Abstract: A process for the production of carbon fibers comprising heat treating a starting material, melt spinning the resulting precursor pitch, infusibilizing the pitch fibers and carbonizing or graphitizing the infusibilized pitch fibers, characterized in that the starting pitch is obtained by heat treating coal tar and/or coal liquefaction pitch at a specific temperature and a specific hydrogen pressure or by mixing coal tar and/or coal liquefaction tar with at least one nucleus-hydrogenated hydrocarbon of 2-3 rings in a specific mixing ratio and then heat treating the resulting mixture at a specific temperature and a specific pressure. In one embodiment, this invention relates to the starting pitch and carbon fibers obtained by said process.

Abstract: A mesophase pitch having ellipsoidal molecules is produced by the polymerization reaction of an aromatic hydrocarbon containing at least two condensed rings in which the coupling polymerization constitutes at least 60% of the polymerization reactions.

Abstract: Disclosed is a process for producing high grade asphaltic materials from low grade bituminous materials and the improved products resulting therefrom. More particularly, there is disclosed a process utilizing a particular type of oxidation catalyst in preparing novel high quality paving grade asphalt cements and novel roofing grade asphalts from poor and marginal quality bituminous materials. Also, the process can be used to prepare novel superior quality asphaltic materials from good quality bituminous flux feedstocks. This process consists of catalytically oxidizing asphalt fluxes, for example, in a single or multi-stage oxidation, using the particular type of catalyst disclosed hereinafter in each stage to chemically modify the flux so that the resultant asphaltic material meets physical requirements necessary for a finished product possessing good temperature susceptibility characteristics.

Abstract: A homogeneous, optically anisotropic pitch used for the production of carbon materials is prepared from a starting oil comprising a substantially chloroform-insoluble matter-free oily or tarry substance. The starting oil is subjected to thermal cracking and polycondensation to form approximately 20-80% of optically anisotropic phase pitch.

Abstract: A process for producing optically anisotropic pitch containing 80% or more of an anisotropic phase. A starting material is pyrolytically polycondensed. Afterward, the material is maintained at a temperature of between 350.degree. and 400.degree. C. to precipitate a portion of the material rich in the anisotropic phase having a high specific gravity. This portion is separated and further heat treated.

Abstract: A process and a product of the process for preparing a pitch suitable for carbon artifact manufacture features a pitch having a weight content of between 80 and 100 percent toluene insolubles. The pitch is derived from a substantially deasphaltenated middle fraction of a feedstock, such as a coal distillate. The middle fraction is rich in 3, 4, 5 and 6 polycondensed aromatic rings. The pitch is characterized as being relatively free of impurities and ash.

Abstract: A low melting point, low molecular weight, heptane insoluble, 1,2,4-trichlorobenzene soluble mesophase pitch useful in carbon fiber spinning as such or as a plasticizer in a carbon fiber spinning composition is obtained by heating chrysene, triphenylene or paraterphenyl as well as mixtures thereof and hydrocarbon fractions containing the same, dissolving the resulting heat treated material with 1,2,4-trichlorobenzene, and separating the insolubles, and then contacting the 1,2,4-trichlorobenzene soluble fraction with a sufficient amount of heptane to precipitate the low melting point, low molecular weight mesophase pitch.

Abstract: A starting pitch for carbon fibers, obtained by mixing (1) a heavy fraction oil boiling at not lower than 200.degree. C. obtained at the time of steam cracking of petroleum with (2) wax and then heat treating the resulting mixture at a specified temperature and pressure thereby to obtain the starting pitch, the thus obtained starting pitch being heat treated to produce a precursor pitch which is melt spun, infusibilized, carbonized or graphitized to obtain the carbon fibers.

Abstract: A method of producing a pitch or a coke, comprising reacting an aromatic hydrocarbon with anhydrous AlCl.sub.3 and an acid salt of an organic amine which acid salt reduces the activity of the AlCl.sub.3, and is miscible with the AlCl.sub.3 to form a molten eutectic salt mixture reactive with the aromatic hydrocarbon.

Abstract: A method of producing carbon or graphite fibres from a pitch obtained from a steam cracking residue of a petroleum fraction which pitch has a .beta. resin content of from 2 to 40% by weight, comprises spinning the pitch into fibres at a temperature higher than the softening point, the fibres being treated to render them infusible and then subjecting the fibres to carbonization by heating, followed by graphitization if desired, characterized in that the treatment to infusibilize the fibres is controlled such that the resin content of the fibres does not exceed 30% by weight. The invention includes carbon and graphite fibres produced by the process.

Abstract: A process and a product of the process for preparing a pitch suitable for carbon artifact manufacture features a pitch having a weight content of between 80 and 100 percent toluene insolubles. The pitch is derived from a deasphaltenated middle fraction of a steam cracker tar feedstock. The middle fraction is rich in 2, 3, 4, and 5 polycondensed aromatic rings. The pitch is characterized as being relatively free of impurities and ash.

Abstract: A process for the preparation of modified pitches and low boiling aromatics and olefins is described. Waste plastic which consists of polymeric chains of olefins is subjected to a thermal treatment in the presence of high boiling aromatics. The modified pitches may be used for the production of carbon articles of high value.

Abstract: A process and a product of the process for preparing a pitch suitable for carbon artifact manufacture features a pitch having a weight content of between 80 and 100 percent toluene insolubles. The pitch is derived from a deasphaltenated middle fraction of a feedstock, such as a cat cracker bottom. The middle fraction is rich in 4, 5 and 6 polycondensed aromatic rings. The pitch is characterized as being relatively free of impurities and ash.

Abstract: A method of producing a highly reactive pitch fraction is disclosed. Coal-tar pitch is extracted with hot chloroform and the pitch solution treated with solid iodine. The solid reaction products are separated and, in the presence of chloroform, decomposed with an aqueous ammonia solution. Following separation of the aqueous phase and removal by distillation of the chloroform, there remains a highly reactive pitch fraction which can be converted into high-anisotropic carbon at low temperatures and in short coking times.

Abstract: A process for producing a carbon fiber includes the steps of heat treating a selected precursor material under high pressure, thereafter solvent extracting the treated precursor material to obtain mesophase pitch, spinning the mesophase pitch into at least one pitch fiber, thermosetting the pitch fiber, and carbonizing the pitch fiber to obtain the carbon fiber.

Abstract: A method is provided for producing cracked oil with a higher yield and coke having a higher fixed carbon content from petroleum heavy oil or tar sand bitumen or crude shale oil in a short time. This method is characterized by subjecting a petroleum heavy oil or tar sand bitumen or crude shale oil to heat treatment together with at least one additive selected from the group consisting of metal salts of dialkyldithiocarbamic acids, diaryldithiocarbamic acids, alkylxanthogenic acids, arylxanthogenic acids, dialkyldithiophosphoric acids, diaryldithiophosphoric acids, organic phosphoric acid esters, benzothiazoles and disulfides.

Abstract: A starting pitch for carbon fibers, obtained by (A) mixing (1) a heavy fraction oil boiling at not lower than 200.degree. C. obtained at the time of steam cracking of petroleum with (2) a hydrogenated oil selected from aromatic hydrocarbons of 2-10 rings in which the nuclei have been hydrogenated and specific fractions boiling at 160.degree.-650.degree. C. and containing such nuclei-hydrogenated hydrocarbons and then (B) heat treating the resulting mixed oil at 370.degree.-480.degree. C. and 2-50 Kg/cm.sup.2.G to obtain the starting pitch for carbon fibers.

Abstract: A starting pitch for carbon fibers, produced by heat treating at 400.degree.-500.degree. C. under a hydrogen pressure of at least 20 Kg/cm.sup.2.G (1) a heavy fraction oil boiling at not lower than 200.degree. C. obtained at the time of fluidized catalytic cracking of petroleum or (3) a mixture of the heavy fraction oil (1) with (2) a heavy fraction oil boiling at not lower than 200.degree. C. obtained at the time of steam cracking of petroleum, the pitch so produced being heat treated to make precursor pitch therein, melt spun, infusibilized and carbonized or further graphitized to obtain the carbon fibers.

Abstract: A traction fluid having a lubricant basestock comprising hydrogenated coal tar containing a saturated fraction having a major portion made up of multiring components of at least three rings and an aromatic fraction which comprises at least 12% by weight of said fluid and contains at least 50% by volume of multiring components.

Abstract: Raw petroleum coke is treated with a solvent to extract the soluble matter. The extracted matter is useful as coker feedstock, fuel, pitch binder, pitch precursor, impregnant and carbon black feedstock. The coke residue may be used without further treatment as a fuel or may be calcined for use in Hall aluminum cell anodes.

Abstract: Coal liquids are disclosed wherein the hydrogen of substantially all of the hydroxyl groups of the coal liquids have been replaced with C.sub.1 to C.sub.20 alkyl or acyl groups.

Abstract: Broadly stated, the present invention comprises: fluxing an isotropic carbonaceous pitch thereby rendering the pitch fluid. Next, the fluxed pitch is introduced into a heating zone where the temperature is maintained in the range of from about 350.degree. C. to about 450.degree. C., thereby resulting in the heat soaking of the fluxed pitch. In a continuous process, at least some of the fluxed pitch is simultaneously removed or drawn off from the heating zone and transferred to a cooling zone. The temperature in the cooling zone generally ranges from above the freezing point of the fluxed pitch to below the temperature in the heating zone, and in a particularly preferred embodiment is maintained at the boiling point of the organic liquid used to flux the pitch. Any solids suspended in the fluxed pitch after heat soaking and cooling are removed by filtering or the like.

Abstract: The present invention contemplates a process for treating an isotropic carbonaceous graphitizable pitch with an organic fluxing liquid to provide a fluid pitch which has suspended therein substantially all of the quinoline insoluble material in the pitch and which solid material is readily separable by filtering, centrifugation and the like. Thereafter, the fluid pitch is treated in at least two steps with an antisolvent compound, the sum total of which is sufficient to precipitate at least a substantial portion of the pitch, the amount of antisolvent employed in each step increasing from the first step to the last step. In a particularly preferred embodiment of the present invention, the fluid pitch is treated in two steps with an antisolvent compound with from 5% to 15% of the antisolvent compound being used in the first step and from 85% to 95% of the antisolvent compound being used in the second step.

Abstract: In a process for the manufacture of pitch foams in which pitches are expanded at elevated temperature by a porogenic agent in a mould, the pitch has a KS softening point of from 70.degree. to 210.degree. C. The initial pressure is such that, at the decomposition temperature of the porogenic agent, the external pressure is higher than the pressure which would normally exist within the pitch at the temperature of operation. After the decomposition of the porogenic agent the pressure is lowered to expand the pitch. The temperature may also be adjusted between the decomposition and decompression stages.These pitch foams can be used as floor coverings, as insulators or as surfaces for the collection of solar energy.Certain foams may be converted to carbon and graphite foams by a process of oxidation to render their surface infusible followed by carbonisation and, if desired, graphitisation.The carbon foams can be used as thermal insulation, as catalyst supports or as filters for corrosive products.

Abstract: An asphalt base stock comprising a solvent refined asphalt having a penetration less than 25 and low ductility mixed with an asphalt cement. The base stock has a low penetration, 25-45, but unexpected high ductility, 150+. The base stock is especially suited for emulsification. When mixed with soils and aggregates, as for road surfaces, the stabilized product exhibits a significant increase in bearing strength over comparable asphalt-emulsion pavements and hot-mix asphalt pavements.

Abstract: Coal liquids are rendered compatible with petroleum liquids by selective oxygen alkylation or oxygen acylation of weakly acidic protons such as phenolic and carboxylic functionalities by means of a phase transfer reaction. Phenolic and carboxylic functional substituents, which are very polar, are converted to relatively non-polar ethers and esters, respectively. The O-alkylation or O-acylation is carried out in a binary liquid phase solution (organic/water). A quaternary ammonium or phosphonium salt is reacted with alkali or alkaline earth base (caustic) to produce the corresponding quaternary ammonium or phosphonium base (an example of a phase transfer reagent). This quaternary base is non-nucleophilic and readily removes the phenolic and carboxylic protons, but does little else to the coal liquid molecules. After the removal of the weakly acidic protons by the quaternary base, the phenoxides and carboxylates which are produced then undergo O-alkylation or O-acylation.

Abstract: Increased solubility of heavy fractions of coal (e.g., coal liquefaction bottoms and coal solubilization bottoms) is obtained by oxygen-alkylation or oxygen-acylation of weakly acidic protons such as phenolic and carboxylic functionalities by means of a phase transfer reaction. Phenolic and carboxylic functional substituents, which are very polar, are converted to relatively nonpolar ethers and esters, respectively. The O-alkylation or O-acylation is carried out in a binary liquid phase solution (organic and water phases with a solid phase suspended in the medium). A quaternary ammonium or phosphonium salt is reacted with alkali or alkaline earth base to produce the corresponding quaternary ammonium or phosphonium base (an example of a phase transfer reagent). This quaternary base is non-nucleophilic and readily removes the phenolic and carboxylic protons but does little else to the coal structures.

Abstract: A process for preparing a pitch for carbon fiber by filtering a heavy pitch having a softening point of 150.degree.-200.degree. C. at a temperature of 250.degree.-300.degree. C. and further treating at the same temperature under reduced pressure.

Abstract: A process for the preparation of petroleum-derived binder pitch, comprising heat treating a mixture of both (1) a heavy fraction boiling at not lower than 200.degree. C. and being obtained by the steam cracking of petroleum such as naphtha and (2) a heavy fraction boiling at not lower than 200.degree. C. and being obtained by the catalytic cracking of petroleum such as gas oil.

Abstract: High quality carbon black forming material convertible with high yield into furnace black having a high abrasion resistance in rubber is prepared by dissolving pitch with conventional thinly liquid carbon black feed stock and mechanically separating suspended matter from the mixture obtained.

Abstract: The present invention contemplates a process for preparing a feedstock for carbon artifact manufacture comprising treating a carbonaceous pitch, which has at least a portion of the polycondensed aromatic oils normally present in the pitch removed, at temperatures in the range generally of from about 350.degree. C. to about 450.degree. C. and for times ranging from several minutes to about 10 hours. Optionally an isotropic carbonaceous pitch is heated at temperatures in the range of about 350.degree. to about 450.degree. C. while simultaneously vacuum stripping the pitch to remove at least a portion and generally greater than 40% of the aromatic oils in the pitch thereby simultaneously removing the aromatic oils from the pitch while conducting the heat treatment.

Abstract: This invention provides a method for solubilizing scrap rubber, or coal and scrap rubber mixtures, in a highly aromatic refinery petroleum solvent to produce homogeneous compositions which have a physical state ranging from flowable pitch-like consistency to asphaltic hardness at ambient temperatures. The products of the present invention are high quality rubberized pitch and asphalt compositions which have utility in applications as caulk, mastic, adhesive, sealant and road paving compositions.

Abstract: A low molecular weight, anisotropic pitch consisting of essentially 100 percent mesophase and suitable for spinning into continuous filaments can be prepared by passing an inert gas through an isotropic carbonaceous pitch at a rate of at least 4.0 scfh. per pound of pitch while heating the pitch at a temperature of from about 380.degree. C. to about 430.degree. C. to produce mesophase and simultaneously agitating the pitch so as to produce a homogeneous emulsion of the mesophase produced and the remaining non-mesophase portion of the pitch, said heating and agitation being continued until the pitch has been essentially completely converted to mesophase and the emulsion has been transformed into an essentially single phase system. When examined under polarized light, the pitches of the present invention are seen to consist of a single phase which is essentially completely anisotropic.

Abstract: An effective and regenerable oil adsorbent is obtained from a pitch-like substance formed by heat-treating a heavy hydrocarbon oil to such an extent that the volatile matter content thereof is about 10% by weight to about 60% by weight, preferably about 30 to about 50% by weight. By using this oil adsorbent, oil-removing purification treatment of oil-contaminated water can be effectively achieved with economical advantages.

Abstract: An improved process for preparing liquid-crystal containing pitches comprises extracting carbonaceous isotropic pitches with an organic solvent system to provide a solvent insoluble fraction which when heated for 10 minutes or less and to temperatures in the range of about 230.degree. C. to 400.degree. C. will upon polarized light microscopy examination of cooled samples display greater than 75% of an optically anisotropic phase.

Abstract: Asphalt compositions are provided containing a ductility improving amount of a refinery stream obtained in the form of a bottoms fraction from a thermofor catalytic cracking or fluid catalytic cracking operation.

Abstract: A product useful as a pour point depressant which comprises the asphaltene component of a thermally treated shale oil is disclosed, as is a process for making it, a method for using it and a concentrate and a composition containing it.

Abstract: This invention provides novel electrode formulations which consist of solid carbonaceous filler, binder pitch, and an additive selected from phosphorus-containing and boron-containing compounds such as phosphorous pentoxide and boric acid.

Abstract: This invention provides a novel asphalt composition suitable for use as a binder for carbon electrodes which consists essentially of a homogeneous blend of three organic materials comprising (1) a highly aromatic hydrocarbon solvent having a specific combination of physical properties and chemical constituency, (2) a benzene-soluble fraction of solvent-refined coal and/or solvent-refined wood, and (3) a benzene-insoluble fraction of solvent-refined coal and/or solvent-refined wood. The novel asphaltic compositions is characterized by low sulfur content and high binding strength, which are desirable properties for application as a carbon electrode binder.

Abstract: A process for increasing that fraction of an isotropic carbonaceous pitch which is capable of being thermally converted to an optically anisotropic carbonaceous pitch having less than 25 wt. % quinoline insolubles is described. Basically, the pitch is heated at elevated temperatures until spherules visible under polarized light begin to appear. Then heating is terminated and the pitch solvent extracted to provide a solvent insoluble fraction which is capable of being thermally converted to the optically anisotropic pitch.

Abstract: A process for the continuous production of petroleum-derived pitch comprising the steps of subjecting a heavy fraction boiling at not lower than 150.degree. C., the heavy fraction being obtained by the steam cracking of petroleum-derived hydrocarbons, to a specified first-step heat treatment, subjecting the first-step treated fraction to a specified second-step heat treatment and then removing the light fraction from the second-step treated fraction thereby to obtain the petroleum-derived pitch.

Abstract: A process for preparing a binder pitch, in which a high-aromatic residual fraction from petroleum raw materials is mixed with a coal tar fraction in weight ratios of about 1:9 to 9:1 and heated, while during heating the mixture is kept in contact with a dehydrogenating agent, in particular an oxygen-containing gas.

Abstract: This invention provides a process for producing road paving asphalt compositions which involves heating an admixture of coal tar and fluidized catalytic cracking syntower bottoms until a homogeneous solubilized product with asphaltic properties is formed. The preferred asphalt compositions have a quantity of scrap rubber incorporated and dissolved therein.

Abstract: A method for dewatering tar-water mixtures obtained from the coking of coal is disclosed. The method involves adding to the tar from 150 to 3,000 ppm of a di-tri butyl ethoxylated phenol compound dissolved in water, heating the tar-water mixture, and then agitating it to allow contact with the chemical additive. This is followed by allowing the mixture to settle forming an aqueous upper phase and a lower dewatering tar phase.

Abstract: Raw material coal for coke production having improved coking property is readily obtainable by a simple step of blending raw material coal having poor coking property with a highly aromatic bituminous substance obtained by heat-treating hydrocarbons.

Abstract: A method for producing an impregnating petroleum pitch in two steps. In the first step, aromatic oils undergo polymerization with a controlled feed of an oxygen-containing gas at a temperature of less than 700.degree. F to a softening point of from about 30.degree. to about 100.degree. C, and in a second step, the pitch is stripped under controlled conditions in an inert environment to a softening point of between 100.degree.-135.degree. C. This low temperature with controlled stripping permits the formation of an impregnating pitch having a beta resin content of less than about 15% with a low quinoline insolubles content, and a Conradson Carbon of about 50%.Benzene Insolubles, as herein disclosed, are determined by ASTM D-2317; Quinoline Insolubles are determined by ASTM D-2318; Conradson Carbon is determined by ASTM D-189; and Softening Point by ASTM D-3104.

Abstract: Pitch is produced continuously by heat treating a heavy hydrocarbon oil at a temperature of 350.degree. to 500.degree. C successively in two or more reactors connected in series, outlet to inlet, recirculating, at the same time, one portion of the liquid output substance from at least one reactor into that reactor, and introducing the output substance (molten pitch) of the final reactor into an after-treatment chamber of duct shape with an inactive atmosphere sealed therewithin thereby to cool the output substance.

Abstract: The invention relates to the upgrading of coal for coking purposes and improved cokes resulting from such upgrading. Pitch obtained as a by-product of pressure-gasification (Lurgi-process) is used as an additive either alone or blended with SRC. The additive is employed in amounts of 1% and 50% by mass, preferably 5 to 15% of the total blend. The additive preferably has an R-and-B softening temperature above 80.degree. C. The additive can be subjected to various treatments, e.g. heating in presence of hydrogen, to improve its characteristics.

Abstract: Improved asphalt compositions are provided which are produced by forming a homogeneous blend of marginal asphalt stock with coal-derived asphaltenes, and air-blowing the homogeneous blend to yield an asphalt composition having a viscosity-penetration index higher than about 2.5 .times. 10.sup.5.

Abstract: A process for producing refractories wherein an impregnant is filled into open pores of the refractories. The impregnant is the thermoplastic resinous material which is obtained by removing a light fraction having a boiling point of less than 200.degree. C under a reduced pressure of 100 mmHg and having a benzene-insoluble fraction content of less than 10% by weight from at least one member selected from the group consisting of a heavy oil obtained by the steam cracking of petroleum and the polymerization product of said heavy oil. The slag penetration resistance, slag erosion resistance and slaking resistance of the impregnated refractories are improved thereby.