Anti-oxidants Or Chemical Change Inhibitants Patents (Class 252/397)
  • Patent number: 5252289
    Abstract: Water-soluble 1,2-dithiole-3-thione derivatives are prepared by reacting a polyoxyalkylated starting material with sulfur. These derivatives are useful as corrosion inhibitors, particularly in aqueous environments.
    Type: Grant
    Filed: January 11, 1993
    Date of Patent: October 12, 1993
    Assignee: Petrolite Corporation
    Inventor: Bernardus A. Oude Alink
  • Patent number: 5236617
    Abstract: A new oxygen absorbent which is used sealed in a pack with a food to prevent the food from deteriorating is disclosed, in which the oxygen absorbent contains ascorbic acid and/or salts thereof, an alkaline compound such as sodium carbonate, a reaction accelerator such as ferrous sulfate, and a silica gel, and improves the flowability and the oxygen absorbability.
    Type: Grant
    Filed: April 21, 1992
    Date of Patent: August 17, 1993
    Assignee: K.K. Ueno Seiyaku Oyo Kenkyujc
    Inventors: Ryuzo Ueno, Akihiko Tabata
  • Patent number: 5180518
    Abstract: The present invention relates to novel oxygen absorbent comprising as main ingredients a 1,2-glycol, glycerine or sugar alcohol with the oxygen absorbent materials.
    Type: Grant
    Filed: April 18, 1990
    Date of Patent: January 19, 1993
    Assignee: Mitsubishi Gas Chemical Co., Inc.
    Inventors: Yasuo Sugihara, Toshio Komatsu, Takashi Kashiba, Hidetoshi Hatakeyama, Teruo Takeuchi
  • Patent number: 5166375
    Abstract: The antioxidant is safe for human health, has excellent antioxidation activity and is suitably utilized for preventing oxidation of unsaturated fatty acids, esters of unsaturated fatty acids and various kinds of products comprising these acids and esters. The oxidation resistant polyunsaturated oil is made by giving strong antioxidation activity to polyunsaturated oils, such as polyunsaturated fatty acids, esters of polyunsaturated fatty acids and polyunsaturated fats.The antioxidant comprises musizin and tocopherol as the effective components. The oxidation resistant polyunsaturated oil and fat of the invention is characterized in that an antioxidant comprising musizin as the effective component is added to a polyunsaturated oil.
    Type: Grant
    Filed: August 8, 1991
    Date of Patent: November 24, 1992
    Assignees: Nippon Oil and Fats Company, Limited, Nagaoka Perfumery Company, Limited
    Inventors: Hiromu Kameoka, Kiyoshi Furukawa, Hiroshi Kihara, Atsuyoshi Nishina
  • Patent number: 5155244
    Abstract: A method of solubilizing a first compound in a second medium where the first compound has a limited solubility in the second medium. In particular, the method comprises reacting the first compound with the second medium. By this reaction, a product is formed whereby an active component of the first compound is covalently incorporated into the second medium.The first compound and second medium each contain at least one reactive group which will react with a reactive group of the other. In addition, the first compound comprises at least one antioxidant which will be covalently bonded to and thus effectively solubilized in the second medium by the reaction.The second medium comprises glyceride derivatives, silicones, fluorocarbons and alkoxylates containing reactive groups such as hydroxy, amino, carboxyl, ester, or amides.
    Type: Grant
    Filed: February 28, 1990
    Date of Patent: October 13, 1992
    Assignee: Karlshamns AB
    Inventors: George H. Greene, James C. Phillips, Jerry F. Stults, Jan P. E. Tellings
  • Patent number: 5145781
    Abstract: Alpha-glycosyl rutin is formed at a high concentration by allowing a saccharide-transferring enzyme to act on a high-rutin content liquid in suspension or solution to effect saccharide-transfer reaction. The resultant alpha-glycosyl rutin is easily recovered from the reaction mixture by allowing it to contact with a synthetic macroreticular resin. Alpha-glycosyl rutin is superior in water-solubility, resistance to light and stability to intact rutin, as well as having the physiological activities as intact rutin has. Thus, alpha-glycosyl rutin is favorably usable as a yellow coloring agent, antioxidant, stabilizer, fading-preventing agent, quality-improving agent, preventive, remedy, uv-absorbent and deterioration-preventing agent in foods, beverages, tobaccos, cigarettes, feeds, pet foods, pharmaceuticals for susceptive diseases, cosmetics including skin-refining agent and skin-whitening agent, and plastics, in addition to the use in vitamin P-enriching agents.
    Type: Grant
    Filed: March 7, 1990
    Date of Patent: September 8, 1992
    Assignee: Kabushiki Kaisha Hayashibara Seibutsu Kagaku Kenkyujo
    Inventors: Yukio Suzuki, Kei Suzuki, Masaru Yoneyama, Hiromi Hijiya, Toshio Miyake
  • Patent number: 5132294
    Type: Grant
    Filed: July 2, 1991
    Date of Patent: July 21, 1992
    Assignee: Kabushiki Kaisha Kobe Seiko Sho
    Inventors: Akio Mimura, Keiichi Takebayashi, Yoshimasa Takahara, Toshihiko Osawa
  • Patent number: 5114716
    Abstract: An anti-oxidant system contains, in combination, at least one stabilized ascorbyl ester, at least one tocopherol or a mixture of tocopherols, or cafeic acid or a derivative thereof, at least one complexing agent and at least one non-thiol polypeptide. The anti-oxidant system is employed to stabilize fatty bodies and cosmetic compositions.
    Type: Grant
    Filed: July 28, 1989
    Date of Patent: May 19, 1992
    Assignee: Societe Anonyme Dite: L'Oreal
    Inventors: Quang L. N'Guyen, Jacqueline Griat, Francois Millecamps, Gerard Lang, Serge Forestier
  • Patent number: 5104997
    Abstract: This invention provides a process for deacidifying paper by contacting the paper with hydrocarbon or halocarbon solutions of certain magnesium and/or zinc alkoxyalkoxides which may have been treated with carbon dioxide to yield low viscosity solutions.
    Type: Grant
    Filed: December 20, 1990
    Date of Patent: April 14, 1992
    Assignee: FMC Corporation
    Inventors: Conard W. Kamienski, Robert S. Wedinger
  • Patent number: 5102673
    Abstract: There are disclosed an oxygen absorbent comprising boron or a reducing boron compound, an alkaline substance and a carrier, an oxygen absorbent parcel formed by enclosing said oxygen absorbent in a permeable packaging parcel, a food package and a package of a metallic or electronic product or part containing said oxygen absorbent parcel.
    Type: Grant
    Filed: October 24, 1990
    Date of Patent: April 7, 1992
    Assignee: Mitsubishi Gas Chemical Company, Inc.
    Inventors: Yasuo Sugihara, Teruo Takeuchi, Hidechika Wakabayashi, Akira Hosomi, Toshio Komatsu
  • Patent number: 5091108
    Abstract: New oxygen scavengers for boiler waters have been discovered, which oxygen scavengers are based upon N,N,N',N'-tetra substituted phenylenediamines. These compounds provide oxygen scavenging capabilities, metal passivating capabilities, volatility such that condensate systems in an operating boilder are protected, and may be formulated with other oxygen scavengers and other common treatment agents used in boiler waters.The preferred tetra substituted phenylenediamines are N,N,N', N'-tetramethyl-1,4-phenylenediamines, or its precursors.
    Type: Grant
    Filed: February 21, 1991
    Date of Patent: February 25, 1992
    Assignee: Nalco Chemical Company
    Inventors: Scott R. Harder, Cynthia A. Soderquist, Claudia C. Pierce
  • Patent number: 5091112
    Abstract: Reducing the copper corrosiveness of organic sulfides by treating them with an alkali metal-containing or alkaline earth metal-containing substance capable of dissolving elemental sulfur (e.g., sodium hydroxide, sodium sulfide, etc.). The process is conducted in a substantially homogeneous liquid reaction medium composed of a mixture of water and at least one ketone. Experiments have shown that it is possible by use of this process to reduce the copper corrosiveness to a level below that exhibited by a product formed by treating the same initial organic sulfide in the same way but in a liquid medium composed solely of water.
    Type: Grant
    Filed: March 19, 1990
    Date of Patent: February 25, 1992
    Assignee: Ethyl Petroleum Additives, Inc.
    Inventors: Edmund F. Perozzi, John F. Sieberth
  • Patent number: 5082593
    Abstract: A non-reduction agent for dielectric ceramics is composed of a(MnO+RO) and (1-a) (BO.sub.3/2 +SiO.sub.2), or of b(LiO.sub.1/2 +RO) and (1-b) (BO.sub.3/2 +SiO.sub.2). Here, R is at least one kind selected from among Mg, Ca, Sr and Ba. In these compositions, a is within a range of 0.01.ltoreq.a.ltoreq.0.90 (Mol ratio), and b is within a range of 0.01.ltoreq.b.ltoreq.0.80 (Mol ratio). These non-reduction agents for dielectric ceramics are added to dielectric ceramic materials containing lead oxide, for example, and used as materials for capacitors. These dielectric ceramics become hard to be reduced even when fired in reducing atmospheres.
    Type: Grant
    Filed: August 18, 1989
    Date of Patent: January 21, 1992
    Assignee: Murata Manufacturing Co., Ltd.
    Inventors: Hiroshi Takagi, Yoshiaki Mori, Yukio Sakabe
  • Patent number: 5057123
    Abstract: A method of stabilizing a diesel fuel formulation by substantially minimizing the oxidation thereof is disclosed. In particular, at least one amine containing copolymer is incorporated into the diesel fuel formulation in an amount sufficient to improve the storage stability and, also, substantially minimize the oxidation thereof. The method of this invention is particularly well suited for substantially minimizing the high temperature oxidation of diesel fuels.
    Type: Grant
    Filed: May 25, 1990
    Date of Patent: October 15, 1991
    Assignee: Texaco Inc.
    Inventors: Sheldon Herbstman, Theodore E. Nalesnik
  • Patent number: 5025050
    Abstract: This invention relates to an ultraviolet-radiation stabilizer flame retarding system containing an N,N'-ethylene-bis(tetrabromophthalimide) or an N,N'-bis(tetrabromophthalimide) predominate product, a hindered-amine light stabilizer, a 2-(2'-hydroxyphenyl)benzotriazole, a titanate, and, optionally, Mg(OH).sub.2 and/or ZnO.
    Type: Grant
    Filed: March 16, 1990
    Date of Patent: June 18, 1991
    Assignee: Ethyl Corporation
    Inventor: James E. Torres
  • Patent number: 4997990
    Abstract: A process for stabilizing vinyl monomers in general, and ar-brominated styrene polymer in particular, against polymerization by mixing a vinyl monomer such as an ar-brominated styrene monomer with a stabilizing amount of iodine composition to produce a stabilized monomer and novel stabilized compositions.
    Type: Grant
    Filed: March 23, 1989
    Date of Patent: March 5, 1991
    Assignee: General Electric Company
    Inventors: Stephen M. Campbell, John C. Wozny
  • Patent number: 4929424
    Abstract: A method of inhibiting the corrosion of the metal surfaces of beer pasteurizing units in contact with halogenated water vapor which comprise treating these halogenated waters with at least 1/4 ppm sulfamic acid for each ppm of halogen present in these waters.
    Type: Grant
    Filed: April 11, 1988
    Date of Patent: May 29, 1990
    Assignee: Nalco Chemical Company
    Inventors: Daniel A. Meier, Michael J. Groshans
  • Patent number: 4917820
    Abstract: Disclosed herein is an ethylene removal agent, a postharvest preservation agent to keep freshness of vegetables, fruits and flowers, and a deodorant comprising (A) at least one compound selected from the group consisting of phosphoric acid, phosphorous acid, hypophosphorous acid, hypochlorous acid and salts of these acids, and (B) specified metal(s) or compound(s) of metal.
    Type: Grant
    Filed: March 1, 1989
    Date of Patent: April 17, 1990
    Assignee: Nippon Kayaku Kabushiki Kaisha
    Inventors: Mutsumi Matsumoto, Masanobu Ogawa
  • Patent number: 4889771
    Abstract: Described is a method of treating wood without pressure using compositions comprising aqueous solutions of one or more lanthanide derivative. Also described is a composition comprising wood and lanthanides or lanthanide derivatives.
    Type: Grant
    Filed: November 17, 1987
    Date of Patent: December 26, 1989
    Assignee: Rhone-Poulenc Inc.
    Inventors: Peter S. Gradeff, John F. Davison
  • Patent number: 4883689
    Abstract: Described is a method of treating wood using compositions comprising an organic solution (non-aqueous solution) of one or more lanthanide derivatives. Also described is a composition comprising wood and lanthanides or lanthanide derivatives. In one embodiment, the treatment occurs under vacuum.
    Type: Grant
    Filed: November 4, 1988
    Date of Patent: November 28, 1989
    Assignee: Rhone Poulenc, Inc.
    Inventor: Peter S. Gradeff
  • Patent number: 4873013
    Abstract: Aqueous cleaner compositions containing an alkali metal halogenite, for example, NcClO.sub.2 ; a stabilizable colorant; and a stabilizing amount of a stabilizer compound which is an ammonium hydroxide. The preferred embodiment further includes an anionic or anionic fluorocarbon surfactant.
    Type: Grant
    Filed: October 13, 1988
    Date of Patent: October 10, 1989
    Assignee: The Dracket Company
    Inventor: Richard S. Hutchings
  • Patent number: 4804494
    Abstract: A copper arsenate composition suitable for incorporation in a copper/chrome/arsenic wood preservative composition is made by reacting copper metal with a source of 5-valent arsenic such as arsenic acid under the oxidizing influence of hydrogen peroxide. The quantity of arsenic acid used may be made consistent with the arsenic to copper ratio required in the final wood preservative composition which may be made up by including a suitable source of chromium with the copper arsenate reaction product.
    Type: Grant
    Filed: April 23, 1987
    Date of Patent: February 14, 1989
    Assignee: Laporte Industries Limited
    Inventors: Ian K. Egerton, Andrew D. J. Broome
  • Patent number: 4803008
    Abstract: An aqueous cleaning composition comprising a surfactant; up to about 50% of a higher boiling solvent, typically an alkyl ether of an alkylene glycol, said solvent introducing impurities into the composition in an amount and of a nature normally chemically incompatible with oxidizable dye chromophores; a dye in an amount to provide a desired tinctorial value, and a stabilizer selected from the group consisting of salts suitable to provide iodide and thiosulfate anions in an amount effective to retard fading of the dye, said compositions having a basic pH when the stabilizer is the thiousulfate salt. In another aspect of the invention, the stabilizer incorporated into compositions containing a solvent, a surfactant, and water, and optionally a dye provides a beneficial cleaning result. In yet another aspect of the invention, the stabilizer beneficially retards the development of malodors when the compositions of the present invention are contained in a PVC container.
    Type: Grant
    Filed: September 23, 1987
    Date of Patent: February 7, 1989
    Assignee: The Drackett Company
    Inventors: Laura A. Ciolino, Shaun F. Clancy
  • Patent number: 4790950
    Abstract: Aqueous cleaner compositions containing an alkali metal halogenite, for example, NaClO.sub.2 ; a stabilizable colorant; and a stabilizing amount of a stabilizer compound which is an ammonium hydroxide. The preferred embodiment further includes an anionic or anionic fluorocarbon surfactant.
    Type: Grant
    Filed: March 7, 1988
    Date of Patent: December 13, 1988
    Assignee: The Drackett Company
    Inventor: Richard S. Hutchings
  • Patent number: 4743473
    Abstract: The invention is a method for pressure treatment of wood using compositions comprising aqueous solutions of one or more lanthanide derivatives. Wood is immersed in a pressure vessel containing a lanthanide derivative composition, and hydrostatic pressure is applied. The treatment is carried out at temperatures not exceeding about 95.degree. C., and more preferably at between about 20.degree. C. and about 30.degree. C. Pressure should be greater than about atmospheric, and preferably about 10 psi to about 300 psi.
    Type: Grant
    Filed: February 20, 1987
    Date of Patent: May 10, 1988
    Assignee: Rhone-Poulenc Inc.
    Inventors: Peter S. Gradeff, John F. Davison
  • Patent number: 4719133
    Abstract: The invention relates to treating wood with a wood preservative by applying in one or more recesses made in the wood solid material together with the wood preservative in such a way that the solid material fills up the recesses at least partly, said solid material having a lower water content than the wood treated and exerts a reinforcing effect upon this wood, when it absorbs water and in result expands and/or when a permanent pressure is exerted upon it.Furthermore, the invention relates to products to be used for this treatment, with which by one single act the filling-up of a recess in the wood to be treated and the closing thereof can be effected.
    Type: Grant
    Filed: August 5, 1985
    Date of Patent: January 12, 1988
    Inventor: Jacob Woudsma
  • Patent number: 4612339
    Abstract: The polyamide polymers, notably the nylons, are effectively heat stabilized, characteristically with good retention of mechanical properties, by formulating therewith stabilizing amounts of (i) at least one lanthanide or yttrium-based compound and (ii) at least one ammonium, or alkali or alkaline earth metal halide.
    Type: Grant
    Filed: March 8, 1985
    Date of Patent: September 16, 1986
    Assignee: Rhone-Poulenc Specialites Chimiques
    Inventor: Bruno Giroud-Abel
  • Patent number: 4578282
    Abstract: A fixative composition for histological, cytological, immunological and proteinaceous preparations comprising a mixture of pyrrolid-2-one, a polyol, a urea and a zinc salt of a non-oxidizing organic or inorganic acid. Also disclosed are devices utilizing such compositions.
    Type: Grant
    Filed: January 4, 1985
    Date of Patent: March 25, 1986
    Inventor: James S. Harrison
  • Patent number: 4575455
    Abstract: A gas scrubbing operation wherein a mixture of gases is scrubbed with a gas scrubbing medium to remove at least one gas component from the mixture is improved by reducing the fouling of apparatus used in the scrubbing operation by adding to the scrubbing medium an antifoulant effective amount of a hydroxylamine compound.
    Type: Grant
    Filed: November 23, 1984
    Date of Patent: March 11, 1986
    Assignee: Atlantic Richfield Company
    Inventor: Richard F. Miller
  • Patent number: 4565648
    Abstract: A process for producing storage-stable solutions of pyrocarbonic acid dialkyl esters in organic liquids inert to these esters comprising adding certain carbonyl compounds, sulfonyl compounds and/or thiourea to these pyrocarbonic acid dialkyl ester solutions. Also the use of these carbonyl compounds, sulfonyl compounds and/or thiourea for producing stabilized polyisocyanate preparations suitable for the production of polyurethane foams.
    Type: Grant
    Filed: August 15, 1983
    Date of Patent: January 21, 1986
    Assignee: Bayer Aktiengesellschaft
    Inventors: Richard Kopp, Wolfgang Reichmann
  • Patent number: 4561995
    Abstract: Drying agents for cut plants provide a basic pH in a solution between approximately 12.4 and 13.2 when the drying is to be provided primarily on the stems of the cut plants. The drying agents include a first material which provides a pH of at least 12.4 in the solution. The first drying agent may constitute an alkaline metasilicate such as sodium metasilicate. The drying agents may also include a second material such as an alkaline carbonate. Sodium or potassium carbonate are preferable. The second drying agent constitutes a buffer to limit the pH in the solution to a value of approximately 13.2.The metasilicate is in the form of a colloid of silicon dioxide and this colloid tends to act primarily on the waxes on the stems to saponify the waxes on the surfaces of the stems. The drying agents form a chemical complex which serves as a protective coating to prevent water from entering into the stems of the plants.
    Type: Grant
    Filed: April 5, 1982
    Date of Patent: December 31, 1985
    Assignee: Fenn & Company
    Inventor: George S. Fenn
  • Patent number: 4556505
    Abstract: A drying agent for cut plants provides a basic pH of at least 11 in a solution and has properties of becoming at least partially insoluble at a pH no greater than approximately 13.4 in the solution. A mold-inhibiting agent is mixed with the drying agent and is provided with properties of remaining inactive until the occurrence of conditions inducing molding of the plant. The mold-inhibiting agent has properties of reacting with moisture under such conditions inducing molding to inhibit such molding.A waterproofing agent is mixed with the drying and mold-inhibiting agents and is provided with properties, at the pH of the drying agent in the solution, for providing for a passage of moisture from the plants while preventing drops or droplets of water from being reabsorbed on the plants. The waterproofing agent may be sodium methyl siliconate.A surface active agent may also be included.
    Type: Grant
    Filed: April 5, 1982
    Date of Patent: December 3, 1985
    Assignee: Fenn & Company
    Inventor: George S. Fenn
  • Patent number: 4540503
    Abstract: This invention relates to a method of controlling the viscosity of siloxane oils in the presence of lead by adding a small amount of a dione such as p-benzoquinone or 2,3-butanedione.
    Type: Grant
    Filed: September 12, 1984
    Date of Patent: September 10, 1985
    Assignee: The United States of America as represented by the United States Department of Energy
    Inventors: A. Andrew Carey, Joel T. Shor
  • Patent number: 4524015
    Abstract: A particulate or granular oxygen absorbent comprising at least one ascorbic compound selected from ascorbic acid, ascorbic acid salts or mixtures thereof, an alkali metal carbonate, an iron compound, carbon black and water and the absorbent coated with a finely divided powder are disclosed.
    Type: Grant
    Filed: August 5, 1983
    Date of Patent: June 18, 1985
    Assignee: Mitsubishi Gas Chemical Company, Inc.
    Inventors: Hideyuki Takahashi, Toshio Komatsu, Yoshiaki Inoue
  • Patent number: 4493821
    Abstract: A fixative composition for histological, cytological, immunological and proteinaceous preparations comprising a mixture of pyrrolid-2-one, a polyol, a urea and a zinc salt of a non-oxidizing organic or inorganic acid. Also disclosed are devices utilizing such compositions.
    Type: Grant
    Filed: February 4, 1982
    Date of Patent: January 15, 1985
    Inventor: James S. Harrison
  • Patent number: 4468338
    Abstract: A transparent soap composition, consisting essentially of(a) over 50% by weight of a complex mixture of the sodium and triethanolamine salts of a fatty acid or acids having from 6 to 18 carbon atoms and an iodine value of 8-15,(b) between 0.2 and 1.0 weight percent of a member or members selected from the group consisting of citric acid, sodium citrate and potassium citrate,(c) between 0.2 and 0.1 weight percent of a member or members selected from the group consisting of sodium metabisulfite, sodium sulfite, sodium bisulfite, potassium bisulfite, sodium hydrosulfite, potassium hydrosulfite and potassium sulfite, and potassium metabisulfite,(d) water.
    Type: Grant
    Filed: June 13, 1983
    Date of Patent: August 28, 1984
    Assignee: Purex Corporation
    Inventor: Gordon A. Lindberg
  • Patent number: 4466902
    Abstract: A rust inhibitor comprising, as an effective component, at least one compound having the following general formulae (A), (B) and (C) ##STR1## wherein R.sub.1 and R.sub.2 are independently a hydrocarbon group having 1 to 6 carbon atoms, R.sub.3 and R.sub.4 are independently a hydrocarbon group having 1 to 4 carbon atoms or a hydrocarbon group containing an aromatic ring and having 6 to 12 carbon atoms, R.sub.5 and R.sub.6 are independently a hydrocarbon group having 1 to 18 carbon atoms, m and n are independently 0 or an integer of 1 to 3, R.sub.3 or R.sub.4 is hydrogen in the case of m or n is 0, X is O, S, SO.sub.2, CO or a hydrocarbon group having 1 to 9 ca toxicity and is easily applicable in either a water-soluble state or an oil-soluble state.
    Type: Grant
    Filed: September 30, 1982
    Date of Patent: August 21, 1984
    Assignee: Ipposha Oil Industries, Co., Ltd.
    Inventors: Shinichi Kumagae, Tatsuo Manabe
  • Patent number: 4458029
    Abstract: Polymerizable liquid synthetic resins, liquidreactive constituents of synthetic resins or liquid additives for plastics, in each case containing mineral fillers, are converted to dry, pourable mixtures by mixing with 0.25-5% by weight of a crystalline synthetic calcium silicate, which can be in diverse stages of hydration and has a high length/width ratio and width dimensions of less than 1 .mu.m, it being possible, by this means, to employ the resins not only as casting resins but also as compression moulding resins and adhesives. In addition, handling and processability are improved.
    Type: Grant
    Filed: September 20, 1982
    Date of Patent: July 3, 1984
    Assignee: Ciba-Geigy Corporation
    Inventor: Kurt Munk
  • Patent number: 4440738
    Abstract: Stable compositions, useful as technetium-99m-based imaging agents, comprise reductic acid or certain structurally-related compounds in combination with a pertechnetate reductant or dissolved in pertechnetate-99m solution. The compositions are especially useful, in combination with a phosphate or phosphonate bone-targeting carrier, for skeletal imaging.
    Type: Grant
    Filed: June 10, 1982
    Date of Patent: April 3, 1984
    Assignee: Mallinckrodt, Inc.
    Inventors: Mahdi B. Fawzi, James J. Benedict, Joseph E. Bugaj, Charles R. Degenhardt, Barry F. Van Duzee
  • Patent number: 4421728
    Abstract: Particulate red amorphous phosphorus is stabilized against oxidative degradation to phosphorus acids and phosphine by the use of titanium dioxide or titanium phosphate.
    Type: Grant
    Filed: July 7, 1982
    Date of Patent: December 20, 1983
    Assignee: ERCO Industries Limited
    Inventor: Helena Twardowska
  • Patent number: 4381251
    Abstract: An oxidation inhibitor comprising;(A) 10 to 200 parts by weight of at least one selected from the group consisting ofSilica powderKaolineMagnesia powderMgO-Cr.sub.2 O.sub.3 refractoriesMg-SiO.sub.2 refractories, andMica(B) 10 to 200 parts by weight of silicic anhydride (SiO.sub.2),(C) 10 to 200 parts by weight of at least one selected from the group consisting of Cr, Al, Ti, Nb, Ni and Cu in the powder form,(D) 5 to 50 parts by weight of at least one selected from the group consisting of colloidal silica and alumina sol, and(E) 1 to 20 parts by weight of water-soluble resin,wherein the ratio of the metal powder to the total solid components is within a range defined by the following formula: ##EQU1## (the total solid components is the sum of (A)+(B)+(C)+(solid component of D)+(E)).
    Type: Grant
    Filed: June 21, 1977
    Date of Patent: April 26, 1983
    Assignee: Nippon Steel Corporation
    Inventors: Minoru Kitayama, Hisao Odashima
  • Patent number: 4371656
    Abstract: A stabilizer for use in a halogen-containing resin is described comprising a crystalline aluminosilicate substituted with ions of a metallic element belonging to Group II or Group IVA of the Periodic Table for Group I (M) metal ion contained in said aluminosilicate and containing 10% by weight of less, as M.sub.2 O, of residual Group I metal ions.
    Type: Grant
    Filed: December 8, 1980
    Date of Patent: February 1, 1983
    Assignees: Nippon Chemical Industrial Co., Ltd., Kosei Co., Ltd.
    Inventors: Kohji Kashiwase, Yasuo Machino, Muneo Mita, Tsunenosuke Hiramatsu, Toshihiko Morishita, Mitsuo Taniguchi
  • Patent number: 4359392
    Abstract: Novel processes are provided for the stabilization of modified celluloses in brine solutions useful for well completion and workover. Copper species are added to such fluids in an amount effective substantially to decrease the rate of decomposition of such cellulose at temperatures above about 225.degree. F.
    Type: Grant
    Filed: December 29, 1980
    Date of Patent: November 16, 1982
    Assignee: Mobil Oil Corporation
    Inventor: Ralph H. Rygg
  • Patent number: 4343733
    Abstract: A synergistic stabilizer combination is provided for use in improving the resistance of polymers, such as olefin polymers and copolymers, to deterioration in physical properties upon exposure to heat. The stabilizer combination contains a quinoline compound, a diamine compound and a magnesium compound in correlated amounts. In addition, olefin polymer compositions such as an ethylene-vinyl acetate copolymer composition containing the synergistic stabilizer combination and a method for preparing the compositions are provided.
    Type: Grant
    Filed: December 1, 1980
    Date of Patent: August 10, 1982
    Assignee: National Distillers & Chemical Corp.
    Inventors: Melvin F. Maringer, Fred K. Morgan
  • Patent number: 4342733
    Abstract: An improved method for inhibiting sulfite oxidation in scrubber liquor of the type containing sulfite species is disclosed. A topping agent selected from the group consisting of polyphosphate compounds, and organo-phosphonic acid compounds, and mixtures thereof, is added to the scrubbing liquor to supplement and enhance the antioxidant activity of sulfite antioxidant agents such as the linear polyethyleneamines and substituted secondary and tertiary aromatic amines.
    Type: Grant
    Filed: January 9, 1981
    Date of Patent: August 3, 1982
    Assignee: Betz Laboratories, Inc.
    Inventors: Joe C. Steelhammer, Paul J. Hutta
  • Patent number: 4340643
    Abstract: A fluid antioxidant for molten metal which comprises glass or ferrite in the form of tiny balloons having three or more sizes. The balloons are coated with powdered silicon and powdered spinel to make their surface softer and more abrasive.
    Type: Grant
    Filed: September 22, 1980
    Date of Patent: July 20, 1982
    Inventor: Kozo Sato
  • Patent number: 4326978
    Abstract: A soap bar which contains, as antimicrobial compound, a halogenated o-hydroxydiphenyl ether, as well as a colorless silicate which is virtually insoluble in water and wich diminishes the discoloration of the soap caused by the antimicrobial compound on exposure to sunlight. There is also disclosed a method of improving the aspect of bars of soap which contain such antimicrobial compounds by adding to the soap base a colorless silicate which is virtually insoluble in water, optionally in conjunction with a fatty acid containing 8 to 22 carbon atoms and/or a N-acylsarcosine.
    Type: Grant
    Filed: November 10, 1980
    Date of Patent: April 27, 1982
    Assignee: Ciba-Geigy Corporation
    Inventor: Boris Moesch
  • Patent number: 4323477
    Abstract: An aqueous copper chromate concentrate substantially free of sulfate anions is provided which can be diluted for use as a wood preservative. The concentrate is formed of a hexavalent chromium compound, a bivalent copper compound, and an acid selected from nitric, sulfamic, fluosilicic, fluoboric and mixtures wherein the total oxide content of CuO and CrO.sub.3 is from 25 to 60%.
    Type: Grant
    Filed: October 3, 1979
    Date of Patent: April 6, 1982
    Assignee: Koppers Company, Inc.
    Inventor: Robert E. Hill
  • Patent number: 4299719
    Abstract: A deoxidizer comprises ferrous carbonate having a specific surface area of at least 20 m.sup.2 /g. The ferrous carbonate can be combined with a mixture of a reduced iron powder and a metal halide; or an alkli metal hydroxide and/or an alkline earth metal hydroxide or calcium oxide and/or ettringite. The deoxidizer is used for the deoxidation of a package so as to substitute oxygen by carbon dioxide.
    Type: Grant
    Filed: October 23, 1979
    Date of Patent: November 10, 1981
    Assignees: Mitsubishi Chemical Ind., Ltd., Teikoku Kako Co., Ltd.
    Inventors: Motohisa Aoki, Isao Kawakami, Masami Nishihara
  • Patent number: RE32991
    Abstract: The disclosed wound dressings have a drug dispersed throughout a polyurethane matrix that is the reaction product of: (A) An isocyante terminated prepolymer formed by reaction of isophorone diisocyanate and a marcoglycol and (B) a monomer containing hydroxyl and vinyl groups. The reaction product is a vinyl terminated polyurethane oligomer which is liquid at room temperature and which may be readily admixed with a pharmacoactive substance and a photosensitizer, formed into a film and cured by exposure to UV light without release of heat.In the most preferred embodiments the foregoing oligomer is codissolved in an organic solvent with a polyurethane polymer which is the reaction product of:dicyclohexyl methane diisocyanate;a polytetramethylene ether polyol having a molecular weight in the range of 1000-3000 daltons; and1,4-butane diol.That solution is then admixed with the pharmacoactive agent, formed into a film and cured.
    Type: Grant
    Filed: July 25, 1988
    Date of Patent: July 18, 1989
    Assignee: Thermedics, Inc.
    Inventors: Michael Szycher, Donald J. Dempsey, Jonathan L. Rolfe