From Polyene Compound Patents (Class 162/169)
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Patent number: 6468393Abstract: Speckle-patterned paper is produced on the paper machine without the use of printing techniques by first preparing speckle-forming material and then introducing this into a contrasting color papermaking furnish. Paper is then made from the speckle-containing furnish in the normal way. The speckle-forming material is produced either by agglomerating a mixture of papermaking fibre, particulate pigment and, preferably, a latex or other binder or by dry comminution of cellulose fibre aggregates in the form of paper or entangled fibre clumps.Type: GrantFiled: November 21, 1997Date of Patent: October 22, 2002Assignee: Arjo Wiggins Fine Papers LimitedInventors: Edward Charles Small, Brian Edward Evans
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Publication number: 20020148576Abstract: Provided herein are compositions useful for inhibiting the formation of gummy residues on equipment in processing operations which liberate tiny adhesive particles having a tendency to agglomerate into larger particles and/or films. The compositions comprise a complex or adduct formed from styrene/methacrylic acid copolymer and calcium ions. The compositions according to the invention may be added to a processing system at any point, either upstream or downstream from the location at which residues are formed. Compositions according to the invention may be applied by spray techniques.Type: ApplicationFiled: February 5, 2001Publication date: October 17, 2002Inventors: Duy T. Nguyen, Rodney W. Parr
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Patent number: 6440269Abstract: A paper-based sheet for wallcoverings that is made in a single pass on a standard paper making machine is described. The sheet has a print side and a barrier side and is made from softwood pulp in an amount of about 15% to about 40% by dry weight; hardwood pulp in an amount of about 30% to about 55% by dry weight; and, mineral filler in an amount of about 15% to about 30% by dry weight. A first coating is applied to the print side of the sheet in an amount of about 5 to about 20 gm/m2 dry weight. A second coating is applied to the barrier side of the sheet in an amount of about 2.5 to about 10 gm/m2 dry weight. The advantage is a strong, durable, alkaline wallcovering that is less expensive to produce, and provides a smooth print surface.Type: GrantFiled: December 6, 1999Date of Patent: August 27, 2002Assignee: Domtar, Inc.Inventor: Harold Freeburn
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Publication number: 20020100567Abstract: A process for sizing paper comprising adding to an aqueous suspension containing cellulosic fibers, and optional fillers, an anionic or cationic sizing dispersion, and a sizing promoter comprising a cationic organic polymer having an aromatic group; and an anionic polymer having an aromatic group selected from step-growth polymers, polysaccharides and naturally occurring aromatic polymers, wherein the sizing dispersion and sizing promoter are added separately to the aqueous suspension.Type: ApplicationFiled: August 6, 2001Publication date: August 1, 2002Inventors: Erik Lindgren, Sten Frolich, Michael Persson
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Patent number: 6425977Abstract: A method of manufacturing a bearing material, a bearing material and a bearing having the bearing material on a strong backing are described.Type: GrantFiled: April 16, 2001Date of Patent: July 30, 2002Assignee: Glacier Garlock Bearings, Inc.Inventors: Julie Ann McDonald, John Edward Wheatley, Anthony Latkowski, David Geoffrey Hall
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Publication number: 20020096271Abstract: A process for de-watering lime mud in a Krafft pulping process is described. The process includes an improvement which comprises adding an effective water-removal rate enhancing amount of an alkyleneamine to the lime mud prior to filtration. The preferred alkyleneamine is ethyleneamine, that is, an amine having at least one —(CR2-CR2-NH—)— unit wherein each R is independently is H or an alkyl (straight-chain, branched, or cyclic) group of from about 1 to about 10 carbon atoms. Ethyleneamines include ethylenediamine, diethylenetriamine, triethylenediamine, triethylenetetramine, tetraethylenepentamine, piperazine, aminoethylpiperazine, and ethyleneamine mixtures such as mixtures of ethyleneamine oligomers having an average molecular weight of about 200-500.Type: ApplicationFiled: September 25, 2001Publication date: July 25, 2002Inventor: Alan P. Croft
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Publication number: 20020096290Abstract: A process for sizing paper comprising adding to an aqueous suspension containing cellulosic fibers, and optional fillers, a sizing dispersion comprising a polymer having an aromatic group, and a sizing promoter comprising a polymer having an aromatic group, wherein the sizing dispersion and the sizing promoter are added separately to the aqueous suspension.Type: ApplicationFiled: August 6, 2001Publication date: July 25, 2002Inventors: Erik Lindgren, Sten Frolich, Michael Persson, Barbro Magnusson
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Patent number: 6416628Abstract: A method of producing dimensionally stable paper and/or paperboard products by treating a hygroreactive cellulosic fiber matrix with a hydrophobic sizing agent solution; and drying the treated fibers using heat and/or pressure so that the hydrophobic sizing agent penetrates the fiber matrix making it hydrophobic.Type: GrantFiled: December 21, 1998Date of Patent: July 9, 2002Assignee: International Paper CompanyInventors: Yan C. Huang, Murray Bruce Lyne, Clifford Kent Hatcher, Gurudatta D. Nadkarni
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Publication number: 20020069989Abstract: Such latex-dispersions used in paper bonding formulations make it possible to obtain acceptable COBB values, even with printing and writing papers or wrapping papers obtained from recycled or de-inked mechanical pulps.Type: ApplicationFiled: June 2, 1997Publication date: June 13, 2002Inventors: BRUNO FERET, ISABELLE BETREMIEUX
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Patent number: 6387213Abstract: A printing paper is provided having the appearance of uncoated paper and improved printability properties approaching those of coated papers. Also provided are a surface treatment formulation having a variable viscosity and a method for producing a printing paper having the appearance of uncoated paper and the improved printability properties approaching those of coated papers.Type: GrantFiled: August 25, 1999Date of Patent: May 14, 2002Assignee: Mohawk Paper Mills, Inc.Inventor: Thomas D. Ruch
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Publication number: 20020053413Abstract: A papermaking method and a composition which utilize, as a drainage aid, a water soluble hydrophobically associative polymer which is a copolymer prepared from monomers which include a hydrophobic ethylenically unsaturated monomer, and one or more of a nonionic ethylenically unsaturated monomer, a cationic ethylenically unsaturated monomer, and an anionic ethylenically unsaturated monomer.Type: ApplicationFiled: December 6, 2000Publication date: May 9, 2002Inventors: Huashi T. Zhang, John C. Harrington
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Patent number: 6365001Abstract: A method for making a nonwoven reinforcing may for vinyl floor coverings is described. A base mat is formed from a mixture of glass fibers and polymeric binder fibers and/or powder, follows by treatment with a second water-based polymeric binder composition. The mat has been found to be highly satisfactory as a substrate for compressible vinyl floor covering.Type: GrantFiled: May 25, 2001Date of Patent: April 2, 2002Assignee: Owens Corning Fiberglas Technology, Inc.Inventors: Gregory S. Helwig, Hendrik Jongetjes, Paul Geel
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Patent number: 6365000Abstract: The present invention is a method of making an ultra soft, multi-ply tissue from non-premium furnish using wet press technology and the product produced thereby.Type: GrantFiled: December 1, 2000Date of Patent: April 2, 2002Assignee: Fort James CorporationInventors: John H. Dwiggins, Frank D. Harper, Galyn A. Schulz, Brian J. Schuh, Michael S. Heath, T. Philips Oriaran
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Patent number: 6322665Abstract: Methods for making high wet performance webs. A polymeric anionic reactive compound is applied heterogenously to a cellulosic fibrous web followed by curing of the compound to crosslink the cellulose fibers. The resulting tissue has high wet resiliency, high wet strength, and a high wet:dry tensile strength ratio.Type: GrantFiled: October 25, 1999Date of Patent: November 27, 2001Assignee: Kimberly-Clark CorporationInventors: Tong Sun, Jeffrey D. Lindsay
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Patent number: 6290815Abstract: The invention relates to a paper sheet containing grit particles giving it, in use, a high abrasion resistance. It is characterized in that it contains grit particles coated in a non-abrasive material, in particular in a polymer. According to the invention, the particles are chosen from alumina, silica, boron nitride, silicon carbide, titanium carbide, tungsten carbide, zirconium oxide, cerium oxide, glass and ceramic particles, or mixtures thereof. The invention also relates to the laminates containing it, as well as to the processes for manufacturing the sheets and the laminates.Type: GrantFiled: September 3, 1997Date of Patent: September 18, 2001Assignee: Arjo Wiggins S.A.Inventors: Henri Magnin, Claude Perrin, Pierre Caulet
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Publication number: 20010018957Abstract: A papermaking stock and a method for improving the retention of pulp fines, mineral fillers, dispersed wood resin, and/or synthetic hydrophobic stickies and cellulose fibers in a cellulosic fiber sheet, employs dendrimeric polymers for increasing the retention of fines, fillers, dispersed hydrophobic particles, and cellulosic fibers. The application in the paper industry provides a means of (1) increasing the retention of fillers in paper and decreasing the loss of filler materials in white water waste from papermaking; (2) increasing the retention of cellulosic fines and fibers in the paper-making process; increasing drainage on the paper machine; and (3) removing a significant fraction of the wood resin, plastics, and stickies from the process stream thus enabling a greater extent of reuse of filtrates and, hence, less effluents from mills, fewer problems from wood resins such as deposit formation, loss of strength of product, and contamination of product with dirt particles.Type: ApplicationFiled: April 4, 2001Publication date: September 6, 2001Inventors: Lawrence Harvey Allen, Marco Savio Polverari
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Patent number: 6280572Abstract: A method of producing dimensionally stable paper and/or paperboard products by treating a hygroreactive cellulosic fiber matrix with a hydrophobic sizing agent solution; and drying the treated fibers using heat and/or pressure so that the hydrophobic sizing agent penetrates the fiber matrix making it hydrophobic.Type: GrantFiled: December 21, 1998Date of Patent: August 28, 2001Assignee: International Paper CompanyInventors: Yan C. Huang, Murray Bruce Lyne, Clifford Kent Hatcher, Gurudatta D. Nadkarni
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Patent number: 6267843Abstract: A method for making a nonwoven reinforcing may for vinyl floor coverings is described. A base mat is formed from a mixture of glass fibers and polymeric binder fibers and/or powder, follows by treatment with a second water-based polymeric binder composition. The mat has been found to be highly satisfactory as a substrate for compressible vinyl floor covering.Type: GrantFiled: December 16, 1998Date of Patent: July 31, 2001Assignee: Owens Corning Fiberglas Technology, Inc.Inventors: Gregory S. Helwig, Hendrik Jongetjes, Paul Geel
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Patent number: 6258211Abstract: Producing high temperature-resistant technical paper, wherein fibers are mixed with a wet paper material pulp and then technical paper is produced from the pulp by the removal of water from the pulp and resulting compacting of the paper material, it is proposed that the fibers added to the wet pulp are fibers which have been cut and previously thermally pre-shrunk so that in practical use under high temperature conditions the finished technical paper experiences a low degree of thermal shrinkage of less than 1%.Type: GrantFiled: August 31, 1999Date of Patent: July 10, 2001Assignee: Culimeta-Alfons Cuylits-Gesellschaft für Textilglas Technologie m.b.H. & Co. KGInventor: Uwe Becker
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Patent number: 6231659Abstract: The sizing agents are mixtures of alkenyl succinic anhydrides in which the alkenyl groups have in the range of about 6 to about 40 carbon atoms, and in which at least 97 wt % of the alkenyl groups are bifurcated on the alpha carbon atom into two branches neither of which has less than two carbon atoms. Other characteristics of the mixture are that (1) 20-50% of the bifurcated alkenyl groups have only one methyl or methylene substituent and no other side chain, and the remainder of such bifurcated groups have two straight chain branches (no side chain) emanating from the alpha carbon atom, (2) at least 3 alkenyl succinic anhydrides that differ in the number of alkenyl carbon atoms are each present in at least 5 wt % in the mixture, (3) no more than about 50 wt % of the alkenyl succinic anhydrides is any given alkenyl succinic anhydride or mixture of isomers having the same number of carbon atoms in their alkenyl groups, (4) the average number of carbon atoms in the alkenyl groups is ca.Type: GrantFiled: June 24, 1999Date of Patent: May 15, 2001Assignee: Albemarle CorporationInventors: Patrick C. Hu, Valerie N. LeGloahec, Michelle R. Free, Dixie E. Goins
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Patent number: 6224714Abstract: Synthetic polymers having hydrogen bonding capability and one or more polysiloxane moieties are capable of providing two distinct properties to paper products, such as tissues, which properties heretofore have been imparted through the use of at least two different molecules. The backbone of these synthetic polymers is based on modified vinyl polymers, such as polyvinyl alcohol, polyacrylamides and polyacrylic acids.Type: GrantFiled: November 24, 1999Date of Patent: May 1, 2001Assignee: Kimberly-Clark Worldwide, Inc.Inventors: Wen Zyo Schroeder, Daniel Arthur Clarahan, Mike Thomas Goulet, Thomas Gerard Shannon
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Patent number: 6210475Abstract: The present invention is directed to paper sizing emulsions, a method of making sizing emulsions, a method of sizing paper products, such as paper and board, and paper or board made using the method and the sizing emulsions of the invention. The paper sizing emulsions of the invention contains at least one sizing agent and a cationic liquid hydroxyalkylated starch that is pumpable and at least partially degraded. Typically, before dilution for mixing with the sizing material, the starch exists as a liquid in water and contains solids in an amount up to about 30 percent by weight, and has a viscosity of up to about 30,000 cps. The starch is diluted with water, before emulsifying the sizing agent to reduce the solids to an amount suitable for emulsification, and used to emulsify the sizing agent. The resulting emulsion can then be used to size paper and board.Type: GrantFiled: September 3, 1999Date of Patent: April 3, 2001Assignee: Bayer CorporationInventors: David L. Dauplaise, Robert Joseph Proverb, Katarzyna Komarowska
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Patent number: 6165320Abstract: This invention relates to a method of sizing paper comprising use of a sizing composition comprising: (a) at least one thermoplastic resin selected from the group consisting of thermoplastic rosins having an acid number less than 50, thermoplastic hydrocarbon resins, thermoplastic polyamides and thermoplastic amide waxes; (b) starch; and (c) surfactant. The sizing takes place substantially in the absence of alum or other aluminum based fixing agents.Type: GrantFiled: June 28, 1999Date of Patent: December 26, 2000Assignee: Hercules IncorporatedInventors: Robert Bates, Gerard J. Broekhuisen, Edwin R. Hensema, Malcolm J. Welch
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Patent number: 6149768Abstract: A method of making a bonded and creped type absorbent paper web that has improved bulk to peel strength characteristics includes steps of (a) printing a low density pattern of a bonding material onto a first and a second side of a paper web; and (b) in no particular sequence with respect to step (a), printing a high density pattern of a bonding material onto the first side of the paper web. Steps (a) and (b) are performed so that the high density pattern of bonding material penetrates into the paper web by a distance that is about 166 to about 470 percent of the distance by which the low density pattern of bonding material penetrates into the web. This results in a web that has superior bulk and peel strength characteristics. Another characteristic of the product is that it has a visible depression pattern in one surface, but not the other surface, which creates an attractive aesthetic effect and has functional benefits as well.Type: GrantFiled: April 8, 1998Date of Patent: November 21, 2000Assignee: Kimberly-Clark Worldwide, Inc.Inventor: Richard R. Hepford
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Patent number: 6077392Abstract: A printing paper is provided having the appearance of uncoated paper and improved printability properties approaching those of coated papers. Also provided are a surface treatment formulation having a variable viscosity and a method for producing a printing paper having the appearance of uncoated paper and improved printability properties approaching those of coated papers.Type: GrantFiled: November 3, 1997Date of Patent: June 20, 2000Assignee: Mohawk Paper Mills, Inc.Inventor: Thomas D. Ruch
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Patent number: 6074528Abstract: A printing paper is provided having the appearance of uncoated paper and improved printability properties approaching those of coated papers. Also provided are a surface treatment formulation having a variable viscosity and a method for producing a printing paper having the appearance of uncoated paper and improved printability properties approaching those of coated papers.Type: GrantFiled: November 3, 1997Date of Patent: June 13, 2000Assignee: Mohawk Paper Mills, Inc.Inventor: Thomas D. Ruch
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Patent number: 6066235Abstract: A mat containing highly machine direction oriented (90% or greater), discontinuous reinforcement fibers, is produced on inclined wire or rotary paper making machinery. Fibers are first uniformly dispersed in an aqueous medium containing thickeners and wetting agents. In one embodiment, antifoaming agents are also added to prevent floating fibers which entangle and reduce orientation. Thermoplastic fibers or particles may also be included. Stock is brought into an open headbox in a flow pattern which allows the fibers to decelerate before approaching the porous suction belt (wire). As the fibers approach the suction belt, the fibers begin to turn and align in the streamline so as to present one end toward the suction wire. The leading ends of the fibers are gripped by the moving belt which drags the fibers out of the dispersion stock in a straight line. The porous mat produced may be dried and bonded through hot air, heat and/or pressure, or chemical binders.Type: GrantFiled: April 3, 1998Date of Patent: May 23, 2000Assignee: E. I. du Pont de Nemours and CompanyInventor: Stephen P. Scheinberg
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Patent number: 6051107Abstract: A process for preparing sized paper which incorporates in the paper a size composition containing polymer latex, wherein the polymer contained in the polymer latex is anionic polymer having properties selected from the group consisting of T.sub.G about -15.degree. C. to about 50.degree. C. and acid number about 30 to about 100, and wherein the polymer latex has a zeta potential of from about -25 to about -70 millivolts over the pH range of about 5 to about 9. A preferred process has the steps: a) providing an aqueous pulp suspension; b) sheeting and drying the aqueous pulp suspension to obtain paper; c) treating the paper by applying to at least one surface of it the size composition containing polymer latex and starch; and d) drying the paper to obtain sized paper. Preferred anionic polymers are copolymers of monomers comprising styrene or substituted styrene, alkyl acrylate or methacrylate and ethylenically unsaturated carboxylic acid.Type: GrantFiled: April 28, 1997Date of Patent: April 18, 2000Assignee: Hercules IncorporatedInventor: Daniel Felix Varnell
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Patent number: 6033524Abstract: A method for increasing retention and drainage of filling components in a paper making furnish in a paper making process comprising the steps of: making a slurry of filling components, treating the slurry with from about 0.003% to about 2.0% by weight based on total solids of a phenolic enhancer to form a pretreated filling components slurry, adding to the furnish the pretreated slurry and adding to the furnish from about 0.003 to about 0.5% by weight based on total solids in the slurry of a polymeric flocculent, whereby retention and drainage of filling components in the paper making furnish is increased. A preferred enhancer is a condensate of phenol and formaldehyde and preferred flocculants contain acrylamide, methacrylamide, and/or N-vinylformamide.Type: GrantFiled: November 24, 1997Date of Patent: March 7, 2000Assignee: Nalco Chemical CompanyInventors: Przemyslaw Pruszynski, Regina Jakubowski, John R. Armstrong, Scott W. Rosencrance
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Patent number: 5939562Abstract: The invention relates to alkene-substituted cyclic carboxylic acid anhydrides which are formed from the reaction of a cyclic carboxylic acid anhydride, including succinic anhydride, and an olefin blend. The olefin blend is made up of internal linear and branched olefins and linear and/or branched .alpha.-olefins, in which blend the olefins contain 13-25 carbon atoms. The alkene-substituted cyclic carboxylic acid anhydride can be used for the preparation of an ASA sizing agent suitable for paper sizing.Type: GrantFiled: June 19, 1997Date of Patent: August 17, 1999Assignee: NESTE OYInventors: Mika Kapanen, Salme Koskimies, Jaana Rantanen, Erkki Halme, Raija Savolainen
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Patent number: 5906712Abstract: The present invention provides a process for producing a fiber reinforced composite which contains the reinforcing fibers uniformly dispersed therein and therefore has uniformity of strength. The process comprises;preparing an aqueous slurry which comprises reinforcing fibers, water-soluble organic polymers A charged in water and particulate organic polymers,adding thereto water-soluble organic polymers B charged opposite to said organic polymers A in water to flocculate the solid components in said aqueous slurry, andthen removing aqueous medium and molding.Type: GrantFiled: June 20, 1994Date of Patent: May 25, 1999Assignee: Unitika Ltd.Inventors: Keiichi Asami, Kiyotaka Nakanishi, Hideki Takahashi, Ritsuko Shidei, Azusa Yamagata, Yoshiaki Echigo
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Patent number: 5902453Abstract: A printing paper is provided having the appearance of uncoated paper and improved printability properties approaching those of coated papers. Also provided are a surface treatment formulation having a variable viscosity and a method for producing a printing paper having the appearance of uncoated paper and improved printability properties approaching those of coated papers.Type: GrantFiled: September 30, 1996Date of Patent: May 11, 1999Assignee: Mohawk Paper Mills, Inc.Inventor: Thomas D. Ruch
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Patent number: 5853634Abstract: A building material and a method for its manufacture is provided wherein cellulosic, polymeric and acid wastes are treated and combined to produce a building panel which demonstrates low weight, high strength and good fire resistance.Type: GrantFiled: August 13, 1997Date of Patent: December 29, 1998Inventor: Orville M. Ontkean
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Patent number: 5824191Abstract: The present invention provides a process for making a paper based product which comprises a paper sheet, an aqueous latex binder and a release agent comprised of an emulsion of lecithin and a fatty acid or derivative thereof. In one embodiment, the process comprises first preparing a slurry of a cellulosic pulp and a polymeric latex binder, and then breaking the stability of the latex so that the polymer particles of the latex are able to be deposited on the fibers of the cellulosic pulp. An emulsion comprised of lecithin and a fatty acid or derivative thereof is added during the process. The addition can be to the slurry, or to the web which is formed when the slurry is drained of liquid. The web is then dried to provide the paper based product. In a preferred embodiment, a slurry of cellulosic pulp is first drained of liquid to form a web, with the polymeric latex binder and emulsion being applied to the web prior to drying.Type: GrantFiled: March 28, 1997Date of Patent: October 20, 1998Assignee: FiberMark Filter & Technical Products, Inc.Inventor: Homan B. Kinsley, Jr.
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Patent number: 5800676Abstract: A method for manufacturing a mineral fiber panel which comprises uniformly dispersing in water 60 to 90% by weight of a mineral fiber, 2 to 19% by weight of an organic binder, 1 to 20% by weight of an inorganic microfiber, 0.5 to 3% by weight of a flocculant and 0.5 to 10% by weight of a thermally expansible resin fine particle which has a diameter after expansion of not less than 0.03 mm but less than 3.0 mm, the expansion degree of the above diameter being at least 3 times, and which has an expansion-starting temperature of 50.degree. to 105.degree. C., as the composition components, to prepare a slurry, and thereafter subjecting the slurry to wet forming and then to drying. The above production process enables the enhancement of productivity and the mineral fiber panel obtained by the above production process is light in weight and excellent in sound-absorbing qualities and fireproof properties.Type: GrantFiled: August 22, 1997Date of Patent: September 1, 1998Assignee: Nitto Boseki Co., Ltd.Inventors: Kazuyoshi Koike, Hidetoshi Kojima
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Patent number: 5800675Abstract: Provided is a process for making a paper based product which comprises first preparing a slurry of a cellulosic pulp, a particulate binder, and an emulsion comprised of lecithin and a fatty acid or derivative thereof. This slurry is then drained of liquid to form a web, with the web being dried to provide the paper based product. The preferred polymeric binder is a hydrolyzed polyvinyl alcohol powder, which binder can be present in the final dried product in amounts of up to about 20 weight percent or more. The use of the emulsion comprised of lecithin and a fatty acid or derivative thereof permits a web containing such a high amount of sticky polymeric binder to be dried at high temperatures, without the web sticking to the drying cans generally used in commercial processes. The process of the present invention thereby permits one to efficiently prepare such a paper based product using conventional, commercial papermaking machinery.Type: GrantFiled: June 7, 1995Date of Patent: September 1, 1998Inventor: Homan B. Kinsley, Jr.
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Patent number: 5785813Abstract: An efficient and effective method for treating tissue making stock to make soft tissues involves adding a softening agent to a first papermaking furnish of short fibers, such as eucalyptus fibers. A second papermaking furnish of long fibers, such as softwood fibers, is blended with the short fiber furnish. Thereafter, wet strength agents and/or dry strength agents are added to the blended furnish. The treated furnish is then fed to a headbox and processed into soft tissue in any suitable manner.Type: GrantFiled: February 24, 1997Date of Patent: July 28, 1998Assignee: Kimberly-Clark Worldwide Inc.Inventors: Michael John Smith, Vinay Kumar Rao, Gary Lee Shanklin
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Patent number: 5759347Abstract: Binders for papercoating slips which permit uniform printability contain a polymer prepared by the seed procedure and comprisingfrom 1 to 49% by weight of a polymer seed A) having a glass transition temperature of from -80.degree. to +25.degree. C. and based on esters of acrylic acid or methacrylic acid, andfrom 51 to 99% by weight of ethylenically unsaturated monomers B), from 10 to 100% by weight of which monomers are butadiene,the polymer seed A being added before or during the polymerization of the ethylenically unsaturated monomers.Type: GrantFiled: August 5, 1996Date of Patent: June 2, 1998Assignee: BASF AktiengesellschaftInventors: Hartmann F. Leube, Thomas Wirth, Dirk Lawrenz
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Patent number: 5690789Abstract: Speckle-patterned paper is produced on the paper machine without the use of printing techniques by first preparing speckle-forming material and then introducing this into a contrasting color papermaking furnish. Paper is then made from the speckle-containing furnish in the normal way. The speckle-forming material is produced either by agglomerating a mixture of papermaking fiber, particulate pigment and, preferably, a latex or other binder or by dry comminution of cellulose fiber aggregates in the form of paper or entangled fiber clumps.Type: GrantFiled: May 4, 1995Date of Patent: November 25, 1997Assignee: The Wiggins Teape Group LimitedInventors: Edward Charles Small, Brian Edward Evans
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Patent number: 5690787Abstract: A method of forming a polymer-reinforced paper which includes preparing an aqueous suspension of fibers, at least about 50 percent, by dry weight, of which are cellulosic fibers; distributing the suspension on a forming wire; removing water from the distributed suspension to form a paper; and treating the paper thus formed with a polymer-reinforcing medium which contains a bulking agent to give the polymer-reinforced paper. The treatment of the paper is adapted to provide in the polymer-reinforced paper from about 15 to about 70 percent, by weight, of bulking agent, based on the dry weight of the cellulosic fibers in the paper. Alternatively, the bulking agent can be added to a polymer-reinforced paper after it has been formed. In certain embodiments, the bulking agent is a polyhydric alcohol. In other embodiments, the bulking agent is a polyethylene glycol having a molecular weight in the range of from about 100 to about 1,500.Type: GrantFiled: March 25, 1996Date of Patent: November 25, 1997Assignee: Kimberly-Clark Worldwide, Inc.Inventors: David Paul Hultman, Donald David Watson, Edward Walter Heribacka
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Patent number: 5589034Abstract: A method of forming a polymer-reinforced paper which includes preparing an aqueous suspension of fibers, at least about 50 percent, by dry weight, of which are cellulosic fibers; distributing the suspension on a forming wire; removing water from the distributed suspension to form a paper; and treating the paper thus formed with a polymer-reinforcing medium which contains a bulking agent to give the polymer-reinforced paper. The treatment of the paper is adapted to provide in the polymer-reinforced paper from about 15 to about 70 percent, by weight, of bulking agent, based on the dry weight of the cellulosic fibers in the paper. Alternatively, the bulking agent can be added to a polymer-reinforced paper after it has been formed. In certain embodiments, the bulking agent is a polyhydric alcohol. In other embodiments, the bulking agent is a polyethylene glycol having a molecular weight in the range of from about 100 to about 1,500.Type: GrantFiled: May 31, 1995Date of Patent: December 31, 1996Assignee: Kimberly-Clark CorporationInventors: David P. Hultman, Donald D. Watson, Edward W. Heribacka
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Patent number: 5466336Abstract: The present invention provides a process for making a paper based product which comprises a paper sheet, an aqueous latex binder and a release agent comprised of an emulsion of lecithin and a fatty acid or derivative thereof. In one embodiment, the process comprises first preparing a slurry of a cellulosic pulp and a polymeric latex binder, and then breaking the stability of the latex so that the polymer particles of the latex are able to be deposited on the fibers of the cellulosic pulp. An emulsion comprised of lecithin and a fatty acid or derivative thereof is added during the process. The addition can be to the slurry, or to the web which is formed when the slurry is drained of liquid. The web is then dried to provide the paper based product. In a preferred embodiment, a slurry of cellulosic pulp is first drained of liquid to form a web, with the polymeric latex binder and emulsion being applied to the web prior to drying.Type: GrantFiled: August 9, 1993Date of Patent: November 14, 1995Assignee: CPG Holdings Inc.Inventor: Homan B. Kinsley, Jr.
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Patent number: 5407535Abstract: The invention relates to a new lottery ticket paper for the manufacture of different kinds of lottery tickets, especially of the "instant lottery ticket" type, and a method of manufacturing said tickets. The lottery ticket paper is characterized in that it comprises a colored, opaque base paper coated on both sides with a composition comprising at least one pigment, a filler, a binder solution, and optionally viscosity regulating agents and some kind of security element. The lottery ticket paper is protected against see-through and various kinds of forgery. It is an environmentally pleasing, nonexpensive and from the production-technical point of view suitable alternative to existing foil-laminated lottery ticket papers.Type: GrantFiled: May 24, 1993Date of Patent: April 18, 1995Assignee: ABTumba BrukInventor: Erik Hansell
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Patent number: 5405501Abstract: Multi-layered tissue paper webs comprising chemical softener compositions and binder materials are disclosed. The multi-layered tissue webs are useful in the manufacture of soft, absorbent paper products such as facial tissues and/or toilet tissues. The multi-layered tissue paper products contain a chemical softening composition comprising a mixture of a quaternary ammonium compound and a polyhydroxy compound. Preferred quaternary ammonium compounds include dialkyl dimethyl ammonium salts such as di(hydrogenated)tallow dimethyl ammonium chloride, di(hydrogenated)tallow dimethyl ammonium methyl sulfate. Preferred polyhydroxy compounds are selected from the group consisting of glycerol, sorbitols, polyglycerols having a weight average molecular weight of from about 150 to about 800, polyoxyethylene glycols and polyoxypropylene glycols having a weight average molecular weight from about 200 to 4000.Type: GrantFiled: June 30, 1993Date of Patent: April 11, 1995Assignee: The Procter & Gamble CompanyInventors: Dean V. Phan, Paul D. Trokhan
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Patent number: 5393379Abstract: A web of nonwoven fibers and thermoplastic matrix polymer is provided that is capable of yielding improved physical properties for articles molded from the web. Also provided are the aqueous dispersion to produce the web and the dried web as a laminate so that it can be molded into shaped articles. The web in addition to the fibers and thermoplastic matrix polymer has a chemically modified thermoplastic polymer. This material can be added to the web by direct addition to the aqueous dispersion or by presence in a mat binder which is applied to the web. Generally, the amount of the chemically modified thermoplastic material present in the web is in the range of around 0.1 to 20 weight percent of the web. When the chemically coupled thermoplastic polymer is added as a mat binder, it can be accompanied by an electron donating organo coupling agent, a stabilizing agent such as one or more carboxylic acids and/or anhydrides which may be monocarboxylic, polycarboxylic aliphatic or cyclic.Type: GrantFiled: April 22, 1993Date of Patent: February 28, 1995Assignee: PPG Industries, Inc.Inventor: Luciano M. Parrinello
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Patent number: 5391225Abstract: An alkenylsuccinic acid emulsion sizing agent, wherein said alkenylsuccinic acid emulsion sizing agent has a solid concentration of at least 25% by weight, and comprises active components comprising an alkenylsuccinic acid present in an amount of at least 50 parts by weight, per 100 parts by weight of the total active components in the alkenylsuccinic acid emulsion sizing agent; and, wherein said alkenylsuccinic acid is obtained by dispersing a product prepared by reacting a branched inner olefin having from 9 to 18 carbon atoms with maleic anhydride in water using an amphoteric acrylamide-series polymer.Type: GrantFiled: October 13, 1993Date of Patent: February 21, 1995Assignee: Mitsubishi Oil. Co., Ltd.Inventors: Hatanaka Shigeto, Hideto Umekawa
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Patent number: 5362614Abstract: Disclosed is a photographic printing paper support which comprises a raw paper having polyolefin resin coats on the both sides, with the raw paper being made from pulp slurry containing an epoxidized higher fatty acid amide and/or an alkylketene dimer and a cationic substance other than epoxidized higher fatty acid amides by the addition thereinto in an early stage of the preparation and further containing anionic colloidal silica and/or anionic bentonite added in a late stage of the preparation after controlling the pulp concentration so as to range from 0.1 to 1.5%.Type: GrantFiled: February 14, 1994Date of Patent: November 8, 1994Assignee: Fuji Photo Film Co., Ltd.Inventors: Shinichiro Serizawa, Shigehisa Tamagawa
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Patent number: 5332473Abstract: An alkaline paper comprising polymeric vesiculated granules, calcium carbonate, and fibrous materials. Alkaline papers made according to the present invention have improved physical properties.Type: GrantFiled: November 9, 1992Date of Patent: July 26, 1994Assignee: ICI Canada Inc.Inventor: Loreen D. Ferguson
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Patent number: 5294300Abstract: An expanded graphite sheet of very large mechanical strength can be produced by compressing a graphite expanded to not less than 50 times as large as normal state in average to be 0.02 to 0.3 g/cm.sup.3 in bulk density, grounding the compressed graphite particles, preparing a slurry together with a fibrilated aramid pulp fiber, and applying a wet process to the slurry to be prepared into a paper.Type: GrantFiled: July 20, 1992Date of Patent: March 15, 1994Assignee: Toyo Tanso Co., Ltd.Inventor: Toshiki Kusuyama
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Patent number: 5277763Abstract: The present invention relates to a basic composition for the manufacture of a product in sheet form, obtained in particular by the wet method, of the type comprising a mixture of a polymer powder of given granulometry and of fibers, characterized in that it comprises a preferably intimate mixture of:a) at least one elastomer powder, of granulometry less than about 500 .mu.m, called elastomer fine dust, andb) fibers of length less than about 10 mm, selected from the group composed of natural fibers, inorganic fibers and mixtures thereof.Type: GrantFiled: August 12, 1992Date of Patent: January 11, 1994Assignee: Arjo Wiggins S.A.Inventors: Bernard Debaux, Pierre Fredenucci