Abstract: A phosphorus modified latex composition useful in the coating of substrates with inorganic fillers. A latex particle having phosphorus groups intimately bound to the particle's surface formed by the emulsion polymerization of a latex with a phosphorus compound. Also a method of preparing a composite sheet and a paper coating latex with the phosphorus modified latex is provided.

Abstract: Sheet composites containing asbestiform crystalline calcium M phosphate fibers wherein M is a metal cation selected from the group consisting of sodium and lithium, and mixtures thereof, are useful as a replacement or substitute for asbestos sheets in applications where fibrous materials are needed.

Abstract: Non-woven, fibrous composite materials in sheet form are disclosed which are particularly useful as dimensionally stable backings and interliners for surface covering laminates. A method of producing these sheets and laminates is also disclosed.

Abstract: The present invention is concerned with a new method for preparing a fibrous product containing cellulosic fibers and which is useful, in particular in lieu of asbestos, in the field of covering panels such as for instance wall and floor covering panels. Said method comprises the formation of a sheet according to a paper-making technique from an aqueous suspension comprising:slightly refined cellulosic fibers having a Schopper-Riegler degree comprised between 15 and 35, in association, if the occasion arises, with non-cellulosic fibers,an inorganic flocculating agent,an organic polymeric binder, andan inorganic filler,and the squeezing of the wet drained sheet under a linear load of 5 to 35 kg/cm, then the drying of the squeezed sheet.The sheet thus obtained is, if the occasion arises, subjected to a mechanical and/or chemical complementary treatment.The invention is also concerned with the sheet obtained according to this method, as a new industrial product.

Abstract: Sheet type felt material comprising 5-20 wt % glass fibers, 40-80 wt % cellulose fibers, 5-25 % binder and 3-20 wt % asphalt. The felt is made on conventional felt making equipment and may be used as siding or roofing underlayment or as facer for foam insulating boards.

Abstract: An antimicrobial additive is incorporated into the binding agent of a heavy-duty, kraft-type paper having the characteristics of substantial density, air impermeability, and improved printability. The antimicrobial additive migrates from within the binding agent onto the paper fibers to substantially eliminate growth of micro-organisms thereon.

Abstract: Resin coated papers having improved properties especially edge penetration are made using an alkyl ketene dimer neutral size, a wet strength resin and an anionic polyelectrolyte to control the streaming potential of the papermaking stock during manufacture of the paper. Advantageously a supplementary size especially an epoxidized fatty acid amide is also used.

Abstract: Paper of improved properties is produced from pulp in which filler is selectively loaded within the fiber lumens by agitating a suspension of pulp and filler until the fiber lumens become loaded with filler, separating the residual suspended filler from the loaded fibers and vigorously washing the pulp until substantially all of the filler on the external surfaces of the fibers is removed.

Abstract: Polymer, co-polymer and/or elastomer containing paper is manufactured for a wide variety of end uses. The paper is remarkably homogeneous and retains its porosity even when it contains large quantities of polymer, co-polymer or elastomer. The latex and the fibrous slurry are mixed at the wet end in conjunction with a polyelectrolyte bridging agent, the bridging agent having a cationic charge and the latex and fibrous material having an anionic charge. In this way, the latex particles in their substantially original size become linked with the fibrous material by means of the intermediate bridging agent and without the latex undergoing any substantially coagulation or precipitation.

Abstract: The present invention relates to a method for preparing a fibrous sheet by paper-making means, according to which the flocculating agent is introduced in the aqueous suspension containing the basic mixture chosen from the group constituted by (i) the fibers alone when there is no non-binding mineral filler, and (ii) the fibers and the non-binding mineral filler when said latter is present, before and after the introduction of the organic binder. It also concerns, as new industrial product, the sheet obtained according to this method. Finally, it relates to the application of said sheet particularly in the domain of coverings (as a replacement for asbestos) and printing-writing supports.

Abstract: A method for the production of a composite material in the form of a web, the material comprising fibres, a curable resin and expanded microspheres. A web of fibres and microspheres is formed, and the curable resin is added subsequently.

Abstract: New process, for preparing by means of a paper manufacturing technique, a thermoplastic sheet reinforced with cellulose fibres, wherein a thermoplastic powder and cellulose fibres are used in association, if necessary with other fibres, and consisting in (1) preparing an aqueous suspension from a base mixture (selected among (i) the fibres and the pulverulent thermoplastic substance when there is no non-binding mineral charge, and (ii) the fibres, the pulverulent thermoplastic substance and the non-binding mineral char harge when the latter is present), an organic binder and a flocculating agent, and with the resulting suspension, forming a sheet by wet process, which is then wrung and dried and (2) if necessary subjecting the resulting thermoplastic sheet to at least a complementary treatment, the weight ratio of pulverulent thermoplastic substance to fibres being between 0.3 and 95.

Abstract: Sheet type felt material and sheet type roofing material such as shingles and rolls made therefrom. The felt comprises 10-60 wt % glass fibers of varying lengths, 15-80 wt % cellulosic fiber and 5-25% binder. The roofing material is felt of the invention saturated with asphaltic saturant and coated with filled asphaltic coating material and conventional roofing granules.

Abstract: A composite paper particularly adapted for use as cover sheets in the production of gypsum wallboard, the paper being sufficiently porous to permit better drainage and more rapid drying in the production of the paper, and when applied to the surfaces of a gypsum slurry for forming wallboard, permits less heat to be utilized in the wallboard conversion, thereby saving energy in the board production required for drying the board. The paper comprises in weight percent:(A) cellulosic fibers in an amount of from about 65% to about 90% and preferably having a fiber freeness of from about 300 ml to about 550 ml Canadian Standard Freeness,(B) calcium sulfate as a filler in an amount of from about 10% to about 35%,(C) a binder in an amount from about 1% to about 31/2%,(D) a flocculant in an amount of from about 0.1% to about 0.2%,(E) a buffering agent in an amount from about 0.

Abstract: Disclosed is absorbent material composed of a consolidated blend of spurted polyolefin pulp, treated with an anionic or nonionic wetting agent substance having a molecular weight less than about 8000, and wood fluff pulp. The absorbent material exhibits a desirable combination of strength, rate of absorbency and total absorbency.

Abstract: A paper cover sheet material for use in the production of gypsum wallboard, the paper cover sheet material having excellent drainage, porosity and drying properties, and a wallboard product produced therefrom, the paper cover sheet material being produced from fibers comprising a major proportion of cellulose fibers and a minor proportion of mineral fibers, the paper composition additionally comprising a cellulose gel, a latex binder and a flocculating agent, thereby enabling the mineral fibers to be dispersed in an aqueous slurry without materially fracturing the fibers, and retaining the shot present in the mineral fibers without permitting the shot to be released and thereby to contaminate the papermaking equipment. The excellent porosity, drying properties and drainage of the paper permit the gypsum wallboard formed with the paper to be readily set and dried with reduced heat energy requirements.

Abstract: A new process for manufacturing sheets made of fibrous material containing latex is characterized in that the pulp containing the fibrous material is prepared in the following way:--adjustment of the pH between 4 and 5.5 and preferably between 4 and 4.5,--addition of an electrolyte, the polarity of which is of the opposite sign to that of the latex used,--addition of a foam inhibitor,--re-adjustment of the pH between 4 and 5.5, if necessary,--addition, preferably by injection, of latex,--second addition of an electrolyte having the same characteristics as indicated above,--possibly addition of resins (phenoplasts or aminoplasts),--re-adjustment of the pH to the previously indicated value, if necessary.The new sheets obtained by this process find use in the field of paper manufacture.

Abstract: Reinforced polymer composites having a uniform mix of fiber, polymer and binder and having good physical properties are prepared by forming dilute aqueous slurries of a solid heat fusible organic polymer, a reinforcing material and a bound charge latex binder.

Abstract: A carboxylated latex is added to an aqueous slurry of fibers to remove metal ions contained in solution. The water is removed to form a felt. The demetallized water removed during felt formation is recycled in a closed process water system. The carboxylated latex is formed by polymerizing an unsaturated carboxylic acid on a substantially surfactant free styrene-diene polymer latex.

Abstract: Flooring felt containing glass fibers, cellulosic fibers, synthetic fibers, particulate inorganic filler, latex binder and calcium hydroxide.

Abstract: A composite paper particularly adapted for use as cover sheets in the production of gypsum wallboard, the paper being sufficiently porous to permit better drainage and more rapid drying in the production of the paper, and when applied to the surfaces of a gypsum slurry for forming wallboard, permits less heat to be utilized in the wallboard conversion, thereby saving energy in the board production required for drying the board. The paper comprises in weight percent:(A) fibers in an amount of from about 65% to about 90% and having a fiber freeness of from about 350 to 550 ml. Canadian Standard Freeness,(B) a mineral filler in an amount from about 10% to about 35%,(C) a binder in an amount from about 1% to about 31/2%,(D) a flocculant in an amount of from about 2 to about 4 lb./ton, and(E) a sizing agent in an effective amount to prevent water penetration.

Abstract: A resin modified asbestos diaphragm is prepared by diluting a heat curable polyvinylidene fluoride homopolymer resin latex containing no more than about 5% resin solids with an aqueous solution containing about 4% to 5% sodium hydroxide. From about 6 to about 11 parts of asbestos fibers are then slowly added to this alkaline resin latex solution for each part of resin solids contained therein with agitation to produce a clear aqueous slurry of resin coated asbestos fibers. To this slurry is then added an aqueous solution of 10% to 15% sodium hydroxide to swell the asbestos fibers. The resulting slurry is deposited on a screen to form a diaphragm which is carefully dried and cured at elevated temperatures to complete the polymerization of the polyvinylidene fluoride resin and form a bonded resin coated asbestos fiber product that is dimensionally stable. Such resin modified asbestos diaphragms may be used in electrolytic cells for electrolyzing alkali metal halide solutions.

Abstract: Synthetic sheet material is resistant to decay by fungus and other microbial organisms and particularly useful in shoe construction, mulch papers and the like. The material comprises a uniform distribution of cellulose and optionally synthetic fiber within a matrix or binder and is formed from a furnish of the fibers; a metallic quinolinolate which lends the material decay resistant; a polymer colloid such as an acrylic latex which prevents the coagulation of the subsequently added elastomeric binder by the metallic quinolinolate; and a cationic polymer which acts as a retaining agent for the metallic quinolinolate in the synthetic sheet material.

Abstract: The properties of a fibrous substrate are improved by application of a composition comprising a hydrophilic air-curing polymer and a compound comprising at least two free radical polymerizable unsaturated groups. The composition can optionally contain in addition a latex of a thermoplastic polymer.

Abstract: The invention relates to a method for the manufacture of diaphragms of fibrous potassium titanate and an organic binder for electrochemical cells and has as the object to develop such a method in such a direction that it allows the manufacture of diaphragms which are relatively thin but have, at the same time, a sufficient long-term chemical and mechanical stability at high operating temperatures. According to the invention, provision is made for this purpose to apply potassium titanate, together with polytetrafluoroethylene and a styrene-butadiene copolymer, from a suspension, to a screen with a mesh width between about 0.1 and 0.4 mm. The diaphragms made by the method according to the invention are suitable particularly as cover layers in fuel cells with an alkaline electrolyte.

Abstract: Terpolymers of maleic anhydride, dicyclopentadiene, and a vinylcyclohexene, preferably 1-vinylcyclohexene-3, are highly effective paper sizing materials.

Abstract: Synthetic sheet material is resistant to decay by fungus and other microbial organisms and particularly useful in shoe construction where flexibility is required. The material comprises a uniform distribution of cellulose and optionally synthetic fiber within an acrylic elastomeric matrix or binder and is formed from a furnish of the fibers; a metallic quinolinolate which lends the material decay resistant; a polymer colloid such as an acrylic latex which prevents the coagulation of the subsequently added acrylic elastomeric binder by the metallic quinolinolate; and a cationic polymer which acts as a retaining agent for the metallic quinolinolate in the synthetic sheet material.

Abstract: A high temperature resistant compressible sheet material has a thickness of 0.001 to 1 inch and includes a crosslinked elastomer as a binder and high temperature staple fibers. A major amount of a particulate filler which has been chemically modified to coreact with the crosslinked elastomer is incorporated into the sheet material. The binder preferably has incorporated therein an addition polymerized silane coupling agent. The sheet material is fabricated according to papermaking techniques. The sheet material is useful in the fabrication of gasketing and in heat shields.

Abstract: A glass fiber filter mat possessing excellent wet strength which is in the form of a non-woven matrix of glass micro-fibers including polymer micro-bits derived, for example, from a non-brittle expanded, thermoplastic styrene polymer or a flexible foamed polyurethane, the micro-bits being substantially free of intact cells. Also included in the filter mat is a cobeat or intimate blend of cellulose fibers and the polymer micro-bits, which may additionally contain polyester fibers, as well as a combination of binders, viz., polyvinyl alcohol and a melamineformaldehyde resin.

Abstract: A process is described that results in the production of a hydrophilic air-drying polymer system suitable for increasing the inter-fiber bonding in a fibrous substrate material. The process comprises passing air through a monomer maintained at a temperature below about 30.degree. C., said monomer having at least two activated unsaturations, until a desired viscosity increase has been achieved.

Abstract: An air filtration mat formed from a mixture of certain proportions of glass micro-fibers, an intimate blend or cobeat of cellulose fibers and micro-bits of an expanded, non-brittle polystyrene, lower polyolefin, or flexible polyurethane, and an organic binding agent such as polyvinyl alcohol or aqueous acrylic or vinyl chloride polymer emulsions distributed uniformly throughout the glass micro-fibers and blend of cellulose fibers and micro-bits. The glass micro-fiber component is made up of an array of fibers having various dimensions, which are mixed in specific proportions. The filter mat may optionally contain fibers of a fiber-forming terephthalate polyester to enhance the wet strength of the web during processing.

Abstract: A sizing composition is provided for glass fibers to render the glass fibers more dispersible in aqueous solutions. The sizing composition has present an aqueous dispersion of cationic imidazoline; aliphatic, aromatic and/or polymeric ester; and polyethylene in an amount equivalent to an amount in the range of about 0.1 to about 1.5 weight percent of the aqueous sizing composition based on an approximately 30 percent active aqueous dispersion. The sizing composition may also contain, depending on the use, other components such as starch, lubricant, emulsifying agents, wetting agents, plasticizers, biocides and the like.

Abstract: A suspension of artificial mineral fibers and cellulosic fibers is dewatered during shaping on a wire. The sheet is thereafter pressed and dried. A latex emulsion binder is added to the mat after the mat has been partially dried to a solids content of 60 to 90%. The mat product has physical properties, including impression resistance, comparable to previously known asbestos-containing products.

Abstract: Disclosed are novel organic pigments adapted particularly for use as fillers for paper. The organic pigments are finely divided particles obtained by graft copolymerizing an ethylenically unsaturated monomer, such as styrene, onto a water-soluble cationic prepolymer in an aqueous solution and in the presence of a free-radical polymerization initiator.

Abstract: An improved process for forming a friction material having metal fibers evenly dispersed in the body of the material. The raw materials for production of the friction material are dispersed in an aqueous slurry. The slurry is formed into a sheet. This sheet is subsequently cured and cut to form brake pads and related friction materials.

Abstract: A transparent, non-stratified, three dimensional resin reinforced fibrous sheet and the process for its preparation is disclosed. A fibrous sheet is impregnated or coated with one or more tri or higher functional monomers that can be polymerized in-situ to form three dimensional polymer resins, in close contact with the fibrous material of the sheet. A transparentized fibrous sheet results which is resistant to water and alcohols, highly and evenly translucent and useful as tracing media vellum as well as a translucent base for sensitizing with reprographic coatings.

Abstract: A pulp insulated electric communications conductor in which the wood pulp fibers of the insulation are coated with an aqueous based cationic deposition aid polymer and then an aqueous based anionic latex polymer. In a process for applying a layer of insulating material to the conductor a slurry of wood pulp fibers is prepared to which first an aqueous based cationic deposition aid polymer is added and then an aqueous based anionic latex polymer is added, the resultant coated wood pulp fibers being applied to the conductor.

Abstract: A mica-filled glass fiber sheet which is smooth, of relatively low porosity, and dimensionally stable is described as is its method of manufacture. The sheet is prepared from a low-consistency aqueous slurry wherein the solids consist essentially of glass fibers, organic fibers, mica, and binder. Based on 100 parts by weight glass fibers, 3 to 15 parts by weight organic fibers, 30 to 100 parts by weight mica flakes, and 5 to 20 parts by weight organic binder are added to the water in preparing the furnish. In forming the sheet, this slurry or furnish is deposited onto a moving screen, the excess water is removed, and the wet laid sheet is dried and the binder set. In a subsequent operation, the sheet is saturated with a resin solution or latex.

Abstract: A fibrous sheet having a high strength and water resistance and having no resin specks on the surface can be produced by producing a sheet from a fiber slury by the known paper making process, to said fiber slurry being added a flocculate of chlorinated polymer latices which has a particle size of 100.mu.-500 .mu. and is prepared by heating said chlorinated polymer latices to a temperature of at least their minimum film-forming temperature and then adding a water soluble cationic polymer or a polyvalent metal salt with stirring. Examples of said chlorinated polymer latices are anionic polyvinyl chloride latex, polyvinylidene chloride latex or the combination thereof.

Abstract: An improved dimensionally stable backing web is disclosed, especially for resilient flooring product and linoleum, comprising cellulosic fiber, a binder, antioxidant, fungicide and glass fiber, as well as optionally dyes or pigments, surfactants and vulcanizing agents. Also optionally present are calcium silicate mineral fiber or synthetic fiber, such as polyolefin, polyester, nylon, acrylic or modacrylic fiber, a cellulose acetate or mixtures thereof. The binder can be a natural rubber or synthetic rubber latex or mixtures thereof. The synthetic rubber latex is preferably selected from the following: styrene-butadiene; carboxylated styrene-butadiene, polyacrylic ester, polyvinyl acetate; polyisobutylene, a copolymer formed from vinyl acetate monomers and acrylic acid; polychloroprene, acrylonitrile-butadiene or carboxylated acrylonitrile-butadiene; polyurethane; a copolymer of ethylene and vinyl acetate; or other elastomeric copolymers.

Abstract: Emulsion polymerization is carried out with reactive surfactants comprised of ring sulfonated maleate half esters of alkoxylated alkyl arylols.

Abstract: An improved method for manufacturing a magnet paper sheet which comprises: thoroughly mixing about 70-90 parts by weight of magnetoplumbite barium ferrite powder and/or magnetoplumbite strontium ferrite powder essentially consisting of particles of primary particle size of about 0.1-2 microns and of secondary particle size smaller than about 20 microns, an anionic synthetic latex containing about 1-10 parts by weight in dry weight of a synthetic rubber and/or a synthetic resin such as SBR, NBR, polyvinyl acetate and polyacrylate, about 2-10 weight % of a cationic organic polymer electrolyte such as polyamine and polyethyleneimine based on the amount of the synthetic rubber and/or resin, and more than about 5 parts by weight of pulp fibers together into a slurry; forming the slurry into a paper sheet; and magnetizing the paper sheet.

Abstract: This invention relates to defoamed compositions and processes for inhibiting foaming in a liquid system containing water. Maleic ester copolymers in admixture with a mineral oil are particularly useful in pulp and paper manufacturing applications. The defoamers of the invention are compositions comprising mineral oil and a polymer which is an alkyl ester of the reaction product of a maleic compound and a monoethylenically unsaturated monomer copolymerizable therewith.

Abstract: A sheet which is a composite of (A) from about 1 percent to about 30 percent of a water-dispersible fiber such as wood fiber, (B) from about 2 percent to about 30 percent of a film-forming, water-insoluble, organic polymer such as a copolymer of styrene and butadiene and (C) from about 60 percent to about 95 percent of a finely-divided, substantially water-insoluble, non-fibrous, inorganic filler such as magnesium hydroxide is prepared by steps comprising:(I) providing an aqueous dispersion of the fiber;(II) mixing therewith (A) the inorganic filler and (B) the organic polymer in the form of an ionically stabilized latex;(III) colloidally destabilizing the resulting mixture to form a fibrous agglomerate in aqueous suspension;(IV) distributing and draining the aqueous dispersion on a porous substrate such as a wire to form a wet web; and(V) drying the web.

Abstract: A non-woven glass fiber-containing sheet composed of a top layer of a mixture of glass fiber with other fiber and a back layer of a mixture of fiber other than glass fiber with polyvinyl chloride fiber or polyvinyl chloride latex flocculate is a suitable substrate for processing it into flooring, walling, roofing, etc. by impregnating it with a polyvinyl chloride sol to strengthen the sheet without exudation of the sol onto the back layer surface.

Abstract: A method for the manufacture of a sheet containing mineral fibers and binder. An aqueous suspension containing fibers and binder is formed into a layer. The layer is de-watered to form a wet sheet. Additional binder is applied evenly to the entire surface of the de-watered sheet. The sheet is then dried. The sheet may be compressed to an extent of 20% during drying.

Abstract: A fibrous product containing (a) a papermaking grade of pulp, (b) a structured particle latex having pH independent cationic groups bound at or near the particle surface and (c) a co-additive. The pulp is represented by unbleached softwood kraft. The latex is represented by a structured-particle latex having (a) a core of a copolymer of styrene and butadiene (b) an encapsulating layer of styrene, butadiene and vinylbenzyl chloride which is reacted with 2-(dimethylamino) ethanol to form quaternary ammonium groups. The co-additive is represented by a hydrolyzed polyacrylamide having a degree of polymerization of 5500. To an aqueous slurry of the pulp are added the latex and an aqueous solution of the co-additive, the resulting suspension is dewatered and dried by heating.

Abstract: A process for preparing a high strength composite by (A) mixing (1) an aqueous slurry of negatively charged, water-insoluble natural or synthetic fiber such as cellulose fiber, (2) a latex having a high density of pH independent cationic charges, such as sulfonium, bound at or near the particle surface, (3) a water-soluble, high molecular weight anionic polymer co-additive, such as a hydrolyzed polyacrylamide and optionally (4) conventional wet end additives; (B) draining water from the resulting aqueous suspension; (C) drying by heating.

Abstract: Disclosed herein is a composite, self-supporting, polyurethane foam sheet prepared by forming an aqueous dispersion of hydrophilic polyurethane foam particles with fibers to serve as a binder therefor, wet-layering the dispersion onto a supporting screen to form a sheet, and removing water from the sheet. If desired, a porous web, woven or non-woven, e.g. paper, cloth, etc., can be positioned on the screen with the dispersion being layered out onto the web to form a laminar composite structure. Whether in sheet form or as a laminar structure the product of the invention is formed rapidly and possesses a desirable soft or cushioning feel.

Abstract: A fibrous sheet bonded with a latex flocculate is produced by adding zinc white powders to a carboxyl modified anionic latex, adjusting the pH to at least 7, adding thereto a water soluble cationic polymer to obtain a latex flocculate, adding thus obtained flocculate to a fiber slurry and subjecting the fiber slurry to a known wet paper making process.