Abstract: A novel cleaner is disclosed, which is added to a reaction thermostat with water as medium in a scientific apparatus, particularly a thermostatic water bath in an automatic analyzer, and has bacteria-proof, fungi-proof and algae-proof effects. The cleaner comprises a triazine derivative and a surface active agent. Furthermore, the cleaner preferably contains a compound represented by a formula [I]: ##STR1## wherein R.sup.1, R.sup.2, R.sup.3 and R.sup.4 independently represent a hydrogen atom, a methyl group or a hydroxymethyl group, and n is an integer of 1 to 5.

Abstract: A method for reducing an isocyanuric acid level concentration in swimming pool water to prevent chlorine lock. The method comprises the steps of adding an effective amount of sodium hydroxide to the pool water and reacting the sodium hydroxide with the isocyanuric acid therein to reduce the isocyanuric concentration to a level of between about 40 to 60 PPM.

Abstract: A method for controlling zebra mussels in ship ballast tanks comprising treating ballast water which contains zebra mussels or which is prone to zebra mussel infestation with an effective amount of a water-soluble dialkyl diallyl quaternary ammonium polymer (polyquat). A preferred polymer is a poly(quaternary ammonium) compound having the recurring structure [DMDAAX.sup.-- ] resulting from the polymerization of monomeric dimethyl diallyl ammonium X.sup.--, wherein X.sup.-- is any suitable anion.

Abstract: A process is provided for controlling the emission of nitrogen dioxide from, and the growth of living organisms in, steam condensate cooling towers and catch basins used in conjunction with a condensate of steam derived from an ammonia containing geothermal brine. The process comprises contacting the condensate, in a substantially continuous manner, with a less-than-stoichiometric amount of an oxidizing agent, which results in the oxidation of nitrite in the condensate to a nitrate. The process optionally provides for periodically introducing a biocide into the condensate in an amount which controls organism growth in the cooling tower and catch basin. To prevent system corrosion, the process may include treating the condensate with a non-organic, phosphate-based corrosion inhibitor and scale dispersant.

Abstract: A toilet cleaning block which releases a halogen disinfecting agent in a controlled, substantially constant rate for 2 to about 4 months of constant contact with water and is then completely dissolved in the water comprises an admixture of an agent which releases a halogen disinfecting agent when in contact with water, about 4 to 10% aluminum hydroxide based on the total weight of the block and up to about 1% by weight of a mold release lubricant, said admixture being in the form of a coherent solid resistant to internal water penetration having a density of 1.10 to 1.60 g/cc, a ratio of effective surface area to weight of about 1:1.05 to 1:1.25 and a crush fracturing strength of about 9-109 kg.

Abstract: A process for abating the emission of hydrogen sulfide and nitrogen oxide from a condensate of steam, derived from a sulfide- and nitrite-containing geothermal brine, comprising introducing an oxidizing agent into the condensate in an amount less than that which would be required to directly oxidize all the sulfide and nitrite to sulfate and nitrate. The process optionally provides for periodically introducing a biocide into the condensate to control the growth of organism therein.

Abstract: A method for controlling zebra mussels in ship ballast tanks comprising treating ballast water which contains zebra mussels or which is prone to zebra mussel infestation with an effective amount of a didecyl dimethyl ammonium halide. A preferred compound is a didecyl dimethyl ammonium chloride.

Abstract: A process for inhibiting the adhesion of bacterial cells to solid surfaces in aqueous systems and thus controlling biological fouling comprising adding a water-soluble ionene polymer to the aqueous systems in an amount ranging from about 0.5 ppm to about 50 ppm based on the weight of aqueous liquid in the system.

Abstract: Method for disinfecting a liquid medium or hard surface containing undesired halogen-sensitive micro-organisms by treatment with substituted N-halo derivatives of imidazolidin-4-ones having substituents at the 2 and 5 positions of the imidazolidin-4-one ring, including N-chloro, N-bromo, N,N'-dichloro, N,N'-dibromo, and N,N'-bromochloro derivatives of imidazolidin-4-ones having substituents selected from hydrogen, alkyl, alkoxy, hydroxy, phenyl, substituted phenyl, or spiro-substitution at the 2 and 5 positions on the ring. These N-halo compounds are stable, noncorrosive biocides which are resistant to direct sunlight, and are useful as disinfectants, sanitizers, and algae inhibitors.

Abstract: A method for controlling zebra mussels in aqueous systems comprising treating aqueous systems which contain zebra mussels or which are prone to zebra mussel infestation with an effective amount of a composition comprising a) a water-soluble dialkyl diallyl quaternary ammonium polymer (polyquat); and b) didecyl dimethyl ammonium halide. A preferred polymer is a poly(quaternary ammonium) compound having the recurring structure [DMDAAX.sup.- ] resulting from the polymerization of monomeric dimethyl diallyl ammonium X.sup.-, wherein X.sup.- is any suitable anion.

Abstract: Polymeric quaternary ammonium trihalides, preferably triiodides, and use of polymeric quaternary ammonium trihalides to inhibit the growth of microorganisms in aquatic systems, to disinfect or sanitize surfaces and to disinfect the skin of animals, including humans.

Abstract: In the processing of a geothermal brine and the recovery of heat therefrom, there are produced a non-condensable gas stream containing hydrogen sulfide and carbon dioxide and a liquid stream comprising a condensate of steam derived from the brine. In accordance with the present invention, the noncondensable gases are introduced into the condensate in the presence of an oxidizing agent to form a gas-liquid mixture. The mixture is maintained at an alkaline pH for a time sufficient for a substantial portion of the hydrogen sulfide to be oxidized. Thereafter, the mixture is introduced into a gas-liquid separation zone for separate recovery of a gas stream comprising a major amount of carbon dioxide and substantially free of hydrogen sulfide. Advantageously, the recovered gas stream is recycled to the geothermal brine process to reduce the pH of the brine and its scaling potential.

Abstract: A process for decomposing a solution of a hydroxylammonium compound includes raising the pH of the solution to about 8 or higher and reacting the alkaline solution with a source of hypohalite ions. The process decomposes solutions of hydroxylammonium salts in a manner which produces benign liquid and gas effluents which can be readily disposed of or discharged.

Abstract: A method for controlling zebra mussels in aqueous systems comprising treating aqueous systems which contain zebra mussels or which are prone to zebra mussel infestation with an effective amount of a didecyl demethyl ammonium halide.

Abstract: A process is provided for controlling the emission of hydrogen sulfide from, and the growth of living organisms in, steam condensate cooling towers and catch basins used in conjunction with steam and condensate of steam derived from hydrogen sulfide-containing geothermal brine. The process comprises contacting the condensate, in a substantially continuous manner, with a small, substantially less-than-stoichiometric amount of an oxidizing biocide, such as trichloro-isocyanuric acid or oxidizing biocide, such as trichloro-isocyanuric acid or 1-bromo-3-chloro-5,5-dimethyl-hydantoin, which results in the oxidation of such hydrogen sulfide precursors as ammonium bisulfide in the condensate to a water-soluble sulfite and/or sulfate, and which slows the growth of organisms in the cooling tower and catch basin.

Abstract: A process for abating the emission of hydrogen sulfide from a condensate of steam, derived from a sulfide-containing geothermal brine, comprising introducing an oxidizing agent into the condensate in an amount less than that which would be required to directly oxidize all the sulfide to sulfate. The process optionally provides for periodically introducing a biocide into the condensate to control the growth of organism therein.

Abstract: The present invention relates to a chloroisocyanuric acid composition having stability during storage characterized by formulating, as a main component, 1 to 200 parts by weight of at least one aluminum sulfate selected from aluminum sulfate (Al.sub.2 (SO.sub.4).sub.3.XH.sub.2 O, X=0 to 18), potassium alum (KAl(SO.sub.4).sub.2.XH.sub.2 O, X=0 to 12) and sodium alum (NaAl(SO.sub.4).sub.2.XH.sub.2 O, X=0 to 12) in 100 parts by weight of trichloroisocyanuric acid and/or dichloroisocyanuric acid.

Abstract: A method for controlling zebra mussels in aqueous systems comprising treating aqueous systems which contain zebra mussels or which are prone to zebra mussel infestation with an effective amount of a water-soluble dialkyl diallyl quaternary ammonium polymer (polyquat). A preferred polymer is a poly(quaternary ammonium) compound having the recurring structure [DMDAAX.sup.- ] resulting from the polymerization of monomeric dimethyl diallyl ammonium X.sup.-, wherein X.sup.- is any suitable anion.

Abstract: A process and formulation are provided for the removal of sulfides from solids and fluids utilizing certain halonitroalkanols. These compounds can rapidly and quantitatively remove hydrogen sulfide, organic sulfides and their salts from solutions, particularly aqueous mixtures.

Abstract: A water insoluble material useful for making biocidal barriers and biocidal filter for use in fluid systems, said material comprising a water insoluble thermoplastic copolymer consisting of an alpha olefin and an alpha, beta-ethylenically unsaturated carboxylic acid, said copolymer having at least one biocidal agent ionically bonded to said copolymer.

Abstract: A method of enhancing the efficacy of anti-microbial chemical compounds in an aqueous medium comprising adding an anionic chemical species to the medium. The anion acts as a competing electron receptor of the terminal cellular reduction reaction. This results in a weakening of the microorganism leaving it more vulnerable to effective action by the anti-microbial chemical.

Abstract: A system for chlorination of a fluid to be treated, which includes a container containing trichlorocyanuric acid in a solid and compact form, a first pipe for supplying the container with dissolving fluid, an evacuation pipe in which the chlorinated fluid circulates, connecting the container to a pipe which contains the fluid to be treated, a chlorine analyzer connected to the pipe and which includes a mechanism for continuously measuring the amount of active chlorine in the treated fluid and released constantly by direct contact of the fluid to be treated with a surface of the trichlorocyanuric acid; and a flow rate regulation mechanism connected to a supply and including a mechanism to for constantly varying a continuous flow rate of the dissolving fluid passing into the container as a function of the amount of active chlorine present in the treated fluid and measured by the chlorine analyzer.

Abstract: In photographic processing apparatus for developing, bleaching-fixing and washing photographic materials, a predetermined quantity of fresh wash water is supplied into a washing tank every time a predetermined amount of the photographic materials have been washed. The fresh wash water is provided by deionizing city water and is reservoired in a replenisher tank. In order to detect a predetermined loss of the fresh wash water in the replenisher tank, a conductivity increasing material is dissolved in the fresh wash water in the replenisher tank when a predetermined quantity of the deionized water is supplied so as to electrically connect a pair of electrodes disposed at a predetermined depth of the replenisher tank. A sterilizer is mixed in the fresh wash water to prevent bacterial growth in the replenisher tank.

Abstract: Water soluble liquid quaternary ammonium polyhalides and quaternary ammonium polyhalides in water soluble admixture with surfactants, and their use in the control of biofouling in aqueous systems.

Abstract: A method of controlling biofouling in a aqueous systems comprising introducing into the system a biocidally effective amount of a water soluble perhalide of the formula: ##STR1## where R.sub.1 and R.sub.2 are hydrogen, hydroxyethyl, alkyl, cyclic alkyl, (alpha, omega)-alkyl, alkyl ether, polyether, heterocyclic ring-substituted alkyl, and halogenated alkyl; n is 2 to 6: X is chlorine, bromine or iodine; and only one of R.sub.1 and R.sub.2 may be hydrogen.

Abstract: Wastewater is effectively disinfected while reducing both chlorine consumption and more particularly the levels of residual chlorine discharged from the wastewater treatment plant. The wastewater is first contacted with a sufficient amount of chlorine to satisfy the chlorine demand and to obtain as low a residual level of chlorine as possible. After the chlorine demand has been satisfied, the wastewater is disinfected with an effective amount of 2,2-dibromo-3-nitrilopropionamide.

Abstract: A method of controlling biofouling in an aqueous system comprising introducing into the system a biocidally effective amount of a water soluble perhalide of the formula: ##STR1## where R.sub.1 and R.sub.2 are hydrogen, hydroxyethyl, alkyl, cyclic alkyl, (alpha, omega)-alkyl, alkyl ether, polyether, heterocyclic ring-substituted alkyl, and halogenated alkyl; n is 2 to 6: X is chlorine, bromine or iodine; and only one of R.sub.1 and R.sub.2 may be hydrogen.

Abstract: The present invention provides a method for the removal of biofilms composed of microorganisms from submerged surfaces in an aqueous medium comprising contacting said biofilm with an aqueous stabilized chlorine dioxide and at least one nutrient source, wherein said nutrient source is provided in an amount effective to result in the generation of one or more acidic compounds by said biofilm, and the aqueous stabilized chlorine dioxide is provided in an amount sufficient, when activated by said one or more acidic compounds generated by said microorganisms, to kill a sufficient number of microorganisms in the biofilm to result in the biofilm's removal. Optionally a second biocide may be provided with or after the nutrient source to kill any microorganisms released from the biofilm during its removal and thereby inhibit the reformation of the biofilm.

Abstract: Recreational water, e.g., swimming pools, as opposed to industrial water, containing a source of free available halogen, e.g., chlorine, is treated with amounts of a 2-oxazolidinone, e.g., 4,4-dimethyl-2-oxazolidinone to thereby inhibit the growth of algae during the absence of biocidal amounts of free available halogen.

Abstract: A chlorine compound containing chemical tablet for dissolution into a surrounding body of water which includes an elongated tablet with length longer than thickness having an elongate central section connecting two opposing obliquely tapered ends along a longitudinal axis and an elongate tablet shell encasing the tablet having a corresponding elongate central section connecting two opposing obliquely tapered ends. The ends of the shell have openings therein and form an inwardly sloping and obliquely angled junction with the shell's elongate central section. The encased tablet lies in a skimmer unit on its side along a longitudinal axis and dissolves in a generally uniform and slow rate.

Abstract: A process for treating water which comprises adding to the water (a) from 1 to 50 ppm of a phosphonium compound of the formula: ##STR1## in which R represents C.sub.1 -C.sub.6 groups which are unsubstituted or substituted by a cyano, hydroxy, esterified hydroxy or aryl group, R.sub.1 represents a C.sub.8 -C.sub.18 alkyl group and X represents chlorine or bromine, and optionally (b) from 0.1 to 100 ppm of an anionic water treatment agent such as a scale or corrosion inhibiting agent.

Abstract: N,N'-dihalo-2-imidazolidinones are described as decontaminants for toxic chemical agents such as the sulfur mustards. Decontamination is effected by contacting the toxic chemical agent with a decontaminating amount of the N,N'-dihalo-2-imidazolidinone, e.g., 1,3-dichloro-4,4,5,5-tetramethyl-2-imidazolidinone.

Abstract: A method of treating an aqueous or non-aqueous system, including paints and adhesives, is described which comprises adding to the system a thiolan of the formula: ##STR1## wherein each of X and Y, which may be the same or different, represents fluorine, chlorine or bromine, in combination with an alkylene bisthiocyanate and a 2-N-alkyl-4-isothiazolin-3-one.

Abstract: A method of controlling the fouling potential of macroinvertebrates, such as mollusks, in aqueous systems which comprises adding to the system an effective controlling amount of a water-soluble quaternary ammonium salt having the following structure: ##STR1## wherein R.sub.1 is an alkyl group having about 6 to 24 carbons; R.sub.2 is an alkyl, aryl or arylalkyl group having about 6 to 24 carbons; R.sub.3 and R.sub.4 are alkyl groups having about 1 to 4 carbons; and X is chloride, bromide, sulfate, bisulfate, nitrate or acetate. Preferably, the quaternary ammonium salt is water-soluble alkyl dimethyl benzyl ammonium chloride having an alkyl chain length from C.sub.6 to C.sub.24 and, most preferably, it has an alkyl distribution of about 40% C.sub.12, 50% C.sub.14 and 10% C.sub.16.

Abstract: A process for converting sulfide ion present in a solution to innocuous, water soluble sulfur species is provided. The process basically includes the steps of contacting the sulfide ion with an oxidizing agent to oxidize it to the water soluble sulfur species and admixing a surface active agent with the solution in an amount sufficient to inhibit precipitation of elemental sulfur and to promote subsequent oxidation. To enhance the formation of the water soluble sulfur species and to speed up the reaction, the oxidation reaction is conducted under alkaline conditions.

Abstract: A method removing cyanuric acid from bather water in swimming pools, spas, and the like. Melamine is added to the bather water in a quantity sufficient to react with the cyanuric acid and form a precipitate. The insoluble precipitate can then be vacuumed or removed through the filtration system of the pool.

Abstract: A method for the control of fouling by marine and fresh water mollusks through the use of an ionene polymer. The disclosed method is particularly useful in controlling fouling by species of fresh water Asiatic clams of the genus Corbicula, the most common of which is C. fluminea.

Abstract: For water-treatment in swimming pools, cooling towers, hot tubs, and other systems, it is desired to feed various chemicals in small quantities but at optimum rates into the system. In several embodiments of the invention the water is recirculated through the system which usually includes a filter. It has been discovered that the chemicals can be fed by enclosing them in generally spherical plastic capsules suggestive of table tennis balls, but about the size of a base ball. The rate of feeding depends upon the size and number of small holes which are provided, or the user pokes through the shell of the capsule, upon the solubility of the chemical, and upon the flow rate of the water through a strainer, skimmer, or other chamber in the system into which the capsule is introduced. The random orientation of the capsule tends to average out variations.

Abstract: N-chloro and N-bromo derivatives of 2-imidazolidinones having substituents at the 4 and 5 positions of the ring are described. More particularly, there are described dichloro, dibromo-, and chlorobromo- derivatives of 2-imidazolidinones having at least three substituents selected from alkyl, alkoxy, hydroxy and substituted phenyl, e.g., para-substituted phenyl, at the 4 and 5 positions on the ring. These N-halo compounds are biocides, e.g., bactericides, and are useful as disinfectants and sanitizers.

Abstract: The use in the treatment of swimming pool water of trichloroisocyanuric acid, the mass median particle diameter of which is from 1 to 20 mm.

Abstract: This invention concerns a process for disinfecting an article by placing the article in an aqueous environment comprising a device that dispenses a chlorine donor and a chlorine acceptor that generate a chlorine biocide for disinfecting the article.

Abstract: Processes and oxidizing agents for oxidizing sulfide ion found in sour water to innocuous, soluble sulfur species are provided. The processes basically comprise contacting the sour water with a nitrogen halogenated triazine or a nitrogen halogenated derivative thereof for a period of time sufficient to convert the sulfide ion to sulfate ion. The processes are particularly useful for removing sulfide ion from oil field produced waters, particularly waters associated with secondary recovery or enhanced oil recovery operations.

Abstract: A process for controlling the formation of undesirable by-products in an aqueous system containing residual halogenated 5,5-dialkyl hydantoins is disclosed. The process comprises the steps of treating the aqueous system with bromide ion and shocking the aqueous medium with free chlorine.

Abstract: The growth of microbiological contaminants in industrial cooling and process waters and in aqueous based products, susceptible to microbiological spoilage on storage, is inhibited by the presence of a phosphorus compound having a hydroxy alkyl group directly attached to the phosphorus atom, such as tetrakis hydroxy methyl phosphonium sulphate.

Abstract: Recirculating water used in closed cycle air-conditioning systems is treated with a 3-chloro-2-oxazolidinone derivative, e.g., 3-chloro-4,4-di(C.sub.1 -C.sub.4)alkyl-2-oxazolidinones such as 3-chloro-4,4-di-methyl-2-oxazolidinone, to prevent the growth of Legionella pneumophila therein.

Abstract: This invention relates to microbicidal/microbistatic compositions for industrial use which comprise 4,5-dichloro-1,2-dithiol-3-one and a haloacetic acid ester and an industrial method of killing and/or inhibiting microbes by using the aforementioned compositions.

Abstract: A system for water treatment includes the steps of superchlorinating the water to a level sufficient to destroy bacterial content in the water very rapidly, passing the water through a sand filter in which the medium includes beads of magnesium hydroxide and subjecting different portions of the filtered water to differing degrees of filtration by an activated charcoal filter, whereby to remove a sufficient proportion of the chlorine added to the water to reduce the residual chlorine to a level sufficient to maintain the water sterile without substantially influencing the taste of the water. Preferably, the sand and charcoal filters are disposed horizontally, and the depths of the filter beds are graded horizontally to provide the differing degrees of filtration to the water.

Abstract: Process for the dehalogenation of aryl and alpha-araliphatic halides comprising contacting the aryl halide or alpha-araliphatic halide with hypophosphite salt, in the presence of a catalytic amount of a noble metal catalyst. This process is useful in the field of organic synthesis and for the removal of environmentally hazardous aryl and alpha-araliphatic halides, including polychlorinated biphenyls and dibenzo-p-dioxins.

Abstract: Method for clarifying bodies of water and removing staining from the containers therefor, particularly swimming pools, by the addition of chlorine and/or bromine ion and ammonium ion to the water.

Abstract: Ferric chloride contained in liquid waste streams comprising higher boiling chlorinated hydrocarbons may be substantially reduced by contacting the waste stream with an amount of water sufficient to convert a substantial amount of the ferric chloride in said stream to solid ferric chloride hexahydrate, and then removing the solid hexahydrate from the waste stream for instance by filtration.