Aluminum Base Patents (Class 148/437)
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Patent number: 5578146Abstract: Articles of manufacture are made of aluminum-beryllium alloys having substantially randomly distributed aluminum-rich and beryllium rich phases to provide substantially isotropic mechanical properties, such as high stiffness and low coefficients of thermal expansion, whereby the articles of manufacture provide more rapid and accurate responses.Type: GrantFiled: January 16, 1996Date of Patent: November 26, 1996Assignee: Brush Wellman, Inc.Inventors: Larry A. Grant, James M. Marder, Wayne L. Wright
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Patent number: 5578144Abstract: To provide a high-strength, high-ductility cast aluminum alloy, which enables a near-net shape product to be produced by improving the casting structure of an aluminum alloy, particularly by using specific constituents and controlling the cooling rate, and a process for producing the same. The high-strength, high-ductility cast aluminum alloy of the present invention is characterized in that it has a structure comprising fine grains of .alpha.-Al, having an average grain diameter of not more than 10 .mu.m, surrounded by a network of a compound of Al-lanthanide-base metal, the .alpha.-Al grains forming a domain, that the domain comprises an aggregate of .alpha.-Al grains which have been refined, cleaved, and ordered in a single direction and that it has a composition represented by the general formula Al.sub.a Ln.sub.b M.sub.c wherein a, b, and c are, in terms of by weight, respectively 75%.ltoreq.a.ltoreq.95%, 0.5%.ltoreq.b<15%, and 0.5%.ltoreq.c<15%.Type: GrantFiled: June 14, 1995Date of Patent: November 26, 1996Assignee: Toyota Jidosha Kabushiki KaishaInventors: Kazuaki Satou, Yukio Okochi
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Patent number: 5573607Abstract: A metal matrix composite of aluminum, magnesium or titanium, and their alloys, containing particles of a silicon boride composition. A preferred form of the boride is silicon hexaboride. A small amount of carbon can be present in the silicon boride composition as Si--B--C. The particles can be pre-blended with particles of the metal prior to melting, or can be added after the melting of the metal. Because of the similar specific gravity of silicon boron compounds and aluminum, very little stirring is required to achieve a homogeneous mixture in the melt. This substantially reduces formation of oxide and hydrogen inclusions. Improved machinability is achieved through utilization of rounded particles. The composite has improved strength, stiffness and reduced thermal coefficient of expansion, thus making the composite composition more useful in industry.Type: GrantFiled: May 6, 1995Date of Patent: November 12, 1996Assignee: Millennium Materials, Inc.Inventor: Samuel C. Weaver
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Patent number: 5571344Abstract: An element for thermally protecting a substrate is deposited on the substrate and comprises a quasicrystalline aluminum alloy having a thermal diffusivity lower than 2.5.times.10.sup.-6 m.sup.2 /s at room temperature and a thermal diffusivity, within the temperature range 650.degree.-750.degree. C., which does not exceed its thermal diffusivity at room temperature by a factor greater than 3. The element may be used to provide heat barriers or bonding layers for substrates. The heat protection element, used in the form of a heat barrier or in the form of a bond coat for neat barriers, exhibits good thermal insulation properties, good mechanical properties, a low specific mass, good resistance to corrosion, and great ease of processing. Further, the invention is useful in limiting heat transfer towards or from parts and components of fittings in many household and industrial devices, for example, heating or cooking devices, smoothing irons, automobile components, and in aeronautic components.Type: GrantFiled: August 9, 1993Date of Patent: November 5, 1996Assignee: Centre National de la Recherche ScientifiqueInventors: Jean-Marie Dubois, Pierre Archambault, Bernard Colleret
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Patent number: 5554234Abstract: The present invention provides a high strength aluminum alloy suitable for use in the manufacture of a fin, said aluminum alloy containing at most 0.1% by weight of Si, 0.10 to 1.0% by weight of Fe, 0.1 to 0.50% by weight of Mn, 0.01 to 0.15% by weight of Ti, and the balance of Al and unavoidable impurities, intermetallic compounds having a diameter not larger than 0.1 .mu.m being distributed within the metal texture of the alloy in a number density of at least 10/.mu.m.sup.3. The present invention also provides a method of manufacturing a high strength aluminum alloy suitable for use in the manufacture of a fin, comprising the steps of heating to 430.degree. to 580.degree. C. an aluminum alloy ingot of the composition noted above, applying a hot rolling treatment to said aluminum alloy ingot to obtain a plate material before the temperature of the aluminum alloy ingot is lowered by at most 50.degree. C.Type: GrantFiled: December 22, 1994Date of Patent: September 10, 1996Assignee: Furukawa Aluminum Co., Ltd.Inventors: Hiroaki Takeuchi, Hiroshi Kano
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Patent number: 5551997Abstract: Disclosed is a practical aluminum based alloy containing 1 to 99 weight percent beryllium, and improved methods of semi-solid processing of aluminum alloys containing beryllium. The present methods avoid molten beryllium, agitation of molten aluminum-beryllium alloys and the need for introducing shear forces by utilizing atomized or ground particles of beryllium mixed with solid, particulate or liquidus aluminum.Type: GrantFiled: March 31, 1994Date of Patent: September 3, 1996Assignee: Brush Wellman, Inc.Inventors: James M. Marder, Warren J. Haws
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Patent number: 5547633Abstract: The specification describes a ternary alloy of aluminium. The alloy described comprises from 80 to 96% by weight of aluminium and from 4 to 20% by weight of titanium and a third element selected from the group consisting of cobalt, chromium, copper, magnesium, nickel and iron. The weight ratio of titanium to ternary alloying element lies in the range from 1:1 to 6:1. The alloy can be aged at a temperature in the range from 300.degree. to 450.degree. C.Type: GrantFiled: September 23, 1994Date of Patent: August 20, 1996Assignee: Monash UniversityInventors: Barry C. Muddle, Jianfeng Nie
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Patent number: 5547522Abstract: A support for a planographic printing plate support in which variations in the quality of the material of the aluminum support are reduced to thereby improve the yield in an electrolytic graining treatment and which is excellent in susceptibility to graining, has no stripe irregularities, and excellent appearance, and a method for producing such a planographic printing plate. An aluminum plate material is formed through a twin-roller continuous casting apparatus and subjected to cold rolling. Successively, the plate is subjected to heat treatment so as to form a surface portion of a depth of at least 15 .mu.m in the thickness direction having no recrystallization in the surface layer. If necessary, the plate may be subjected to cold rolling again as final rolling. Thereafter, the plate is subjected to correction.Type: GrantFiled: April 3, 1995Date of Patent: August 20, 1996Assignee: Fuji Photo Film Co., Ltd.Inventors: Masaya Matsuki, Hirokazu Sawada, Akio Uesugi
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Patent number: 5547524Abstract: A planar sheet of structurally hardened aluminum alloy, having, after quenching and aging, mechanical strength which varies continuously in a particularly defined direction of the planar sheet. The planar sheet is produced in a process comprising quenching and final aging, where the final aging comprises heating for a defined period of time a first portion of the plate or sheet including a first edge to a first temperature T and a second portion of the plate or sheet including an opposite edge to a second temperature t<T.Type: GrantFiled: June 21, 1994Date of Patent: August 20, 1996Inventors: Pierre Sainfort, Herve Vichery, Benoit Commet
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Patent number: 5541007Abstract: An aluminum alloy wiring layer comprising 0.01 to 1.0 wt. % of scandium, or 0.01 to 1.0 wt. % of scandium and 0.01 to 3.0 wt. % of at least one element selected from the group consisting of silicon, titanium, copper, boron, hafnium and rare-earth elements other than scandium, and the balance aluminum having a purity of not less than 99.99%. A process for producing the same and an aluminum alloy sputtering target used therefor are also disclosed. The aluminum alloy wiring layer of the present invention is suitable as an advanced large-scale integrated circuit.Type: GrantFiled: July 19, 1994Date of Patent: July 30, 1996Assignee: Mitsubishi Chemical CorporationInventors: Tadao Ueda, Kazunari Takemura
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Patent number: 5531840Abstract: A method of producing a support for a planographic printing plate, which comprises after continuous casting an aluminum plate having a thickness of not more than 3 mm from molten aluminum by a twin roller continuous casting method, heat-treating the aluminum plate and then reducing the thickness of the plate to 0.5 mm or less by cold rolling.Type: GrantFiled: November 15, 1994Date of Patent: July 2, 1996Assignee: Fuji Photo Film Co., LTD.Inventors: Akio Uesugi, Tsutomu Kakei
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Patent number: 5529645Abstract: Thin wall lightweight panels which are subjected to high temperature solutioning and rapid quenching to impart high strength properties without distortion, warping or oil-canning. The panels are produced by casting in a mold cavity having an interconnected recess network which surrounds thin wall-forming areas and distributes molten metal uniformly thereto. The recess network forms a waffle pattern reinforcing rib network surrounding the thin-wall areas, lending strength and dimensional stability thereto during the heat treatment and quenching steps, to prevent distortion, warping and oil-canning.Type: GrantFiled: May 17, 1994Date of Patent: June 25, 1996Assignee: Northrop Grumman CorporationInventor: Kermit J. Oswalt
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Patent number: 5523050Abstract: A method is described for preparing a refined or reinforced eutectic or hyper-eutectic metal alloy, comprising: melting the eutectic or hyper-eutectic metal alloy, adding particles of non-metallic refractory material to the molten metal matrix, mixing together the molten metal alloy and the particles of refractory material, and casting the resulting mixture under conditions causing precipitation of at least one intermetallic phase from the molten metal matrix during solidification thereof such that the intermetallics formed during solidification wet and engulf said refractory particles. The added particles may be very small and serve only to refine the precipitating intermetallics in the alloy or they may be larger and serve as reinforcing particles in a composite with the alloy. The products obtained are also novel.Type: GrantFiled: March 15, 1993Date of Patent: June 4, 1996Assignee: Alcan International LimitedInventors: David J. Lloyd, Iljoon Jin
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Patent number: 5520754Abstract: A composition and method for producing a low density, high stiffness aluminum alloy which is capable of being processed into structural components having a desired combination of tensile strength, fracture toughness and ductility. The method includes the steps of forming, by spray deposition, a solid Al-Li alloy workpiece consisting essentially of the formula Al.sub.bal Li.sub.a Zr.sub.b wherein "a" ranges from greater than about 2.5 to 7 wt %, and "b" ranges from greater than about 0.13 to 0.6 wt %, the balance being aluminum, said alloy having been solidified at a cooling rate of about 10.sup.2 to 10.sup.4 K/sec. The method further includes several variations of selected thermomechanical process steps for: (1) eliminating any residual porosity which may be present in the workpiece as a result of the spray deposition step; and (2) producing components for a wide range of applications.Type: GrantFiled: April 25, 1994Date of Patent: May 28, 1996Assignee: Lockheed Missiles & Space Company, Inc.Inventors: Deborah L. Yaney, Richard E. Lewis
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Patent number: 5512241Abstract: Weld filler alloys comprising aluminum, copper, lithium and, optionally, silver are disclosed which possess significantly improved fabricability and weldability. The weld filler alloys are free of magnesium and can be easily drawn into weld wire that is useful for welding aluminum-base alloys. Weldments made with the filler alloys exhibit highly improved mechanical, physical and corrosion resistance properties. The weld filler alloys may be used to weld cryogenic containers for space launch vehicles and the like.Type: GrantFiled: April 13, 1994Date of Patent: April 30, 1996Assignee: Martin Marietta CorporationInventors: Lawrence S. Kramer, Joseph R. Pickens, Carl E. Cross
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Patent number: 5509978Abstract: The present invention provides a high strength and anti-corrosive aluminum-based alloy essentially consisting of an amorphous structure or a multiphase amorphous/fine crystalline structure, which is represented by the general formula Al.sub.x M.sub.y R.sub.z. In this formula, M represents at least one metal element selected from the group consisting of Ti, V, Cr, Mn, Fe, Co, Cu, Zr, Nb, Mo and Ni, and R represents at least one element or mixture selected from the group consisting of Y, Ce, La, Nd and Mm (misch metal). Additionally, in the formula, x, y and z represent the composition ratio, and are atomic percentages satisfying the relationships of x+y+z=100, 64.5.ltoreq.x.ltoreq.95, 5.ltoreq.y.ltoreq.35, and 0<z.ltoreq.0.4.Type: GrantFiled: February 9, 1995Date of Patent: April 23, 1996Assignee: Yamaha CorporationInventors: Tsuyoshi Masumoto, Akihisa Inoue, Yuma Horio
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Patent number: 5507888Abstract: Methods for making an aluminum alloy bicycle frame and for making tubes for such frames including use of an aluminum alloy containing about 0.5 to 1.3% magnesium, about 0.4 to 1.2% silicon, and about 0.6 to 1.2% copper and preferred practices for making extruded and drawn tubing of the alloy and making bicycle frames from the tubing. The preferred practices include extrusion temperature control and other aspects of extrusion and drawing.Type: GrantFiled: November 15, 1993Date of Patent: April 16, 1996Assignee: Aluminum Company of AmericaInventors: John A. Dickson, Jr., Thomas J. Klemp, Arvid H. Sorensen, Robert L. Clottu
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Patent number: 5503692Abstract: A novel method is disclosed for removing or eliminating anisotropic material properties typically found in conventionally rolled or otherwise processed aluminum-lithium alloy products obtained from conventional aluminum fabrication mills. The method comprises imparting a predetermined amount of strain to the conventionally rolled alloy sheet whereby the alloy experiences dynamic recrystallization. Through this process, the mill-imposed crystallographic texturing, which initially sets up the undesired anisotropic characteristics, is eliminated. A preferred technique for imparting strain to the sheet stock is superplastic forming.Type: GrantFiled: November 4, 1993Date of Patent: April 2, 1996Assignee: Rockwell International Corp.Inventors: Gardner R. Martin, Claire E. Anton
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Patent number: 5503689Abstract: An aluminum alloy composition for sheet product consists essentially of 0.3 to 1.1 wt. % silicon, 0.4 to 1.0 wt. % iron, 0.009 to 0.25 wt. % copper and optionally, minor amounts of manganese, magnesium, chromium, zinc, titanium and other incidental impurities with the balance aluminum. In making aluminum sheet from this composition, the aluminum alloy is continuously cast into an intermediate gauge sheet product and directly cold rolled without an intermediate thermal treatment to final gauge. Optionally, the final gauge sheet product can be subjected to a known temper practice. Using the iron, silicon and copper-containing aluminum alloy composition, a sheet product is produced which has acceptable mechanical properties for use as general purpose aluminum sheet, semi-rigid aluminum container stock, consumer wrap container cutter bars and the like.Type: GrantFiled: April 8, 1994Date of Patent: April 2, 1996Assignee: Reynolds Metals CompanyInventors: Bennie R. Ward, Stanley M. Boyd, James P. Martin
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Patent number: 5490885Abstract: A method of treating a blank of an aluminium base alloy comprising a combination of heat treatments and cold forming operations to produce a highly recovered semi-fabricated wrought product that is not statically recrystallized and that is inherently non-superplastic and is capable of superplastic deformation only after an initial non-superplastic deformation to achieve dynamic recrystallization.Type: GrantFiled: August 3, 1994Date of Patent: February 13, 1996Assignee: Alcan International LimitedInventors: William S. Miller, Roger Grimes
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Patent number: 5489418Abstract: An Al-based alloy represented by the general formula Al.sub.bal Ti.sub.a M.sub.b and Al.sub.bal Ti.sub.a M.sub.b Q.sub.c wherein M represents at least one element selected from among V, Cr, Mn, Co, Cu, Y, Zr, Nb, Mo, Hf, Ta and W; Q represents at least one element selected from Mg and Si; and a, b and c are, in percentages by weight, 7.ltoreq.a.ltoreq.20, 0.2.ltoreq.b.ltoreq.20 and 0.1.ltoreq.c.ltoreq.5. A compacted and consolidated material are produced by melting a material having the above alloy composition, rapidly solidifying the melt into powder or flakes; compacting the resultant powder or flakes; and subjecting the compacted powder or flakes to press forming and consolidating by a conventional plastic working. The aluminum-based alloy and the compacted and consolidated material thereof have a high strength and a good ductility and an excellent strength at high temperature.Type: GrantFiled: October 26, 1994Date of Patent: February 6, 1996Assignee: YKK CorporationInventor: Kazuhiko Kita
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Patent number: 5489347Abstract: An aluminum alloy fin material for heat-exchanger with excellent thermal conductance and strength after brazing comprising 0.005 to 0.8 wt. % of Si, 0.5 to 1.5 wt. % of Fe, 0.1 to 2.0 wt. % of Ni, and a balance of Al and inevitable impurities is disclosed. The aluminum alloy fin material can additionally contain 0.01 to 0.2 wt. % of Zr and/or at least one element of the group consisting of not more than 2.0 wt. % of Zn, not more than 0.3 wt. % of In, and not more than 0.3 wt. % of Sn.Type: GrantFiled: July 27, 1994Date of Patent: February 6, 1996Assignees: Furukawa Electric Co., Ltd., Nippondenso Co., Ltd.Inventors: Fujio Himuro, Takeyoshi Doko
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Patent number: 5484493Abstract: Aluminum base alloy consisting essentially of from 0.1 to 3.0% boron, from 1 to 10% titanium and the balance essentially aluminum wherein the aluminum matrix contains TiB.sub.2 particles dispersed throughout said matrix having an average particle size of less than 1 micron, and wherein the matrix contains clusters of said TiB.sub.2 particles greater than 10 microns in size with an average of less than 4 of said clusters per 2 cm.sup.2. The alloy is prepared by adding a boron containing material selected from the group consisting of borax, boron oxide, boric acid and mixtures thereof, and K.sub.2 TiF.sub.6 to a bath of molten aluminum and stirring the molten mixture.Type: GrantFiled: January 27, 1995Date of Patent: January 16, 1996Assignee: KB Alloys, Inc.Inventors: David K. Young, William C. Setzer, Francis P. Koch, Robert A. Rapp, Michael J. Pryor, Noel Jarrett
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Patent number: 5484492Abstract: A cast hypereutectic Al-Si alloy having 12% to 15% Si, and a method of producing such alloy. The alloy and a melt used in the method has at least one element of a first group of elements and at least one element of a second group of elements and further comprises Cu 1.5 to 5.5%; Ni 1.0 to 3.0%; Mg 0.1 to 1.0%; Fe 0.1 to 1.0%; Mn 0.1 to 0.8%; Zr 0.01 to 0.1; Zn 0 to 3.0%; Sn 0 to 0.2%; Pb 0 to 0.2%; Cr 0 to 0.1; Si modifier (Na, Sr) 0.001 to 0.1%; B (elemental) 0.05% maximum; Ca 0.03% maximum; P 0.05% maximum; and others 0.05% maximum each, the balance, apart from incidental impurities being Al. The element of the first group provides stable nucleant particles in the melt. The element of the second groups forms an intermetallic phase such that crystals of the phase form in advance of and nucleate primary Si to provide complex particles which promote nucleation of Al-Si eutectic on cooling of the melt below the eutectic solidification temperature.Type: GrantFiled: July 7, 1994Date of Patent: January 16, 1996Assignee: Comalco Aluminum LimitedInventors: Kevin P. Rogers, Christian Simensen
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Patent number: 5480496Abstract: A method of making twin roll cast clad material includes producing a composite material using a liner stock produced by drag casting techniques. The drag cast liner stock can be directly used in a twin roll continuous casting process without additional process steps such as heat treatment, surface cleaning and/or rolling. The drag cast liner stock can be applied to one or both of the surfaces of the twin roll cast material to produce a composite material that is useful in a cast form or can be adapted for reduction by rolling processes or the like. The twin roll cast cladding process can utilize aluminum alloy core and cladding materials to form a brazing sheet from the as-cast composite material.Type: GrantFiled: March 29, 1994Date of Patent: January 2, 1996Assignee: Reynolds Metals CompanyInventor: Bennie R. Ward
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Patent number: 5480498Abstract: A method of producing aluminum alloy sheet product includes casting a slab, homogenizing the cast slab, and hot rolling the homogenized slab to provide an intermediate gauge product. The temperature and other operating parameters of the hot rolling process are controlled so that the temperature of the intermediate gauge product exiting the hot rolling step is between about 500.degree. F. and 650.degree. F. Preferably, the temperature does not exceed 575.degree. F. The intermediate gauge product is then subjected to a cold reduction of 45% to 70%, annealed, and cold rolled to final gauge. The combination of controlling the hot rolling to provide a desired exit temperature of the intermediate gauge product and annealing prior to cold rolling to final gauge minimizes or eliminates the appearance of ridging or roping line defects in the aluminum sheet product when subjected to further straining in a forming or stamping operation.Type: GrantFiled: May 20, 1994Date of Patent: January 2, 1996Assignee: Reynolds Metals CompanyInventors: Armand J. Beaudoin, J. Daniel Bryant, Alan J. Janousek, Rajeev G. Kamat, H. Edwin Oliver, Robert M. Ramage
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Patent number: 5472920Abstract: The invention relates to the thermal barriers, to a process and material for their production, and to their application. Thermal barriers consist of a material comprising at least one refractory oxide with low thermal diffusivity and at least one quasicrystalline aluminum alloy, the proportion of which represents from 2-30% by volume. They can be produced by deposition of a mixture of refractory oxide and of quasicrystalline alloy in vapor phase, or from a mixture of refractory oxide and quasicrystalline aluminum alloy in the molten state, or else by deposition onto the support to be protected with the aid of an oxygen-gas torch fed with material using a flexible cord which contains the refractory oxide and the quasicrystalline alloy. The applications include the protection of components of aircraft or motor vehicle engines, of aeronautical or aerospace components, of chemical reactors or of electrical households appliances.Type: GrantFiled: December 22, 1993Date of Patent: December 5, 1995Assignee: Societe Nouvelle de Metallisation IndustriesInventors: Jean-Marie Dubois, Philippe Cathonnet
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Patent number: 5462614Abstract: A method of producing a support for a planographic printing plate, which reduces the scattering in the material of the aluminum support, improves the yield of the electrolytic surface graining treatment, and is able to produce lithographic printing plates having superior surface graining aptitude. Aluminum material with a width of 1000 mm and a thickness of 6 mm is formed in the continuous casting twin-roller thin plate device. It is then cold rolled to a plate thickness of 3 mm, and after conducting annealing at 400.degree. C., cold rolling (including correction) is further conducted to bring it to 0.3 mm and form the samples. The temperature distribution of the molten metal at the outlet of the molten metal supply nozzle is kept within a predetermined range.Type: GrantFiled: March 8, 1994Date of Patent: October 31, 1995Assignee: Fuji Photo Film Co., Ltd.Inventors: Hirokazu Sawada, Akio Uesugi, Masaya Matsuki
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Patent number: 5462612Abstract: An aluminum alloy casting comprising 4.0 to 13.0% of Si, 4.5% or below of Cu, 1.5% or below of Mg, and the rest of Al in weight ratio is produced by a production method which adds a metallic hydride to a molten aluminum alloy for casting at a temperature of liquidus line or above. This method makes the shape of pores generated in the casting circular and fine, and an average crystal grain diameter to be 1/3 or below of a thickness of the casting, thereby, an aluminum alloy casting having excellent airtightness can be produced.Type: GrantFiled: March 25, 1994Date of Patent: October 31, 1995Assignee: Hitachi Metals, Ltd.Inventors: Shigetaka Morita, Yoshio Igarashi, Masanao Suzuki
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Patent number: 5458700Abstract: A high-strength aluminum alloy consisting of an amorphous phase containing quasicrystals constituted of aluminum as the principal element, a first additive element consisting of at least one rare earth element and a second additive element consisting of at least one element other than aluminum and rare earth elements, and a crystalline phase consisting of the principal element and the first additive element and the second additive element contained in a supersaturated solid solution form, the amorphous phase containing quasicrystals being contained in a volume percentage of 60 to 90%. The contents of the additive elements preferably fall within a hatched range in the figure, still preferably within a range covered with dot-dash lines in the figure.Type: GrantFiled: April 28, 1994Date of Patent: October 17, 1995Assignees: Tsuyoshi Masumoto, Akihisa Inoue, Yoshida Kogyo K.K.Inventors: Tsuyoshi Masumoto, Akihisa Inoue, Mitsuru Watanabe, Junichi Nagahora, Toshisuke Shitata
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Patent number: 5456772Abstract: A support for a planographic printing plate support in which variations in the quality of the material of the aluminum support are reduced to thereby improve the yield in an electrolytic graining treatment and which is excellent in susceptibility to graining, has no stripe irregularities, and excellent appearance, and a method for producing such a planographic printing plate. An aluminum plate material is formed through a twin-roller continuous casting apparatus and subjected to cold rolling. Successively, the plate is subjected to heat treatment so as to form a surface portion of a depth of at least 15 .mu.m in the thickness direction having no recrystallization in the surface layer. If necessary, the plate may be subjected to cold rolling again as final rolling. Thereafter, the plate is subjected to correction.Type: GrantFiled: October 7, 1993Date of Patent: October 10, 1995Assignee: Fuji Photo Film Co., Ltd.Inventors: Masaya Matsuki, Hirokazu Sawada, Akio Uesugi
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Patent number: 5449421Abstract: In an aluminum alloy composite material including an aluminum alloy matrix and a reinforcing material such as fibers, whisker or particles, intermetallic compounds made of Al and at least one selected from a group of Fe, Ni, Co, Cr, Cu, Mn, Mo, V, W, Ta, Nb, Ti and Zr are finely dispersed in the matrix existing among reinforcing material elements so as to maintain rigidity of the matrix alloy necessary to support the reinforcing material elements at high temperature. Optimum shapes and volumetric density of such intermetallic compounds are experimentally obtained.Type: GrantFiled: February 20, 1991Date of Patent: September 12, 1995Assignee: Toyota Jidosha Kabushiki KaishaInventors: Kaneo Hamajima, Atsuo Tanaka, Tadashi Dohnomoto, Yoshio Fuwa, Hirohumi Michioka
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Patent number: 5441697Abstract: Very fine TiC whiskers having a mean diameter smaller than 1 micron are generated by pellets including Ti powder and graphite powder being added to a molten mass of pure Al or an Al alloy, or by a graphite powder being added to a molten mass of an Al alloy containing Ti, with argon gas being blown into the molten mass so as thereby to generate TiC whiskers in void spaces formed in the molten mass by bubbles of the gas. When the molten mass with the TiC whiskers thus formed therein is compressed, the interstices of the TiC whiskers generated in the void spaces are filled with the molten metal so as thereby to form colonial composite material portions dispersed in the molten mass, thus providing a metallic composite material reinforced by very fine TiC whiskers. The density of the colonial composite material portions can be increased by applying a filtering process to the molten mass.Type: GrantFiled: August 5, 1993Date of Patent: August 15, 1995Assignee: Toyota Jidosha Kabushiki KaishaInventors: Tetsuya Nukami, Tetsuya Suganuma
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Patent number: 5439536Abstract: Strength anisotropy of aluminum-lithium alloy wrought products is reduced by subjecting these types of alloys to improved T8 temper practice. The wrought product, after solution heat treating and quenching, is subjected to a combination of cold rolling and stretching steps prior to aging. The cold rolling can range between 1 and 20% reduction with the stretching step ranging between 0.5-10%. The cold rolling step may be performed in one or a multiple of passes. When multiple passes are used, the cold rolling may be done in different directions to further enhance reductions in strength anisotropy for these types of alloys. An aluminum-lithium alloy wrought product subjected to the improved T8 temper practice has an increased minimum tensile yield stress throughout its thickness and in various directions to facilitate commercial application of the product in high strength applications.Type: GrantFiled: May 2, 1994Date of Patent: August 8, 1995Assignee: Reynolds Metals CompanyInventor: Alex Cho
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Patent number: 5431751Abstract: A high strength aluminum alloy is expressed by a general formula, Al.sub.a X.sub.b Mm.sub.c, in which "X" stands for at least one element selected from the group consisting of Ti, V, Cr, Mn, Fe, Co, Ni, Cu and Zr, "Mm" stands for a misch metal, a content "a" of aluminum falls in a range of from 95.2 to 97.5 atomic %, and a content "b" of "X" and a content "c" of the "Mm" fall in a hatched area enclosed by points "A," "B," "C" and "D" of accompanying FIG. 1 on atomic % basis, and whose metallic phase includes microcrystalline phases or mixed phases containing amorphous phases in a volume content of less than 50% and the balance of microcrystalline phases. As a result, the amorphous phases or the microcrystalline phases are dispersed uniformly in its base microcrystalline phases appropriately, and at the same time the thus generating base microcrystalline phases are reinforced by forming solid solutions including the "Mm" and the transition metal element "X" as well.Type: GrantFiled: February 5, 1993Date of Patent: July 11, 1995Assignee: Toyota Jidosha Kabushiki KaishaInventors: Yukio Okochi, Kazuaki Sato, Tetsuya Suganuma, Akira Kato, Tsuyoshi Masumoto, Akihisa Inoue
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Patent number: 5422066Abstract: Aluminum-base alloys in a peak-aged condition and magnesium-base alloys in the form of cast products and wrought products capable of having improved combinations of yield strength and fracture toughness are disclosed. The aluminum-base alloy products are comprised of 0.5 to 4.5 wt %. lithium, about 0.01 to 1 ppm Na, about 0.01 to 1 ppm K, less than 0.1 ppm Rb, less than 0.1 ppm Cs, and the remainder comprising aluminum. Aluminum-base alloy products in a peak-aged condition have: (i) a grain boundary region substantially free of liquid phase eutectics comprised of Na and K that form embrittlement phases at room temperature; and (ii) an increase in fracture toughness compared to an aluminum-lithium alloy having greater than 5 ppm aggregate alkali metal.Type: GrantFiled: June 14, 1993Date of Patent: June 6, 1995Assignee: Comalco Aluminium LimitedInventor: Donald Webster
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Patent number: 5419789Abstract: An aluminum-based alloy which consists Al and 0.1 to 25 atomic % of at least two transition metal elements and has a structure in which at least quasicrystals are homogeneously dispersed in a matrix composed of Al or a supersaturated Al solid solution. The quasicrystals are preferably composed of an I-phase alone or a mixed phase of an I-phase and a D-phase and preferably has a volume nfraction of 20% or less. Specifically, the aluminum-based alloy has the composition represented by the general formula Al.sub.bal Ni.sub.a X.sub.b or Al.sub.bal Ni.sub.a X.sub.b M.sub.c wherein X is one or two elements selected between Fe and Co; M is at least one element selected from among Cr, Mn, Nb, Mo, Ta and W; 5.ltoreq.a.ltoreq.10; 0.5.ltoreq.b.ltoreq.10; and 0.1.ltoreq.c.ltoreq.5. The alloy is excellent in hardness and strength both at room temperature and high temperature and in heat resistance and has a high specific strength. It can retain the excellent characteristics even when affected by the heat of working.Type: GrantFiled: September 3, 1993Date of Patent: May 30, 1995Assignee: YKK CorporationInventor: Kazuhiko Kita
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Patent number: 5415708Abstract: Aluminum base alloy consisting essentially of from 0.1 to 3.0% boron, from 1 to 10% titanium and the balance essentially aluminum wherein the aluminum matrix contains TiB.sub.2 particles dispersed throughout said matrix having an average particle size of less than 1 micron, and wherein the matrix contains clusters of said TiB.sub.2 particles greater than 10 microns in size with an average of less than 4 of said clusters per 2 cm.sup.2. The alloy is prepared by adding a boron containing material selected from the group consisting of borax, boron oxide, boric acid and mixtures thereof, and K.sub.2 TiF.sub.6 to a bath of molten aluminum and stirring the molten mixture.Type: GrantFiled: June 2, 1993Date of Patent: May 16, 1995Assignee: KBAlloys, Inc.Inventors: David K. Young, William C. Setzer, Francis P. Koch, Robert A. Rapp, Michael J. Pryor, Noel Jarrett
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Patent number: 5415709Abstract: The present invention provides a high-strength, abrasion resistant aluminum alloy having a composition represented by the general formula Al.sub.a M.sub.b X.sub.c Z.sub.d Si.sub.e, wherein M is at least one element selected from the group consisting of Fe, Co, and Ni; X is at least one element selected from the group consisting of Y, La, Ce and Mm (mischmetal); Z is at least one element selected from the group consisting of Mn, Cr, V, Ti, Mo, Zr, W, Ta and Hf; and a, b, c, d and e are all expressed by atom percent and range from 50 to 89 %, 0.5 to 10 %, 0.5 to 10 %, 0 to 10 % and 10 to 49 %, respectively, with the proviso that a+b+c+d+e =100 %, the alloy containing fine Si precipitates and fine particles of intermetallic compounds dispersed in an aluminum matrix. The aluminum alloy may further contain not greater than 5 % of at least one element selected from the group consisting of Cu, Mg, Zn and Li. The alloy can be warm-worked at 300.degree.-500.degree. C.Type: GrantFiled: December 7, 1993Date of Patent: May 16, 1995Assignee: YKK CorporationInventor: Kazuhiko Kita
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Patent number: 5413650Abstract: The mechanical properties of aluminium alloy extrusion in a specified transverse direction are improved by upsetting the extrusion billet in at least one direction chosen with reference to the specified transverse direction. For example, the extrusion billet may be of generally circular cross-section with one or two opposite segments arising. The extrusion may be subjected to thermomechanical treatment and/or vibration treatment. A preferred final thermomechanical treatment is also described.Type: GrantFiled: March 8, 1993Date of Patent: May 9, 1995Assignee: Alcan International LimitedInventors: Martin R. Jarrett, William Dixon
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Patent number: 5407636Abstract: An Al-based alloy represented by the general formula Al.sub.bal Ti.sub.a M.sub.b and Al.sub.bal Ti.sub.a M.sub.b Q.sub.c wherein M represents at least one element selected from among V, Cr, Mn, Co, Cu, Y, Zr, Nb, Mo, Hf, Ta and W; Q represents at least one element selected from Mg and Si; and a, b and c are, in percentages by weight, 7.ltoreq.a.ltoreq.20, 0.2.ltoreq.b.ltoreq.20 and 0.1.ltoreq.c.ltoreq.5. A compacted and consolidated material is produced by melting a material having the above alloy composition, rapidly solidifying the melt into powder or flakes; compacting the resultant powder or flakes; and subjecting the compacted powder or flakes to press forming and consolidating by a conventional plastic working. The aluminum-based alloy and the compacted and consolidated material thereof have a high strength, a good ductility and an excellent strength at high temperatures.Type: GrantFiled: January 25, 1993Date of Patent: April 18, 1995Assignee: YKK CorporationInventor: Kazuhiko Kita
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Patent number: 5405462Abstract: A superplastic aluminum-based alloy material consisting of a matrix formed of aluminum or a supersaturated aluminum solid solution, whose average crystal grain size is 0.005 to 1 .mu.m, and particles made of a stable or metastable phase of various intermetallic compounds formed of the main alloying element (i.e., the matrix element) and the other alloying elements and/or of various intermetallic compounds formed of the other alloying elements and distributed evenly in the matrix, the particles having a mean particle size of 0.001 to 0.1 .mu.m. The superplastic aluminum-based alloy material is produced from a rapidly solidified material consisting of an amorphous phase, a microcrystalline phase or a mixed phase thereof by optionally heat treating at a prescribed temperature for a prescribed period of time and then subjecting to a single or combined thermo-mechanical treatment. The superplastic aluminum-based alloy material of the present invention is suited for to superplastic working.Type: GrantFiled: February 23, 1994Date of Patent: April 11, 1995Assignees: Tsuyoshi Masumoto, Akihisa Inoue, Kenji Higashi, Yoshida Kogyo K.K.Inventors: Tsuyoshi Masumoto, Akihisa Inoue, Kenji Higashi, Katsumasa Ohtera, Makoto Kawanishi
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Patent number: 5393357Abstract: Strength anisotropy of aluminum-lithium alloy wrought products is reduced by subjecting these types of alloys to improved T8 temper practice. The wrought product, after solution heat treating and quenching, is subjected to a combination of cold rolling and stretching steps prior to aging. The cold rolling can range between 1 and 20% reduction with the stretching step ranging between 0.5-10%. The cold rolling step may be performed in one or a multiple of passes. When multiple passes are used, the cold rolling may be done in different directions to further enhance reductions in strength anisotropy for these types of alloys. An aluminum-lithium alloy wrought product subjected to the improved T8 temper practice has an increased minimum tensile yield stress throughout its thickness and in various directions to facilitate commercial application of the product in high strength applications.Type: GrantFiled: October 6, 1992Date of Patent: February 28, 1995Assignee: Reynolds Metals CompanyInventor: Alex Cho
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Patent number: 5383986Abstract: Strength and ductility for a aluminum-lithium alloy wrought product in the transverse direction is improved by subjecting these types of alloys to improved T8 temper practice. The wrought product, after solution heat treating and quenching is subjected to a multiple step stretching sequence prior to aging, the total percent reduction for the multiple step stretching sequence ranging between 1 and 20 percent reduction. In the multiple step stretching sequence, each of the stretching steps may have the same or different amounts of percent reduction to achieve the desired total percent reduction. An aluminum-lithium alloy wrought product subjected to the improved T8 temper practice has increased tensile yield stress and percent elongation in its transverse direction to facilitate commercial application of the product in high strength applications.Type: GrantFiled: March 12, 1993Date of Patent: January 24, 1995Assignee: Reynolds Metals CompanyInventor: Alex Cho
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Patent number: 5374295Abstract: Disclosed are heat resistant aluminum alloy powders and alloys including Ni, Si, either at least one of Fe and Zr or at least one of Zr and Ti. For instance, the alloy powders or alloys consist essentially of Ni in an amount of from 5.7 to 20% by weight, Si in an amount of from 0.2 to 25% by weight, at least one of Fe in an amount of from 0.6 to 8.0% by weight and Cu in an amount of from 0.6 to 5.0% by weight, and the balance of Al. The alloy powders or alloys are optimum for a matrix of heat and wear resistant aluminum alloy-based composite materials including at least one of nitride particles and boride particles in an amount of 0. 5 to 10% by weight with respect to the whole composite material taken as 100% by weight. The alloy powders, alloys and composite materials are satisfactory applicable to the component parts of the recent automobile engines which should produce a high output.Type: GrantFiled: March 3, 1993Date of Patent: December 20, 1994Assignees: Toyota Jidosha Kabushiki Kaisha, Toyo Aluminum Kabushiki KaishaInventors: Hirohisa Miura, Kunihiko Imahashi, Yasuhiro Yamada, Hirohumi Michioka, Jun Kusui, Akiei Tanaka
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Patent number: 5372780Abstract: Aluminium alloys are described which after suitable processing can be used to produce lithographic printing plates of improved stoving resistance. The alloys consist es",Vially of at least 99.00% by weight of aluminium, from 0.02 to 0.15% by weight in total of zirconium and/or hafnium and from 0.05 to 0.25% by weight of manganese, with the remainder being incidental impurities. Improved stoving resistance is particularly shown with 0.02 to 0.08% zirconium and from 0.05 to 0.15% manganese, especially when stoving takes place at 240.degree. C. or above.Type: GrantFiled: July 15, 1992Date of Patent: December 13, 1994Assignee: Alcan International LimitedInventors: Peter K. F. Limbach, Graeme J. Marshall, Ricky A. Ricks
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Patent number: 5368658Abstract: The present invention provides high strength, heat resistant aluminum-based alloys having a composition represented by the general formula: Al.sub.a M.sub.b X.sub.cwherein:M is at least one metal element selected from the group consisting of V, Cr, Mn, Fe, Co, Ni, Cu, Zr, Ti, Mo, W, Ca, Li, Mg and Si;X is at least one metal element selected from the group consisting of Hf, Nb, and Ta; anda, b and c are atomic percentages falling within the following ranges:50.ltoreq.a.ltoreq.95, 0.5.ltoreq.b.ltoreq.35 and 0.5.ltoreq.c.ltoreq.25, the aluminum-based alloy being in an amorphous state, microcrystalline state or a composite state thereof. The aluminum-based alloys possess an advantageous combination of properties of high strength, heat resistance, superior ductility and good processability which make then suitable for various applications.Type: GrantFiled: February 19, 1993Date of Patent: November 29, 1994Assignees: Yoshida Kogyo K.K., Tsuyoshi MasumotoInventors: Tsuyoshi Masumoto, Akihisa Inoue, Katsumasa Odera, Masahiro Oguchi
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Patent number: 5362341Abstract: A method of producing aluminum can sheet having high strength and low earing characteristics comprises providing an aluminum alloy ingot and then hot rolling the ingot in a single-stand hot reversing mill to produce a first intermediate gauge sheet. The first intermediate gauge sheet is then cold rolled to produce a second intermediate gauge sheet. This second intermediate gauge sheet is passed through a heat source as a single web so that the second intermediate gauge sheet is continuously annealed. After heating, the second intermediate gauge sheet is quenched and coiled again. Finally, the coiled second intermediate gauge sheet is cold rolled again to produce the final gauge aluminum can sheet having high strength and low earing characteristics.Type: GrantFiled: January 13, 1993Date of Patent: November 8, 1994Assignee: Aluminum Company of AmericaInventors: Scott L. Palmer, Robert E. Sanders, W. Bryan Steverson, Lyndon Morgan
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Patent number: 5362340Abstract: A method of producing aluminum can sheet having low earing characteristics. An aluminum alloy ingot is provided and is heated to a temperature between about 527.degree. to 571.degree. C. (980.degree. to 1060.degree. F.). After this, the ingot is hot rolled in a single-stand reversible hot mill to produce an intermediate gauge sheet. The intermediate gauge sheet is then cold rolled to produce a final gauge aluminum can sheet having low eating characteristics.Type: GrantFiled: March 26, 1993Date of Patent: November 8, 1994Assignee: Aluminum Company of AmericaInventors: Marilyn Daly, Scott L. Palmer, Robert E. Sanders, Jr., W. Bryan Steverson, Lyndon Morgan
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Patent number: 5350468Abstract: A process for producing amorphous alloy materials having high toughness and high strength from various alloy powders, thin ribbons or bulk materials consisting of an amorphous phase by heating them to a temperature at which intermetallic compounds or other compounds are not produced. During this heating, fine crystal grains consisting of a supersaturated solid solution made of a main alloying element and additive elements and having a mean grain diameter of 5 nm to 500 nm are precipitated and uniformly dispersed in a volume percentage of 5 to 50% throughout an amorphous matrix. In the process, when deformation, pressing or other working is simultaneously conducted with the heating, consolidation or combining of the resultant alloy materials can also be effected in the same production procedure. The amorphous alloy used in the production process preferably comprises Al, Mg or Ti as a main element and, as additive elements, rare earth elements and/or other elements.Type: GrantFiled: September 2, 1992Date of Patent: September 27, 1994Assignees: Tsuyoshi Masumoto, Akihisa Inoue, Yoshida Kogyo K.K.Inventors: Tsuyoshi Masumoto, Akihisa Inoue