Having Utility As A Reactive Material In An Electrochemical Cell; E.g., Battery, Etc. Patents (Class 252/182.1)
-
Patent number: 9979019Abstract: A composite positive electrode active material including: an overlithiated layered oxide (OLO) including vanadium (V) and magnesium (Mg), wherein the vanadium and magnesium have a molar ratio of about 1:2. Also a method of manufacturing the composite positive electrode active material, a positive electrode including the composite positive electrode, and a lithium battery including the positive electrode.Type: GrantFiled: October 23, 2015Date of Patent: May 22, 2018Assignees: SAMSUNG ELECTRONICS CO., LTD., SAMSUNG SDI CO., LTD.Inventors: Byongyong Yu, Donghan Kim, Jinhwan Park, Jayhyok Song, Andrei Kapylou, Sungjin Ahn
-
Patent number: 9979022Abstract: A positive electrode material includes: Li2Ni?M1?M2?Mn?O4-? that has a layered structure including a Li layer and a Ni layer, and in which a Ni—O bond length is shorter than that calculated from the Shannon's ionic radii. ? satisfies a relation of 0.50<??1.33, ? satisfies a relation of 0??<0.67, ? satisfies a relation of 0.33???1.1, ? satisfies a relation of 0???1.00, ? satisfies a relation of 0???1.00, M1 represents at least one selected from Co and Ga, M2 represents at least one selected from Ge, Sn and Sb. A positive electrode material may indicate a peak intensity ratio (I003/I104) of 0.9 or more in a measurement of a powder X-ray diffraction indexed with a space group of R3m.Type: GrantFiled: March 30, 2016Date of Patent: May 22, 2018Assignee: DENSO CORPORATIONInventors: Yuta Shimonishi, Nobuo Yamamoto, Shigeki Komine, Yoshinori Satou, Yuki Tachibana
-
Patent number: 9966600Abstract: Disclosed are a transition metal precursor for preparing a lithium composite transition metal oxide, a method for preparing the precursor, and a lithium composite transition metal oxide. The transition metal precursor includes a composite transition metal compound having a composition represented by Formula (1) and a Mn content of 60 to 85 mol %: NiaMbMn1-(a+b)(OH1-x)2??(1) where M is at least one selected from the group consisting of Ti, Co, Al, Cu, Fe, Mg, B, Cr, Zr, Zn and period II transition metals, 0.15?a?0.3, 0?b?0.1 and 0<x<0.5. The lithium composite transition metal oxide has a composition represented by Formula (2) and a Mn content of 60 to 85 mol %: Li1+z[NiaMbMn1-(a+b)]2O4-yAy??(2) where M is at least one selected from the group consisting of Ti, Co, Al, Cu, Fe, Mg, B, Cr and period II transition metals, A is a monoanion or dianion, 0.15?a?0.3, 0.005?b?0.1, ?0.1?z?0.1 and 0?y?0.1.Type: GrantFiled: December 3, 2014Date of Patent: May 8, 2018Assignee: LG Chem, Ltd.Inventors: Byung Chun Park, Seong Hoon Kang, Minsuk Kang, Wang Mo Jung, Ho Suk Shin, Sang Min Park, Geungi Min
-
Patent number: 9966644Abstract: A cathode for a lithium air battery, the cathode including: an organic-inorganic composite material including a coating layer on at least one portion of a surface thereof, wherein the coating layer includes a positively charged silane compound and an ionic bond forming anion. Also a lithium air battery including the same, and a method of manufacturing the cathode.Type: GrantFiled: June 16, 2015Date of Patent: May 8, 2018Assignee: SAMSUNG ELECTRONICS CO., LTD.Inventors: Victor Roev, Hyunjin Kim, Taeyoung Kim, Dongmin Im
-
Patent number: 9960449Abstract: Provided is a non-aqueous electrolyte secondary battery with reduced resistance in a low SOC range, with the battery having a coating on its negative electrode active material. This invention provides a non-aqueous electrolyte secondary battery comprising a positive electrode that has a positive electrode active material layer comprising a positive electrode active material, a negative electrode that has a negative electrode active material layer comprising a negative electrode active material, and a non-aqueous electrolyte. The negative electrode active material has a coating. The coating comprises an oxalato complex-derived component and an N-methyl-2-pyrrolidone-derived component. The non-aqueous electrolyte secondary battery internally comprises tungsten. The tungsten content per unit capacity of the non-aqueous electrolyte secondary battery is 0.0048 g/Ah to 0.0078 g/Ah.Type: GrantFiled: December 21, 2015Date of Patent: May 1, 2018Assignee: TOYOTA JIDOSHA KABUSHIKI KAISHAInventor: Koji Takahata
-
Patent number: 9954220Abstract: The present invention relates to a method of manufacturing an amorphous electrode material comprising the steps of: mixing an ionic liquid containing halide compound, nanostructures and precursors to form initially planar sheets of compounds of the halide and an element of the precursor to form a mixture; cooling the mixture to a temperature below ambient temperature, typically less than 3° C.; whereby the planar sheets are coated with the ionic liquid and curled to form microspheres of agglomerations of the curled planar sheets interconnected by the nanostructures. The invention further relates to an electrode material and to an interconnected network of electrode material.Type: GrantFiled: June 15, 2012Date of Patent: April 24, 2018Assignee: MAX-PLANCK-GESELLSCHAFT ZUR FORDERUNG DER WISSENSCHAFTEN E.V.Inventors: Chilin Li, Joachim Maier
-
Patent number: 9947920Abstract: A composition for use in a lithium ion battery includes a plurality of elongate elements and a plurality of particles. The elongate elements and particles each include a metal or semi-metal selected from one or more of the group including silicon, tin, germanium, aluminum or mixtures thereof. The composition may include additional ingredients such as a binder, a conductive material and a further electro-active material, such as graphite. The compositions can be used for the fabrication of electrodes, preferably anodes in the manufacture of lithium ion batteries and optionally batteries based on magnesium ions or sodium ions. The composition is able to intercalate and release lithium during the charging and discharging cycles respectively of a battery into which it has been incorporated. Methods of fabricating the composition and electrodes including the composition are included as well as electrodes thus prepared and devices including such electrodes.Type: GrantFiled: January 18, 2017Date of Patent: April 17, 2018Assignee: Nexeon LimitedInventor: Mino Green
-
Patent number: 9932242Abstract: Provided is a method for manufacturing a cathode active material for a lithium secondary battery, the method including heat-treating a precursor aqueous solution containing a lithium precursor, a transition metal precursor, and an organic acid containing a carboxyl group, and having a chelation index (C.I) value less than 1 and 0.5 or more, wherein the chelation index value is defined by transmittance of a peak located in a wavenumber from 1,700 to 1,710 cm?1 and transmittance of a peak located in a wavenumber from 1,550 to 1,610 cm?1 in Fourier transform infrared (FTIR) spectroscopy spectrum.Type: GrantFiled: December 6, 2012Date of Patent: April 3, 2018Assignee: SK Innovation Co., Ltd.Inventors: Jung In Yeon, Kook Hyun Han, Min Gu Kang, Seong Ho Lee
-
Patent number: 9928968Abstract: In one aspect, an energy storage device comprises one or more organic electrodes comprising one or more melanin-based energy storage materials and cations, with the one or more melanin-based energy storage materials reversibly binding the cations while the biocompatible energy storage device is in an inactive state, and the one or more melanin-based energy storage materials releasing the cations to provide energy while the energy storage device is in an active state.Type: GrantFiled: August 14, 2015Date of Patent: March 27, 2018Assignee: Carnegie Mellon UniversityInventors: Christopher J. Bettinger, Jay F. Whitacre, Young Jo Kim
-
Patent number: 9909222Abstract: Method comprising providing at least one solid carbide chemical compound and reducing a metal cation with use of the solid carbide chemical compound. A method comprising producing elemental carbon material from the oxidation of carbide in at least one carbide chemical compound (e.g., calcium carbide) in at least one anode of an electrochemical cell apparatus, such as a galvanic cell apparatus. The cathode can be a variety of metals such as zinc or tin. The reaction can be carried out at room temperature and normal pressure. An external voltage also can be applied, and different forms of carbon can be produced depending on the reactants used and voltage applied. For carrying out the method, an apparatus comprising at least one galvanic cell comprising: at least one anode comprising at least one carbide chemical compound, and at least one cathode.Type: GrantFiled: October 19, 2015Date of Patent: March 6, 2018Assignee: WEST VIRGINIA UNIVERSITY RESEARCH CORPORATIONInventors: Alfred H. Stiller, Christopher L. Yurchick
-
Patent number: 9911975Abstract: The present application relates to a carbon nanotube-sulfur composite including a carbon nanotube aggregate, and a method for preparing the same.Type: GrantFiled: October 8, 2014Date of Patent: March 6, 2018Assignee: LG CHEM, LTD.Inventors: Min Seo Kim, Seong Ho Lee, Minchul Jang, Da Young Sung
-
Patent number: 9882240Abstract: A graft copolymer comprising a backbone polymer and a branched-chain polymer, and represented by formula (I), where A, B, Ra, Rb, Rc, Rd, Re, Rf, G1, G2, G3, G4, Y1, Y2, and k are as defined in the specification. A process for producing the grate copolymer, a process for preparing a gel polymer electrolyte including the graft copolymer, and an intermediate copolymer of the graft copolymer are also disclosed.Type: GrantFiled: August 11, 2014Date of Patent: January 30, 2018Assignee: NATIONAL CHENG KUNG UNIVERSITYInventors: Ping-Lin Kuo, Sheng-Shu Hou, Chung-Yu Lu, Ching-An Wu, Chih-Hao Tsao, Chun-Han Hsu
-
Patent number: 9882214Abstract: An improved method of forming a precipitated transition metal salt useful to make a lithium transition metal oxide useful for making a lithium ion battery comprises the following. A transition metal solution comprised of a dissolved transition metal salt in water and an alkali solution comprised of an alkali salt dissolved in water are introduced into a reactor having an inlet and an outlet connected by a tubular member having therein packing. The rate in which said solutions are introduced are such that the pH of the overall solution in the reactor has pH of 5 to 12 and the time of reaction (mere seconds to several minutes) in the reactor is sufficient to form a precipitated transition metal salt in an effluent liquid. The transition metal salt precipitate in the effluent is discharged from the reactor and the salt separated from the effluent, where it can be purified by washing and dried and subsequently heated with a lithium compound to form a lithium metal oxide useful for making lithium ion batteries.Type: GrantFiled: October 16, 2014Date of Patent: January 30, 2018Assignee: Dow Global Technologies LLCInventors: Edward L. Lee, Fu Zhou
-
Patent number: 9876229Abstract: A manufacturing method of the invention includes: a process of preparing a positive electrode which includes a positive electrode mixture layer, a negative electrode which includes a negative electrode mixture layer, and a non-aqueous electrolyte; and a process of accommodating the positive electrode, the negative electrode, and the non-aqueous electrolyte in a battery case. The non-aqueous electrolyte contains lithium sulfate. In addition, when a BET specific surface area of the negative electrode mixture layer is referred to as X (m2/g) and an addition amount of the lithium sulfate with respect to a total amount of the non-aqueous electrolyte is referred to as Y (mass %), the following relationships are satisfied: 3?X?4.3; 0.02?Y?0.1; and Y/X?0.023.Type: GrantFiled: March 28, 2016Date of Patent: January 23, 2018Assignee: TOYOTA JIDOSHA KABUSHIKI KAISHAInventors: Hiroshi Yamasaki, Tatsuya Hashimoto
-
Patent number: 9871245Abstract: There is provided a process for preparing a crystalline electrode material, the process comprising: providing a liquid bath comprising the electrode material in a melted state; and introducing a precursor of the electrode material into the liquid bath, wherein the electrode material comprises lithium, a metal and phosphate. There is also provided a crystalline electrode material, comprising lithium substituted by less than 0.1 atomic of Na or K; Fe and/or Mn, substituted by less than 0.1 atomic ratio of: (a) Mg, Ca, Al and B, (b) Nb, Zr, Mo, V and Cr, (c) Fe(III), or (d) any combinations thereof; and PO4, substituted by less than 20% atomic weight of an oxyanion selected from SO4, SiO4, BO4, P2O7, and any combinations thereof, the material being in the form of particles having a non-carbon and non-olivine phase on at least a portion of the surface thereof.Type: GrantFiled: May 28, 2013Date of Patent: January 16, 2018Assignees: Johnson Matthey Public Limited Company, Universite de Montreal, La Corporation de L'Ecole Polytechnique de MontrealInventors: Michel Gauthier, Dean MacNeil, Joseph Wontcheu, Patrice Chartrand, Guoxian Liang
-
Patent number: 9859563Abstract: Material compositions are provided that may comprise, for example, a vertically aligned carbon nanotube (VACNT) array, a conductive layer, and a carbon interlayer coupling the VACNT array to the conductive layer. Methods of manufacturing are provided. Such methods may comprise, for example, providing a VACNT array, providing a conductive layer, and bonding the VACNT array to the conductive layer via a carbon interlayer.Type: GrantFiled: January 9, 2017Date of Patent: January 2, 2018Assignee: Georgia Tech Research CorporationInventors: Gleb Nikolayevich Yushin, Kara Linn Evanoff
-
Patent number: 9843040Abstract: A negative electrode active material for an electric device includes an alloy containing Si in a range from 23% to 64% exclusive, Sn in a range from 4% to 58% inclusive, Zn in a range from 0% to 65% exclusive, and inevitable impurities as a residue. The negative electrode active material can be obtained with a multi DC magnetron sputtering apparatus by use of, for example, silicon, tin and zinc as targets. An electric device such as a lithium ion secondary battery employing the negative electrode active material can improve cycle life of the battery and ensure a high capacity and high cycle durability.Type: GrantFiled: October 29, 2012Date of Patent: December 12, 2017Assignee: Nissan Motor Co., Ltd.Inventors: Manabu Watanabe, Osamu Tanaka, Masao Yoshida
-
Patent number: 9831483Abstract: A cathode element is formed as a continuous single element with a plurality of cathode leaves connected by cathode bridges. An anode element is similarly formed as a continuous single element with a plurality of anode leaves connected by anode bridges. The cathode element and anode element can be aligned and interleaved at spaces between adjacent leaves. The resulting battery pre-stack can then be folded along its bridges in alternating directions to form a battery stack whose layers alternate between an anode and cathode, and which requires minimal components and minimal or no welds.Type: GrantFiled: May 11, 2016Date of Patent: November 28, 2017Assignee: Pacesetter, Inc.Inventor: Russell Bruch
-
Patent number: 9831528Abstract: A manufacturing method according to the present invention includes: preparing a positive-electrode active material including sulfate ions by 0.04 mmol/m2 to 0.16 mmol/m2 per unit specific surface area; manufacturing a positive electrode by use of the positive-electrode active material including sulfate ions; manufacturing a negative electrode by use of a negative-electrode active material; assembling a battery assembly by accommodating the positive electrode, the negative electrode, and a nonaqueous electrolyte including lithium difluoro bis-oxalate phosphate in a battery outer case, wherein an additive amount (?mol) of the lithium difluoro bis-oxalate phosphate in the nonaqueous electrolyte is determined so as to satisfy Formula (I); and performing a charging process on the battery assembly at least once.Type: GrantFiled: June 3, 2015Date of Patent: November 28, 2017Assignee: TOYOTA JIDOSHA KABUSHIKI KAISHAInventor: Hiroshi Tsubouchi
-
Patent number: 9819024Abstract: The present invention provides an energy storage device comprising a cathode region or other element. The device has a major active region comprising a plurality of first active regions spatially disposed within the cathode region. The major active region expands or contracts from a first volume to a second volume during a period of a charge and discharge. The device has a catholyte material spatially confined within a spatial region of the cathode region and spatially disposed within spatial regions not occupied by the first active regions. In an example, the catholyte material comprises a lithium, germanium, phosphorous, and sulfur (“LGPS”) containing material configured in a polycrystalline state. The device has an oxygen species configured within the LGPS containing material, the oxygen species having a ratio to the sulfur species of 1:2 and less to form a LGPSO material.Type: GrantFiled: January 11, 2017Date of Patent: November 14, 2017Assignee: QuantumScape CorporationInventors: Cheng-Chieh Chao, Zhebo Chen, Tim Holme, Marie A. Mayer, Gilbert N. Riley, Jr.
-
Patent number: 9812707Abstract: Disclosed is lithium iron phosphate having an olivine crystal structure, wherein the lithium iron phosphate has a composition represented by the following Formula 1 and carbon (C) is coated on the particle surface of the lithium iron phosphate containing a predetermined amount of sulfur (S). Li1+aFe1?xMx(PO4?b)Xb??(1) (wherein M, X, a, x, and b are the same as defined in the specification).Type: GrantFiled: April 11, 2014Date of Patent: November 7, 2017Assignee: LG CHEM, LTD.Inventors: Hyun Kuk Noh, Hong Kyu Park, Cheol-Hee Park, Su-min Park, JiEun Lee
-
Patent number: 9806329Abstract: Disclosed are a negative electrode for a rechargeable lithium battery that includes a plurality of non-sheet-shaped graphite particles, at least one silicon-based particle in a void formed by assembling the non-sheet-shaped graphite particles, and a sheet-shaped graphite powder between the non-sheet-shaped graphite particles, the void, or both thereof, wherein a size of the silicon particle is smaller than a length of the longest axis of the sheet-shaped graphite powder.Type: GrantFiled: March 9, 2016Date of Patent: October 31, 2017Assignee: Samsung SDI Co., Ltd.Inventors: Young-Jin Choi, Yong-Chan You, Sang-Hyuck Ahn, Su-Kyung Lee, Deok-Hyun Kim, Xianhui Meng, Sang-Pil Kim
-
Patent number: 9799461Abstract: As an electrode for a power storage device, an electrode including a current collector, a first active material layer over the current collector, and a second active material layer that is over the first active material layer and includes a particle containing niobium oxide and a granular active material is used, whereby the charge-discharge cycle characteristics and rate characteristics of the power storage device can be improved. Moreover, contact between the granular active material and the particle containing niobium oxide makes the granular active material physically fixed; accordingly, deterioration due to expansion and contraction of the active material which occur along with charge and discharge of the power storage device, such as powdering of the active material or its separation from the current collector, can be suppressed.Type: GrantFiled: August 28, 2012Date of Patent: October 24, 2017Assignee: Semiconductor Energy Laboratory Co., LTD.Inventors: Kosei Noda, Kazutaka Kuriki, Nobuhiro Inoue
-
Patent number: 9799884Abstract: A manufacturing method of the invention includes: a process of preparing a positive electrode which includes a positive electrode mixture layer, a negative electrode which includes a negative electrode mixture layer, and a non-aqueous electrolyte; and a process of accommodating the positive electrode, the negative electrode, and the non-aqueous electrolyte in a battery case. The non-aqueous electrolyte contains lithium sulfate. In addition, when a BET specific surface area of the negative electrode mixture layer is referred to as X (m2/g) and an addition amount of the lithium sulfate with respect to a total amount of the non-aqueous electrolyte is referred to as Y (mass %), the following relationships are satisfied: 3?X?4.3; 0.02?Y?0.1; and Y/X?0.023.Type: GrantFiled: March 28, 2016Date of Patent: October 24, 2017Assignee: TOYOTA JIDOSHA KABUSHIKI KAISHAInventors: Hiroshi Yamasaki, Tatsuya Hashimoto
-
Patent number: 9793587Abstract: An electrode includes a plant-derived porous carbon material having an ability to catalyze oxygen reduction.Type: GrantFiled: May 4, 2017Date of Patent: October 17, 2017Assignee: Sony CorporationInventors: Hironori Iida, Kenichi Murata, Takaaki Nakagawa, Shinichiro Yamada
-
Patent number: 9786914Abstract: There is provided a Co-based 5-V spinel-type lithium manganese-containing complex oxide not only having an operating potential of 4.5 V or higher but also being capable of extending its capacity region of a 5.5 to 5.5 V region and being capable of enhancing its energy density as well. There is proposed a spinel-type lithium cobalt manganese-containing complex oxide having a crystal structure classified as a space group Fd-3m and being represented by the general formula [Lix(CoyMn3?x?y)O4??] (wherein 0.90?x?1.15 and 0.75?y?1.25), wherein the oxide has a crystallite size measured by a Rietveld method using the fundamental method of 100 nm to 200 nm, an interatomic distance of Li—O of 1.80 ? to 2.00 ?, and a strain of 0.20 to 0.50.Type: GrantFiled: December 4, 2014Date of Patent: October 10, 2017Assignee: Mitsui Mining & Smelting Co., Ltd.Inventors: Kyohei Yamaguchi, Natsumi Ito, Tsukasa Takahashi, Tetsuya Mitsumoto, Shinya Kagei, Yoshimi Hata
-
Patent number: 9786913Abstract: To provide a cathode active material for a non-aqueous electrode rechargeable battery, with which it is possible to improve input/output characteristics, particularly by reducing resistance in a low SOC state in which DCIR increases, and to provide a manufacturing method for same. The cathode active material includes layered hexagonal crystal lithium nickel manganese composite oxide particles represented by the general formula (A): Li1+uNixMnyCozMtO2 (where 0?u?0.20, x+y+z+t=1, 0.30?x ?0.70, 0.10?y?0.55, 0?z?0.40, 0?t?0.10, and M is one or more elements selected from Al, Ti, V, Cr, Zr, Nb, Mo, and W), and further including Na, Mg, Ca and SO4, in which the total amount of Na, Mg and Ca is 0.01 to 0.1 mass %, the amount of SO4 is 0.1 to 1.0 mass %, and the ratio of the integrated intensity of the diffraction peak on plane (003) to that on plane (104) obtained by powder X-ray diffraction measurement using CuK? rays is 1.20 or greater.Type: GrantFiled: July 22, 2014Date of Patent: October 10, 2017Assignee: SUMITOMO METAL MINING CO., LTD.Inventors: Katsuya Inoue, Hiroyuki Toya
-
Patent number: 9780386Abstract: A composite for a lithium air battery, wherein the composite is represented by Formula 1: MCxN(1?x)??Formula 1 wherein M in Formula 1 is at least one selected from a metal element and a metalloid element, and 0<x<1.Type: GrantFiled: August 5, 2015Date of Patent: October 3, 2017Assignee: SAMSUNG ELECTRONICS CO., LTD.Inventors: Soonchul Kwon, Dongjin Ham, Victor Roev, Dongmin Im
-
Patent number: 9748573Abstract: A mesoporous silicon compound includes a mesoporous silicon phase, a metal silicide phase, and a carbon phase. The metal silicide is embedded in mesoporous silicon particles, the surfaces of which are coated with a carbon layer. A weight ratio of elemental silicon to the metal element is from 2:3 to 900:1. The pores of the mesoporous silicon particles have a size distribution from two nanometers to eighty nanometers.Type: GrantFiled: August 3, 2012Date of Patent: August 29, 2017Assignee: Robert Bosch GmbHInventors: Jun Yang, Pengfei Gao, Jingjun Zhang, Longjie Zhou
-
Patent number: 9748045Abstract: Provided is a nonaqueous lithium storage element which is obtained by housing an electrode body and a nonaqueous electrolyte solution containing a lithium salt in an outer case, said electrode body being composed of a negative electrode that is composed of a negative electrode collector and a negative electrode active material layer laminated on one or both surfaces of the negative electrode collector, a positive electrode that is composed of a positive electrode collector and a positive electrode active material layer laminated on one or both surfaces of the positive electrode collector, and a separator.Type: GrantFiled: December 5, 2013Date of Patent: August 29, 2017Assignee: Asahi Kasei Kabushiki KaishaInventors: Nobuhiro Okada, Takeshi Kamijo, Shiro Mori, Takashi Yamasaki, Akiko Kaneko
-
Patent number: 9748570Abstract: The invention relates to cathode materials for Li-ion batteries having a size dependent compositions. The lithium metal oxide powder has a general formula LiaNixCoyMnzM?mO2±eAf, with 0.9<a<1.1, 0.2?x?0.9, 0<y?0.4, 0<z?0.7, 0?m?0.35, e<0.02, 0?f?0.05 and 0.9<(x+y+z+m+f)<1.1; M? consisting of either one or more elements from the group Al, Mg, Ti, Cr, V, Fe and Ga; A consisting of either one or more elements from the group F, C, Cl, S, Zr, Ba, Y, Ca, B, Sn, Sb, Na and Zn. The powder has a particle size distribution defining a D10 and a D90; wherein either x1?x2?0.005; or z2?z1?0.005; or both x1?x2?0.005 and z2?z1?0.005; x1 and z1 being the values of x and z of particles having a particle size D90; and x2 and z2 being the values of x and z of particles having a particle size D10.Type: GrantFiled: May 14, 2012Date of Patent: August 29, 2017Assignee: UmicoreInventors: Randy De Palma, Jens Paulsen, JiHye Kim
-
Patent number: 9742002Abstract: A positive electrode composition for nonaqueous electrolyte secondary battery comprises a lithium transition metal complex oxide represented by a general formula LiaNi1?x?yCoxM1yWzM2wO2, where 1.0?a?1.5, 0?x?0.5, 0?y?0.5, 0.002?z?0.03, 0?w?0.02, 0?x+y?0.7, M1 represents at least one selected from the group consisting of Mn and Al, and M2 represents at least one selected from the group consisting of Zr, Ti, Mg, Ta, Nb and Mo; and a boron compound comprising at least boron element and oxygen element.Type: GrantFiled: April 16, 2013Date of Patent: August 22, 2017Assignee: NICHIA CORPORATIONInventors: Kousuke Shimokita, Kenta Kawai, Kiyofumi Inouchi
-
Patent number: 9735430Abstract: A power storage device with high capacity or high energy density is provided. A highly reliable power storage device is provided. A long-life power storage device is provided. An electrode includes an active material, a first binder, and a second binder. The specific surface area of the active material is S [m2/g]. The weight of the active material, the weight of the first binder, and the weight of the second binder are a, b, and c, respectively. The solution of {(b+c)/(a+b+c)}×100÷S is 0.3 or more. The electrode includes a first film in contact with the active material. The first film preferably includes a region in contact with the active material. The first film preferably includes a region with a thickness of 2 nm or more and 20 nm or less. The first film contains a water-soluble polymer.Type: GrantFiled: January 16, 2015Date of Patent: August 15, 2017Assignee: SEMICONDUCTOR ENERGY LABORATORY CO., LTD.Inventors: Kai Kimura, Kazutaka Kuriki, Teppei Oguni, Aya Uchida
-
Patent number: 9728814Abstract: Pressure relief mechanisms can provide an outlet for cathode pressure buildup during battery operation. Mechanical cathode modifications can control cathode interfaces during battery operation. Pressure relief mechanisms and mechanical modifications can be utilized to improve performance, longevity and/or to prevent failure of batteries, such as during cycling of liquid metal batteries.Type: GrantFiled: November 7, 2014Date of Patent: August 8, 2017Assignee: AMBRI INC.Inventors: David J. Bradwell, Alex T. Vai, Tom Kinney, Sean Theriault, Garrett Lau
-
Patent number: 9716274Abstract: A cathode active material for sodium batteries has excellent discharge capacity, and a sodium battery has the cathode active material for sodium batteries. A cathode active material for sodium batteries is represented by a general formula Na4Co(3-x)Mx(PO4)2P2O7; M is any of Fe, Cr, Mn and Al; X is 0.015?x?0.21 when M is Fe; X is 0.03?x?0.18 when M is Cr; X is 0.006?x?0.24 when M is Mn; and X is 0.03?x?0.06 when M is Al.Type: GrantFiled: August 25, 2014Date of Patent: July 25, 2017Assignee: TOYOTA JIDOSHA KABUSHIKI KAISHAInventor: Masafumi Nose
-
Patent number: 9711792Abstract: Provided is a positive electrode active material for lithium ion secondary batteries, having a crystal structure containing a layered Li2MnO2 structure with a high theoretical electrical capacity as a basic skeleton, and having both a high theoretical electrical capacity and a high open-circuit voltage by increasing an open-circuit voltage to a value of more than 2 V by replacing a part of manganese ions with calcium ions by adding the calcium ions. That is, a positive electrode active material for secondary batteries mainly containing a compound represented by a chemical composition formula Li2?xMn1?yCayO2, and an electrode and a battery including the same are realized. In the formula, x satisfies 0<x<1.3, and y satisfies 0.2<y<0.9.Type: GrantFiled: March 10, 2014Date of Patent: July 18, 2017Assignee: HITACHI, LTD.Inventor: Yusuke Asari
-
Patent number: 9698419Abstract: A battery with improved properties is provided. The battery has a cathode material prepared by the complexometric formulation methodology comprising MnXp wherein: Mj is at least one positive ion selected from the group consisting of alkali metals, alkaline earth metals and transition metals and n represents the moles of said positive ion per mole of said MjXp; and Xp is a negative anion or polyanion selected from Groups IIIA, IV A, VA, VIA and VIIA and may be one or more anion or polyanion and p representing the moles of said negative ion per moles of said MjXp. The battery has a discharge capacity at the 1000th discharge cycle of at least 120 mAh/g at room temperature at a discharge rate of 1 C when discharged from at least 4.6 volts to at least 2.0 volts.Type: GrantFiled: March 17, 2014Date of Patent: July 4, 2017Assignee: Nano One Materials Corp.Inventors: Teresita Frianeza-Kullberg, Lennart H. Kullberg
-
Patent number: 9698430Abstract: A lithium-lanthanum-titanium oxide sintered material has a lithium ion conductivity 3.0×10?4 Scm?1 or more at a measuring temperature of 27° C., the material is described by one of general formulas (1-a)LaxLi2-3xTiO3-aSrTiO3, (1-a)LaxLi2-3xTiO3-aLa0.5K0.5TiO3, LaxLi2-3xTi1-aMaO3-a, and Srx-1.5aLaaLi1.5-2xTi0.5Ta0.5O3 (0.55?x?0.59, 0?a?0.2, M=at least one of Al, Fe and Ga), and concentration of S is 1500 ppm or less. The material is obtained by sintering raw material powder mixture having S content amount of 2000 ppm or less in the entirety of raw material powders for mixture, that is, titanium raw material, lithium raw material, and lanthanum raw material.Type: GrantFiled: July 12, 2013Date of Patent: July 4, 2017Assignees: TOHO TITANIUM CO., LTD., NAKASHIMA SANGYO CO., LTD., THE GAKUSHUIN SCHOOL CORPORATIONInventors: Mamoru Nakashima, Yoshiyuki Inaguma, Mikio Nakashima
-
Patent number: 9680179Abstract: The main object of the present invention is to provide a sulfide solid electrolyte material which copes with both the restraint of the increase in interface resistance and the restraint of the increase in bulk resistance. The present invention solves the above-mentioned problems by providing a sulfide solid electrolyte material characterized by containing at least one of Cl and Br.Type: GrantFiled: August 19, 2011Date of Patent: June 13, 2017Assignee: TOYOTA JIDOSHA KABUSHIKI KAISHAInventors: Yasushi Tsuchida, Noriaki Nishino, Takamasa Ohtomo
-
Patent number: 9666860Abstract: A lead-acid battery comprising: —at least one negative electrode comprising lead-based battery electrode material and at least one region of capacitor material overlying the lead-based battery electrode material, each electrode being in electrical connection to an outer terminal of the battery, and —at least one positive lead-dioxide based battery electrode, each positive electrode being in electrical connection to a second outer terminal of the battery, —separator interleaving the facing electrodes; —electrolyte filling at least the space of the electrodes and separators wherein the capacitor material overlying the lead-based battery electrode material comprises 20-65% by weight of a high electrical conductivity carbonaceous material, 30-70% of a high specific surface area carbonaceous material, at least 0.1% lead and binder.Type: GrantFiled: March 20, 2008Date of Patent: May 30, 2017Assignees: COMMONWEALTH SCIENTIFIC AND INDUSTRIAL RESEARCH ORGANISATION, THE FURUKAWA BATTERY CO., LTD.Inventors: Lan Trieu Lam, Jun Furukawa, Toshimichi Takada, Daisuke Monma, Tetsuya Kanou
-
Patent number: 9660260Abstract: Provided are a cathode active material coated with a fluorine-doped spinel-structured lithium metal manganese oxide, a lithium secondary battery including the same, and a method for preparing the same. The cathode active material has improved chemical stability and provides improved charge/discharge characteristics at elevated temperature (55-60° C.) and high rate. The cathode active material allows lithium ions to pass through the coating layer with ease and is chemically stable, and thus may be used effectively as a cathode active material for a high-power lithium secondary battery.Type: GrantFiled: September 1, 2015Date of Patent: May 23, 2017Assignee: KOREA INSTITUTE OF SCIENCE AND TECHNOLOGYInventors: Si Hyoung Oh, Byung Won Cho, Kyung Yoon Chung, Hae Ri Lee
-
Patent number: 9660263Abstract: Materials are presented of the formula: Ax My Mizi O2?d, where A is sodium or a mixed alkali metal including sodium as a major constituent; x>0; M is a metal or germanium; y>0; Mi, for i=1, 2, 3 . . . n, is a transition metal or an alkali metal; zi?0 for each i=1, 2, 3 . . . n; 0<d?0.5; the values of x, y, zi and d are such as to maintain charge neutrality; and the values of x, y, zi and d are such that x+y+?zi>2?d. The formula includes compounds that are oxygen deficient. Further the oxidation states may or may not be integers i.e. they may be whole numbers or fractions or a combination of whole numbers and fractions and may be averaged over different crystallographic sites in the material. Such materials are useful, for example, as electrode materials in rechargeable battery applications. Also presented is a method of preparing a compound having the formula Ax My Mizi O2?d.Type: GrantFiled: December 23, 2014Date of Patent: May 23, 2017Assignees: Sharp Kabushiki Kaisha, Faradion LimitedInventors: Emma Kendrick, Robert Gruar
-
Patent number: 9647263Abstract: A composition for use in a lithium ion battery includes a plurality of elongate elements and a plurality of particles. The elongate elements and particles each include a metal or semi-metal selected from one or more of the group including silicon, tin, germanium, aluminum or mixtures thereof. The composition may include additional ingredients such as a binder, a conductive material and a further electro-active material, such as graphite. The compositions can be used for the fabrication of electrodes, preferably anodes in the manufacture of lithium ion batteries and optionally batteries based on magnesium ions or sodium ions. The composition is able to intercalate and release lithium during the charging and discharging cycles respectively of a battery into which it has been incorporated. Methods of fabricating the composition and electrodes including the composition are included as well as electrodes thus prepared and devices including such electrodes.Type: GrantFiled: September 2, 2011Date of Patent: May 9, 2017Assignee: Nexeon LimitedInventor: Mino Green
-
Patent number: 9620810Abstract: A secondary battery capable of obtaining superior cycle characteristics and superior swollenness characteristics is provided. The secondary battery includes a cathode and an anode capable of inserting and extracting an electrode reactant; and an electrolyte containing a solvent and an electrolyte salt. The anode has an anode active material layer on an anode current collector. The anode active material layer contains a plurality of crystalline anode active material particles having silicon (Si) as an element. The plurality of anode active material particles contain a spherical particle and a nonspherical particle.Type: GrantFiled: November 12, 2009Date of Patent: April 11, 2017Assignee: SONY CORPORATIONInventors: Takakazu Hirose, Kenichi Kawase, Kazunori Noguchi, Takayuki Fujii
-
Patent number: 9608292Abstract: A lithium-ion battery is provided that has a fast charge and discharge rate capability and low rate of capacity fade during high rate cycling. The battery can exhibit low impedance growth and other properties allowing for its use in hybrid electric vehicle applications and other applications where high power and long battery life are important features.Type: GrantFiled: December 30, 2013Date of Patent: March 28, 2017Assignee: A123 Systems LLCInventors: Antoni S. Gozdz, Andrew C. Chu, Ricardo Fulop, Yet-Ming Chiang, Gilbert N. Riley, Jr., Roger Lin
-
Patent number: 9608271Abstract: The present invention provides a positive electrode active material for nonaqueous electrolyte secondary battery including a lithium transition metal composite oxide represented by the following formula: LiaNixMn2-xFeyBzO4 wherein 1.00?a?1.30, 0.30?x?0.60, 0.003?y?0.200, and 0.003?z?0.200.Type: GrantFiled: March 24, 2015Date of Patent: March 28, 2017Assignee: NICHIA CORPORATIONInventors: Tomooki Kawasaki, Kenichi Kobayashi
-
Patent number: 9601773Abstract: The current disclosure relates to an anode material with the general formula MySb-M?Ox—C, where M and M? are metals and M?Ox—C forms a matrix containing MySb. It also relates to an anode material with the general formula MySn-M?Cx—C, where M and M? are metals and M?Cx—C forms a matrix containing MySn. It further relates to an anode material with the general formula Mo3Sb7—C, where —C forms a matrix containing Mo3Sb7. The disclosure also relates to an anode material with the general formula MySb-M?Cx—C, where M and M? are metals and M?Cx—C forms a matrix containing MySb. Other embodiments of this disclosure relate to anodes or rechargeable batteries containing these materials as well as methods of making these materials using ball-milling techniques and furnace heating.Type: GrantFiled: February 18, 2014Date of Patent: March 21, 2017Assignee: BOARD OF REGENTS, THE UNIVERSITY OF TEXAS SYSTEMInventors: Arumugam Manthiram, Danielle Applestone, Sukeun Yoon
-
Patent number: 9601761Abstract: A composite cathode active material, a method of preparing the composite cathode active material, a cathode including the composite cathode active material, and a lithium battery including the cathode. The composite cathode active material includes a lithium intercalatable material; and a garnet oxide, wherein an amount of the garnet oxide is about 1.9 wt % or less, based on a total weight of the composite cathode active material.Type: GrantFiled: April 25, 2014Date of Patent: March 21, 2017Assignee: SAMSUNG ELECTRONICS CO., LTD.Inventors: Jun-young Mun, Jae-myung Lee, Gue-sung Kim, Yoon-sok Kang, Myung-hoon Kim, Jun-ho Park, Jin-hwan Park, Jae-gu Yoon, Byung-jin Choi
-
Patent number: 9590242Abstract: Disclosed are precursor particles of a lithium composite transition metal oxide for lithium secondary batteries, wherein the precursor particles of a lithium composite transition metal oxide are composite transition metal hydroxide particles including at least two transition metals and having an average diameter of 1 ?m to 8 ?m, wherein the composite transition metal hydroxide particles exhibit monodisperse particle size distribution and have a coefficient of variation of 0.2 to 0.7, and a cathode active material including the same.Type: GrantFiled: May 29, 2014Date of Patent: March 7, 2017Assignee: LG Chem, Ltd.Inventors: Seong Hoon Kang, Byung Chun Park, Ho Suk Shin, Sang Min Park, Hong Kyu Park
-
Patent number: 9589735Abstract: Embodiments of the present disclosure provide for materials that include conch shell structures, methods of making conch shell slices, devices for storing energy, and the like.Type: GrantFiled: March 11, 2014Date of Patent: March 7, 2017Assignee: KING ABDULLAH UNIVERSITY OF SCIENCEInventors: Xixiang Zhang, Yingbang Yao, Zhihong Wang