises immersing a hot-rolled steel material in foams obtained by adding a blowing agent to water, which foams have a water content of 0.01 to 80 g/100 ml, to cool the steel material by the foams. According to this method, a product having a good quality can be stably obtained by a uniform cooling.
    Type: Grant
    Filed: June 30, 1988
    Date of Patent: June 5, 1990
    Assignee: Nippon Steel Corporation
    Inventors: Norio Anzawa, Hisashi Yazaki, Kozi Adachi, Naoki Watanabe, Shuichi Miyabe, Kozo Kitazawa
  • Patent number: 4871402
    Abstract: By adding an appropriate amount, 1 to 12 weight percent, based on the amount of magnesium oxide present and Loss On Ignition values of powdered magnesium metal to the magnesium oxide aqueous slurry composition used to make a separating-agent composition in the making of grain-oriented silicon electrical steel, there are obtained composition, an article, and a method characterized principally by a substantial decrease in the rate of rejections of the product of the final texturizing anneal because of coating defects--such difficulties as bare spots, and metal-overlay pattern. Moreover, the magnetic properties may be improved because of improved control of the propagation of the internally oxidized zone of the steel.
    Type: Grant
    Filed: June 21, 1988
    Date of Patent: October 3, 1989
    Assignee: Allegheny Ludlum Corporation
    Inventors: Nazmi Toker, Leroy R. Price
  • Patent number: 4826545
    Abstract: A method of quenching metal components utilizing a water based quenching composition which includes a polyvinylpyrrolidone polymer of high molecular weight and in relatively high concentrations and thereafter power washing the parts to remove the polymeric film. Another preferred embodiment uses the same high molecular weight polyvinylpyrrolidone in combination with two rust inhibiting agents which greatly extend the time during which the quenchant film left on the quenched parts remains water soluble, while still providing an excellent approximation of the cooling curve characteristic of an oil quenchant.
    Type: Grant
    Filed: June 2, 1987
    Date of Patent: May 2, 1989
    Inventors: Robert W. Foreman, Anthony G. Meszaros
  • Patent number: 4790888
    Abstract: A method and composition for stopping-off nitrogen and/or carbon diffusion into metal surfaces. The composition, which is a mixture of a refractory material selected from the group of zirconium and aluminosilicate, sodium silicofluoride and sodium silicate, is coated onto the metal surface where diffusion is to be prevented. The mixture is cured and the metal part is subjected to elevated temperatures for carburizing, nitriding, or carbonitriding. The coating prevents nitrogen and/or carbon diffusion at the coated area. After treatment the coating is removed.
    Type: Grant
    Filed: February 22, 1988
    Date of Patent: December 13, 1988
    Assignee: Kolene Corporation
    Inventor: Charles M. Bessey
  • Patent number: 4778540
    Abstract: A method and a bath agent for forming a carbide or diffusion layer on the surface of an article to be treated by immersing the article in a molten salt bath. The salt bath comprises borax, at least one oxide of a surface layer forming element (SFE) selected from the group consisting of an oxide of a Va-Group element of the Periodic Table and an oxide of chromium, and aluminum. The amounts of the SFE-oxide and of aluminum to the whole amount of the bath are 9.5 to 21.5 wt% and 4 to 7.5 wt%, respectively. The treating method provides the extended life of the bath, the facilitation of washing off the bath agent adhered to the treated article, etc.
    Type: Grant
    Filed: June 30, 1987
    Date of Patent: October 18, 1988
    Assignee: Kabushiki Kaisha Toyota Chuo Kenkyusho
    Inventors: Tohru Arai, Hatsuhiko Oikawa
  • Patent number: 4775430
    Abstract: For improving the properties of a glass film on a grain-oriented electrical steel sheet, the annealing separator applied on a decarburized steel sheet is prepared by: calcining at a high temperature to reduce the activity thereof; hydrating only on the outermost layer of MgO particles; and adding a Ti, B, or S compound to MgO.
    Type: Grant
    Filed: December 19, 1986
    Date of Patent: October 4, 1988
    Assignee: Nippon Steel Corporation
    Inventors: Osamu Tanaka, Hiroshi Sato
  • Patent number: 4738731
    Abstract: A method of quenching metal components utilizing a water based quenching composition which includes a polyvinylpyrrolidone polymer of high molecular weight and in relatively high concentrations and thereafter power washing the parts to remove the polymeric film. Another preferred embodiment uses the same high molecular weight polyvinylpyrrolidone in combination with two rust inhibiting agents which greatly extend the time during which the quenchant film left on the quenched parts remains water soluable, while still providing an excellent approximation of the cooling curve characteristic of an oil quenchant.
    Type: Grant
    Filed: October 6, 1986
    Date of Patent: April 19, 1988
    Assignee: Park Chemical Company
    Inventors: Robert W. Foreman, Anthony G. Meszaros
  • Patent number: 4666535
    Abstract: A method is provided for improving core-loss values of grain-oriented silicon steel after final texture annealing by boronizing the steel to levels of 0.001 to 0.009 wt. % after applying a boron-containing material to the final texture annealed steel, heating to 1850.degree. to 2200.degree. F., maintaining the steel at such temperature to infuse boron into other steel, and cooling the steel at a rate of 100.degree. F./hour or less.
    Type: Grant
    Filed: April 15, 1986
    Date of Patent: May 19, 1987
    Assignee: Allegheny Ludlum Corporation
    Inventor: James G. Benford
  • Patent number: 4642141
    Abstract: A grain-oriented silicon steel sheet having high magnetic induction and low iron loss can be obtained by adhering uniformly at least one member selected from the group consisting of elements of Ge, Sn, Pb, As, Bi and Zn and compounds containing these elements to the surfaces of a silicon steel sheet before or after the decarburization annealing in a method for producing grain-oriented silicon steel sheets. According to this method, a hot rolled steel sheet is subjected to at least one cold rolling, the finally cold rolled steel sheet is subjected to a decarburization annealing, and the decarburized steel sheet is applied with an annealing separator consisting mainly of MgO and then subjected to a final annealing, or by carrying out the adhesion treatment of element in combination with a preliminary annealing before the decarburization annealing in the above described method, or by using the annealing separator further containing Bi or a Bi-containing compound in the above described method.
    Type: Grant
    Filed: May 24, 1985
    Date of Patent: February 10, 1987
    Assignee: Kawasaki Steel Corporation
    Inventors: Yoshiaki Iida, Katsuo Iwamoto
  • Patent number: 4632708
    Abstract: An annealing separator used in a finishing annealing step for producing a grain-oriented electrical steel sheet usually contains magnesia. The present invention is characterized by including, based on 100 parts by weight of magnesia, from 0.2 to 20 parts by weight of ferromanganese nitride or manganese nitride which consists of a composition (Mn.sub.1-x Fe.sub.x)N.sub.y having x and y values corresponding to A, B, C, and D and falling within a region surrounded by A, B, C, and D shown in the appended FIG. 1.The annealing separator according to the present invention is effective for stabilizing secondary recrystallization and improving the properties of a forsterite film.
    Type: Grant
    Filed: April 4, 1986
    Date of Patent: December 30, 1986
    Assignee: Nippon Steel Corporation
    Inventors: Toyohiko Konno, Yozo Suga, Motoharu Nakamura, Hajime Komatsu
  • Patent number: 4596612
    Abstract: A metal quenchant fluid which is a mixture of water and a polyalkylene glycol and a inhibitor is substantially nitrite free. The inhibitor is a soluble product obtained by mixing a carboxylic acid having 4 to 12 carbon atoms in the molecule, an amine such as an alkanolamine boiling above 150.degree. C. at atmospheric pressure and a copper chelating agent such as NN diethanol methylene benzotriazole.
    Type: Grant
    Filed: October 22, 1984
    Date of Patent: June 24, 1986
    Assignee: BP Chemicals Limited
    Inventor: Manuel Fradique
  • Patent number: 4584033
    Abstract: A method of quenching which comprises the steps of (a) immersing a metal heated to an elevated temperature in a quenchant composition comprising an aqueous-solution of a sufficiently hydrophilic water-soluble or water-dispersible organic polymer of the formula:Y[AR].sub.xto provide a solution containing 15.
    Type: Grant
    Filed: June 28, 1985
    Date of Patent: April 22, 1986
    Assignee: Union Carbide Corporation
    Inventors: Ronald H. Harding, Paul L. Matlock
  • Patent number: 4582547
    Abstract: A method for producing an annealing separator coating on grain oriented silicon steel prior to final texture annealing to improve the coating uniformity and prevent oxidation of the steel surface during this annealing operation. The method comprises coating the steel with a conventional coating, such as magnesium oxide, having an addition of an inert, high temperature refractory annealing separator agent, preferably calcined alumina.An annealing separator composition is also provided.
    Type: Grant
    Filed: May 7, 1984
    Date of Patent: April 15, 1986
    Assignee: Allegheny Ludlum Steel Corporation
    Inventor: LeRoy R. Price
  • Patent number: RE33445
    Abstract: A method of quenching which comprises the steps of (a) immersing a metal heated to an elevated temperature in a quenchant composition comprising an aqueous-solution of a sufficiently hydrophilic water-soluble or water-dispersible organic polymer of the formula:Y[AR].sub.xto provide a solution containing .[.15.0.]. .Iadd.from about 1 to about 20 .Iaddend.
    Type: Grant
    Filed: April 10, 1989
    Date of Patent: November 20, 1990
    Assignee: Union Carbide Chemicals and Plastics Company Inc.
    Inventors: Ronald H. Harding, Paul L. Matlock
  • Patent number: RE34119
    Abstract: A method of quenching metal components utilizing a water based quenching composition which includes a polyvinylpyrrolidone polymer of high molecular weight and in relatively high concentrations and thereafter power washing the parts to remove the polymeric film. Another preferred embodiment uses the same high molecular weight polyvinylpyrrolidone in combination with two rust inhibiting agents which greatly extend the time during which the quenchant film left on the quenched parts remains water soluable, while still providing an excellent approximation of the cooling curve characteristic of an oil quenchant.
    Type: Grant
    Filed: January 23, 1989
    Date of Patent: November 3, 1992
    Assignee: Park Chemical Company
    Inventors: Robert W. Foreman, Anthony G. Meszaros