Having Utility As A Reactive Material In An Electrochemical Cell; E.g., Battery, Etc. Patents (Class 252/182.1)
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Patent number: 11569497Abstract: The invention relates to a process for the preparation of a vanadium-carbon phosphate composite material, a vanadium-carbon phosphate composite material obtained according to the process, and to the uses of the composite material, especially as a precursor for the synthesis of electrochemically-active materials, electrode or active anode material.Type: GrantFiled: February 1, 2018Date of Patent: January 31, 2023Assignees: CENTRE NATIONAL DE LA RECHERCHE SCIENTIFIQUE, UNIVERSITE DE PICARDIE JULES VERNEInventors: Rénald David, Christine Surcin, Mathieu Morcrette
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Positive electrode active material for lithium ion secondary batteries and method for producing same
Patent number: 11569504Abstract: The production method is a method for producing a positive electrode active material for a lithium ion secondary battery which contains at least nickel and lithium, the method including: a firing process in which a mixture of a nickel compound powder and a lithium compound powder is fired; and a water washing process in which a lithium-nickel composite oxide powder obtained in the firing process is washed with water, wherein the firing process is performed under conditions such that a value obtained by dividing a ratio of an amount-of-substance of lithium to a total amount-of-substance of transition metals other than lithium in the lithium-nickel composite oxide powder after the washing with water by a ratio of an amount-of-substance of lithium to a total amount-of-substance of transition metals other than lithium in the lithium-nickel composite oxide powder before the washing with water exceeds 0.95.Type: GrantFiled: October 22, 2018Date of Patent: January 31, 2023Assignee: SUMITOMO METAL MINING CO., LTD.Inventors: Yasutaka Kamata, Yuji Kawakami, Tomomichi Nihei -
Patent number: 11555094Abstract: The present invention relates to a method for stabilizing aqueous dispersions, notably of polymers based on vinylidene fluoride (VDF), and to the use of the stabilized aqueous dispersion thus obtained in electrochemical applications.Type: GrantFiled: March 20, 2018Date of Patent: January 17, 2023Assignee: SOLVAY SPECIALTY POLYMERS ITALY S.P.A.Inventors: Serena Carella, Eliana Ieva, Mirko Mazzola, Giulio Brinati
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Patent number: 11552323Abstract: A biofuel cell includes a cathode, an anode, and a microbial community. At least one of the anode and the cathode contains a biochar prepared from a Trapa natans husk as an electrode material, and the anode is located in the microbial community. By using the biochar prepared from the Trapa natans husk as the electrode material, not only can the power density of the biofuel cell be increased, but the economic benefits of waste recycling can also be achieved.Type: GrantFiled: December 25, 2020Date of Patent: January 10, 2023Assignee: National Tsing Hua UniversityInventors: Fang-Yi Lin, Yao-Yu Lin, Chia-Chieh Hsu, Han-Yi Chen, Tzu-Yin Liu
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Patent number: 11545668Abstract: A method for producing an electrode material for a lithium-ion secondary battery. The method includes the following steps: (a) mixing components of a basic ingredient or active substance of electrode material and a conductive carbon material to obtain a conductive carbon material-composited material; (b) mixing the conductive carbon material-composited material and a surface layer-forming material; an (c) burning the mixture obtained at step (b) to obtain the electrode material. Also, a lithium-ion secondary battery including an electrode which comprises the material.Type: GrantFiled: October 21, 2013Date of Patent: January 3, 2023Assignee: HYDRO-QUEBECInventors: Vincent Gariepy, Abdelbast Guerfi, Kazuma Hanai, Pierre Hovington, Shinji Saito, Takehiko Sawai, Kazunori Urao, Karim Zaghib
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Patent number: 11522172Abstract: A negative electrode for a lithium metal battery, a manufacturing method thereof, and a lithium battery including the same. An adhesive layer including a binder and a conductive material between the negative current collector and the negative active material improves conductivity while also improving adherence between a negative current collector and a negative active material of the lithium battery.Type: GrantFiled: August 1, 2019Date of Patent: December 6, 2022Assignee: LG ENERGY SOLUTION, LTD.Inventor: Jeong In Yu
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Patent number: 11515531Abstract: According to one embodiment, an electrode is provided. The electrode includes an active material-containing layer. The active material-containing layer contains an active material and a flat plate-shaped silicate.Type: GrantFiled: February 27, 2020Date of Patent: November 29, 2022Assignee: KABUSHIKI KAISHA TOSHIBAInventors: Yasunobu Yamashita, Keigo Hoshina, Yasuhiro Harada, Norio Takami
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Patent number: 11515528Abstract: Described herein are improved composite anodes and lithium-ion batteries made therefrom. Further described are methods of making and using the improved anodes and batteries. In general, the anodes include a porous composite having a plurality of agglomerated nanocomposites. At least one of the plurality of agglomerated nanocomposites is formed from a dendritic particle, which is a three-dimensional, randomly-ordered assembly of nanoparticles of an electrically conducting material and a plurality of discrete non-porous nanoparticles of a non-carbon Group 4A element or mixture thereof disposed on a surface of the dendritic particle. At least one nanocomposite of the plurality of agglomerated nanocomposites has at least a portion of its dendritic particle in electrical communication with at least a portion of a dendritic particle of an adjacent nanocomposite in the plurality of agglomerated nanocomposites.Type: GrantFiled: March 10, 2022Date of Patent: November 29, 2022Assignees: GEORGIA TECH RESEARCH CORPORATION, SILA NANOTECHNOLOGIES, INC.Inventors: Gleb Yushin, Oleksandr Magazynskyy, Patrick Dixon, Benjamin Hertzberg
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Patent number: 11495797Abstract: A negative electrode active material including a silicon-carbon-based particle, the silicon-carbon-based particle having a SiCx matrix and boron doped in the SiCx matrix, wherein x of the SiCx matrix is 0.3 or more and less than 0.6.Type: GrantFiled: November 6, 2018Date of Patent: November 8, 2022Assignee: LG ENERGY SOLUTION, LTD.Inventors: Il Geun Oh, Eun Kyung Kim, Yong Ju Lee, Rae Hwan Jo, Su Min Lee, Jung Hyun Choi
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Patent number: 11490740Abstract: The invention pertains to a method of monitoring the quality of a mattress during its lifetime, wherein the mattress is an assembly of multiple separate parts, wherein the parts are mechanically interconnected, the method comprising during its lifetime, assessing at least one property of the mattress, determining whether or not the property meets a predetermined specification, and when the property does not meet the predetermined specification, identifying a part of the said multiple separate parts that corresponds to the property, removing the identified part from the assembly and optionally replacing the removed part with a replacement part, wherein the mattress that is monitored is manufactured by forming the mechanical interconnection with an adhesive, which adhesive has a first order phase-transition temperature between 80° C. and 180° C.Type: GrantFiled: July 29, 2019Date of Patent: November 8, 2022Assignee: COVESTRO (NETHERLANDS) B.V.Inventors: Alwin Papegaaij, Geert Doorlag, Hendrik Willem Dijkman, Jan Henderikus Udding
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Patent number: 11489158Abstract: Use of aluminum in a lithium rich cathode material of the general formula (I) for suppressing gas evolution from the cathode material during a charge cycle and for increasing the charge capacity of the cathode material.Type: GrantFiled: December 18, 2018Date of Patent: November 1, 2022Assignee: Dyson Technology LimitedInventors: Matthew Robert Roberts, Peter George Bruce, Francis Gachau Kinyanjui
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Patent number: 11472715Abstract: The method of making carbon-zinc oxide (C—ZnO) nanoparticles includes grinding a mixture of zinc nitrate hexahydrate (Zn(NO3)2.6H2O) and furfural (C4H3OCHO) to produce a ground mixture. As a non-limiting example, the zinc nitrate hexahydrate (Zn(NO3)2.6H2O) and the furfural (C4H3OCHO) may be placed in a mortar and ground, by hand with a pestle, for approximately 10 minutes. The ground mixture is then heated to produce the C—ZnO nanoparticles. As a non-limiting example, the ground mixture may be heated in a quartz tube at a temperature of approximately 500° C.Type: GrantFiled: February 6, 2021Date of Patent: October 18, 2022Assignee: KING FAISAL UNIVERSITYInventors: Sajid Ali Ansari, Nazish Parveen, Abdullah Aljaafari, Adil Ahmed Al Shoaibi
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Patent number: 11476456Abstract: A lithium cobalt-based positive electrode active material is provided. The lithium cobalt-based positive electrode active material includes a core portion including a lithium cobalt-based oxide represented by Formula 1 and a shell portion including a lithium cobalt-based oxide represented by Formula 2, wherein the lithium cobalt-based positive electrode active material includes 2500 ppm or more, preferably 3000 ppm or more of a doping element M based on the total weight of the positive electrode active material. An inflection point does not appear in a voltage profile measured during charging/discharging a secondary battery including the lithium cobalt-based positive electrode active material.Type: GrantFiled: November 13, 2018Date of Patent: October 18, 2022Inventors: Chi Ho Jo, Min Kyu You, Sung Bin Park, Hyuck Hur, Jin Tae Hwang, Wang Mo Jung
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Patent number: 11462724Abstract: A method for manufacturing electrodes includes mixing a powder to form a homogenous blend, injecting a lubricant into the homogenous blend to form a dough, kneading the dough to form a fibrillated dough, and outputting segments of the fibrillated dough. The method also includes processing the segments into a continuous plaque, drying the continuous plaque to form an active material sheet, laminating portions of the active material sheet to a current collector substrate to form an electrode blank, and sectioning the electrode blank into electrodes.Type: GrantFiled: April 27, 2022Date of Patent: October 4, 2022Assignee: ZAF ENERGY SYSTEMS, INCORPORATEDInventors: Michael J. Gordon, Shiloh J. Williams, Allen Charkey, Andrew Souder, II
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Patent number: 11450847Abstract: Alkaline electrochemical cells are provided, wherein dissolved zinc oxide or zinc hydroxide is included at least in the free electrolyte solution, and/or solid zinc oxide or zinc hydroxide is included in the anode, so as to slow formation of a zinc oxide passivation layer on a zinc electrode. Methods for preparing such cells are also provided.Type: GrantFiled: November 5, 2019Date of Patent: September 20, 2022Assignee: Energizer Brands, LLCInventors: Robert P. Johnson, Robert E. Ray, Jr., Weiwei Huang, Zhufang Liu, Steven J. Limmer
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Patent number: 11450853Abstract: An object of the present invention is to provide a carbon material for negative electrodes of non-aqueous secondary batteries having a high capacity, a high output, excellent cycle characteristics and a low irreversible capacity. The present invention relates to a carbon material for negative electrodes of non-aqueous secondary batteries, the carbon material comprising: (1) a composite carbon particles (A) containing elemental silicon, and (2) amorphous composite graphite particles (B) in which graphite particles (C) and amorphous carbon are composited.Type: GrantFiled: May 27, 2016Date of Patent: September 20, 2022Assignee: Mitsubishi Chemical CorporationInventors: Daigo Nagayama, Tooru Fuse, Hisako Kondo
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Patent number: 11450888Abstract: One aspect of the present invention is a nonaqueous electrolyte for an energy storage device comprising: an alkali metal salt; a first aprotic organic solvent coordinating to an alkali metal ion in the alkali metal salt, and not including a fluorine atom; a second aprotic organic solvent including a fluorine atom; and an additive comprising a polar group and a group including a fluorine atom, wherein a content of the alkali metal salt is no less than 0.9 mol/kg and less than 2 mol/kg, a content of the first aprotic organic solvent with respect to the content of the alkali metal salt in terms of a molar ratio is no less than 0.7 and no greater than 4, and a content of the second aprotic organic solvent with respect to a total amount of the first aprotic organic solvent, the second aprotic organic solvent and the additive is no less than 40% by volume.Type: GrantFiled: August 10, 2018Date of Patent: September 20, 2022Assignees: GS Yuasa International Ltd., THE DOSHISHAInventors: Hiroe Nakagawa, Katsuyuki Takahashi, Minoru Inaba, Takayuki Doi, Ryo Matsumoto
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Patent number: 11444272Abstract: The present disclosure relates to a positive electrode for a solid electrolyte battery which includes: a positive electrode current collector; a first positive electrode active material layer formed on at least one surface of the positive electrode current collector and including a first positive electrode active material, a first solid electrolyte and a first electrolyte salt; and a second positive electrode active material layer formed on the first positive electrode active material layer and including a second positive electrode active material, a second solid electrolyte, a second electrolyte salt and a plasticizer, wherein the plasticizer has a melting point of 30-130° C. The present disclosure also relates to a solid electrolyte battery including the positive electrode.Type: GrantFiled: April 10, 2019Date of Patent: September 13, 2022Inventors: Ji-Hoon Ryu, Jung-Pil Lee, Sung-Joong Kang, Eun-Bee Kim, Hyo-Sik Kim, Suk-Woo Lee, Jae-Hyun Lee
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Patent number: 11424438Abstract: A cathode active material for a lithium secondary battery, the cathode method including a core including a lithium metal oxide and a coating layer disposed on the surface and the inner grain boundaries of the core, wherein the coating layer includes a metal carbide, and a method of manufacturing the same.Type: GrantFiled: September 19, 2019Date of Patent: August 23, 2022Assignees: Hyundai Motor Company, Kia Motors CorporationInventors: Jieun Lee, Yeolmae Yeo, Seung-Min Oh, Sang Mok Park, Yoon Sung Lee, Dongjun Kim
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Patent number: 11424456Abstract: A mixed conductor, a method of preparing the same, and a cathode, a lithium-air battery, and an electrochemical device each including the mixed conductor. The mixed conductor is represented by Formula 1 and having electronic conductivity and ionic conductivity: LixMO2-???Formula 1 wherein, in Formula 1, M is a Group 4 element, a Group 5 element, a Group 6 element, a Group 7 element, a Group 8 element, a Group 10 element, a Group 11 element, a Group 12 element, or a combination thereof, and 0<x<1 and 0???1 are satisfied.Type: GrantFiled: October 21, 2019Date of Patent: August 23, 2022Assignee: SAMSUNG ELECTRONICS CO., LTD.Inventors: Sangbok Ma, Hyukjae Kwon, Hyunpyo Lee, Donghwa Seo, Dongmin Im
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Patent number: 11411251Abstract: An electrolyte including: a lithium salt; a non-aqueous solvent; a compound represented by Formula 1; and a compound represented by Formula 2 wherein R1, R2, R3, R11, and R12 in Formulae 1 and 2 are as described in the detailed description.Type: GrantFiled: December 9, 2019Date of Patent: August 9, 2022Assignees: SAMSUNG ELECTRONICS CO., LTD., SAMSUNG SDI CO., LTD.Inventors: Insun Park, Myongchun Koh, Jinah Seo, Dongyoung Kim, Yeonji Chung
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Patent number: 11387463Abstract: Provided is an electrode for an electrochemical device that has excellent peel strength and can ensure a high level of safety of an electrochemical device. The electrode for an electrochemical device includes a current collector and an electrode mixed material layer on the current collector. The electrode mixed material layer contains an electrode active material, a binder, and a foaming agent. The binder is a polymer including a diene monomer unit and/or nitrile group-containing monomer unit, and in which the total proportion constituted by the diene monomer unit and nitrile group-containing monomer unit is 10 mass % to 80 mass %. Volume resistivity RA of a laminate of the electrode mixed material layer and current collector at 25° C. is 0.1 ?·cm to 200 ?·cm, and a ratio of volume resistivity RB of the laminate at 350° C. relative to volume resistivity RA of the laminate at 25° C. is 10 or more.Type: GrantFiled: July 17, 2018Date of Patent: July 12, 2022Assignee: ZEON CORPORATIONInventors: Yasuhiro Isshiki, Kenya Sonobe
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Patent number: 11365130Abstract: The present invention provides a positive electrode active material precursor for a lithium secondary battery, in which the positive electrode active material precursor is represented by the following composition formula (I), a ratio (?/?) between a half width ? of a peak that is present within a range of a diffraction angle 2?=19.2±1° and a half width ? of a peak that is present within a range of 2?=38.5±1° is equal to or greater than 0.9 in powder X-ray diffraction measurement using a CuK? beam: NixCoyMnzMw(OH)2??(I) [0.7?x<1.0, 0<y?0.20, 0?z?0.20, 0?w?0.1, and x+y+z+w=1 are satisfied, and M is one or more selected from the group consisting of Mg, Ca, Sr, Ba, Ti, Zr, V, Nb, Cr, Mo, W, Fe, Ru, Cu, Zn, B, Al, Ga, Si, Sn, P, and Bi].Type: GrantFiled: October 31, 2017Date of Patent: June 21, 2022Assignees: SUMITOMO CHEMICAL COMPANY, LIMITED, TANAKA CHEMICAL CORPORATIONInventors: Yuichiro Imanari, Yusuke Maeda
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Patent number: 11359215Abstract: A bacterially induced crystal particle is formed by a composite shell that encloses a hollow space. The composite shell layer includes a biomaterial and a metallic material. The biomaterial includes cell wall or cell membrane of a bacterium. The metallic material includes oxides, sulfides, selenides, acid salt compounds of a transition metal, or any combination thereof. When the bacterially induced crystal particle is spheric, the composite shell is formed by two dome-shaped portions, and a thickness of each of the dome-shaped portions is not less than 1/73 of a diameter of the bacterially induced crystal particle. Alternatively, when the bacterially induced crystal particle is rod-shaped, the thickness of the dome-shaped portions is not less than 1/73 of a width of the bacterially induced crystal particle, and a thickness of the cylindrical portion is not less than 1/37 of the width of the bacterially induced crystal particle.Type: GrantFiled: November 17, 2017Date of Patent: June 14, 2022Assignee: ACON-HOLDING INC.Inventor: Pao-Hung Lin
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Patent number: 11348741Abstract: This invention relates to electrical engineering. In particular, the invention relates to the design of electrochemical device storing electric energy, and can be used in modern power engineering, for example, in devices storing regenerative braking energy in transport, as traction batteries for electric transport (electric vehicles, hybrid electric vehicles), in emergency power systems when operating in a floating or trickle charge mode. The invention ensures steady operation of this device due to stable preservation of a given concentration of electrolyte components on the electrodes, and improvement of service life in various modes of operation.Type: GrantFiled: December 14, 2018Date of Patent: May 31, 2022Assignee: Geyser Batteries OYInventors: Aleksey Ivanovich Belyakov, Nelya Vasilievna Khodyrevskaya, Mikhail Serafimovich Zvyagintsev
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Patent number: 11322729Abstract: A method for manufacturing zinc negative electrodes includes mixing a powder including zinc with polytetrafluoroethylene to form a homogenous blend, injecting a lubricant into the homogenous blend to form a dough, kneading the dough to form a fibrillated dough, and extruding the fibrillated dough through a die to form a ribbon. The method also includes calendering the ribbon to a target thickness to form a plaque, drying the plaque to form an active material sheet, laminating portions of the active material sheet to a current collector substrate to form an electrode blank, and sectioning the electrode blank into zinc negative electrodes.Type: GrantFiled: November 5, 2021Date of Patent: May 3, 2022Assignee: ZAF ENERGY SYSTEMS, INCORPORATEDInventors: Michael J. Gordon, Shiloh J. Williams, Allen Charkey, Andrew Souder, II
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Patent number: 11289691Abstract: The present invention discloses a spherical or spherical-like lithium battery cathode material, a battery and preparation methods and applications thereof. The chemical formula of the cathode material is: LiaNixCoyMnzMbO2, wherein 1.0?a?1.2; 0.0<b?0.05; 0.30?x?0.90; 0.05?y?0.40; 0.05?z?0.50; x+y+z+b=1; M is one or two or more of Mg, Ti, Al, Zr, Y, Co, Mn, Ni, Ba and a rare earth element. A single ?-NaFeO2 type layered structure of the cathode material is shown by a powder X-ray diffraction pattern and full width at half maximum FWHM (110) of the (110) diffraction peak near a diffraction angle 2? of 64.9° is in the range of 0.073 to 0.Type: GrantFiled: January 24, 2020Date of Patent: March 29, 2022Assignee: Guizhou Zhenhua E-Chem Inc.Inventors: Chaoyi Zhou, Lijuan Wang, Zhu'an Yin, Daixiang Yang, Qianxin Xiang, Ming Mei, Peng Peng
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Patent number: 11271210Abstract: A lithium battery cathode material comprises lithium transition metal-based material selected from lithium transition metal oxides and lithium transition metal phosphates, and crystalline silicon carbide residing at grain boundaries of the lithium transition metal-based material, forming conductive pathways along the grain boundaries, the crystalline silicon carbide being less than 10 wt. % of the cathode material.Type: GrantFiled: December 4, 2019Date of Patent: March 8, 2022Assignee: Apple Inc.Inventors: Mona Shirpour, Tetsuya Ishikawa, Sally S. Lou, Juchuan Li, Shawn William Snyder
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Patent number: 11258055Abstract: The present invention relates to a cathode active material for a lithium secondary battery, and more particularly, to a cathode active material for a lithium secondary battery, which includes a core portion and a shell portion surrounding the core portion, in which a total content of cobalt in the core portion and the shell portion is 5 to 12 mol %, and the content of cobalt in the core portion and the shell portion is adjusted to be within a predetermined range. In the cathode active material precursor and the cathode active material for a secondary battery prepared using the same according to the present invention, optimal capacity of a lithium secondary battery may be increased by adjusting the cobalt content in the particles of the cathode active material, and life characteristics may be enhanced by improving stability.Type: GrantFiled: November 21, 2018Date of Patent: February 22, 2022Assignee: ECOPRO BM CO., LTD.Inventors: Sung Jin Jang, Moon Ho Choi, Jun Won Suh, Jung Han Lee, Ji Hyun Nam, Seung Woo Choi
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Patent number: 11251431Abstract: A high discharge capacity in an all-solid-state battery in which lithium vanadium phosphate is used in a positive electrode active material layer and a negative electrode active material layer. An all-solid-state battery wherein a positive electrode active material layer and a negative electrode active material layer contain lithium vanadium phosphate, which includes a Li- and V-containing polyphosphate compound and satisfies 1.50<Li/V?2.30, with the percentage of divalent V included in the V being 5˜80%. Thus, a high discharge capacity can be provided.Type: GrantFiled: March 28, 2018Date of Patent: February 15, 2022Assignee: TDK CORPORATIONInventor: Takeo Tsukada
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Patent number: 11239457Abstract: According to one embodiment, provided is a nonaqueous electrolyte battery including a positive electrode, a negative electrode, and a nonaqueous electrolyte. The positive electrode includes a spinel type lithium-manganese composite oxide and a lithium cobalt oxide, which satisfy formula (1): 0.01?B/(A+B)<0.05. The negative electrode includes a titanium-containing oxide. The nonaqueous electrolyte battery satisfies formula (2): 0.3?C/D 0.8. A is a weight ratio (wt %) of the spinel type lithium-manganese composite oxide. B is a weight ratio (wt %) of the lithium cobalt oxide. C is a pore specific surface area (m2/g) of the positive electrode. D is a pore specific surface area (m2/g) of the negative electrode.Type: GrantFiled: March 22, 2019Date of Patent: February 1, 2022Assignees: KABUSHIKI KAISHA TOSHIBA, Toshiba Infrastructure Systems & Solutions CorporationInventors: Ryo Hara, Dai Yamamoto, Kazuhiro Namba
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Patent number: 11217808Abstract: A raw material of an electrolyte solution that is to be dissolved in a solvent to form an electrolyte solution, and the raw material of an electrolyte solution is a raw material of an electrolyte solution that is a solid or semisolid that contains Ti in an amount of 2 mass % to 83 mass % inclusive, Mn in an amount of 3 mass % to 86 mass % inclusive, and S in an amount of 6 mass % to 91 mass % inclusive.Type: GrantFiled: November 2, 2018Date of Patent: January 4, 2022Assignees: SUMITOMO ELECTRIC INDUSTRIES, LTD., TAYCA CORPORATIONInventors: Hirokazu Kaku, Ryouta Tatsumi, Tatsuya Tsurumura
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Patent number: 11189823Abstract: The present invention provides a power battery and a positive electrode plate thereof. The positive electrode plate includes a positive current collector and a positive active material layer formed on the positive current collector. The positive active material layer contains a mixture of lithium iron phosphate and FeF3, or a mixture of lithium iron phosphate and LiFe2F6, or a mixture of lithium iron phosphate, FeF3 and LiFe2F6. FeF3 or LiFe2F6 has a high gram capacity of more than 200 mAh/g and has a charge and discharge interval close to that of lithium iron phosphate, which can improve the energy density and the safety performance of the power battery.Type: GrantFiled: June 10, 2019Date of Patent: November 30, 2021Assignee: Contemporary Amperex Technology Co., LimitedInventors: Ruifa Li, Xiaomei Liu, Guopeng Teng, Yonggang Xu, Bo Li
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Patent number: 11158853Abstract: Provided are electrochemically active secondary particles that provide excellent capacity and improved cycle life. The particles are characterized by a plurality of nanocrystals with small average crystallite size. The reduced crystallite size reduces impedance generation during cycling thereby improving capacity and cycle life. Also provided are methods of forming electrochemically active materials, as well as electrodes and electrochemical cells employing the secondary particles.Type: GrantFiled: April 27, 2017Date of Patent: October 26, 2021Assignee: CAMX Power LLCInventors: Adrian Pullen, Jane Rempel, Suresh Sriramulu, David Ofer
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Patent number: 11152160Abstract: The high-rate hybrid supercapacitor (HSC) has a positive electrode made from copper oxide (CuO)-cobalt oxide (CoO) core-shell nanocactus-like heterostructures produced on a nickel foam substrate, a negative electrode made by coating nickel foam with graphene ink, and a separator of cellulose paper. The heterostructures each have a core of CuO nanoflakes and a shell of CoO nanoneedles extending from the nanoflakes. The HSC achieves a specific capacity of 173.9 mA h g?1 at 1 A g?1 and long cycle life with 94% retention over 5000 cycles at 4 A g?1, and also exhibits a stable operating voltage window of 1.6 V, energy density of 56.5 W h kg?1, and cycling stability of 98.8% retention with coulombic efficiency of 98.7% over 4000 cycles.Type: GrantFiled: September 15, 2020Date of Patent: October 19, 2021Assignee: UNITED ARAB EMIRATES UNIVERSITYInventors: Ihab M. Obaidat, Hee-Je Kim, Chandu V. V. Muralee Gopi, Sambasivam Sangaraju
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Patent number: 11152616Abstract: To provide a hydroxide precursor having a high density, a method for producing a lithium transition metal composite oxide using the precursor, a positive active material having a large discharge capacity per unit volume, which uses the composite oxide, an electrode for nonaqueous electrolyte secondary battery, and a nonaqueous electrolyte secondary battery. A method for producing a transition metal hydroxide precursor for use in production of a lithium transition metal composite oxide, including adding a solution containing a transition metal (Me) into a reaction tank in which a water solvent of dissolution of a complexing agent and a reducing agent has been charged in advance to coprecipitate a transition metal hydroxide that includes Mn and Ni, or Mn, Ni and Co, and has a mole ratio Mn/Me of larger than 0.5 and a mole ratio Co/Me of 0.15 or less.Type: GrantFiled: July 5, 2017Date of Patent: October 19, 2021Assignee: GS Yuasa International Ltd.Inventors: Daisuke Endo, Hiromasa Muramatsu
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Patent number: 11145849Abstract: The invention relates to methods for producing Si/C composite particles, characterised in that mixtures containing silicon particles, one or more oxygen-free polymers, one or more carbon additives based on a carbon modification and one or more liquid dispersing agents are dried by spray drying and the pre-composite particles thus obtained are thermally treated.Type: GrantFiled: February 27, 2017Date of Patent: October 12, 2021Assignee: WACKER CHEMIE AGInventors: Dennis Troegel, Jelena Pantelic-Seidl
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Patent number: 11133524Abstract: The present invention relates to a negative electrode active material which includes a secondary particle including a first particle which is a primary particle, wherein the first particle includes a first core and a first surface layer which is disposed on a surface of the first core and contains carbon, and the first core includes a metal compound which includes one or more of a metal oxide and a metal silicate and one or more of silicon and a silicon compound; a method of preparing the same; an electrode including the same; and a lithium secondary battery including the same.Type: GrantFiled: June 2, 2017Date of Patent: September 28, 2021Assignee: LG CHEM, LTD.Inventors: Jung Hyun Choi, Yong Ju Lee, Eun Kyung Kim
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Patent number: 11127939Abstract: Electrode material, for a lithium-ion-based electrochemical cell, containing primary particles of a Mn-containing spinel-type metal oxide selected from the group consisting of spinel-type lithium-nickel-manganese-oxide, spinel-type lithium-manganese-oxide, and mixtures thereof. Mn of the Mn-containing spinel-type metal oxide is partially substituted with a substitution-element selected from the group consisting of Si, Hf, Zr, Fe, Al, V and mixtures thereof and the primary particles are aggregated in order to form secondary particles, with the secondary particles having the shape of a microsphere.Type: GrantFiled: December 21, 2018Date of Patent: September 21, 2021Assignee: Bayerische Motoren Werke AktiengesellschaftInventors: Kamelia Detig-Karlou, Ann-Christin Gentschev, Miriam Karin Keppeler, Sung-Jin Kim, Madhavi Srinivasan
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Patent number: 11108044Abstract: A rechargeable lithium battery includes an electrolyte, a negative electrode, and a positive electrode. The negative electrode includes a negative active material layer on a negative current collector, and includes a carbon-based negative active material. The negative electrode having a Degree of Divergence (DD) value of about 19 to about 60. The positive electrode includes a positive active material layer and a positive current collector, and includes a positive active material and a porous structured additive. The content of the porous structured additive is about 0.01 wt % to about 2 wt % based on 100 wt % of the positive active material layer.Type: GrantFiled: November 1, 2017Date of Patent: August 31, 2021Assignee: Samsung SDI Co., Ltd.Inventors: Junkyu Lee, Bokhyun Ka, Na-Ri Seo, Kyeuyoon Sheem, Jinhyon Lee, Eun-Hyung Choi
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Patent number: 11101467Abstract: A metal-ion secondary battery is provided. The metal-ion secondary battery includes a positive electrode. The positive electrode includes at least one current-collecting layer and at least one active layer, wherein the current-collecting layer and the active layer are mutually stacked, and the current-collecting layer has at least one first through-hole.Type: GrantFiled: August 8, 2017Date of Patent: August 24, 2021Assignee: INDUSTRIAL TECHNOLOGY RESEARCH INSTITUTEInventors: Chien-Chih Chiang, Kuang-Yao Chen, Chun-Hsing Wu, Chang-Chung Yang, Wen-Sheng Chang
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Patent number: 11094933Abstract: Electrodes for rechargeable batteries that include silicon and a binder are provided. Binders for use with silicon electrodes are provided, including polysiloxane binders that can be prepared prior to preparation of the electrode, or provided as monomers to be cure-polymerized at the time of the curing of the electrode.Type: GrantFiled: July 18, 2017Date of Patent: August 17, 2021Assignee: University of Kentucky Research FoundationInventors: Susan A. Odom, Darius A Shariaty, Yang-Tse Cheng
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Patent number: 11088389Abstract: A lithium iron phosphate electrochemically active material for use in an electrode and methods and systems related thereto are disclosed. In one example, a lithium iron phosphate electrochemically active material for use in an electrode is provided including, a dopant comprising vanadium and optionally a co-dopant comprising cobalt.Type: GrantFiled: June 8, 2016Date of Patent: August 10, 2021Assignee: A123 SYSTEMS LLCInventors: Chuanjing Xu, Maha Hammoud, Judith M. Laforest, Hyojin Lee, Derek Johnson
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Patent number: 11063250Abstract: The present invention relates to a cathode active material composition for a lithium secondary battery and a lithium secondary battery including the same, and more particularly, to a cathode active material composition for a lithium secondary battery, including a mixture of particles which are different in Ni composition and size and prepared at the same heat treatment temperature, and a lithium secondary battery including the same. According to the present invention, optimal capacity manifestation temperatures of a coarse particle and a fine particle may be adjusted to be similar by adjusting an Ni content of the coarse particle and the fine particle, and thus, a lithium secondary battery having enhanced output and lifetime may be manufactured.Type: GrantFiled: November 15, 2018Date of Patent: July 13, 2021Assignee: ECOPRO BM CO., LTD.Inventors: Moon Ho Choi, Jun Won Suh, Jung Han Lee, Ji Hyun Nam, Sung Jin Jang, Seung Woo Choi
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Patent number: 11040881Abstract: A method for preparing a Na3V2(PO4)2F3 material, including at least the steps: a) reducing the vanadium oxide, V2O5, under a reducing atmosphere in the absence of elementary carbon and in the presence of at least one phosphate anion precursor in order to form vanadium phosphate, VPO4; and b) exposing, under an inert atmosphere, a mixture of the VPO4 material obtained in step a) with an effective amount of sodium fluoride, NaF, and at least one hydrocarbon- and oxygen-containing compound which is a source of elementary carbon, to temperature conditions that are favourable for calcining said mixture so as to form said Na3V2(PO4)2F3 compound. Also, a related electrode material, an electrode and a secondary sodium battery using the presented material.Type: GrantFiled: October 13, 2016Date of Patent: June 22, 2021Assignees: COMMISSARIAT A L'ENERGIE ATOMIQUE ETAUX ENERGIES ALTERNATIVES, CENTRE NATIONAL DE LA RECHERCHE SCIENTIFIQUE, UNIVERSITE DE PICARDIE JULES VERNESInventors: Nikita Hall, Sylvain Boulineau, Laurence Croguennec, Sébastien Launois, Christian Masquelier, Loïc Simonin
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Patent number: 11038169Abstract: Provided are a cobalt oxide (Co3O4) for a lithium secondary battery, having an average particle diameter (D50) of about 14 ?m to about 19 ?m and a tap density of about 2.1 g/cc to about 2.9 g/cc, a method of preparing the cobalt oxide, a lithium cobalt oxide for a lithium secondary battery prepared from the cobalt oxide, and a lithium secondary battery including a cathode including the lithium cobalt oxide.Type: GrantFiled: September 5, 2017Date of Patent: June 15, 2021Assignee: Samsung SDI Co., Ltd.Inventors: Junseok Park, Seonyoung Kwon, Youngki Kim, Jihyun Kim, Dohyung Park, Sooyoun Park
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Patent number: 11031593Abstract: The present invention relates to a method of producing a cobalt-coated precursor, the cobalt-coated precursor produced by the method and a positive electrode active material for a lithium secondary battery, the positive electrode active material which is prepared using the cobalt-coated precursor and, more particularly, to a method of preparing a new positive electrode active material having improved high capacity and stability by coating cobalt on the surface of a precursor in the precursor step, thereby improving characteristics of the precursor degraded when washed with water, and a positive electrode active material prepared by the method.Type: GrantFiled: January 2, 2017Date of Patent: June 8, 2021Assignees: ECOPRO BM CO., LTD., SAMSUNG SDI CO., LTD.Inventors: Moon Ho Choi, Jong Seung Shin, Hyun Jong Yu, Suk Yong Jeon, Eun Ok Oh, Sang Wook Lee, Yoon Young Choi
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Patent number: 11021367Abstract: Provided is a porous lithium composite phosphate-based compound containing lithium and having open pores formed in primary particles. As the open pores are formed in the primary particles themselves, a contact area between an electrolyte and the lithium composite phosphate-based compound is maximized, and low conductivity is compensated for, such that a diffusion rate of lithium ions is remarkably increased, and when the lithium composite phosphate-based compound is used as an active material of a secondary battery, the secondary battery may be charged and discharged at a high speed. Additionally, there are advantages in that an electrode density may be significantly increased in addition to the increase in the diffusion rate of the lithium ions, and charge and discharge cycle characteristics may be significantly stable.Type: GrantFiled: August 14, 2019Date of Patent: June 1, 2021Assignee: SK INNOVATION CO., LTD.Inventors: Min Gu Kang, Seong Ho Lee, Jung In Yeon, Kook Hyun Han, Jung Hwan Kim
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Patent number: 11024846Abstract: A high energy/power density, long cycle life and safe lithium ion cell capable of long-term deep discharge/storage near zero-volt is described. The cell utilizes a near zero-volt storage capable anode, such as a spinel Li4Ti5O12, coupled to a high voltage, high-energy and/or high-power density cathode, such as LiNi0.5Mn1.5O4. The near zero-volt storage cell is rechargeable and affords safety advantages for battery transportation, storage, and handling, and significant cost reductions for cell maintenance. The cells produce high-energy and/or high-power densities and long cycle life. The cell anode, cathode, and separator active materials are coated with one or more protection or stability enhancing and/or conductivity enhancing materials to enhance electrochemical performance and to strengthen stabilities for long-term cycle life and storage life.Type: GrantFiled: March 22, 2018Date of Patent: June 1, 2021Assignee: ADA Technologies, Inc.Inventor: Weibing Xing
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Patent number: 10953380Abstract: Provided is a process for manufacturing 2D inorganic compound platelets, the process comprising (a) preparing a first stock containing a 3D layered inorganic compound material dispersed in a liquid medium, (h) injecting the first stock into a continuous reactor having a vortex flow, (c) operating the continuous reactor to form a reaction product suspension containing 2D inorganic compound platelets dispersed in the liquid medium, and (d) separating and recovering said 2D inorganic compound platelets from said product suspension. The product suspension may be directed to flow back to the continuous director for further processing for at least another pass through the reactor, prior to step (d). The continuous reactor is preferably a Couette-Taylor reactor.Type: GrantFiled: October 21, 2019Date of Patent: March 23, 2021Assignee: Global Graphene Group, Inc.Inventors: Yi-jun Lin, Hsuan-Wen Lee, Aruna Zhamu, Bor Z. Jang