With Ageing, Solution Treating (i.e., For Hardening), Precipitation Hardening Or Strengthening Patents (Class 148/682)
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Patent number: 6482276Abstract: A copper alloy with excellent punchability, comprising 0.2 to 0.35 wt % of Cr, 0.1 to 0.5 wt % of Sn, and 0.1 to 0.5 wt % of Zn, the balance being made of Cu and unavoidable impurities, wherein, in a Cu matrix, a precipitation phase A of Cr or a Cr compound of 0.1 to 10 &mgr;m in maximum diameter, is provided, at a density in number of 1×103 to 3×105/mm2, and a precipitation phase B of Cr or a Cr compound of 0.001 to 0.030 &mgr;m in maximum diameter, is provided, at a density in number that is 10 times or more of that of the precipitation phase A.Type: GrantFiled: April 10, 2001Date of Patent: November 19, 2002Assignee: The Furukawa Electric Co., Ltd.Inventors: Takao Hirai, Yoshimasa Ohyama, Takayuki Usami
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Patent number: 6478902Abstract: The method is used to fabricate pure copper sputter targets. It includes first heating a copper billet to a temperature of at least 500° C. The copper billet has a purity of at least 99.99 percent. Then warm working the copper billet applies at least 40 percent strain. Cold rolling the warm worked copper billet then applies at least 40 percent strain and forms a copper plate. Finally, annealing the copper plate at a temperature above about 250° C. forms a target blank. The target blank has equiaxed grains having an average grain size of less than 40 &mgr;m. The grains of the target blank have (111), (200), (220) and (311) orientations with the amount of the grains having each of the orientations being less than 50 percent.Type: GrantFiled: December 5, 2000Date of Patent: November 12, 2002Assignee: Praxair S.T. Technology, Inc.Inventors: Holger Koenigsmann, Alfred Snowman, Shailesh Kulkarni
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Publication number: 20020139459Abstract: A method of manufacturing the rolled copper foil by a process which comprises hot rolling an ingot repeating cold rolling and annealing alternately, and finally cold rolling the work to a foil, the annealing immediately preceding the final cold rolling being performed under conditions that enable the annealed recrystallized grains to have a mean grain diameter of not greater than 20 &mgr;m, the reduction ration of the final cold rolling being beyond 90.0%, whereby excellent flex fatigue property and adequate softening property are achieved.Type: ApplicationFiled: December 4, 2001Publication date: October 3, 2002Applicant: Nippon Mining & Metals Co., Ltd.Inventors: Takaaki Hatano, Yoshio Kurosawa
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Patent number: 6458222Abstract: A brass for forging which has an apparent Zn content of 37 to 50 wt % and contains 0.5 to 7 wt % Sn. The brass has a microstructure of at least an &agr; phase and a &ggr; phase at a temperature of 300 to 550° C. and has crystal grain sizes which are made fine. A process for preparing brass involving making the crystal grain size of brass material fine and plastic working the brass material at 300 to 550° C.Type: GrantFiled: May 8, 2000Date of Patent: October 1, 2002Assignee: Toto Ltd.Inventors: Ryuji Matsubara, Nobuyuki Ashie, Katsuaki Nakamura
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Patent number: 6436206Abstract: The present invention relates to copper base alloys containing tin, phosphorous, iron, and zinc and having phosphide particles uniformly distributed through the alloy matrix, which phosphide particles include fine and coarse phosphide particles. The alloy is produced using a process which comprises casting a copper base alloy consisting essentially of tin in an amount greater than about 1.5 wt. % up to 4.0 wt. %, phosphorous from 0.01 to 0.20 wt. %, iron from 0.01 to 0.80 wt. %, zinc in an amount greater than 1.0 wt. % up to 8.0 wt. %, and the balance essentially copper; homogenizing at least once for at least one hour at from 1000° F. to 1450° F.; rolling to final gauge including at least one process anneal for at least one hour at 650° F. to 1200° F. followed by slow cooling, preferably at a rate in the range of 20° F. to 200° F. per hour; and stress relief annealing at final gauge for at least one hour at 300° F. to 600° F.Type: GrantFiled: April 1, 1999Date of Patent: August 20, 2002Assignee: Waterbury Rolling Mills, Inc.Inventor: Ashok K. Bhargava
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Patent number: 6395110Abstract: The present invention provides a copper-based alloy characterized by: having a composition of 58.0 to 63.0% by weight of Cu, 0.5 to 4.5% by weight of Pb, 0.05 to 0.25% by weight of P, 0.5 to 3.0% by weight of Sn, 0.05 to 0.30% by weight of Ni, and the balance of Zn and inevitable impurities; having a texture uniformly fragmented to acquire excellent corrosion resistance and hot working property; having undergone a given drawing work and heat treatment to acquire excellent mechanical properties including tensile strength, proof strength and elongation; and having internal stress thoroughly removed to excel in stress-corrosion cracking resistance.Type: GrantFiled: October 7, 1999Date of Patent: May 28, 2002Assignee: Kitz CorporationInventors: Tadao Mizoguchi, Kozo Itoh, Kazuaki Yajima
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Publication number: 20020011288Abstract: The present invention provides a copper-based alloy characterized by: having a composition of 58.0 to 63.0% by weight of Cu, 0.5 to 4.5% by weight of Pb, 0.05 to 0.25% by weight of P, 0.5 to 3.0% by weight of Sn, 0.05 to 0.30% by weight of Ni, and the balance of Zn and inevitable impurities; having a texture uniformly fragmented to acquire excellent corrosion resistance and hot working property; having undergone a given drawing work and heat treatment to be exalted in mechanical properties including tensile strength, proof strength and elongation; and having internal stress thoroughly removed to excel in stress-corrosion cracking resistance.Type: ApplicationFiled: October 7, 1999Publication date: January 31, 2002Inventors: TADAO MIZOGUCHI, KOZO ITOH, KAZUAKI YAJIMA
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Publication number: 20010052377Abstract: A copper alloy with excellent punchability, comprising 0.2 to 0.35 wt % of Cr, 0.1 to 0.5 wt % of Sn, and 0.1 to 0.5 wt % of Zn, the balance being made of Cu and unavoidable impurities, wherein, in a Cu matrix, a precipitation phase A of Cr or a Cr compound of 0.1 to 10 &mgr;m in maximum diameter, is provided, at a density in number of 1×103 to 3×105/mm2, and a precipitation phase B of Cr or a Cr compound of 0.001 to 0.030 &mgr;m in maximum diameter, is provided, at a density in number that is 10 times or more of that of the precipitation phase A.Type: ApplicationFiled: April 10, 2001Publication date: December 20, 2001Inventors: Takao Hirai, Yoshimasa Ohyama, Takayuki Usami
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Patent number: 6197134Abstract: A process for producing a fcc metal consisting of copper having random orientations comprising cross rolling which is performed to achieve a total draft of at least 20% with the rolling axis being offset at 15° or more in each pass to a total offset of at least 90°, and subsequent full annealing which is accompanied by recrystallization, the fcc metal satisfying the following relationships: I(200)/I(111)≦2.3 and I(220)/I(111)≦1.0, where I(111), I(200) and I(220) are the integral intensities of the (111), (200) and (220) faces, respectively, of crystal faces as measured by X-ray diffractiometry.Type: GrantFiled: September 29, 1999Date of Patent: March 6, 2001Assignee: Dowa Mining Co., Ltd.Inventors: Toshihiro Kanzaki, Fumi Tanabe
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Patent number: 6153031Abstract: A higher order beryllium-nickel-copper alloy a process for making the same, and an article of manufacture comprising the alloy, the alloy being represented by the formula (0.15-0.5% Be)+(0.40-1.25% Ni)+(0-0.25% Sn)+[0.06-1% Zr) and/or (0.06-1% Ti)], the balance copper, where the sum of % Zr and % Ti is generally within a range of 0.06% and 1%, the alloy being characterized by improved electrical conductivity, bend formability and stress relaxation resistance without sacrificing strength.Type: GrantFiled: September 7, 1999Date of Patent: November 28, 2000Assignee: Brush Wellman, Inc.Inventors: John C. Harkness, Shelley J. Wolf
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Patent number: 6136104Abstract: A copper alloy which is adapted for use as terminals and connectors, which comprises from 0.1 wt % to less than 0.5 wt % of Ni, from larger than 1.0 wt % to less than 2.5 wt % of Sn, from larger than 1.0 wt % to 15 wt % of Zn, and further comprises from at least one element selected between from 0.0001 wt % to less than 0.05 wt % of P and from 0.0001 wt % to 0.005 wt % of Si, and the balance being Cu and inevitable impurities The alloy has an electrical conductivity of 90% or below relative to a maximum electrical conductivity of an annealed copper alloy and an area ratio of insoluble matters such as precipitates is 5% or below.Type: GrantFiled: July 7, 1999Date of Patent: October 24, 2000Assignee: Kobe Steel, Ltd.Inventors: Motohisa Miyafuji, Hirofumi Arai, Koya Nomura
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Patent number: 6063217Abstract: High strength, high conductivity copper alloy wire and a cable therefrom and method for manufacturing same, wherein the copper alloy contains chromium from 0.15-1.30%, zirconium from 0.01-0.15% and the balance essentially copper. The alloy wire is heat treated, cold worked to an intermediate gage, heat treated, cold worked to final gage, and finally heat treated.Type: GrantFiled: April 9, 1998Date of Patent: May 16, 2000Assignee: Fisk Alloy Wire, Inc.Inventors: Joseph Saleh, Eric Fisk
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Patent number: 6001196Abstract: A higher order beryllium-nickel-copper alloy a process for making the same, and an article of manufacture comprising the alloy, the alloy being represented by the formula (0.15-0.5% Be) +(0.40-1.25% Ni)+(0-0.25% Sn)+[(0.06-1% Zr) and/or (0.06-1% Ti)], the balance copper, where the sum of % Zr and % Ti is generally within a range of 0.06% and 1%, the alloy being characterized by improved electrical conductivity, bend formability and stress relaxation resistance without sacrificing strength.Type: GrantFiled: October 28, 1996Date of Patent: December 14, 1999Assignee: Brush Wellman, Inc.Inventors: John C. Harkness, Shelley J. Wolf
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Patent number: 5993574Abstract: A higher order beryllium-nickel-copper alloy a process for making the same, and an article of manufacture comprising the alloy, the alloy being represented by the formula (0.15-0.5% Be)+(0.40-1.25% Ni)+(0-0.25% Sn)+[(0.06-1% Zr) and/or (0.06-1% Ti)], the balance copper, where the sum of % Zr and % Ti is generally within a range of 0.06% and 1%, the alloy being characterized by improved electrical conductivity, bend formability and stress relaxation resistance without sacrificing strength.Type: GrantFiled: November 7, 1997Date of Patent: November 30, 1999Assignee: Brush Wellman, Inc.Inventors: John C. Harkness, Shelley J. Wolf
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Patent number: 5916386Abstract: A copper base alloy consisting essentially of tin in an amount from about 1.0 to 11.0% by weight, phosphorous in an amount from about 0.01 to 0.35% by weight, iron in an amount from about 0.01 to about 0.8% by weight, and the balance essentially copper, including phosphide particles uniformly distributed throughout the matrix, is described. The alloy is characterized by an excellent combination of physical properties. The process of forming the copper base alloy described herein includes casting, homogenizing, rolling, process annealing and stress relief annealing.Type: GrantFiled: July 28, 1998Date of Patent: June 29, 1999Assignee: Waterbury Rolling Mills, Inc.Inventor: Ashok K. Bhargava
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Patent number: 5824167Abstract: In the present invention, in order to minimize the amount of deformation due to heat treatment, the content of Be is lowered than the conventional ones, and the decrease in strength accompanied by decreasing Be, is compensated by dissolving strengthening of Si and Al, and precipitation strengthening of intermetallic compounds NiBe and CoBe. Further, by precipitating such intermetallic compounds, workability and heat resistance are also improved simultaneously and aging treatment conditions are also made flexible. Thus, according to the present invention, a beryllium-copper alloy having excellent strength, workability and heat resistance, can be provided economically, and particularly as for aging materials, users' burden can be markedly decreased.Type: GrantFiled: October 30, 1995Date of Patent: October 20, 1998Assignee: NGK Insulators, Ltd.Inventors: Shuhei Ishikawa, Hiroyuki Hiramitsu, Yoshihisa Ishiguro, Kazumasa Yashiro
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Patent number: 5814168Abstract: High-strength, high-electroconductivity copper alloys are produced by preparing an ingot of a copper alloy containing 0.05-0.40 wt % Fe, 0.05-0.40 wt % Ni, 0.01-0.30 wt % P, and optionally a total of 0.03-0.50 wt % of either Sn or Zn or both and a total of 0.05-0.50 wt % of at least one element of Ag, B, Mn, Cr, Si, Ti or Zr, with the balance being Cu and incidental impurities, heating the ingot to 800.degree. to 950.degree. C. and hot working it by a reduction ratio of 50% or more, quenching the hot worked material from 600.degree. C. or above to 300.degree. C. or below at a cooling rate of at least 1.degree. C./sec, heat treating the quenched material at 380.degree. to 520.degree. C. for 60 to 600 minutes without performing cold working, and cold working and heat treating it at 450.degree. C. or below, to precipitate an Fe--Ni--P system intermetallic compound in the Cu matrix as uniform and fine grains not larger than 50 nanometers.Type: GrantFiled: June 13, 1996Date of Patent: September 29, 1998Assignee: Dowa Mining Co., Ltd.Inventors: Koichi Hatakeyama, Akira Sugawara, Toshihiro Kanzaki
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Patent number: 5798008Abstract: A method for producing copper alloy materials for molds for continuous steel casting and molds as produced by the method. The molds are highly resistant to thermal fatigue and are hardly cracked. To produce the materials, cast ingots of a copper-based chromium-zirconium alloy comprising from 0.2 to 1.5% by weight of Cr and from 0.02 to 0.2% by weight of Zr are heated at between 900.degree. C. and 1000.degree. C. for 30 minutes or longer and then rolled, while hot, at a reduction ratio of 60% or more to be at 850.degree. C. or higher at which the hot rolling is finished , and immediately after the hot rolling, these are rapidly cooled to 400.degree. C. or lower at a cooling rate of 10.degree.C./sec or more, and then aged at between 400.degree. C. and 520.degree. C. for from 1 hour to 5 hours.Type: GrantFiled: July 15, 1996Date of Patent: August 25, 1998Assignee: Mitsubishi Materials CorporationInventors: Keishi Nogami, Masato Koide, Takashi Morimoto, Yutaka Koshiba
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Patent number: 5653826Abstract: A high strength steel composition comprising ferrite and martensite/banite phases, the ferrite phase having primarily vanadium and mobium carbide or carbonitride precipitates, is prepared by a first rolling above the austenite recrystallization temperature; a second rolling below the anstenite recrystallization temperature; a third rolling between the Ar.sub.3 and Ar.sub.1 transformation points, and water cooling to below about 400.degree. C.Type: GrantFiled: June 7, 1995Date of Patent: August 5, 1997Assignee: Exxon Research and Engineering CompanyInventors: Jayoung Koo, Michael John Luton
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Patent number: 5391243Abstract: A wire for electric railways comprises a copper alloy which consists essentially, by weight percent, of 0.1 to 1.0% Cr, 0.01 to 0.3% Zr, and 10 ppm or less O, and if required, further contains at least one element selected from the group consisting of 0.01 to 0.1% Si and 0.001 to 0.05% Mg, with the balance being Cu and inevitable impurities. The wire is manufactured by hot working a copper alloy billet having the above composition, immediately quenching the hot worked billet to prepare an element wire, cold working the element wire at least once, and subjecting the cold worked element wire to aging treatment.Type: GrantFiled: October 28, 1993Date of Patent: February 21, 1995Assignees: Mitsubishi Materials Corporation, Railway Technical Research InstituteInventors: Motoo Goto, Shizuo Kawakita, Yoshiharu Mae, Takuro Iwamura, Yutaka Koshiba, Kenji Yajima, Syunji Ishibashi, Hiroki Nagasawa, Atsushi Sugahara, Sumihisa Aoki, Haruhiko Asao
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Patent number: 5354388Abstract: A process for producing the beryllium-copper alloy comprises the steps of casing a beryllium-copper alloy composed essentially of 1.00 to 2.00% by weight of Be, 0.18 to 0.35% by weight of Co, and the balance being Cu, rolling the cast beryllium-copper alloy, annealing the alloy at 500.degree. to 800.degree. C. for 2 to 10 hours, then cold rolling the annealed alloy at a reduction rate of not less than 40%, annealing the cold rolled alloy again at 500.degree. to 800.degree. C. for 2 to 10 hours, thereafter cold rolling the alloy to a desired thickness, and subjecting the annealed alloy to a final solid solution treatment. The beryllium-copper alloy obtained by this producing process is also disclosed, in which an average grain size is not more than 20 .mu.m, and a natural logarithm of a coefficient of variation of the grain size is not more than 0.25.Type: GrantFiled: June 11, 1993Date of Patent: October 11, 1994Assignee: NGK Insulators, Ltd.Inventors: Keigo Nojiri, Takaharu Iwadachi
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Patent number: 5322575Abstract: A copper base alloy for terminals that is superior in all aspects of tensile strength, spring limits, conductivity, and stress relaxation characteristics can be produced by a process repeating the cycles consisting of hot-rolling, cold-rolling and annealing, in which process an ingot is prepared by melting and casting an alloy containing 1.0-3.0 wt % Ni, 0.02-0.15 wt % P. 0.5-2.0 wt. % Sn and, as an optional component, 0.01-2.0 wt % Zn, with the balance being Cu and incidental impurities, and with the ratio of weight percentages of Ni to P being within the range of 10-50%.Type: GrantFiled: March 24, 1993Date of Patent: June 21, 1994Assignees: Dowa Mining Co., Ltd., Yazaki Corporation, Nihon Bell Parts Co., Ltd.Inventors: Takayoshi Endo, Kenji Takenouchi, Mikio Nishihata, Toshio Asano, Akira Sugawara
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Patent number: 5149499Abstract: A cooper base alloy and process having high electrical conductivity. An alloy consists of from 0.005 to 0.15% by weight Niobium, about 0.005 to 0.15% by weight Iron, 0.01 to 0.05% by weight phosphorus, and the balance copper.Type: GrantFiled: September 6, 1991Date of Patent: September 22, 1992Assignee: Poongsam CorporationInventors: Young G. Kim, Han I. Yoo, Sang K. Han, Deung Y. Lee