Inorganic Crystalline Solid Patents (Class 252/584)
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Publication number: 20100117036Abstract: A polycrystalline transparent ceramic article including lutetium is presented. The article includes an oxide with a formula of ABO3, having type A lattice sites and type B lattice sites. The lattice site A may further comprise a plurality of elements, in addition to lutetium. Type B lattice site includes aluminum. An imaging device, a laser assembly, and a scintillator including the lutetium-based article is provided. A method of making the above article is also provided.Type: ApplicationFiled: January 21, 2010Publication date: May 13, 2010Applicant: GENERAL ELECTRIC COMPANYInventors: Kalaga Murali Krishna, Venkat Subramaniam Venkataramani, Mohan Manoharan
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Publication number: 20100013376Abstract: Composition comprising one or more energy donors and one or more energy acceptors, wherein energy is transferred from the energy donor to the energy acceptor and wherein: the energy acceptor is a colloidal nanocrystal having a lower band gap energy than the energy donor; the energy donor and the energy acceptor are separated by a distance of 40 nm or less; wherein the average peak absorption energy of the acceptor is at least 20 meV greater than the average peak emission energy of the energy donor; and wherein the ratio of the number of energy donors to the number of energy acceptors is from about 2:1 to about 1000:1.Type: ApplicationFiled: July 16, 2008Publication date: January 21, 2010Inventors: Garry R. Maskaly, Richard D. Schaller, Victor I. Klimov
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Publication number: 20100002324Abstract: The present invention provides compositions (“Optical Nanomaterial Compositions”) comprising one or more nano-materials and an optical coupling gel or an optical adhesive. The invention also provides methods for using the Optical Nanomaterial Compositions as an index-matching gel, an optical adhesive or an optical film, all of which are suitable for optical and sensing de-vices applications, including but not limited to noise suppression, passive Q-switching, mode-locking, waveform shaping, optical switching, optical signal regeneration, phase conjugation, in filter devices, dispersion compensation, wavelength conversion, soliton stabilization, microcavity applications, in interferometers (such as the Gires-Tournois interferometer), optical, magneto-optical or electro-optical modulation, biochemical sensors and photodetectors.Type: ApplicationFiled: August 24, 2007Publication date: January 7, 2010Applicant: CAMBRIDGE ENTERPRISE LIMITEDInventors: Oleksiy Rozhin, Andrea Ferrari, William Ireland Milne
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Publication number: 20090321761Abstract: A coating for converting optical spectrum includes: a transparent colloid layer and an emitter material unit. The emitter material unit is used to convert one part of a short-wavelength band of a light source into a long-wavelength band. The emitter material unit has at least one first emitter body and at least one second emitter body both mixed with the transparent colloid layer, the at least one first emitter body is an inorganic silicate compound, and the at least one second emitter body is aan organic dye. Hence, the color rendering index (CRI) and the range of color temperature of white light generated by an LED chip package module using the coating are increased according to the function of the emitter material unit for converting one part of a short-wavelength band of a light source into a long-wavelength band.Type: ApplicationFiled: September 30, 2008Publication date: December 31, 2009Applicant: PARAGON TECHNOLOGIES CO., LTD.Inventors: Chao-Chin Wu, Kwang-Chao Huang, Wei-Chun Yang
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Publication number: 20090256120Abstract: A nonlinear optical crystal having a chemical formula of YiLajAlkB16O48, where 2.8?i?3.2, 0.8?j?1.2, i and j sum to about four, and k is about 12 is provided. The nonlinear optical crystal is useful for nonlinear optical applications including frequency conversion. Nonlinear optical crystals in a specific embodiment are characterized by UV blocking materials (e.g., some transition metals and lanthanides) at concentrations of less than 1,000 parts per million, providing high transmittance over portions of the UV spectrum (e.g., 175-360 nm).Type: ApplicationFiled: March 14, 2009Publication date: October 15, 2009Applicant: Deep Photonics CorporationInventor: Theodore Alekel
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Patent number: 7588743Abstract: The present invention provides a cesium-rubidium-borate nonlinear optical crystal, which is represented by the chemical formula CsxRb1?xB3O5 (0<x<1), and belongs to the P212121 space group with the unit cell parameters in the following range: a=8.202-8.514 ?, b=10.075-9.140 ?, c=5.375-6.207 ? and Z=4. A preparation method of the crystal is as follows: a cesium salt, a rubidium salt and a boron-containing compound are mixed pro rata, heated, kept at a temperature, and then cooled down to obtain the cesium-rubidium-borate. The cesium-rubidium-borate and a flux are mixed and heated to form a melt to obtain a mixing melt. Then a seed crystal attached to a seed rod is dipped into the mixing melt and the seed rod is rotated simultaneously. The melt is kept at 620-780° C., and then cooled down slowly at a rate of 0-5° C. per day. The obtained crystal is drawn out of the melt surface and cooled down to room temperature. Thereby, the cesium-rubidium-borate nonlinear optical crystal is obtained.Type: GrantFiled: June 23, 2005Date of Patent: September 15, 2009Assignee: Technical Institute of Physics and Chemistry, Chinese Academy of SciencesInventors: Rukang Li, Chuangtian Chen
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Patent number: 7534377Abstract: Novel nonlinear optical materials are described having the general formula MxM?yScz(BO3)4 where M and M?are metals, typically rare earth metals, and the sum of x, y, and z is about four. One example of such a material is La0.7Y0.3Sc3(BO3)4. Exemplary crystalline materials according to the general formula exhibit useful optical characteristics and desirable physical properties for nonlinear optical applications. Novel compositions and devices using the nonlinear optical materials also are described.Type: GrantFiled: July 14, 2003Date of Patent: May 19, 2009Assignee: State of Oregon acting by and through the State Board of Higher Education on behalf of Oregon State UniversityInventors: Douglas A. Keszler, Jennifer L. Stone-Sundberg, Ning Ye, Michael A. Hruschka
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Patent number: 7527755Abstract: In one embodiment, a ferroelectric material is processed by placing the material in an environment including metal vapor and heating the material to a temperature below the Curie temperature of the material. This allows the bulk conductivity of the ferroelectric material to be increased without substantially degrading its ferroelectric domain properties. In one embodiment, the ferroelectric material comprises lithium tantalate and the metal vapor comprises zinc.Type: GrantFiled: May 9, 2005Date of Patent: May 5, 2009Assignee: Silicon Light Machines CorporationInventors: Ronald O. Miles, Ludwig L. Galambos, Janos J. Lazar, Gabriel C. Risk, Alexei L. Alexandrovski, Gregory D. Miller, David Caudillo, Joseph M. McRae, Gisele L. Foulon
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Patent number: 7521262Abstract: The present invention is directed to a silicon substrate having a monolayer formed by an electrochemically-induced reaction between silicon hydride moieties on the silicon surface and optionally substituted alkynes covalently bound to the surface of the silicon substrate and to a method for electrochemically producing such a functionalized silicon substrate. The method of forming a covalently bound monolayer on a silicon surface comprises the steps of contacting the silicon surface with a C2-C24 alkyne and electrografting optionally substituted alkynes to the silicon surface.Type: GrantFiled: December 10, 2004Date of Patent: April 21, 2009Assignee: Purdue Research FoundationInventors: Jillian M. Buriak, Michael P. Stewart, Edward Robins
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Patent number: 7504053Abstract: A nonlinear optical crystal having a chemical formula of YiLajAlkB16O48, where 2.8?i?3.2, 0.8?j?1.2, i and j sum to about four, and k is about 12 is provided. The nonlinear optical crystal is useful for nonlinear optical applications including frequency conversion. Nonlinear optical crystals in a specific embodiment are characterized by UV blocking materials (e.g., some transition metals and lanthanides) at concentrations of less than 1,000 parts per million, providing high transmittance over portions of the UV spectrum (e.g., 175-360 nm).Type: GrantFiled: June 16, 2008Date of Patent: March 17, 2009Assignee: Deep Photonics CorporationInventor: Theodore Alekel
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Patent number: 7504154Abstract: The present invention is directed to a salt optic provided with a multilayer coating in order to improve upon the moisture resistance of a salt optic, when compared to the moisture resistance of an uncoated salt optic. In one aspect, the present invention is comprised of a coated salt optic having at least a first coating layer and a second coating layer, the first coating layer being surface-smoothing layer and adhesion layer, and the second coating layer being a moisture barrier layer.Type: GrantFiled: March 23, 2005Date of Patent: March 17, 2009Assignee: Lockheed Martin CorporationInventors: James Neil Johnson, David Corbin Burton, Kevin Warner Flanagan
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Publication number: 20080296541Abstract: A composition of matter and method of forming a radiation shielding member at ambient temperatures in which the composition of matter includes a ‘cold-fired’ chemically bonded oxide-phosphate ceramic cement matrix; with one or more suitably prepared and distributed radiation shielding materials dispersed in the ‘cold-fired’ chemically bonded oxide-phosphate ceramic cement matrix.Type: ApplicationFiled: June 4, 2008Publication date: December 4, 2008Applicant: CO-OPERATIONS, INC.Inventors: Judd Hamilton, Vernon D. Hamilton
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Patent number: 7449134Abstract: Noble crystal of 4-dimethylamino-4-stilbazolium tosylate (DAST) useful as an electro-optical element. A DAST crystal having a size effective for use as an electro-optical element is provided by a twin crystal of DAST. The twin crystal of DAST can be obtained according to a seed crystallization method or a slope crystal growing method.Type: GrantFiled: July 21, 2006Date of Patent: November 11, 2008Assignees: Daiichi Pure Chemicals Co., Ltd., Daiichi Pharmaceutical Co., Ltd.Inventors: Atsushi Izumi, Yuta Ochiai, Shinsuke Umegaki, Tomo Iwamura, Makoto Suzuki, Hidetaka Sakurai, Shinji Yamaguchi
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Publication number: 20080230752Abstract: A method of creating and controlling the particle spacing of a regular lattice of monodisperse particles or a mixture of monodisperse particles by using an electric field.Type: ApplicationFiled: December 22, 2005Publication date: September 25, 2008Inventors: Christopher L. Bower, David Snoswell, Brian Vincent
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Patent number: 7420331Abstract: A ceramic discharge vessel is provided wherein the vessel comprises a hollow body for enclosing a discharge and the hollow body is made of a polycrystalline dysprosium oxide containing a luminescent dopant that emits one or more visible light wavelengths when stimulated by radiation generated by the discharge. Preferably, the polycrystalline dysprosium oxide has been doped with one or more of europium, cerium, or terbium in an amount from about 0.1 to about 10 percent by weight on an oxide basis.Type: GrantFiled: June 24, 2005Date of Patent: September 2, 2008Assignee: Osram Sylvania Inc.Inventors: George C. Wei, Walter P. Lapatovich, Joanne M. Browne, Kailash C. Mishra, Madis Raukas
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Publication number: 20080193635Abstract: The invention relates to an anti-reflecting coating (20) comprising a combined inner coating (21), made of anti-reflecting silicon, and outer coating (22) made of carbon in the form of an amorphous diamond which is essentially non-porous and essentially devoid of foreign species. The invention also relates to a method for the production of an anti-reflecting coating and to the use thereof as a coating for a solar batter (10). The coating is less likely to deteriorate with time and can improve the spectral domain of efficient conversion of radiation.Type: ApplicationFiled: June 1, 2005Publication date: August 14, 2008Inventors: Vladimir Aroutiounian, Khachatur Martirosyan Avan-Arindj, Patrick Soukiassian
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Patent number: 7393618Abstract: A color conversion member composition (10) including (A) a color filter material (1), (B) a photoluminescent inorganic nanocrystal (3), (C) a medium (5), and (D) two or more solvents (5), wherein all of the solvents (D) are good solvents for one of the color filter material (A) (1) and the photoluminescent inorganic nanocrystal (B) (3), the solvents (D) include a good solvent and a poor solvent for the other of the color filter material (A) (1) and the photoluminescent inorganic nanocrystal (B) (3), and the good solvent has a vapor pressure higher than that of the poor solvent.Type: GrantFiled: December 19, 2006Date of Patent: July 1, 2008Assignee: Idemitsu Kosan Co., Ltd.Inventors: Atau Ioku, Satoshi Hachiya
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Patent number: 7378042Abstract: A material for harmonic generation has been made by substitutional changes to the crystal LaCa4 (BO3)3 also known as LaCOB in the form Re1xRe2yRe3zCa4(B03)3O where Re1 and Re2, (rare earth ion 1 and rare earth ion 2) are selected from the group consisting of Sc, Yttrium, La, Ce, Pr, Nd, Sm, Eu, Gd, Th, Dy, Ho, Er, Tm, Yb, and Lu; Re3 is Lanthanum; and x+y+z=1.Type: GrantFiled: January 10, 2007Date of Patent: May 27, 2008Assignee: Lawrence Livermore National Security, LLCInventors: Christopher A. Ebbers, Kathleen I. Schaffers
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Patent number: 7364673Abstract: The present invention discloses a widely wavelength tunable polychrome colloidal photonic crystal device whose optical Bragg diffraction stop bands and higher energy bands wavelength, width and intensity can be tuned in a continuous and fine, rapid and reversible, reproducible and predictable fashion and over a broad spectral range by a controlled expansion or contraction of the colloidal photonic lattice dimension, effected by a predetermined change in the electronic configuration of the composite material. In its preferred embodiment, the material is a composite in the form of a film or a patterned film or shape of any dimension or array of shapes of any dimension comprised of an organized array of microspheres in a matrix of a cross-linked metallopolymer network with a continuously variable redox state of charge and fluid content.Type: GrantFiled: October 9, 2003Date of Patent: April 29, 2008Assignee: The Governing Council of the University of TorontoInventors: Andre Arsenault, Hernan Miguez, Ian Manners, Geoffrey Alan Ozin
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Patent number: 7335322Abstract: A photochromic includes a laminated film including a composite oxide film composed of at least two elements selected from the group consisting of Ti, Mn, Co, Ni, Zn, and Sn, and the group consisting of Mg, Al, and Si, respectively, and a transparent conductive film, wherein the light transmission property is changed by UV irradiation.Type: GrantFiled: March 7, 2006Date of Patent: February 26, 2008Assignee: Shinoda Plasma CorporationInventors: Akira Nakazawa, Tsutae Shinoda
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Publication number: 20080008868Abstract: One embodiment of the invention provides a method including molding composite panels that are UV resistant, substantially free of fiber readout, and have visible fibers from epoxy compositions comprising resins having aromatic rings.Type: ApplicationFiled: April 16, 2007Publication date: January 10, 2008Applicant: GENERAL MOTORS CORPORATIONInventors: Richard P. Atkins, Choongyong Kwag, Chen-Shih Wang
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Patent number: 7259913Abstract: A Faraday rotator in which the isolation function based on a temperature rise is not deteriorated even when the Faraday rotator is used for a high output laser of not smaller than 1W output at a wavelength of not larger than 1.1 ?m includes sapphire crystals or rutile crystals bonded as radiation substrates to the incident side and outgoing side of a bismuth substituted type rare earth metal iron garnet crystal (RIG) film, the thickness of the RIG film being not smaller than 130 ?m and not larger than 200 ?m.Type: GrantFiled: February 6, 2006Date of Patent: August 21, 2007Assignee: Sumitomo Metal Mining Co. Ltd.Inventor: Junji Iida
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Patent number: 7260124Abstract: A material for harmonic generation has been made by substitutional changes to the crystal LaCa4(BO3)3 also known as LaCOB in the form Re1xRe2yRe3zCa4(B03)3O where Re1 and Re2, (rare earth ion 1 and rare earth ion 2) are selected from the group consisting of Sc, Yttrium, La, Ce, Pr, Nd, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb, and Lu; Re3 is Lanthanum; and x+y+z=1.Type: GrantFiled: January 10, 2007Date of Patent: August 21, 2007Assignee: The Regents of the University of CaliforniaInventors: Christopher A. Ebbers, Kathleen I. Schaffers
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Patent number: 7198738Abstract: The present invention provides a cesium-lithium-borate crystal, which can be used as a high-performance wavelength converting crystal, having a chemical composition expressed as CsLiB6O10, and substituted cesium-lithium-borate crystals expressed by the following formula: Cs1?xLi1?yMx+yB6O10 or Cs2(1?z)Li2LzB12O20 (where, M is an alkali metal element, and L is an alkali earth metal element); a method for manufacturing same by heating and melting; and an optical apparatus using such crystals.Type: GrantFiled: December 23, 2005Date of Patent: April 3, 2007Assignee: Research Development Corporation of JapanInventors: Takatomo Sasaki, Akio Hiraki, Yusuke Mori, Sadao Nakai
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Patent number: 7179405Abstract: A material for harmonic generation has been made by substitutional changes to the crystal LaCa4 (BO3)3 also known as LaCOB in the form Re1xRe2yRe3zCa4(BO3)3O where Re1 and Re2, (rare earth ion 1 and rare earth ion 2) are selected from the group consisting of Sc, Yttrium, La, Ce, Pr, Nd, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb, and Lu; Re3 is Lanthanum; and x+y+z=1.Type: GrantFiled: October 1, 2002Date of Patent: February 20, 2007Assignee: The Regents of the University of CaliforniaInventors: Christopher A. Ebbers, Kathleen I. Schaffers
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Patent number: 7163649Abstract: A composition formed from Group II fluorides in which the composition has little or no intrinsic birefringence at a selected wavelength. The composition is a mixed solid solution of CaF2 with a second crystal of SrF2 or BaF2. The resulting composition is in the form of Ca1?xSrxF2 or Ca1?xBaxF2, or a combination of SrF2 and BaF2, in the form of Ca1?x?ySrxBayF2. The specific form of the composition that effectively nulls out the intrinsic birefringence at a selected wavelength within the UV range is determined in one preferred method from the magnitudes of the intrinsic birefringences of the components, CaF2, SrF2, and BaF2.Type: GrantFiled: July 9, 2002Date of Patent: January 16, 2007Assignee: The United States of America as represented by the Secretary of CommerceInventors: John H. Burnett, Zachary H. Levine, Eric L. Shirley
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Patent number: 7157024Abstract: The present invention relates to a metal oxide particle comprising tin atom, zinc atom, antimony atom and oxygen atom, having a molar ratio SnO2:ZnO:Sb2O5 of 0.01–1.00:0.80–1.20:1.00 and having a primary particle diameter of 5 to 500 nm; and a process for producing the metal oxide particle comprising the steps of: mixing a tin compound, a zinc compound and an antimony compound in a molar ratio SnO2:ZnO:Sb2O5 of 0.01–1.00:0.80–1.20:1.00; and calcining the mixture at a temperature of 300 to 900° C. The metal oxide particle is used for several purposes such as antistatic agents, UV light absorbers, heat radiation absorbers or sensors for plastics or glass, etc.Type: GrantFiled: May 24, 2004Date of Patent: January 2, 2007Assignee: Nissan Chemical Industries, Ltd.Inventors: Tadayuki Isaji, Osamu Fujimoto
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Patent number: 7074351Abstract: The present invention provides compositions containing transparent thermoplastic polymer, surface-modified oxide particles with a particle size of less than 200 nm, and organic NIR absorbers. The compositions of the present invention may find use in reducing diathermancy in sheets, films, glazing systems and roofing systems which may be incorporated into automobiles and buildings.Type: GrantFiled: April 23, 2001Date of Patent: July 11, 2006Assignee: Leibniz-Institut fur Neue Materialien gem. GmbHInventors: Martin Döbler, Werner Hoheisel, Helmut Schmidt, Ralph Nonninger, Martin Schichtel, Martin Jost
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Patent number: 7003981Abstract: Using sol-gel techniques, an optical gain medium has been fabricated comprising a glass ceramic host material that includes clusters of crystalline oxide material, especially tin oxide, and that is doped with active ions concentrated at the clusters. The active ions are preferentially located at the nanoclusters so that they experience the relatively low phonon energy of the oxide and are insensitive to the phonon energy of the host. A host with a high phonon energy, such as silica, can therefore be used without the usual drawback of reduced carrier lifetimes through enhanced nonradiative decay rates.Type: GrantFiled: October 1, 2002Date of Patent: February 28, 2006Assignee: University of SouthhamptonInventors: Elizabeth Taylor, Gilberto Brambilla, Norberto Chiodini, Alberto Paleari, Giorgio Spinolo, Franca Morazzoni, Roberto Scotti
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Patent number: 6991753Abstract: An optically active composition (100) for optical applications has been identified. The optically active composition (100) can include at least one cyclic molecule having a nanocore (112) disposed within the cyclic molecule to form a filled ring (108). The composition (100) is optically transmissive for at least one photonic wavelength that would not otherwise be transmitted by the composition (100) if the nanocore were absent from the cyclic molecule. The cyclic molecule can be a carbon ring, an aromatic ring, or a heterocyclic ring. The filled ring (108) can be attached to a chiral molecule which is a repeat unit (102) in a polymeric backbone. A second filled ring (110) which causes the composition to be optically transmissive at a second wavelength also can be attached to the chiral molecule (102) as well. An electric field can be applied to the filled ring (108) to adjust the wavelength at which filled ring (108) is transmissive.Type: GrantFiled: January 6, 2004Date of Patent: January 31, 2006Assignee: Harris CorporationInventors: Randy T. Pike, Dennis Tebbe
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Patent number: 6966998Abstract: A method of providing covert security features for documents such as vouchers, packaged goods and banknotes in which the document is provided with a dopant. The dopant consisting of a material which can be identified by examination of its response to visible wavelength photon radiation and which can be applied directly on or into the document or can be fused into glass matrices before application.Type: GrantFiled: November 8, 1999Date of Patent: November 22, 2005Inventor: Alexander Rollo Spowart
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Patent number: 6929764Abstract: Ordered, monodisperse macroporous polymers, their corresponding ordered, monodisperse colloids, and methods of preparing them are disclosed. The methods use an ordered, monodisperse colloidal template to define the polymer pore morphology, which in turn acts as a mold for the growth of a new ordered, monodisperse colloid. The macroporous polymer may be prepared with either spherical or ellipsoidal pores from a wide variety of polymeric systems. The new ordered, monodisperse colloid may be grown from a wide variety of materials including ceramics, semiconductors, metals and polymers. These materials are potentially useful in optical, micro-filtering and drug delivery applications.Type: GrantFiled: November 19, 2001Date of Patent: August 16, 2005Assignee: William Marsh Rice UniversityInventors: Peng Jiang, Vicki L. Colvin
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Patent number: 6888663Abstract: The invention relates to an optical component comprising a dispersion of layered minute particulate materials in a binder, the layered materials having a layer thickness, a concentration of particulate in the binder, and a basal plane spacing sufficient to provide a component having a light transmissivity of at least 50%.Type: GrantFiled: October 7, 2002Date of Patent: May 3, 2005Assignee: Eastman Kodak CompanyInventors: Robert P. Bourdelais, Narasimharao Dontula, Debasis Majumdar, Cheryl J. Kaminsky
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Patent number: 6863842Abstract: An optical component formed of a material that blocks noise-causing visible and near-infrared rays selectively or as a whole while transmitting far-infrared rays to the extent possible, and a method for producing the component. The component is produced by adding at least one additive that blocks visible and near-infrared rays to a ceramic material of ZnS, ZnSe, or Ge. The component is most suitable for a particular purpose or use of an optical component, such as a window or lens to be used in a high-performance infrared apparatus, because noise-causing visible and near-infrared rays are blocked.Type: GrantFiled: November 29, 2001Date of Patent: March 8, 2005Assignee: Sumitomo Electric Industries, Ltd.Inventor: Masato Hasegawa
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Patent number: 6846681Abstract: The present invention is directed to a silicon substrate having a monolayer formed by an electrochemically-induced reaction between silicon hydride moieties on the silicon surface and optionally substituted alkynes covalently bound to the surface of the silicon substrate and to a method for electrochemically producing such a functionalized silicon substrate. The method of forming a covalently bound monolayer on a silicon surface comprises the steps of contacting the silicon surface with a C2-C24 alkyne and electrografting optionally substituted alkynes to the silicon surface.Type: GrantFiled: July 19, 2002Date of Patent: January 25, 2005Assignee: Purdue Research FoundationInventors: Jillian M. Buriak, Michael P. Stewart, Edward Robins
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Patent number: 6835368Abstract: This invention relates to the field of materials of the photorefractive crystal. The composition of these crystals is Li1−xNb1+yO3: Fem, Mn, where M can be magnesium, indium, or zinc; when using q to denote the ion valence of M (q=2 when M is Mg or Zn, and q=3 when M is In), the values of x, y, m, and n are in the range of 0.05≦x≦0.13, 0.00≦y≦0.01, 5.0×10−5≦m≦7.5×10−4, and 0.02≦qn≦0.13. This invention greatly improves the photorefractive properties of LiNbO3 crystals: makes it have a high diffraction efficiency (more than 68%), a fast response speed for photorefraction (an order of magnitude faster than iron doped LiNbO3), and a high resistance to optical scattering (the light intensity threshold to photorefractive fan scattering near two orders of magnitude larger than LiNbO3: Fe). This invention is an excellent three-dimensional optical storage material and has a vast potential market.Type: GrantFiled: June 18, 2001Date of Patent: December 28, 2004Assignee: Nankai UniversityInventors: Yongfa Kong, Jingjun Xu, Guangao Li, Qian Sun, Baiquan Tang, Hui Huang, Ziheng Huang, Shaolin Chen, Xiaojun Chen, Guangyin Zhang
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Patent number: 6783705Abstract: The invention features an optical medium for calibrating UV absorbance detectors, methods for making such an optical medium, and methods for calibrating UV absorbance detectors using such a medium. The optical calibration medium includes a gel-sol silica glass monolith with a rare-earth dopant therein. The rare-earth dopant exhibits at least one spectral feature in at least the far UV range. The constituents of the gel-sol silica glass monolith are selected so the rare-earth doped sol-gel glass monolith exhibits a transmittance in the far UV range so each distinct spectral feature of the rare-earth dopant in the far UV range is discernable. The transmittance in a particular embodiment is at least about 50% at about 250 nm. The rare earth materials selected for use as dopants are those exhibiting a wide range of spectral features, preferably over a range from about 190 nm to about 700 nm and more particularly exhibit at least one distinct spectral feature in the range from about 190 nm to about 300 nm.Type: GrantFiled: April 11, 1997Date of Patent: August 31, 2004Assignee: Waters Investments LimitedInventor: Michael J. Leveille
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Patent number: 6770223Abstract: Faraday rotator garnet thick films have improved specific Faraday rotations without requiring a bias magnet. Films of nominal composition BiX(EuZHo1-Z)3-XFe5-YGaYO12 are grown lattice matched to available {Gd2.68Ca0.32}[Ga1.04Mg0.32Zr0.64](Ga3)O12 substrates. The film is prepared with Z ≦0.45, which allows higher concentrations of Bi to be included in the film than prior compositions. The increased amount of Bi results in a higher specific Faraday rotations for the film. For devices such as non-reciprocal optoelectronic devices that require 45-degree rotators, the increased specific Faraday rotation results in the use of thinner films of reduced path length as well as increased crystal growth yields.Type: GrantFiled: December 13, 2002Date of Patent: August 3, 2004Assignee: Integrated Photonics, Inc.Inventors: Robert R. Abbott, Vincent J. Fratello, Steve J. Licht, Irina Mnushkina
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Publication number: 20040123794Abstract: There are provided a method of superflattening an oxide crystal that is soluble neither with acid nor with alkaline, a method of making a ReCa4O(BO3)3 family oxide single crystal thin film using the superflattening method, a ReCa4O(BO3)3 family oxide single crystal thin film having a SHG property, a superflattening method for light incident/emitting surfaces, and a defect assessing method for oxide crystals. The surface of an oxide crystal that is soluble neither with acid nor with alkaline is reduced with a reducing agent, the reduced oxide crystal surface is dissolved with an aqueous solution of acid or alkaline, the surface dissolved oxide crystal is heat-treated in the atmosphere, whereby the surface of an oxide crystal that is soluble neither with acid nor with alkaline is superflattened to an atomic level.Type: ApplicationFiled: September 15, 2003Publication date: July 1, 2004Inventors: Hideomi Koinuma, Yuji Matsumoto, Takatomo Sasaki, Yusuke Mori, Masashi Yoshimura
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Patent number: 6740262Abstract: A light-transmitting (fluorescent) sintered body formed of specific substances different from the prior art materials, solving problems that the performance or efficiency, uses and manufacturing methods are limited which have not been solved with the prior art light-transmitting sintered body and which provides a light-emitting tube and an electric discharge lamp using a light-transmitting (fluorescent) sintered body formed of the specific substance. Provided are a light-transmitting sintered body mainly formed of a compound having a Mugnetplumbite structure or a &bgr;-alumina structure except for aluminum oxide, a light-transmitting sintered body mainly formed of a compound containing rare earth elements with an ionic valence of two, aluminum element and oxygen element as main components and an light-transmitting sintered body formed of mainly of a compound containing elements with an ionic valence of two except for rare earth elements, rare earth elements and oxygen element as main components.Type: GrantFiled: May 8, 2001Date of Patent: May 25, 2004Assignee: Matsushita Electric Industrial Co., Ltd.Inventor: Shozo Oshio
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Patent number: 6652780Abstract: A process for oxidizing iron ions contained within iron-doped lithium niobate. The process comprises the steps of protonating the iron-doped lithium niobate crystal and then placing the same into a pressure chamber where between 10-100 atmospheres of dry, ultra-pure pressurized oxygen are applied. While under pressure, the crystal is heated to approximately 950° C. at a rate not to exceed 50° C. per minute, and preferably at a rate not less than 25° C. per minute. The resulting lithium niobate crystal will thereafter contain iron ions wherein the divalent iron ion ratio to the trivalent iron ion ratio is approximately 1:100.Type: GrantFiled: March 6, 2002Date of Patent: November 25, 2003Assignee: Northrop GrummanInventor: Harold M Stoll
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Patent number: 6620347Abstract: A crystal filter and a method of making a crystal filter capable of transmitting radiation within a particular pass band is disclosed. The crystal filter is particularly appropriate for a UV detection system, where the pass band is between about 200 to about 350 nm. A UV detection system incorporating the crystal filter is also described. One embodiment of crystal filter is formed from a single-crystal transparent host, such as a fluoride host, codoped with lanthanide or actinide fluorides and lanthanide or actinide nitrides, oxides, borides, carbides or hydroxides. Filter crystals according to the present invention can be grown by various crystal growth methods, including Czochralski and Bridgeman crystal growth methods.Type: GrantFiled: October 6, 1999Date of Patent: September 16, 2003Assignee: Coherent, Inc.Inventor: Dominic N. Lo Iacono
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Patent number: 6589450Abstract: The present invention relates to a material comprising a matrix, apatite and at least one europium composite compound of the general formula MexmMy3Rzn, wherein mx+3y=nz; Mexm=Mex′m′+Mex″m″+ . . . ; Rzn=Rz′n′+Rz″n″+ . . . ; mx=m′x′+m″x″+ . . . ; nz=n′z′+n″z″+ . . . ; x≧1.0 ≧y≧0.01. Me represents yttrium, lanthanum, cerium, praseodymium, neodymium, samarium, europium, gadolinium, dysprosium, holmium, erbium, ytterbium, aluminum, bismuth, tin, titanium, manganese, calcium, barium, zinc, cadmium, sodium, potassium, rubidium, cesium, R represents oxygen, sulfur, fluorine, bromine, phosphorus, boron, vanadium, molybdenum, tungsten, germanium or compounds thereof, and m and n represent the charge of a Me or R ion, respectively. The composition for the production of the material comprises (wt. % ) apatite 0.01-10.Type: GrantFiled: July 28, 2000Date of Patent: July 8, 2003Inventors: Ljubov Robertovna Bratkova, Robert Nikolaevich Schelokov
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Patent number: 6572786Abstract: A phosphor capable of preventing a deterioration in luminous characteristics thereof, particularly, high-temperature operation characteristics thereof due to a SiO2-containing pigment added thereto. The phosphor has a pigment contained therein, wherein the pigment has SiO2 added thereto and is melted, to thereby be coated with sodium glass. This permits gas generated during operation of the phosphor to be adsorbed on the phosphor as compared with a conventional phosphor to which the pigment subjected to the above-described treatment is not added, resulting in luminance retention of the phosphor after operation thereof being increased. In particular, it permits characteristics of the non-driven phosphor after the high-temperature operation test to be enhanced.Type: GrantFiled: April 23, 2001Date of Patent: June 3, 2003Assignee: Futuba CorporationInventors: Kuniaki Kawatsu, Toshinori Suzuki, Chiyuki Hayakawa
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Patent number: 6551528Abstract: As a wavelength conversion crystal whose double refraction index is controllable, a crystal represented by a formula (I), M1xM21−xCa4O(BL3)3, where each of M1 and M2 represents one or more types of different rare earth elements and 0<x<1, is used, and as a novel means for second harmonics generation, a nonlinear optical crystal represented by a formula (II), GdxY1−xCa4O(BO3)3, where 0.01≦x≦0.35, is used to generate second harmonics.Type: GrantFiled: November 14, 2000Date of Patent: April 22, 2003Assignee: Japan Science and Technology CorporationInventors: Takatomo Sasaki, Yusuke Mori, Masashi Yoshimura
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Publication number: 20030030039Abstract: The present invention provides a cesium-lithium-borate crystal, which can be used as a high-performance wavelength converting crystal, having a chemical composition expressed as CsLiB6O10, and substituted cesium-lithium-borate crystals expressed by the following formula:Type: ApplicationFiled: August 15, 2002Publication date: February 13, 2003Inventors: Takatomo Sasaki, Akio Hiraki, Yusuke Mori, Sadao Nakai
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Patent number: 6514435Abstract: High density, photon-gated persistent spectral holeburning is effectuated in rare earth doped II-VI compounds such as MgS, CaS, BaS and SrS. Two-photon ionization of rare earth ions is performed, selected by a narrow band laser, producing narrow regions of reduced absorption (optical holes) in the absorption spectrum of a rare earth ion. These holes are useful for such applications as high density memory (especially, high density re-writable or photo-erasable memory), spectral holographic memory, communication, etc., and demonstrate great survivability over reading cycles, thermal cycles and elevated temperatures. The embedment of the rare earth doped II-VI compound in a matrix comprising a polymeric material (such as PMMA), prior to the effectuation of the holeburning, may be advantageous for many embodiments. Inventive practice has successfully burned two hundred forty photon gated spectral holes in the zero phonon line (ZPL) of the 4f-5d transition of Eu2+ in a magnesium sulfide host.Type: GrantFiled: March 2, 2000Date of Patent: February 4, 2003Assignee: The United States of America as represented by the Secretary of the NavyInventors: Zameer Ul Hasan, Veerendra Kumar Mathur
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Patent number: 6508960Abstract: A solid state laser device made from a nonlinear optic quaternary alloy of Silver, Gallium, Selenium and Tellurium semiconductor material or Silver, Gallium, Sulfur and Tellurium semiconductor material. The Tellurium component in each alloy provides quaternary alloying anion modification of an underlying ternary semiconductor crystal and achieves tuning of the birefringence and tuning of the wavelength passband of the semiconductor material. The tuned quaternary alloy enables beam walkoff-free noncritical phase match operation of the laser device including use of a phase match angle supporting optimum use of the material's nonlinear properties, maximized useful length of the material crystal, room temperature wavelength changing operation, significantly increased second order nonlinear susceptibility, a factor of ten reduction in the walk-off angle and photon energy conversion efficiencies several times those usually achieved.Type: GrantFiled: July 26, 1999Date of Patent: January 21, 2003Assignee: The United States of America as represented by the Secretary of the Air ForceInventors: Melvin C. Ohmer, David E. Zelmon, Jonathan T. Goldstein
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Patent number: 6500364Abstract: In one embodiment of the present invention, the material is a non-linear optical compound with a general chemical formula (&Sgr;iM&agr;i1)(&Sgr;jM&bgr;j2)(&Sgr;kM&ggr;k3)Be2O5 Formula 1 wherein M1, M2, and M3 are mono-, di-, or tri-valent metal ions respectively; wherein (&Sgr;i&bgr;i)=X and ranges from 0 to 6, (&Sgr;j&bgr;j)=Y and ranges from 0 to 3, and (&Sgr;k&ggr;k)=Z and ranges from 0 to 2, (hereinafter referred to as “MBE2O5” compounds).Type: GrantFiled: March 12, 2001Date of Patent: December 31, 2002Assignee: ReyTech CorporationInventors: Thomas A. Reynolds, Theodore Alekel, Douglas A. Keszler
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Patent number: 6497830Abstract: An ultraviolet light absorber containing, as an active ingredient, a zinc oxide type solid solution which is represented by the formula (1), (Zn)1−xM3+x−&dgr;O (1) wherein M3+ is a trivalent metal such as Al, Fe, Ce or Ti, x is a number in the range of 0<x<=0.2, and &dgr; is a cationic lattice defect, and has an average secondary particle diameter of from 0.1 to 1.5 &mgr;m in a plate form and a BET specific surface area of at least 5 m2/g, an ultraviolet light resistant resin composition containing a resin and the above zinc oxide type solid solution and a sun block cosmetic material containing the above zinc oxide type solid solution.Type: GrantFiled: March 14, 2001Date of Patent: December 24, 2002Assignee: Kabushiki Kaisha Kaisui Kagaku KenkyujoInventor: Shigeo Miyata