Abstract: The product of Fischer-Tropsch Synthesis is separated to recover a product boiling above and below about 400.degree. F which is thereafter separately process over different beds of ZSM-5 crystalline zeolite under conditions promoting the formation of fuel oil products and gasoline of a higher octane rating.
Abstract: The total product effluent of Fischer-Tropsch synthesis separated from catalyst fines is passed in contact with a crystalline zeolite catalyst represented by ZSM-5 before separation into desired product fractions and C.sub.5 minus gaseous products are catalytically converted to gasoline boiling components.
Abstract: Upgrading of Fischer-Tropsch synthesis product is accomplished by water washing the product effluent to separate oxygenates therefrom, separating the washed effluent to recover a C.sub.3 -C.sub.4 rich fraction, a C.sub.5 plus gasoline fraction, a light fuel oil fraction and a heavy fuel oil fraction which is subjected to hydrodewaxing conditions to produce additional light fuel oil and gasoline boiling product. The light fuel oil products were hydrotreated and the synthesis gasoline is octane improved with ZSM5 crystalline zeolite.
Abstract: Upgrading a fraction of a heavy Fischer-Tropsch oil to jet fuel by hydropretreating a 350.degree. to 850.degree. F boiling fraction; separating the hydrotreated product into a 650.degree. F minus and a 650.degree. F plus fraction, separating the650.degree. F minus fraction to provide a 350.degree. F minus naphtha boiling range fraction and a 350.degree. to 650.degree. F light distillate fraction; distilling the 350.degree. to 650.degree. F hydrotreated fraction to provide a fraction boiling in the range of 350.degree. F to 550.degree. F separate from a 550.degree. to 650.degree. F fraction processing either of the 650.degree. F plus fraction above separated or the 350.degree. to 550.degree. F boiling fraction above obtained over a catalyst comprising a crystalline aluminosilicate zeolite having a silica to alumina ratio of at least 12 and a constraint index of 1 to 12 with hydrogen, at a temperature of about 500.degree. to 800.degree.
Abstract: A combination process is provided for upgrading 650.degree. F minus product of Fischer-Tropsch Synthesis to provide high yield of high octane gasoline along with improved yields of light fuel oil product. Polymerization and alkylation of C.sub.5 minus gaseous material provide products suitable for blending with gasoline and fuel oil product. A ZSM5 catalyst is relied upon to improve the octane rating of C.sub.5 plus gasoline product of an end point within the range of about 320.degree. F up to about 430.degree. F.
Abstract: Upgrading of Fischer-Tropsch synthesis product is obtained by separating a 560.degree. F minus hydrocarbon fraction from gaseous C.sub.5 rich material and a water phase comprising oxygenates. Alcohols may be recovered from the water phase for conversion to gasoline boiling components. C.sub.5 rich material is converted to gasoline boiling material with a ZSM-5 crystalline zeolite and upgrading of the 560.degree. F minus hydrocarbon fraction is accomplished with a ZSM-5 crystalline zeolite catalyst.
Type:
Grant
Filed:
September 18, 1975
Date of Patent:
August 9, 1977
Assignee:
Mobil Oil Corporation
Inventors:
James C. Kuo, Charles Dwight Prater, John J. Wise
Abstract: A combination process is provided which upgrades the C.sub.3 to 650.degree. F product of Fischer-Tropsch Synthesis to form gasoline product of improved octane rating by contact with ZSM-5 crystalline zeolite and hydrogenation of light fuel oil to improve its stability and color characteristics. Gaseous products are converted to alkylate in the gasoline boiling range. The yield of light fuel oil may be increased by reducing the end point of the gasoline fraction to about 320.degree. F.
Abstract: A Fischer-Tropsch synthesis effluent is separated into gaseous, gasoline boiling, light fuel oil and heavy fuel oil products for upgrading to more desirable products by conversion over a special class of crystalline zeolites suitable for the purpose. Water washing of the separated fractions may be practiced to recover oxygenates from any separated fraction before further upgrading of oxygenates and hydrocarbons.
Abstract: Residual hydrocarbons stocks obtained after atmospheric distillation are converted into light distillates by certain sequences of processing steps including catalytic cracking, high and low pressure catalytic hydrotreatment, deasphalting, gasification and thermal cracking or coking.
Abstract: Hydrocarbon mixtures (e.g. "waxy" crude oils) are transported as a slurry by first fractionating the mixture into at least a relatively low pour point fraction and a relatively high pour point fraction. Thereafter, the high pour point fraction is congealed by dispersing it as particles into the bottom of a tower having a continuous stream of water flowing countercurrent to the dispersed fraction and wherein the water in at least the upper portion of the tower is at a temperature sufficient to congeal the dispersed particles. The particles pass upwardly through the tower and through an interface within the tower, the interface being the juncture of water and the low pour point fraction being introduced into the top portion of the tower. A portion of the resulting slurry is withdrawn and transported in a conduit at temperatures below those which bring about solution of the congealed particles in the low pour point fraction.
Abstract: A C.sub.6 hydrocarbon stream is converted to benzene, cyclohexane and a motor fuel blending stock by a combination of steps comprising fractionation, hydrogenation and isomerization of the fractions boiling in the isohexanes range and above the n-hexane range, and reforming of the fraction boiling in the n-hexane range and separately recovering a motor fuel blending stock, cyclohexane and benzene as products of the process.
Abstract: Residual oils are upgraded to lube oil base stocks by a combination process involving deasphalting, solvent extraction and hydrocracking arranged to particularly promote the efficient production of lube oil products.
Abstract: A method for the operation of a hydrodewaxing unit wherein a petroleum distillate is separated into two streams, one having a pour point of above about 30.degree.F, and the other having a pour point of less than about 30.degree.F., the 30.degree.F plus pour point fraction is treated in a hydrodewaxing unit with a ZSM-5 type catalyst under hydroprocessing conditions while the 30.degree.F. minus pour point portion is untreated and combined with the hydrodewaxed product. The process yields a net production of hydrogen, and exhibits excellent catalyst aging characteristics.
Type:
Grant
Filed:
June 5, 1974
Date of Patent:
May 11, 1976
Assignee:
Mobil Oil Corporation
Inventors:
Nai Yuen Chen, Bernard M. Gillespie, Henry R. Ireland, Thomas R. Stein
Abstract: Upgrading a full boiling range naphtha by the combination of reforming only a low boiling portion of the naphtha followed by contacting the reformate product thereof combined with the high boiling portion of the naphtha over a ZSM-5 type catalyst conversion operation is described.
Abstract: A process combination is described for upgrading a gasoline product of fluid cracking by treatment with a ZSM-5 catalyst wherein the cracking operation is performed under conditions to provide a depentanized gasoline product of cracking containing not more than 15 wt.% olefins before ZSM-5 treatment thereof for octane improvement.
Type:
Grant
Filed:
April 2, 1974
Date of Patent:
April 13, 1976
Assignee:
Mobil Oil Corporation
Inventors:
William E. Garwood, Donald M. Nace, Hartley Owen