Abstract: Strontium oxide (SrO) nanoparticle and various concentrations of chitosan (CS)-doped SrO nanocomposite were synthesized via co-precipitation method. A variety of characterization techniques including were done for characterizing and qualifying the nanocomposite. X ray powder diffraction affirmed cubic and tetragonal structure of SrO nanoparticle and CS-doped SrO nanocomposite with a decrease in crystallinity upon doping. Fourier transform infrared spectrum endorsed existing functional groups on CS/SrO surfaces while d-spacing was estimated using high resolution Transmission electron microscopes images. UV-Visible and Photoluminescence spectroscopy spectra showed an increase in band gap energies with an increase in doping concentration. Elemental composition of CS-doped SrO nanocomposite deposited with different doping concentrations was studied using Energy dispersive Spectroscopy.

Abstract: The present disclosure belongs to the field of environmental protection and relates to a method for remediating groundwater chlorophenols organic contamination. The method includes determining a location of a contamination source; setting up an injection well based on the location of the contamination source; and injecting a remediation reagent into groundwater in a to-be-remediated region through the injection well so as to degrade chlorophenols organic contamination in the groundwater in the to-be-remediated region.

Abstract: A process is disclosed for treating water, such as wastewater, with air or oxygen-enriched air under alkaline conditions to decompose and remove acrolein and acrolein byproducts from the water and/or wastewater. The process is able to lower the concentration of acrolein and acrolein byproducts from water to a sufficiently low level suitable for discharge to a municipal sewer collection system with reduced occurrence of the decomposition by-products of acrolein converting back to acrolein in the water. One embodiment of the process treats contaminated water containing acrolein with air or oxygen-enriched air by sparging or bubbling air or oxygen-enriched air through the contaminated water. The contaminated water can be treated with air or oxygen-enriched air where the contaminated water is initially adjusted to a pH greater than 7.0 for a time to convert at least a portion of the acrolein to 3-hydroxypropanal to obtain fully treated water and prevent conversion of 3-hydroxypropanal back to acrolein.

Abstract: Disclosed is a masking material intended to be disseminated by an ammunition or a launcher to create a cloud that masks a target with respect to electromagnetic radiation in a given wavelengths range. This material contains at least one aluminium oxyhydroxide, such as boehmite or pseudoboehmite. Also disclosed is an ammunition enabling the dissemination of such masking material and the use of aluminium oxyhydroxide, such as boehmite or pseudoboehmite as a masking material that can be disseminated by an ammunition.

Abstract: The present description relates to a method and a system for generating a Fenton reagent. Particularly, the description relates to a method and a system for oxidizing contaminants from wastewater. The Fenton reagent can react with various organic compounds and metallic elements. The method of producing an in-situ Fenton reagent comprises: providing an aqueous solution comprising at least one contaminant; providing at least one column comprising i) an inlet and an outlet separated by a flow chamber, and ii) a mass of iron fibre in the flow chamber between the inlet and the outlet; providing at least one dispenser retaining a hydrogen peroxide generating solid and permitting passage of the aqueous solution through the dispenser; optionally acidifying the solution upstream of the at least one column, and passing the aqueous solution through the at least one column.

Abstract: Manage sulfur present as sulfur or a sulfur compound in a hydrocarbon feedstream while effecting dehydrogenation of hydrocarbon(s) (e.g. propane) contained in the hydrocarbon feedstream to its/their corresponding olefin (e.g. propylene where the hydrocarbon is propane) without subjecting the feedstream to desulfurization before it contacts a fluidizable dehydrogenation catalyst that is both a desulfurant and a dehydrogenation catalyst and comprises gallium and platinum on an alumina or alumina-silica catalyst support with optional alkali or alkaline earth metal such as potassium. Contact with such a catalyst yields a desulfurized crude olefin product that corresponds to the hydrocarbon and has a reduced amount of sulfur or sulfur compounds relative to the sulfur or sulfur compounds present in the hydrocarbon feedstream prior to contact with the catalyst.

Abstract: Methods for the use of peracid compositions having decreased hydrogen peroxide concentration for various water treatments, including oil- and gas-field operations, and/or other aseptic treatments are disclosed. In numerous aspects, peracetic acid is the preferred peracid and is treated with a peroxide-reducing agent to substantially reduce the hydrogen peroxide content. Methods for using the treated peracid compositions for treatment of drilling fluids, frac fluids, flow back waters and disposal waters are also disclosed for improving water condition, reducing oxidizing damage associated with hydrogen peroxide and/or reducing bacteria infestation.

Abstract: Provided is a water treatment device that suppresses the degradation of electrodes in a capacitive de-ionization treatment section and is capable of maintaining high water treatment capability. The water treatment device includes an activated carbon treatment section that receives an inflow of water having a total organic carbon concentration of 100 mg/l or less and adsorbs and removes organic matters contained in the water; and, on the downstream side of the activated carbon treatment section, a capacitive de-ionization treatment section including a pair of electrodes to which voltages having polarities opposite to each other are applied, a flow path, and ion exchange membranes. Ions contained in the water are adsorbed to the electrodes with voltages applied thereto, and voltages reverse to the voltages at the time of ions adsorption are applied to the electrodes to release the ions from the electrodes.

Abstract: Embodiments described herein generally relate to apparatus and methods for reducing CO2 from flue gas. Methods may include performing a chemisorption process in a first reactor comprising using at least a chemisorption solution comprising a sorbent. Methods may also include performing a desorption process treating the chemisorption solution with a powdered desorption catalyst after the chemisorption process has been performed.

Abstract: Dissolved oxygen in alcohol is efficiently removed with a simple configuration. Device for removing dissolved oxygen in alcohol has a hydrogen-occluding metal catalyst in which hydrogen is occluded, the catalyst being charged in a device. Dissolved oxygen is removed from alcohol that contains the dissolved oxygen by bringing the alcohol into contact with the hydrogen-occluding metal catalyst. A method of removing dissolved oxygen in alcohol has removing dissolved oxygen from alcohol that contains the dissolved oxygen by bringing the alcohol into contact with a hydrogen-occluding metal catalyst which occludes hydrogen.

Abstract: The method of producing activated carbon from fuel oil includes mixing the fuel oil with an activating chemical at room temperature to produce an activated fuel oil, carbonizing the activated fuel oil to produce activated carbon, and optionally washing the activated carbon produced. The produced activated carbon has high efficiency and it may be activated in a process that requires a comparatively low amount of energy, thus allowing the activated carbon to be regenerated in-situ.

Abstract: The invention relates to a method for treating wastewater containing nitroaromatics and nitrohydroxyaromatics, as for example arises in the production of nitroaromatics or in the production of nitrohydroxyaromatics, by a two-stage method consisting of pre-reduction and wet oxidation.

Abstract: Blending an electrically active, anodically coloring, electrochromic polymer with a non-electrochromic, non-electrically conductive binder polymer greatly enhances the performance of the anodically coloring, electrochromic polymer in an electrochromic device over time. In addition to improved physical characteristics of the blend, e.g., film build, durability etc, the coloristic properties, including color space and color strength, of the device comprising the blend are more durable than when using the neat polymer, and in certain instances, the color space and color intensity provided by the blend is superior to that available from the neat polymer.

Abstract: An activated carbon cloth-supported bimetallic Pd—Cu nanocatalyst is disclosed comprising about 1 wt % Pd and about 0.35-0.45 wt % Cu and having a surface Cu/Pd metal ratio of about 8-10 m2/m2. The nanocatalyst is capable of removing nitrate and/or nitrite from wastewater with a high selectivity to nitrogen.

Abstract: Catalysts prepared from abundant, cost effective metals, such as cobalt, nickel, chromium, manganese, iron, and copper, and containing one or more neutrally charged ligands (e.g., monodentate, bidentate, and/or polydentate ligands) and methods of making and using thereof are described herein. Exemplary ligands include, but are not limited to, phosphine ligands, nitrogen-based ligands, sulfur-based ligands, and/or arsenic-based ligands. In some embodiments, the catalyst is a cobalt-based catalyst or a nickel-based catalyst. The catalysts described herein are stable and active at neutral pH and in a wide range of buffers that are both weak and strong proton acceptors. While its activity is slightly lower than state of the art cobalt-based water oxidation catalysts under some conditions, it is capable of sustaining electrolysis at high applied potentials without a significant degradation in catalytic current. This enhanced robustness gives it an advantage in industrial and large-scale water electrolysis schemes.

Abstract: An odor control composition may be dosed to a wastewater treatment system to control hydrogen sulfide levels. The composition may include a sulfide-reducing agent and an oxidizer. Synergy between the compounds of the odor control composition may facilitate efficient reduction of hydrogen sulfide levels. The sulfide-reducing agent and the oxidizer may be present in a single odor control composition or may be dosed to the system separately.

Abstract: A method and system of providing ultrapure water for semiconductor fabrication operations is provided. The water is treated by utilizing a free radical scavenging system and a free radical removal system. The free radical scavenging system can utilize actinic radiation with a free radical precursor compound, such as ammonium persulfate. The free radical removal system can comprise use of a reducing agent. The ultrapure water may be further treated by utilizing ion exchange media and degasification apparatus. A control system can be utilized to regulate addition of the precursor compound, the intensity of the actinic radiation, and addition of the reducing agent to the water.

Abstract: The invention relates to a method for recovering gold by solvent extraction from an acidic chloride-containing aqueous solution or from slurry containing gold-bearing solids using a diester-based reagent that is poorly soluble in water as organic extraction solution. In accordance with the method, gold is extracted extremely effectively, but other precious metals and many other metals quite sparingly. Gold is stripped from the extraction phase with pure water, from which the gold can be reduced either chemically or electrochemically.

Abstract: The present invention relates to method and a system of reducing chromium (VI) from a chromium bearing solution. The reduction of the chromium (VI) is achieved by contacting the chromium bearing solution which comprises chromium (VI) ions in an aqueous solution with iron fibres in an exchange mass under oxidation-reduction potential conditions at a pH of at least 2.5, with entry of iron ions into solution in the aqueous solution and reduction of the chromium (VI) ions to chromium (III) recovered in the exchange mass. A solution substantially free of chromium (VI) ions and total chromium is produced and discharged from the exchange mass.

Abstract: Described herein is a liquid filtration device is disclosed comprising a fluid conduit fluidly connecting a fluid inlet to a fluid outlet; and a water filtration medium disposed in the fluid conduit; the water filter medium comprising a metal-containing particulate, wherein the metal-containing particulate comprises a thermolysis product of a metal carboxylate; and methods of removing chloramines from aqueous solutions.

Abstract: The present invention provides a liquid handling system comprising a reactor, wherein the reactor is structured such that it contains a gaseous phase and an aqueous phase, both phases being in contact with a heterogeneous hydrogenation catalyst immobilised or suspended within the aqueous phase, wherein the gaseous phase comprises hydrogen and wherein the aqueous phase comprises (i) a solution of amines; and (ii) nitrosamine and/or nitramine compounds resulting from amine-based gas sweetening processes. The invention further relates to a process for in-situ destruction of compounds in the aqueous phase from a scrubber system, wherein the process comprises contacting the aqueous phase with a gas phase comprising hydrogen and a heterogeneous catalyst, wherein the aqueous phase comprises (i) a solution of amines; and (ii) nitrosamine and/or nitramine compounds resulting from amine-based gas sweetening.

Abstract: The present invention includes a method for scavenging nitric oxide. The method includes contacting the nitric oxide with cerium oxide nanoparticles having a low 3+/4+ ratio.

Abstract: A method of decreasing the concentration of certain contaminants in liquids by the chemical reduction of the contaminant using a hydride. A suitable reactor is charged with the contaminated liquid. An amount of catalyst and then an amount of hydride are added to the reactor. The hydride reacts with the contaminant in the liquid, chemically reducing and thus destroying a portion of the contaminant and thereby reducing the concentration of the contaminant in the liquid. Additional hydride can be added to further reduce the concentration to meet a desired level.

Abstract: Disclosed is a method of controlling a real-time oxidation-reduction potential in a hot water system to inhibit corrosion in the hot water system. The method includes defining one or more operational protective zones in the hot water system. One or more of the operational protective zones includes an oxidation-reduction potential probe that is operable to measure a real-time oxidation-reduction potential in the hot water system at operating temperature and pressure. The probe transmits the measured real-time potential to the controller, which assesses and interprets the transmitted potential to determine whether it conforms to an oxidation-reduction potential setting. If the measured potential does not conform the oxidation-reduction potential setting, the controller is operable to feed or remove one or more active chemical species into or from the hot water system and further operable to change at least one system parameter.

Abstract: A treatment system for degrading chlorinated dense non-aqueous phase liquids (DNAPLs) is disclosed. The treatment system comprises a solvent system and hydrophobic zero valent irons distributed in the solvent system. In addition, the method of remediation of groundwater is also disclosed by using the treatment system.

Abstract: A method and system of providing ultrapure water for semiconductor fabrication operations is provided. The water is treated by utilizing a free radical scavenging system and a free radical removal system. The free radical scavenging system can utilize actinic radiation with a free radical precursor compound, such as ammonium persulfate. The free radical removal system can comprise use of a reducing agent. The ultrapure water may be further treated by utilizing ion exchange media and degasification apparatus. A control system can be utilized to regulate addition of the precursor compound, the intensity of the actinic radiation, and addition of the reducing agent to the water.

Abstract: A method and system of providing ultrapure water for semiconductor fabrication operations is provided. The water is treated by utilizing a free radical scavenging system and a free radical removal system. The free radical scavenging system can utilize actinic radiation with a free radical precursor compound, such as ammonium persulfate. The free radical removal system can comprise use of a reducing agent. The ultrapure water may be further treated by utilizing ion exchange media and degasification apparatus. A control system can be utilized to regulate addition of the precursor compound, the intensity of the actinic radiation, and addition of the reducing agent to the water.

Abstract: A mercury remediation method and apparatus for reducing mercury levels in water to a nanogram per liter level that uses four treatment steps: (1) chelation; (2) oxidation; (3) reduction; and (4) air stripping, vapor/liquid separation. There is a fifth step in the process, which does not involve the wastewater. It is to scrub the stripper air of the volatile mercury in an off-gas adsorption unit or to condense volatile mercury in a cryogenic mercury trap.

Abstract: Provided are methods and systems for continuously producing low concentrations of chlorine dioxide from dilute solutions of sodium chlorite. The low concentrations of chlorine dioxide produced allow for reduced exposure risk with direct application of the chlorine dioxide stream. The incorporation of a suitable chlorine dioxide detector permits continuous monitoring and control of chlorine dioxide production ensuring that the process stays within regulatory guidelines. Pretreatment of reaction water is preferred for achieving suitable conversion rates of the low concentrations of chlorite to chlorine dioxide.

Abstract: Methods, apparatus and systems for treating wastewater onboard small marine vessels. A pre-determined volume of wastewater generated onboard the vessel is mixed with a larger volume of seawater. This mixture is disinfected and subjected to further oxidation. The excess oxidants are neutralized and the treated effluent is discharged overboard the vessel.

Abstract: A system for treating ballast water in ballast tanks onboard vessels is provided. The system comprises one or more ballast tanks, a circulation pump circulating or recirculating, via a tubing, ballast water from and to the one or more ballast tanks, a nitrogen and/or carbon dioxide generator connected to the tubing on the delivery side of the recirculation pump in such a manner that nitrogen and/or carbon dioxide can be supplied to the ballast water, and one or more nozzle heads functionally connected to the tubing and arranged in one or more ballast tanks. The one or more nozzle heads comprises at least one nozzle for injecting the gas-containing water into the ballast tanks. At least one nozzle is configured for powered rotation about a first and a second axis which is perpendicular or not perpendicular to the first axis to the effect that a three-dimensional mixer pattern is produced.

Abstract: The present invention relates to a method for improving a wastewater purification process for a wastewater stream containing organic materials, raw sludge, a plurality of mercaptans, grit and grease wherein the raw sludge is thickened in the wastewater stream by injecting polymers. The method includes a step of injecting an additive agent prior to thickening the raw sludge to reduce odor produced by the organic materials and the mercaptans.

Abstract: Accelerated dechlorination of soil and water contaminated with chlorinated solvents in situ is achieved by delivering ferric ammonium citrate into the soils and/or water. The induction of ferric ammonium citrate into sulfate-rich reducing conditions initiates a combined abiotic and biotic mechanism for the dechlorination of subsurface contaminants. Initial and rapid removal of chlorinated solvents is achieved by way of reductive transformation, a mechanism utilizing the creation of an iron-bound soil mineral (pyrite) followed by stimulating conditions for enhanced biological natural attenuation.

Abstract: A hybrid chemical/mechanical water treatment plant and method employing rapid sulfur dioxide chemical disinfection and dewatering technology in conjunction with lime and oxidization/reduction agents to removal pharmaceuticals and personal care products from waters to meet operating constraints and environmental permitting restrictions and siting limitations for water treatment.

Abstract: A method for providing for the use of underground aquifers for water storage for municipalities or recharge. Water is treated and injected for storage in the aquifer by the addition of a small amount of a sulfide compound to remove dissolved oxygen and prevent dissolution of negative valence sulfur bearing minerals, such as pyrite, in the subsurface. The stored water may be subsequently withdrawn from the aquifer and treated to remove residual amounts of sulfide ions. The withdrawn water being suitable as potable water, irrigation water, industrial use water, and aquifer water level enhancement water.

Abstract: The invention is directed to processes for treating biosolids that result in high-value, nitrogen-containing, slow-release, organically-augmented inorganic fertilizer that are competitive with less valuable or more costly conventional commercially manufactured fertilizers. The process involves conditioning traditional waste-water biosolids and processing the conditioned biosolids continuously in a high throughput manufacturing facility. The exothermic design and closed loop control of the primary reaction vessel decreases significantly the amount of power necessary to run a manufacturing facility. The process utilizes green technologies to facilitate decreased waste and enhanced air quality standards over traditional processing plants. The fertilizer produced from recovered biosolid waste is safe and meets or exceeds the United States Environment Protection Agency (USEPA) Class A and Exceptional Quality standards and is not subject to restrictions or regulations.

Abstract: In one embodiment, a grey water treatment system includes an oxidation reactor for oxidizing grey water. The grey water treatment system also includes a biological reduction and precipitation system with microbes designed to remove one or more target components from the oxidized grey water.

Abstract: Methods for the use of peracid compositions having decreased hydrogen peroxide concentration for various water treatments, including oil- and gas-field operations, and/or other aseptic treatments are disclosed. In numerous aspects, peracetic acid is the preferred peracid and is treated with a peroxide-reducing agent to substantially reduce the hydrogen peroxide content.

Abstract: An improved method that requires no electricity or moving parts to increase lime utilization where pebble quicklime (CaO) and/or hydrated lime (Ca(OH)2) is used for mine drainage treatment. Lime utilization at such facilities has been historically poor due to the low solubility, high density, and large particle size of pebble quicklime. This invention takes two passive technologies, a diversion well-inspired MixWell system followed by a TROMPE-driven, air lift mixer for enhancing lime dissolution. It showed an estimated 40 to 57 percent reduction in lime usage.

Abstract: A controlled release remediation composition or compositions, a method making such composition(s), a method of using such composition(s), and a remediation system including such composition(s) are disclosed. The disclosed controlled release remediation composition or compositions include at least one chemical oxidant agent, optionally, at least two chemical oxidant agents; at least one encapsulant polymer; and, optionally, at least one matrix polymer. The disclosed controlled release remediation composition or compositions are capable of substantially constantly releasing an amount of the at least one chemical oxidant agent, optionally, amounts of the at least two chemical oxidant agents, for example, into an aqueous system such as may be found at a contaminated site, over at least about a one month period up to over about a three month period.

Abstract: A method of degrading halogenated organic compounds, to use of the method for decontaminating PFOS (perfluorooctanesulfonic acid) and PFOA (perfluorooctanoic acid) contaminated medium, and a composition such as that which is suitable to be applied in said method.

Abstract: The invention is directed to a process to prepare metal nanoparticles or metal oxide nanoparticles by applying a cathodic potential as an alternating current (ac) voltage to a solid starting metal object which solid metal object is in contact with a liquid electrolyte comprising a stabilising cation. The invention is also directed to the use of the nanoparticles as a catalyst.

Abstract: A process for affecting reductive conversion reactions in a reactor using the palladized bacterial cellulose immobilized on a support for reductive conversion reactions in a reactor.

Abstract: A dechlorinator for dechlorinating a stream of water comprises a housing comprising an inlet and an outlet. The housing defines a flow path between the inlet and the outlet. A filter is operatively supported in the housing and located in the flow path. At least one dechlorinating tablet is operatively supported in the housing and located in the flow path downstream of the filter for dechlorinating water flowing from the filter to the outlet.

Abstract: Hydrophobically modified Si-containing polyamines are useful for treating scale in industrial process streams. Preferred hydrophobically modified Si-containing polyamines are particularly useful for treating aluminosilicate scale in difficult-to-treat industrial process streams, such as in the Bayer alumina process streams, nuclear waste streams and kraft paper mill effluent streams.

Abstract: Light expanded clay aggregates are described that are prepared by firing and expanding a clay-based material, wherein metals such as palladium, copper or nickel are added to the clay together with iron prior to expansion and firing. The expanded clay aggregates can be used for cleaning of water contaminated with halogenated organic compounds. The latter are chemically degraded to harmless compounds in proximity of the added metals. The aggregates can be used as a reactive medium for treatment of contaminated groundwater, wastewater and landfill leachate.

Abstract: A method for treating ballast water with sulfurous acid to kill invasive species and remove oxygen from the ballast water to preserve hulls from rusting.

Abstract: Light expanded clay aggregates are described that are prepared by firing and expanding a clay-based material, wherein metals such as palladium, copper or nickel are added to the clay together with iron prior to expansion and firing. The expanded clay aggregates can be used for cleaning of water contaminated with halogenated organic compounds. The latter are chemically degraded to harmless compounds in proximity of the added metals. The aggregates can be used as a reactive medium for treatment of contaminated groundwater, wastewater and landfill leachate.

Abstract: The present invention relates to a method for reduce treating ballast water which has been subjected to a biocidal treatment with a chlorine-based oxidizing agent or an oxygen-based oxidizing agent, by using a tablet or pellet of sodium sulfite.

Abstract: A method and apparatus for treating waste water utilizing two energized agitated electrochemical reaction reactor units (each utilizing approximately 10 amps per gallon) with a reaction time of approximately 5 minutes wherein the first reaction vessel has a pH below 7 and a second reaction vessel has a pH of above the pH of the first reaction vessel and the effluent flows from a first agitated electrochemical reaction vessel to a degassing tank and then flows to a second agitated electrochemical reaction vessel and then to a flocculation tank.