Abstract: A method for ammonia decomposition is disclosed. The method may comprise providing a catalyst comprising an alumina support and a layer adjacent to the support. The layer comprises a perovskite phase comprising aluminum, cerium, and lanthanum, an oxide of at least one of an alkali metal and a rare earth metal, and an active metal. The method may comprise bringing the catalyst in contact with ammonia at a temperature of from about 400° C. to 700° C. to generate a reformate stream comprising hydrogen and nitrogen at an ammonia conversion efficiency of at least about 70%. The method may further comprise directing the hydrogen to a fuel cell to generate electricity. The method may further comprise generating heat for a reformer comprising the catalyst by combustion of gases or by electricity generated from hydrogen.

Abstract: A method of forming a contact to a semiconductor device is provided that forms an alloy composed of nickel (Ni), platinum (Pt), aluminum (Al), titanium (Ti) and a semiconductor material. The methods may include forming a nickel and platinum semiconductor alloy at a base of a via. A titanium layer having an angstrom scale thickness is deposited in the via in contact with the nickel platinum semiconductor alloy. An aluminum containing fill is deposited atop the titanium layer. A forming gas anneal including an oxygen containing atmosphere is applied to the structure to provide a contact alloy comprising nickel, platinum, aluminum, titanium and a semiconductor element from the contact surface of the semiconductor device.

Abstract: The present invention relates to a method for conditioning a soot-containing syngas stream in a single integrated apparatus containing a scrubbing vessel wherein particulate matter is decoupled from the waste water stream.

Abstract: Methods for the combined elimination of both ammonia and lower alkanes and/or hydrogen, which are contained in one or more waste gas streams in an industrial plant, are disclosed herein. The method is effectuated by combined oxidation and reduction according to the reduction-oxidation process, wherein the ammonia and the lower alkanes and/or hydrogen are completely or partially reacted by chemical reaction to form nitrogen, carbon dioxide and water. The waste gas stream containing ammonia and lower alkanes and/or hydrogen is passed over one or more catalysts for the combined oxidation and reduction, and the oxygen content in the waste gas stream is set in such a way that ammonia and the lower alkanes and/or hydrogen are oxidized first in an oxidation zone to form nitrogen, carbon dioxide and water, and the nitrogen oxides resulting therefrom are subsequently reduced in a reduction zone to form elemental nitrogen.

Abstract: The goal of the invention consists in making available a method for supplying fuel to a pressurized gasification system, which ensures, in economically efficient manner, that the emission of pollutants from the coal transfer and the transport is minimized or completely avoided. This is achieved in that a gas that contains at least 10 ppm vol. CO is used for transfer and/or conveying, whereby a gas that contains oxygen is mixed into this gas, and that this gas mixture is heated to a temperature that oxidizes at least 10% of the pollutants contained in the gas.

Abstract: A system (10) for delivery of dilute fluid, utilizing an active fluid source (12), a diluent fluid source (14), a fluid flow metering device (24) for dispensing of one of the active and diluent fluids, a mixer (28) arranged to mix the active and diluent fluids to form a diluted active fluid mixture, and a monitor (42) arranged to sense concentration of active fluid and/or diluent fluid in the diluted active fluid mixture, and responsively adjust the fluid flow metering device (24) to achieve a predetermined concentration of active fluid in the diluted active fluid mixture. A pressure controller (38) is arranged to control flow of the other of the active and diluent fluids so as to maintain a predetermined pressure of the diluted active fluid mixture dispensed from the system. The fluid dispensed from the system then can be adjustably controlled by a flow rate controller, e.g., a mass flow controller, to provide a desired flow to a fluid-utilizing unit, such as a semiconductor process tool.

Abstract: The invention relates to methods and products for producing fatty acids by manipulating metabolic function in plants and fungus. The fatty acids generated according to the invention may be useful in the production of biofuels.

Abstract: A combined plant is provided. The combined plant of continuously supplying hydrogen and nitrogen to an ammonia synthesis facility that continuously synthesizes ammonia from hydrogen and nitrogen, the combined plant including: a hydrogen production facility for acquiring solar energy and producing hydrogen by utilizing a part of the acquired solar energy; a nitrogen production facility for producing nitrogen from air and supplying the nitrogen to the ammonia synthesis facility; and a hydrogen storage facility for storing the hydrogen produced by the hydrogen production facility and supplying the produced hydrogen to the ammonia synthesis facility.

Abstract: The invention relates to a method for extracting hydrogen from a gas containing methane, especially natural gas. Hydrocarbons contained in the gas are catalytically broken down in a reformer (4) by steam in order to form hydrogen, carbon monoxide and carbon dioxide. Catalytic conversion of the obtained carbon monoxide with steam occurs in a downstream conversion step in order to form carbon monoxide and water. Carbon dioxide is removed from the converted gas flow (8) by gas washing (7), and the washed hydrogen-rich gas flow (10) is subsequently divided in a pressure-swing adsorption system (11) into a product gas flow (12) made of hydrogen and a waste gas flow (13). The waste gas flow (13) is introduced with hydrogen (14), which is separated from the gas flow (10) after gas washing, into a reformer (4) which is essentially a carbon-free combustible gas, and is combusted there. The invention also relates to a system for carrying out the method.

Abstract: An ammonia and fertilizer production process is based on partial oxidation of fossil fuel, which co-produces polycarbonsuboxide. The four step process is low-cost and low-carbon-dioxide emission. It comprises the steps of reacting fossil fuel with oxygen in air and steam in an electric discharge plasma to produce a gas exit stream of polycarbonsuboxide, hydrogen with associated nitrogen (110); cooling the gas stream to condense and separate the polycarbonsuboxide as a solid polymer (120); compressing the gas stream to pressures for synthesis of ammonia (140); and, converting the gas stream to ammonia by employing a catalytic converter (150). Optional steps involve gas cleanup, which include removal of contaminants from the gas stream and adding hydrogen or nitrogen to the gas stream to adjust the ratio of hydrogen to nitrogen to three to one, respectively, prior to converting the gas stream to ammonia (130).

Abstract: Ammonia is catalytically produced from a nitrogen-hydrogen mixture. First of all, a vaporous feed mixture, which comprises 30 to 60 vol-% methanol and 40 to 70 vol-% steam and has a volume ratio steam:methanol of 1 to 3, is passed through at least one bed of a breakdown catalyst at pressures in the range from 30 to 200 bar, the temperatures in the catalyst bed lying in the range from 200 to 500° C. From the catalyst bed, a first gas mixture is withdrawn, which, calculated dry, comprises 40 to 80 vol-% H2 and 10 to 30 vol-% CO2. The first gas mixture is cooled, CO2 is removed in a gas cleaning, and a second gas mixture is generated, which comprises at least 95 vol-% nitrogen and hydrogen, and which is supplied as synthesis gas to an ammonia synthesis for the catalytic production of ammonia.

Abstract: Ammonia synthesis gas production having a shift reaction stage employing a copper-based catalyst wherein the air supplied to the process is passed through an absorber that removes sulfur and/or halide contaminants, is described. The absorber has a support carrying an absorbent for sulfur compounds and/or absorbent for halide compounds. The removal of the contaminants improves the lifetime e.g. copper-zinc low temperature shift catalysts.

Abstract: The invention concerns a method for producing a gas mixture containing hydrogen and carbon monoxide, and optionally nitrogen, from at least a hydrocarbon such as methane, propane, butane or LPG or natural gas, which consists in performing a partial catalytic oxidation (1) of one or several hydrocarbons, at a temperature of 500° C., at a pressure of 3 to 20 bars, in the pre of oxygen or a gas containing oxygen, such as air, to produce hydrogen and carbon monoxide; then in recuperating the gas mixture which can subsequently be purified or separated, by pressure swing adsorption, temperature swing adsorption of by permeation (3), to produce hydrogen having a purity of at least 80% and a residue gas capable of supplying a cogeneration unit In another embodiment, the gas mixture can subsequently be purified of its water vapour impurities and carbon dioxide to obtain a thermal treatment atmosphere containing hydrogen, carbon monoxide and nitrogen.

Abstract: Apparatus and a method of providing a water-based fluid with active hydrogen having selected characterstics including providing at least one material (10) having selected characteristics and supply of hydrogen atoms from at least one material (10) to fluid, whereby the fluid receives hydrogen atoms from the material (10), which hydrogen atoms have the selected characteristics.

Abstract: A system for producing ammonia by integrating blast furnace ironmaking with ammonia production wherein cryogenic rectification links the two systems enabling the production of ammonia synthesis gas from blast furnace gas for use in the ammonia production.

Abstract: The present invention provides a process for the production of a synthesis gas mixture containing carbon oxides and hydrogen from a hydrocarbon feedstock material comprising: providing a reforming zone having a plurality of chambers charged with a catalyst effective for catalysis of at least one reforming reaction; supplying to the chambers of the reforming zone a vaporous mixture of the hydrocarbon feedstock and a reforming reagent; maintaining the reforming zone under suitable reforming conditions for reforming of the hydrocarbon feedstock and reforming reagent to form the synthesis gas mixture by supplying to the reforming zone a fuel for heating the chambers by combustion and by supplying to the steam reforming zone a vaporous steam comprising combustion oxygen in which the fuel may be combusted; humidifying the vaporous steam comprising combustion oxygen; exchanging heat between the humidified vaporous steam comprising combustion oxygen entering the reforming zone and the synthesis gas mixture exiting th

Abstract: A process for the generation of a protective nitrogen-based atmosphere for the performance of heat treatments of metal articles in three phases, including an initial phase in which a gaseous hydrocarbon feed and an oxidant containing oxygen react on a first catalyst to form a reaction product, a second phase in which the reaction product is added to nitrogen contaminated by the presence of oxygen and a third phase in which the reaction product is conveyed to a second catalyst to form a low-dew point gaseous mixture as a protective atmosphere.

Abstract: A method for extinguishing hydrogen fires comprises introducing to the hydrogen fire a fire extinguishing concentration of 1,1,1,2,3,3,3-heptafluoropropane and maintaining the concentration until the fire is extinguished. The method includes heptafluoropropane at a range of 13-30% volume/volume in the air. The fire extinguishing methods also include the use of heptafluoropropane in blend with other fire extinguishing compounds. Also disclosed are atmospheres of hydrogen, an oxidizer, and a sufficient amount of 1,1,1,2,3,3,3-heptafluoropropane to render the atmosphere incapable of supporting combustion of the hydrogen, as well as related methods for preparing such atmospheres.

Abstract: The invention generally relates to gelled oil compositions which employ aluminum complex soaps as gelling agents. The gelled oils comprise an oil component, a bleed inhibitor of polybutene, and optional amounts of antioxidant and pour point depressant. The gelled oils are particularly suited for use as buffer tube gels and as filling compounds for waveguides.

Abstract: A process for producing low-cost furnace atmospheres suitable for annealing and heat treating ferrous and non-ferrous metals and alloys, brazing metals and ceramics, sealing glass to metals, and sintering non-ferrous metal and ceramic powders from non-cryogenically produced nitrogen containing from 0.05 to 5.0% residual oxygen is presented. The disclosed process involves 1) mixing non-cryogenically produced nitrogen with a predetermined amount of dissociated ammonia, 2) passing the mixture through a low-pressure drop catalytic reactor, 3) converting the residual oxygen to an acceptable form such as moisture and reducing the residual oxygen level to below about 10 ppm, and 4) using the resultant gaseous mixture for annealing and heat treating ferrous and non-ferrous metals and alloys, brazing metals and ceramics, sealing glass to metals, and sintering non-ferrous metal and ceramic powders.

Abstract: The invention is a processing aid for thermoplastic polyesters which is a salt of a polycarboxylic acid or the salt of a polycarboxylic partial ester. The polycarboxylic acids are partial esters or sales of modified acids such as succinic acid, adipic acid, phthalic acid, citric acid, dicarboxylphenyl group and the like. The addition of the processing aid improves the slip and transparency.

Abstract: Aqueous compositions of emulsified oxyaluminum acylate solutions comprising solutions of oxyaluminum acylate in a largely water insoluble solvent, an alcohol or an organic acid, an emulsifier or mixture of emulsifiers, and water are provided. Articles comprising substrates rendered water-repellent with such emulsions are provided as well. A process for the preparation of such articles is also provided.

Abstract: A carbonaceous feedstock, e.g. coal or heavy oil, having a low hydrogen to carbon atomic ratio is partially oxidized using air, or oxygen enriched or depleted air, to form a crude gas which is subjected to catalytic shift and excess steam removal. Carbon dioxide and nitrogen are then removed from the resultant raw gas, which has a hydrogen to nitrogen, plus carbon monoxide, volume ratio in the range 0.5 to 1.5 and a nitrogen content at least 10 times the carbon monoxide content, in a pressure swing adsorption process thereby producing a product gas stream containing at least 50% hydrogen and 0.5 to 40% nitrogen, by volume. The waste gas from the pressure swing adsorption may be catalytically combusted to power a turbine driving the compressor for the air or the crude gas.

Abstract: The combination of copper and molybdenum salts is shown to be an effective antioxidant and anti-wear additive for hydrocarbons, such as lube oils. Accordingly the present invention is directed to a lube oil having improved oxidation stability, providing improved wear protection with reduced friction and comprising:A. a basestock, andB. an effective amount of a copper salt and a molybdenum salt.

Abstract: A process for the production of ammonia wherein excess nitrogen is fed to the secondary reformer and a cryogenic unit is employed to obtain a nitrogen-rich stream which is recycled at least in part to the cryogenic unit.

Abstract: What are disclosed are lubricating greases containing aluminum complex soaps prepared from aluminum isopropoxides modified for stability and improved flash point.

Abstract: Effluent gas streams for steam reforming, partial oxidation or coal gasification operations are advantageously treated in shift conversion, scrubbing and pressure swing adsorption units for recovery of a purified, hydrogen-containing product gas stream. By recycling a portion of the waste gas removed from the pressure swing adsorption system to the shift conversion unit and/or to the effluent gas generation operation, enhanced product recovery is achieved without the necessity for employing low temperature shift or for achieving essentially complete removal of the carbon dioxide content of the gas being treated prior to its passage to said pressure swing adsorption system.

Abstract: The invention comprises a novel stabilizing system useful for imparting resistance to oxidative breakdown comprising:(1) a metal deactivator azine of the formula: ##STR1## where: R.sub.1 and R.sub.2 can be hydrogen, alkyl with 1-12 carbon atoms, alkoxy with 1-12 carbon atoms, carbalkoxy with 1-12 carbon atoms, halogen, hydroxy, nitro and amino groups and X.sub.1 and X.sub.2 can be hydrogen, alkyl with 1-12 carbon atoms or di-, tri- or tetramethylene bridges to the aromatic ring.(2) an amine;(3) a metal compound selected from the group consisting of metals or metal salt; and(4) a lubricating oil selected from the group consisting of mineral oils or synthetic hydrocarbon oils.

Abstract: A process for producing a gas stream for ammonia synthesis in which a gas stream containing hydrogen and nitrogen in excess of ammonia synthesis requirements, e.g. obtained by partial oxidation of natural gas, coal or oil, is treated to remove other component gases and thereafter subjected to a separation stage, e.g. in a cryogenic separator, to separate a hydrogen-nitrogen stream having the desired hydrogen:nitrogen ratio which is injected into the reactor for ammonia synthesis, and a waste nitrogen stream which may be utilized in power generation or washing stages.

Abstract: Lubricating oils are stabilized against oxidative degradation by the use of a stabilizer comprising (A) an amine wherein the amine is a substituted benzylamine, or a substituted 1-amino-1,2,3,4-tetrahydronaphthalene, (B) a metal deacturator and (C) a metal or metal salt. Optionally a metal deactivator can be incorporated into the system. The preferred substitute benzylamine is N(alpha-methyl benzyl)amine the preferred naphthalamine is phenyl-alpha-naphthalamine.

Abstract: The present invention is a method of generating Class 302 type carrier gas for use in carburizing processes. The gas has a composition of approximately 40% nitrogen, 40% hydrogen and 20% carbon monoxide. The nitrogen is mixed with the methanol in a vaporizer where the methanol is vaporized. The vaporized methanol and nitrogen mixture is heated in a catalyst filled retort where methanol reacts to yield hydrogen and carbon monoxide. The relative volume percents of the nitrogen, hydrogen, and carbon monoxide is substantially the same as in the Class 302 type carrier gas.

Abstract: A normally solid thermoplastic material having a low softening point containing at least one metal salt of a metal selected from the group consisting of a metal of Group I, II, III or IV of the Periodic Table and a fatty acid having about 8 to about 30 carbon atoms per molecule and a silicone compound incorporated into or onto the thermoplastic material, the metal salt and the silicone compound being present in amounts sufficient to significantly reduce blocking between contact surfaces of the thermoplastic material and a lubricating composition containing the thermoplastic material.

Abstract: This is a continuous process for producing ammonia synthesis gas and includes the partial oxidation of particles of solid carboniferous fuels entrained in nitrogen. In the process, air is separated into high pressure nitrogen and substantially pure oxygen. A first stream of said nitrogen is used as a safe pneumatic vehicle in a grinding and transport operation which introduces ground, finely divided solid carbonaceous fuel into a venturi injector where the particles of solid fuel are dispersed in a second stream of said nitrogen. The solid fuel-nitrogen gaseous dispersion is then reacted with a free-oxygen containing gas preferably in the absence of supplemental H.sub.2 O, other than any moisture normally found in the reactants, in a freeflow partial oxidation synthesis gas generator. The nitrogen stream serves as a carrier for the particles of solid carbonaceous fuel and as a temperature moderator in the gas generator. After cleaning, shifting, and purifying the raw synthesis gas, a gaseous mixture of N.sub.

Abstract: An atmosphere of nitrogen containing hydrogen is generated by cracking amia and recycling a previously generated atmosphere that already had been used. The atmosphere generated by cracking, and the recovered atmosphere that previously had been used, are subjected in a reactor to a catalytic treatment at a temperature between 0.degree. to 600.degree. C and then, after passing through a refrigeration arrangement, the resultant atmosphere is prepared for use. As one example, the atmosphere is adapted to be used as a protective atmosphere for metallurgical heat-treating furnaces.

Abstract: A nitrogen-rich inert gas mixture is produced by the partial oxidation of a hydrocarbonaceous feed containing substantially no metals nor noncombustible materials with air in a free-flow, unpacked, refractory-lined gas generator at a temperature in the range of about 1300.degree. to 3000.degree. F. and a pressure in the range of about 1 to 250 atmospheres. The product gas will comprise a mixture of nitrogen, argon and carbon dioxide and may contain small amounts of hydrogen and carbon monoxide, depending on the O/C atomic ratio selected. The atomic ratio of free oxygen in said air to carbon in said hydrocarbonaceous fuel is in the range of about 1.7 to stoichiometric, or slightly less than stoichiometric. By operating at this level of O/C atomic ratio, the H.sub.2 + CO content of the product gas may be minimized or deleted, substantially all of the particulate carbon may be oxidized, substantially no NO.sub.x is produced, and the product gas contains substantially no free oxygen.

Abstract: An improved process for manufacture of a purified gas containing hydrogen and carbon monoxide is described wherein a fuel is partially combusted in a reactor to produce a crude gas product containing soot, ash and contaminating gases such as HCN, H.sub.2 S and COS, the crude gas product is subsequently cooled in a waste heat boiler and the cooled gas is washed in a scrubber to remove the entrained soot particles. In this improved process, removal of soot, ash and gaseous contaminants from the cooled crude gas product is facilitated by washing the cooled gas in a scrubber with an aqueous salt solution containing at least 10% by weight of an alkaline water-soluble salt, which salt solution is subsequently regenerated by removal of absorbed gases and suspended solids (soot and ash) and recycled to the scrubber.

Abstract: Granulated coals or cokes derived from coal, in sizes up to about 3/4 inch and containing ash matter with an initial deformation temperature below about 2,300.degree.F, are fed to a slow fluidized bed comprising relatively large particles of coke intermingled with roughly spherical ash agglomerates, maintained at about 1,900.degree.F to about 2,450.degree.F, and supplied with a gasification medium, for example, steam mixed with oxygen or air. A fast fluidized bed of coke fines is superimposed above the slow bed and is contiguous therewith. Gasification products are discharged together with relatively fine particles of coke, which are collected and returned to the fast bed. Ash agglomerates are withdrawn from the bottom of the slow bed via a standpipe leading to a slagging grate. Combustion of coke fines in a forehearth beneath the slagging grate creates slagging temperatures therein and at the grate. Molten slag falls through a taphole and into a pool of water, from which slag frit and water are discharged.

Abstract: Granulated coals or cokes derived from coal, in sizes up to about 3/4 inch and containing ash matter with an initial deformation temperature above about 2,300.degree.F, are fed to a slow fluidized bed comprising relatively large particles of coke intermingled with roughly spherical ash agglomerates, maintained at about 2,050.degree.F to 2,650.degree.F, and supplied with a gasification medium, for example, steam mixed with oxygen or air. A fast fluidized bed of coke fines is superposed above the slow bed and is contiguous therewith. Gasification products are discharged together with relatively fine particles of coke, which are collected and returned to the fast bed. Ash agglomerates are withdrawn from the bottom of the slow bed via a standpipe leading to a mechanical grate. An oxidizing medium is introduced below the grate to consume coke particles that accompany the ash agglomerates entering the standpipe.

Abstract: A method of stopping of a winding machine that hoists and lowers an object prevents abrasion of the electromagnetic brake and the descent of load. The winding machine, which winches a load up or down in response to a torque command TREF to the electric motor M produced by the speed controller ASR in accordance with the a speed command NREF generated by the speed command generation circuit NRC, operates at the stopping of the machine to cease the motor control if the motor speed NFB is zero after the torque command to the motor M is brought to zero for a predetermined length of time following the issuance of a brake command to the electromagnetic brake which is coupled directly to the motor M.