Abstract: A method is provided of selecting operating parameters for an aromatization process having at least penultimate and final stages, each containing a respective catalyst, for optimum aromatic barrel per calendar day (AB/CD) production of product having a selected RON and/or over a particular run length. The catalyst lives are determined at constant LHSV for the penultimate and final stage catalysts for a given feed RON to each stage as a function of the change in RON from that of the feed to that of the C.sub.5+ effluent from the respective stage. The penultimate stage C.sub.5+ effluent RON is selected to be such that the lives of the catalysts in each stage are substantially equal. Preferably the yield of C.sub.5+ effluent from each stage and the life of the catalyst used in each stage is determined as a function of the pressure of that stage. The operating pressures of the stages are then selected to be within about 30% of that which gives the highest AB/CD.

Abstract: Provided is a reforming process for producing a high purity benzene product using a non-acidic zeolitic catalyst. The high purity benzene is extracted from a light fraction of reformate that has less than 500 ppm by weight toluene. Generally, a hydrocarbon feed is reformed in a reformer under reforming conditions in the presence of a non-acidic catalyst to produce a reformate. That reformate is separated into a light fraction and a heavy fraction. The extraction unit, preferably an extractive distillation unit, is then used to separate the light fraction into an aromatic extract stream and a nonaromatic raffinate stream.

Abstract: A process combination is disclosed to selectively upgrade naphtha to obtain gasoline which is in accordance with current standards for reformulated fuels. A naphtha feedstock is fractionated to selectively direct light naphtha to isomerization or blending, a head-cut fraction to reforming, and a heavy potion to selective isoparaffin synthesis to yield light and heavy synthesis naphtha and isobutane. The heavy potion of the synthesis naphtha is processed by reforming. Light naphtha may be isomerized, with or without recycle of low-octane components of the product. A gasoline component is blended from light, synthesis, and reformate products from the process combination.

Abstract: This invention deals with a process for converting aliphatic C.sub.2 -C.sub.6 hydrocarbons into C.sub.6.sup.+ aromatics and C.sub.3.sup.= /C.sub.4.sup.= olefins. The process involves combining dehydrocyclodimerization (DHCD) with dehydrogenation. Thus, the feedstream is first sent to a DHCD zone which produces an effluent stream which contains C.sub.6.sup.+ aromatics along with C.sub.1 -C.sub.5 hydrocarbons. This effluent stream is separated into a stream containing C.sub.1 -C.sub.4 hydrocarbons and one containing C.sub.6.sup.+ aromatics. The C.sub.1 -C.sub.4 containing stream is flowed to a dehydrogenation zone to produce C.sub.3.sup.= /C.sub.4.sup.= olefins.

Abstract: A low severity continuous reforming process that operates at conditions to provide a low coke production provides an improved reformulated gasoline fuel. The conditions for the reforming operation include high space velocity, relatively high temperature and low hydrogen to hydrocarbon ratios. Despite the higher temperature, the process provides stable coke production rates at a very low level while providing relative high hydrogen yields. The lower severity operation and the high hydrogen yield facilitate the removal of benzene from the reformulated gasoline pool while avoiding the anticipated hydrogen deficit that such operations would produce.

Abstract: A naphtha feed is contacted in a penultimate aromatic forming stage under catalytic aromatic forming conditions with a first catalyst. The effluent from the penultimate stage is contacted in a final aromatic forming stage under catalytic aromatic forming conditions and at substantially the same pressure as is maintained in the penultimate stage with a second catalyst. The pressure is selected to provide optimal aromatic production per calendar day from the final stage.

Abstract: A two stage process for reforming a naphtha feed at low severities with tin modified platinum-iridium catalysts. In particular, both high selectivity, and high activity are manifested by such catalysts in reforming a naphtha feed at low severities in a first fixed-bed reforming stage which is comprised of a series of reforming zones, or reactors; i.e., within the dehydrogenation and ring isomerization zones of a reforming unit. The first stage zones are charged with a tin-containing platinum-iridium catalyst, and the naphtha feed reformed to produce an intermediate RON clear C.sub.5 + liquid reformate. The intermediate octane product of the first reforming stage is passed to a second stage which is comprised of one or more moving-bed reforming zones, or reactors, which are operated in a continuous catalyst regeneration mode with platinum containing catalyst.

Abstract: A hydrocarbon feedstock is catalytically reformed to effect dehydrocyclization of paraffins in a process combination comprising a first reforming zone containing a mixed reforming catalyst and sulfur sorbent and a sulfur-removal zone utilizing a manganese component to preclude sulfur from the feed to a second reforming zone. The process combination shows substantial benefits over prior art processes in achieving reforming-catalyst stability.

Abstract: A process is provided for catalytic reforming or dehydrocyclization of hydrocarbons using a catalyst comprising a noble metal, and an intermediate pore size crystalline silicate having a high silica to alumina ratio and a relatively low alkali content. Preferably, the crystalline silicate is in the form of small crystallite size, such as less than 5 microns. The reforming or dehydrocyclization process is sulfur tolerant so that the reforming can be carried out in the presence of sulfur or with periodic exposure to sulfur.

Abstract: A two stage process for catalytically reforming a gasoline boiling range hydrocarbonaceous feedstock. The reforming is conducted in two stages wherein the first stage is operated in a fixed-bed mode, and the second stage is operated in a moving-bed continual catalyst regeneration mode. A gaseous stream comprised of hydrogen and predominantly C.sub.4.sup.-- hydrocarbon gases are separated between stages. A portion of the hydrogen-rich gaseous stream is recycled and the remaining portion along with the C.sub.5.sup.+ stream are sent to second stage reforming.

Abstract: Catalytic reforming wherein the lead reactor contains a catalyst comprised of platinum and a relatively low level of Re on an inorganic oxide support. The tail reactor contains a tin modified platinum-iridium catalyst wherein the metals are substantially uniformly dispersed throughout the inorganic oxide support.

Abstract: A hydrocarbon feedstock is catalytically reformed to effect dehydrocyclization of paraffins in a process combination comprising a first reforming zone and a sulfur-removal zone utilizing a manganese component to preclude sulfur from the feed to a second reforming zone. The process combination shows substantial benefits over prior art processes in the stability of the extremely sulfur-sensitive catalyst utilized in the second reforming zone.

Abstract: Staged-Acidity Naphtha Reforming provides increased C.sub.5+ liquid yields by systematically adjusting catalyst acidity within a multireactor reformer to match the different acid strengths required to selectively aromatize naphthene and paraffin hydrocarbon as they traverse the reformer train.

Abstract: A process for reforming a naphtha feed at low severities with tin modified platinum-iridium catalysts. In particular, both high selectivity, and high activity are manifested by such catalysts in reforming a naphtha feed at low severities in the lead reactor, or reactors, of a series of reactors; i.e., within the dehydrogenation and ring isomerization zone, or zones, of a reforming unit. The lead reactors of the series are charged with a tin-containing platinum-iridium catalyst, and the naphtha feed reformed to produce a low RON clear C.sub.5 + liquid reformate. The low octane product of the lead reactors may be transferred to a mogas pool, into blending components, or all or some part of the product further reformed. Preferably, the product is further reformed in a tail reactor, and preferably the tail reactor is charged with a non-tin containing platinum, or platinum-iridium catalyst.

Abstract: A process for removing residual sulfur from a hydrotreated naphtha feedstock is disclosed. The feedstock is contacted with molecular hydrogen under reforming conditions in the presence of a less sulfur sensitive reforming catalyst, thereby converting trace sulfur compounds to H.sub.2 S, and forming a first effluent. The first effluent is contacted with a solid sulfur sorbent, removing the H.sub.2 S and forming a second effluent. The second effluent is contacted with a highly selective reforming catalyst under severe reforming conditions.

Abstract: A process is provided for the hydrogenation of benzene and the isomerization of a light naphtha feedstock consisting essentially of a stream having a boiling range of from about 50.degree. F. to about 240.degree. F. comprising the steps of contacting the light naphtha feedstock at isomerization conditions in an isomerization reaction zone with an isomerization catalyst in the presence of hydrogen and producing an isomerization reaction zone effluent, combining the isomerization reaction zone effluent with a supplemental benzene-containing stream comprising at least 1 weight percent benzene and forming a hydrogenation zone feedstock, and hydrotreating the hydrogenation zone feedstock at hydrogenation conditions in a hydrogenation reaction zone with a hydrogenation catalyst in the presence of hydrogen for producing an isomerate product comprising less than 0.1 weight percent benzene.

Abstract: A process combination is disclosed to selectively upgrade naphtha to obtain gasoline which is in accordance with current standards for reformulated fuels. A naphtha feedstock is fractionated to selectively direct light naphtha to isomerization or blending, a heart-cut fraction to reforming, and a heavy portion to selective isoparaffin synthesis to yield light and heavy synthesis naphtha and isobutane. The heavy portion of the synthesis naphtha is processed by reforming. Light naphtha may be isomerized, with or without recycle of low-octane components of the product. A gasoline component is blended from light, synthesis, and reformate products from the process combination.

Abstract: A two stage process for catalytically reforming a gasoline boiling range hydrocarbonaceous feedstock. The reforming is conducted in two stages wherein the first stage is operated in a fixed bed mode, and the second stage is operated in a moving bed continuous catalyst regeneration mode. A hydrogen-rich stream is recycled through both stages.

Abstract: A hydrocarbon feedstock is catalytically reformed to effect dehydrocyclization of paraffins in a process combination comprising a first reforming zone and a sulfur-removal zone utilizing a manganese component to preclude sulfur from the feed to a second reforming zone. The process combination shows substantial benefits over prior art processes in the stability of the extremely sulfur-sensitive catalyst utilized in the second reforming zone.

Abstract: A two stage process for catalytically reforming a gasoline boiling range hydrocarbonaceous feedstock. The reforming is conducted in two stages wherein the first stage is operated in a fixed bed mode, and the second stage is operated in a moving bed continual catalyst regeneration mode. A gaseous stream comprised of hydrogen and predominantly C.sub.4.sup.- and a C.sub.5.sup.+ liquid stream are produced between stages. A portion of the hydrogen-rich stream is recycled and the and the remaining portion and an aromatics-lean stream, which is obtained during aromatics separation between stages, is sent to second stage reforming.

Abstract: Disclosed is a process for catalytically reforming a gasoline boiling range hydrocarbonaceous feedstock. The reforming is conducted in multiple stages with heavy aromatics removal between the first and second stages.

Abstract: A two stage catalytic reforming process. The first stage is comprised of two separate fixed-bed reforming units each comprised of one or more serially connected fixed-bed reforming zones. The second stage is comprised of one or more moving-bed reforming zones with continual catalyst regeneration. A hydrogen-rich gaseous stream is separated after each fixed-bed unit and a portion is recycled to the respective fixed-bed reforming zones.

Abstract: A two stage process for catalytically reforming a gasoline boiling range hydrocarbonaceous feedstock. The reforming is conducted in two stages wherein the first stage is operated in a moving-bed mode with the catalyst being continually regenerated, and the second stage is operated in a fixed-bed mode.

Abstract: A reforming system for reforming gasoline boiling range hydrocarbon streams, which system is comprised of two or more parallel fixed-bed reforming stages sharing a common moving-bed reforming stage.

Abstract: A method is provided of selecting operating parameters for a reforming process having at least penultimate and final reforming stages, each containing a respective catalyst, for optimum OB/CD production of product reformate having a selected RON and/or over a particular run length. The catalyst lives are determined at constant LHSV for the penultimate and final stage catalysts for a give feed octane to each stage as a function of the change in RON from that of the feed to that of the C.sub.5 + effluent from the respective stage. The penultimate stage C.sub.5 + effluent RON is selected to be such that the lives of the catalysts in each stage are substantially equal. Preferably the yield of C.sub.5 + effluent from each stage and the life of the catalyst used in each stage is determined as a function of the reforming pressure of that stage. The operating pressures of the stages are then selected to be within about 30% of that which gives the highest OB/CD.

Abstract: A naphtha feed is contacted in a penultimate reforming stage under catalytic reforming conditions with a first catalyst. The effluent from the penultimate reforming stage is contacted in a final reforming stage under catalytic reforming conditions and at substantially the same pressure as is maintained in the penultimate reforming stage with a second catalyst. The reforming pressure is selected to provide optimal OB/CD production of product reformate of a desired RON from the final stage.

Abstract: A catalytic reforming process in which sulfur moieties are removed from a gaseous product stream by use of a sulfur trap comprised of about 10 to about 70 wt. % nickel dispersed on a support. The sulfur which is removed is both sulfur which is inherent in the feed as well as sulfur which results from presulfiding the catalyst.

Abstract: Improved, dehydrocyclization and low-pressure reforming processes based on a non-acidic metal containing crystalline microporous indium catalyst, in which the feed is rich in C.sub.6 -C.sub.7 low octane hydrocarbons, such as paraffins, and in which the reformate has increased aromatic content and increased octane value over that of the feed are disclosed.

Abstract: Disclosed is a process for catalytically reforming a gasoline boiling range hydrocarbonaceous feedstock in the presence of hydrogen in a reforming unit comprised of a plurality of serially connected reactors wherein one or more of the reactors contains a noble metal-containing zeolite catalyst selected from alkaline faujasites and L-type zeolite which zeolites are prepared by a: (a) treating the alkaline faujasite or L-type zeolite with one or both of Pt(acetylacetonate).sub.2 or Pd(acetylacetonate).sub.2 for an effective amount of time; and (b) calcining the so treated zeolite at a temperature from about 250.degree. C. to about 600.degree. C. for an effective amount of time.

Abstract: A hydrocarbon feedstock is catalytically reformed in a process which comprises contacting the feedstock in an initial catalyst zone with a catalyst comprising platinum, germanium and halogen on a solid catalyst support. The product from the first catalyst zone is contacted in a terminal catalyst zone with a catalyst having the essential absence of germanium and comprising platinum, halogen and a metal promoter on a solid catalyst support.

Abstract: A process for catalytically reforming a gasoline boiling range hydrocarbonaceous feedstock wherein the reforming is conducted in two or more stages wherein each stage is separated from another stage by aromatics removal from the reaction stream of a preceding stage. Reforming in at least one of the downstream reactors is conducted in the presence of a catalyst comprised of a nobel metal, an inorganic support, and a promotor metal; or a catalyst comprised of a Group VIII metal on a type-X, type-Y, or type-L zeolitic support.

Abstract: The process disclosed is for the improved reforming of petroleum fractions by catalytic conversion to a mixture of hydrocarbons rich in aromatics. In the process, naphtha fraction is contacted with two types of catalysts (1) a conventional reforming catalyst and (2) an acidic reforming catalyst containing a crystalline iron silicate. Splitting the reformate into two fractions and recycling the same to the two different reaction zones containing the two types of catalysts. The fraction recycled to the acidic reforming catalyst is rich in aromatics.

Abstract: An improved, low-pressure dehydrocyclization and/or reforming process based on a non-acidic metal containing crystalline microporous tin catalyst, in which the feed is rich in low octane hydrocarbons, such as paraffins, and in which the product has increased aromatic content and increased octane value over that of the feed.

Abstract: A hydrocarbon feedstock is catalytically reformed in a process which comprises contacting the feedstock in an initial catalyst zone with a catalyst comprising platinum, germanium and halogen on a solid catalyst support. The product from the first catalyst zone is contacted in a terminal catalyst zone with a catalyst having the essential absence of germanium and comprising platinum, halogen and a metal promoter on a solid catalyst support.

Abstract: A hydrocarbon feedstock is catalytically reformed in a process which comprises contacting the feedstock in a first catalyst zone with a catalyst consisting essentially of platinum, germanium and halogen on a solid catalyst support. The product from the first catalyst zone is contacted in a second catalyst zone with a catalyst comprising platinum, germanium, halogen and a metal promoter on a solid catalyst support.

Abstract: An improved process for pretreating a naphtha comprising contacting said naphtha prior to reforming with a zeolite catalyst containing at least one noble metal and at least one alkali metal.

Abstract: An improved zeolite catalyst containing at least one noble metal and at least one alkali metal wherein the amount of the latter component exceeds the cationic exchange capacity of the zeolite has been found to be highly useful for catalytic reforming.

Abstract: A process for removing residual sulfur from a hydrotreated naphtha feedstock is disclosed. The feedstock is contacted with molecular hydrogen under reforming conditions in the presence of a less sulfur sensitive reforming catalyst, thereby converting trace sulfur compounds to H.sub.2 S, and forming a first effluent. The first effluent is contacted with a solid sulfur sorbent, removing the H.sub.2 S and forming a second effluent. The second effluent is contacted with a highly selective reforming catalyst under severe reforming conditions.

Abstract: A combined reforming and isomerization process wherein at least a portion of the hydrogen produced in the reforming process is passed with a C.sub.5 -C.sub.6 range normal paraffin feedstock to an isomerization zone, containing an isomerization catalyst, at isomerization condition to produce an isomerized C.sub.5 -C.sub.6 product stream and passing the C.sub.5 -C.sub.6 isomerized product stream to a reformate separation zone (hydrogen stripping and topping zones) and recovering at least a major portion of the isomerized C.sub.5 -C.sub.5 product stream with the reformate for use as a high octane gasoline product.

Abstract: The invention concerns a combined process of catalytically hydroreforming a heavy naphtha in at least one reaction zone (10) and catalytically hydroisomerizing a light naptha in at least one reaction zone (34).The invention is characterized in that the hydrogen produced in the hydroreforming unit (line 27) is used to isomerize the light naphtha, the obtained reformate and isomerate being fractionated preferably together in the same stabilization column (51 in FIG. 1).A better thermal integration, a better recovery of light hydrocarbons and a lowering of the utilities requirements and investments, as compared with units operating separately, are thus achieved.

Abstract: Disclosed is a process for catalytically reforming a gasoline boiling range hydrocarbonaceous feedstock wherein the reforming is conducted in two or more stages wherein each stage is separated from another stage by aromatics removal from the reaction stream of a preceding stage. The resulting aromatics-lean stream is passed to a downstream reforming stage.

Abstract: A process for converting a C.sub.2 -C.sub.12 paraffinic hydrocarbon feed to aromatics comprising passing the feed through a first conversion zone wherein the feed contacts a noble metal/low acidity medium pore size zeolite catalyst, and then passing the resulting hydrocarbon mixture through a second conversion zone wherein the resulting hydrocarbon mixture contacts a medium pore size acidic zeolite catalyst.

Abstract: A process for splitting a feed containing C.sub.6 cycloparaffins, C.sub.6 normal paraffins, and higher boiling hydrocarbons uses an isomerization zone to open the rings of cyclic hydrocarbons and a single fractionation zone to separate the feed and the isomerization product into a C.sub.7 plus stream that can be used as a feed stream to a reformer and an isoparaffin stream consisting of C.sub.6 and lighter hydrocarbons that is deficient in cyclic hydrocarbons. The process uses a chlorided platinum-alumina catalyst to open rings and isomerize C.sub.6 hydrocarbons. Additional feed streams of normal C.sub.5 paraffins may be added to the process ahead of the isomerization zone to increase the yield of isoparaffin from the isomerization zone. This process offers a simple flow scheme that yields a high volume of high octane isomerate while reducing the quantity of C.sub.6 cyclic hydrocarbons in a reformer feed. Converting the C.sub.

Abstract: Disclosed is an improved method for catalytically reforming a gasoline boiling range naphtha in a reforming unit comprised of a plurality of serially connected reactors, each containing a halogenated reforming catalyst. The level of halide is maintained in each reactor, particularly the downstream reactors by injecting into each reactor a mixture of water and halide at a ratio of 20:1 to 60:1, respectively.

Abstract: A process is provided for converting a feedstock comprising a preponderant amount of C.sub.2 -C.sub.10 aliphatic compounds to a product having a high proportion of benzene in a two stage process, with the effluent from the first stage passing directly to the second stage, i.e., with no intermediate processing such as purification or separation. In the first stage, the feedstock is contacted under suitable conversion conditions with a catalyst comprising an aluminosilicate zeolite having a Constraint Index in the approximate range of 1 to 12 and a degree of acidity indicated by an alpha value of at least about 3.

Abstract: A process for the upgrading of a hydrocarbon feedstock which includesproviding a feedstock including C.sub.4 and higher hydrocarbons which include paraffins and cycloparaffinic hydrocarbons;contacting the feedstock with a conventional naphtha reforming catalyst at an elevated temperature and at a liquid hourly space velocity (LHSV) of greater than approximately 5, when the cycloparaffin content is approximately 10% by weight or greater;and contacting the feedstock with a metal-containing ZSM-5 type zeolite catalyst at an elevated temperature at approximately 0.5 to 2 LHSV when the initial cycloparaffin content is reduced to less than approximately 10% by weight, and solely with a metal-containing ZSM-5 type zeolite catalyst at an elevated temperature at approximately 0.2 to 2 LHSV when the initial cycloparaffin content is less than approximately 10% by weight.

Abstract: A process is disclosed for reforming a hydrocarbon in a multi-stage endothermic reforming series of reforming reactors where the hydrocarbon is passed through a series of reforming reactors to form a reformate with substantial reduction in polynuclear aromatic compounds. An adsorption zone comprising an adsorbent selective for adsorption of polynuclear aromatics is situated intermediate the series of reactors. The adsorbent is followed by an intermediate heating means to insure that the temperature of the hydrocarbon product entering the next reforming stage is at a temperature sufficient that the hydrocarbon product will have a temperature of at least 750.degree. F. when egressing from the next respective reforming zone. The contemplated reforming feeds are C.sub.6 to C.sub.10 naphthas having a boiling point of 100.degree. F. to 400.degree. F. while the ultimate reformate is used as a blending agent for gasolines to increase the octane value of the respective gasoline.

Abstract: An improved two-step process for the conversion of lower molecular weight paraffins, the process comprising contacting in a first step a C.sub.2 -C.sub.10 alkane-rich feedstock with a siliceous zeolite catalyst in a primary fluidized bed reaction zone under high temperature dehydrogenation conditions to obtain an intermediate product comprising oligomerizable olefinic hydrocarbons and aromatics; and then contacting in a second step the intermediate product with a siliceous zeolite catalyst in a secondary fluidized bed reaction zone under low temperature oligomerization conditions to obtain a final product comprising gasoline boiling range aliphatic and aromatic hydrocarbons.

Abstract: A multi-stage catalytic reforming process using a catalyst having a high rhenium to platinum ratio in the first stage or stages and a catalyst having a still higher rhenium to platinum ratio for the last stage. The process comprises:(a) contacting a naphtha feed with a first stage catalyst comprising rhenium and platinum, and having a rhenium to platinum weight ratio of at least 1.7, under catalytic reforming conditions in one or more first reforming stages of a reforming unit to obtain intermediate reformate; and(b) contacting the intermediate reformate, under catalytic reforming conditions in a last stage of the reforming unit, with a last stage catalyst comprising rhenium and 0.2 to 2.0 weight percent platinum, and having sufficient rhenium so that the last stage catalyst has at least 0.5 weight percent rhenium beyond that necessary to attain a 1.7 rhenium to platinum weight ratio.

Abstract: An improved two-step process for the conversion of lower molecular weight paraffins, the process comprising contacting in a first step a C.sub.2 -C.sub.10 alkane-rich feedstock with a siliceous zeolite catalyst in a primary fluidized bed reaction zone under high temperature dehydrogenation conditions to obtain an intermediate product comprising oligomerizble olefinic hydrocarbons and aromatics; and then contacting in a second step the intermediate product with a siliceous zeolite catalyst in a secondary fluidized bed reaction zone under low temperature oligomerization conditions to obtain a final product comprising gasoline boiling range aliphatic and aromatic hydrocarbons.