Including Subsequent Reshaping (e.g., Stretching, Etc.) Patents (Class 264/173.15)
  • Patent number: 7678316
    Abstract: A method that includes coextruding two or more thermoplastic resin streams through a profiled die plate, which die plate is shaped to form a nonplanar film (three dimensional) preferably with a regularly oscillating peak and valley structure that oscillates from a top surface to a bottom surface forming longitudinally extending ridges on both faces of the film. The film is formed by coextruding the film through the oscillating die plate opening causing partitioning of the resins in different zones in the width direction of the film. Flattening of the film results in a film with side-by-side zones formed of different polymers or relative proportions of polymers.
    Type: Grant
    Filed: June 8, 2004
    Date of Patent: March 16, 2010
    Assignee: 3M Innovative Properties Company
    Inventors: Ronald W. Ausen, Janet A. Venne, Jayshree Seth
  • Publication number: 20100055429
    Abstract: A monoaxially oriented film including heat sealable layer including an ethylene-propylene impact copolymer and a metallocene-catalyzed propylene-butene elastomer. The heat sealable layer may include a metallocene-catalyzed ethylene-butene elastomer. The film is oriented at least 4 times in the machine direction and exhibits excellent linear directional tear properties in the machine direction and excellent heat seal performance. This film formulation and orientation is suitable for pouch applications requiring an “easy-tear” linear tear feature and excellent hermetic seal properties, particularly for retort pouches.
    Type: Application
    Filed: August 17, 2009
    Publication date: March 4, 2010
    Applicant: TORAY PLASTICS (AMERICA), INC.
    Inventors: Mark S. Lee, Harold E. Koehn, Emilio Coletta, Matthew H. Brown
  • Publication number: 20100026987
    Abstract: A primary object of the present invention is to provide a multilayer heat-shrinkable styrene-based film that makes it possible, even when the film is transparent, to confirm that the film is correctly applied on a drink bottle and the like as a label. The present invention provides a heat-shrinkable styrene-based film having at least one layer containing a styrene-based resin containing a copolymer b1 of 98 to 40% by weight vinyl aromatic hydrocarbon and 2 to 60% by weight aliphatic unsaturated carboxylic acid ester, and/or a block copolymer b2 of 70 to 85% by weight vinyl aromatic hydrocarbon and 15 to 30% by weight conjugated diene hydrocarbon, and a fluorescent brightening agent in an amount of 100 to 2,000 weight ppm with respect to the total weight of the styrene-based resin. The present invention also provides a heat-shrinkable film having a three-layer structure containing front and back layers and a core layer, wherein the above-mentioned copolymer b1 and/or copolymer b2 forms the core layer.
    Type: Application
    Filed: November 30, 2007
    Publication date: February 4, 2010
    Applicant: Gunze Limited
    Inventors: Masaharu Maruo, Akira Morikawa, Naoki Ohno, Tadayoshi Tanaka
  • Patent number: 7655291
    Abstract: A co-extruded film including talc and a method for preparing the film includes a polyester resin containing talc. The films may be single layer films or multi-layered structures such as ABA or AB structured films. Multi-layered films have talc in at least the A layer of the multi-layered film. If talc is present in the B layer, the A layer preferably includes a greater percentage of talc relative to the percentage of talc present in said B layer. The method uses readily available, low cost talc as an additive to achieve a co-extruded polyester film having simultaneously reduced transparency and reduced gloss to provide a translucent polyester film.
    Type: Grant
    Filed: October 14, 2003
    Date of Patent: February 2, 2010
    Assignee: Toray Plastics (America), Inc.
    Inventor: Yijun Ye
  • Publication number: 20090297820
    Abstract: A film, for use in a label and a related method, including a print skin layer, a base layer, and an adhesive skin layer having at least one heat-activated thermoplastic polymer. The film is stretched biaxially in both a machine direction and a transverse direction. The stretch ratio in a first direction is greater than 2:1 to 10:1, the stretch ratio in a second direction ranges in value from 1.02:1 to 1.8:1, the film has an ASTM D1204 shrinkage at 100° C. of at least 0.5% in both the machine and transverse directions, and the film has an ASTM D882 2% secant modulus of at least 679,134 kPa (98,500 psi) in the first direction.
    Type: Application
    Filed: May 28, 2009
    Publication date: December 3, 2009
    Applicant: AVERY DENNISON CORPORATION
    Inventors: John E. KOVALCHUK, Moris AMON
  • Publication number: 20090255624
    Abstract: The present invention relates generally to the packaging materials. More specifically, the invention relates to materials and methods suitable for use as packaging materials whereby the appearance of grease, fat or oil staining on the packaging material is reduced or eliminated.
    Type: Application
    Filed: March 23, 2009
    Publication date: October 15, 2009
    Inventor: RICHARD J. GOULD
  • Publication number: 20090253032
    Abstract: A multi-layer, microporous polyolefin membrane comprising first microporous layers constituting at least both surface layers and at least one second microporous layer disposed between both surface layers; said first microporous layer being made of a first polyolefin comprising (i) polypropylene, or (ii) a mixture of 50% or more by mass of polypropylene and a polyethylene resin; said second microporous layer being made of a second polyolefin comprising (i) a mixture of 7% or less by mass of ultra-high-molecular-weight polyethylene having weight-average molecular weight of 1×106 or more and the other polyethylene than said ultra-high-molecular-weight polyethylene, (ii) the other polyethylene than said ultra-high-molecular-weight polyethylene, or (iii) a mixture of 50% or less by mass of polypropylene and said mixture (i) or said polyethylene (ii); said second microporous layer having a larger average pore diameter than that of said first microporous layer; and the total thickness of said first microporous layer
    Type: Application
    Filed: April 9, 2007
    Publication date: October 8, 2009
    Applicant: TONEN CHEMICAL CORPORATION
    Inventors: Kotaro Takita, Shintaro Kikuchi
  • Publication number: 20090252902
    Abstract: A heat sealable, multi-layer film structure for multi-color printing or lamination processes and method for making the same are provided. The multi-layer film structure may include a core layer comprising a thermoplastic polymer and essentially no migratory slip agents; a functional layer on a first side of the core layer, wherein the functional layer is a printable layer or a laminatable layer; and a heat sealable skin layer on a second side of the core layer, the heat sealable skin layer comprising a thermoplastic polymer and a slip system. The multi-layer film structure is prepared without any migratory slip additives. Without migratory slip additives, the multi-layer film structure exhibits excellent machinability on typical packaging equipment.
    Type: Application
    Filed: April 8, 2008
    Publication date: October 8, 2009
    Inventors: Eric W. Bender, George F. Cretekos
  • Patent number: 7563399
    Abstract: The invention relates to a method for manufacturing a multilayer biaxially oriented film which comprises at least five layers having the arrangement A/B/C/B/A, the inner layer C being synthesized from an ethylene-vinyl-alcohol copolymer (EVOH layer) and an adhesion promoting layer B made of modified polyolefin being applied on both sides on each surface of the EVOH layer C and a layer A made of a partially crystalline thermoplastic polyolefin being applied to the surfaces of the particular adhesion promoting layers, characterized in that the melts corresponding to the individual layers of the film are coextruded through a sheet die, the multilayer film thus obtained is drawn off on one or more roll(s) for solidification, the film is subsequently stretched in the longitudinal direction and then in the transverse direction using a tenter frame, the EVOH layer C and the adhesion promoting layers B and the layer A are coextruded at the same width, and the tenter hooks of the frame engage all five layers jointly a
    Type: Grant
    Filed: November 28, 2003
    Date of Patent: July 21, 2009
    Assignee: Treofan Germany GmbH & Co. KG
    Inventors: Detlef Busch, Christian Peters, Joachim Jung
  • Patent number: 7550102
    Abstract: A method of making a composite tubular article made up of at least two concentric members, the outer of said members being tubular and the inner of said members being at least cylindrical and preferably tubular, and struts disposed in supporting and positioning orientation between the inner and outer members, by extruding a moldable material into the desired profile; stretching the inner tubular member over a cooling mandrel and disposing a cooling sleeve over the outer tubular member under conditions sufficient to solidify the article; twisting and longitudinally pulling the solidified article, so that it rotates over the cooling mandrel and inside the cooling sleeve while it is moving down stream across the cooling mandrel, whereby causing the extrudate to be twisted into a helical shape.
    Type: Grant
    Filed: August 1, 2002
    Date of Patent: June 23, 2009
    Assignee: Proteus, Inc.
    Inventor: F. John Herrington
  • Patent number: 7524447
    Abstract: One method for making a laminate material comprising a first surface layer comprising resorcinol arylate polyester chain members and a second surface layer suitable for bonding to a substrate, comprises co-extruding a polymeric first surface layer material and a polymeric second surface layer material through a die and into the first nip of a calender roll stack comprising a first surface roll and a second surface roll that define the first nip, to form the laminate material. A nip load in the first nip of greater than or equal to about 400 N/cm can be applied to the laminate, and the laminate material can be collected from the roll stack. The first roll and the second roll can each have a surface smoothness of less than or equal to about 5 micrometers and temperatures of about 40° C. to about 150° C.
    Type: Grant
    Filed: July 20, 2004
    Date of Patent: April 28, 2009
    Assignee: Sabic Innovative Plastics IP B.V.
    Inventors: Himanshu Asthana, M. Shoen Davis, Hari K. Harikumar, Martin J. Lindway, Aniruddha Moitra, Chetan J. Parikh, Om Prakash, Michael T. Roland, Robert A. Schiff, Robert W. Walker, Georgios S. Zafiris
  • Patent number: 7479322
    Abstract: A radiation-curable composite layered sheet or film comprising at least one substrate layer and one outer layer, said outer layer being composed of a radiation-curable composition having a glass transition temperature of more than 40° C.
    Type: Grant
    Filed: March 26, 2007
    Date of Patent: January 20, 2009
    Assignees: BASF Aktiengesellschaft, DaimlerChrysler AG
    Inventors: Rainer Koeniger, Erich Beck, Achim Grefenstein, Reinhold Schwalm, Margit Veeh, Claudia Vogel, Walter Aichholzer, Thomas Gruber, Karl Holdik
  • Publication number: 20080274293
    Abstract: A spiral wound fiber that includes birefringent interfaces is useful in different optical devices. One type of wound fiber includes at least first and second material layers. At least one of the layers is polymeric and at least one of the layers is birefringent. The spiral wound fiber may be used alone, or in an optical device. Such an optical device can include the fiber embedded within a matrix or attached to a substrate. The spiral wound fiber can be made by rolling a stack of at least two layers, by coextruding the two layers or by coating a rotating form.
    Type: Application
    Filed: March 31, 2006
    Publication date: November 6, 2008
    Inventors: Shandon D. Hart, William J. Kopecky, Patrick R. Fleming, Kristin L. Thunhorst
  • Patent number: 7405008
    Abstract: The present invention includes a laminate and formation of a laminate having at least one layer of an ionomer and at least one layer of an acid polymer or blend of acid polymer and a thermoplastic polyolefin that can be thermoformed to form a shaped laminate. The shaped laminate can then be contacted with a plastic substrate such as a thermoplastic polyolefin to form a composite article by such means as, for example, injection molding. The laminate can be pigmented to eliminate the need to paint the surface of the plastic substrate. Impact and scratch resistant articles can be formed from the laminated substrate such as automotive parts, appliance body parts and sporting equipment.
    Type: Grant
    Filed: May 31, 2005
    Date of Patent: July 29, 2008
    Assignee: ExxonMobil Chemical Patents Inc.
    Inventors: Joseph D. Domine, Jeffrey Valentage, Prasadarao Meka
  • Publication number: 20080138598
    Abstract: The present disclosure provides an apparatus and methods for producing co-extruded composite webs including a continuous layer of an extruded matrix material, and a multiplicity of included phases embedded in the continuous layer. The included phases are surrounded by the matrix material to form a single-layer composite web within a feed block having an internal die body. The included phases are separate from each other by being discontinuous in the cross-web direction, but the included phases may be substantially continuous in the down-web direction. In some exemplary embodiments, the co-extruded single-layer composite web may be used in a single-layer or multi-layer article. In other exemplary embodiments, the single-layer co-extruded composite web may be in the form of a sheet, a film, a blown film, a filament, a fiber, a tube, and the like.
    Type: Application
    Filed: December 8, 2006
    Publication date: June 12, 2008
    Inventors: Matthew J. Michel, Jay M. Jennen, Laurence E. Schwanz, David L. Vall
  • Publication number: 20080124563
    Abstract: A heat shrinkable multi-layer film including an intermediate layer containing polypropylene, and outer layers formed on both sides of the intermediate layer, wherein the outer layers contain a styrene-butadiene-styrene block copolymer, polypropylene, and a styrene-ethylene-propylene-styrene block copolymer or styrene-ethylene-butylene-styrene block copolymer.
    Type: Application
    Filed: November 26, 2007
    Publication date: May 29, 2008
    Applicant: C.I. KASEI COMPANY, LIMITED
    Inventor: NORIYUKI SHIMA
  • Patent number: 7378145
    Abstract: The present invention relates to a transparent, hot-embossable, biaxially oriented polyester film having a base layer (B), an amorphous outer layer (A) with a coating on this outer layer (A), and a crystalline outer layer (c). The invention further relates to the use of such film and to a process for its production.
    Type: Grant
    Filed: October 19, 2007
    Date of Patent: May 27, 2008
    Assignee: Mitsubishi Polyester Film GmbH
    Inventors: Matthias Konrad, Bodo Kuhmann, Gottfried Hilkert
  • Patent number: 7335424
    Abstract: A co-extruded laminate of at least one layer of an ionomer and at least one layer of an acid polymer that can be thermoformed with a plastic substrate such as a polyolefin. The laminate can be pigmented to eliminate the need to paint the surface of the plastic substrate. Articles can be formed from the laminated substrate such as automotive parts and sporting equipment.
    Type: Grant
    Filed: May 31, 2005
    Date of Patent: February 26, 2008
    Assignee: ExxonMobil Chemical Patents Inc.
    Inventors: Joseph D. Domine, Jeffrey Valentage, Prasadarao Meka
  • Patent number: 7320773
    Abstract: A biodegradable laminate sheet having as its object to provide a formed body superior in heat resistance, shock resistance, transparency and formability, and having non-stretched polylactic acid-family resin layer of which the crystallinity is 20% or less, and a layer comprising a biodegradable resin other than a polylactic acid-family resin.
    Type: Grant
    Filed: July 10, 2003
    Date of Patent: January 22, 2008
    Assignee: Mitsubishi Plastics, Inc.
    Inventor: Yosuke Egawa
  • Patent number: 7318961
    Abstract: The invention is directed to monoaxially drawn polyolefin multilayer film, tape or yarn of the AB or ABA type, having a stretch ratio of more than 12, having an E-modulus of at least 10 GPa, substantially consisting of a central layer (B) of a polyolefin selected from polyethylene and polypropylene, and one or two other layers (A) of a polyole fin from the same class as the material of the central layer B, the DSC melting point of the material of the said other layers (A) being lower than the DSC melting point of the material of the said central layer (B), wherein the central layer (B) is between 50 and 99 wt. % of the material and the other layers (A) between 1 and 50 wt. %. The present invention further relates to a method of manufacturing such a tape, film or yarn.
    Type: Grant
    Filed: July 19, 2002
    Date of Patent: January 15, 2008
    Assignee: Lankhorst Indutech B.V.
    Inventors: Joachim Loos, Johannes Antonius Joseph Jacobs, Antonius Andreas Johannes Maria Peijs, Tilo Schimanski
  • Publication number: 20070237972
    Abstract: The invention relates to a multilayer polyester film comprising a hydrolysis stabilizer, wherein the hydrolysis stabilizer is an epoxidized alkyl ester of fatty acid or is a mixture of epoxidized alkyl esters of fatty acid or is an epoxidized fatty acid glyceride or is a mixture of epoxidized fatty acid glycerides, and at least one external layer of the film does not comprise the hydrolysis stabilizer. The form in which the hydrolysis stabilizer is added to the polyester can be that of dry liquid, absorbed by a carrier material.
    Type: Application
    Filed: March 30, 2007
    Publication date: October 11, 2007
    Inventors: Holger KLIESCH, Martin Jesberger, Bodo Kuhmann, Ingo Fischer, Dagmar Klein
  • Patent number: 7264884
    Abstract: A stretch film presenting controlled permeability to gases, manufactured by process of balloon co-extrusion and consisting of outer layers (S2) of stretchable polmeric material and by one or two inner barrier layers (S3) of a EVOH based polymeric matrix, which is made stretchable by the addition of a suitable plasticizer in such a percentage as to conciliate the stretchablity with the desired barrier effect, said layers of different material being reciprocally secured by means of layers (S4) of adhesive material. The polymeric matrix which forms the barrier material and the plasticizer are intimately mixed inside a double-screw corotating extruder, immediately before the phase of co-extrusion, through a premelting of the polymeric matrix and the subsequent injection of the plasticizer in liquid phase.
    Type: Grant
    Filed: December 21, 2001
    Date of Patent: September 4, 2007
    Assignee: A.W.A.X. Progettazione e Ricerca
    Inventors: Renato Rimondi, Angelo Cappi, Carlo Nicoletti
  • Patent number: 7238411
    Abstract: The present invention is a multilayer polyester film comprising a layer A and a layer B which are laminated alternately, the layer A constituting the outermost layer on both sides of the film, wherein (1) the layer A comprises a polyester A, and the layer B comprises a polyester B, (2) the melting point of the polyester A is higher than the melting point of the polyester B by at least 15° C., (3) the layer A is a layer having an oriented structure, and the layer B is a layer having a substantially unoriented structure, (4) the ratio (a/b) of the total thickness (a) of the layer A to the total thickness (b) of the layer B is 0.01 to 3, and (5) the in-plane tensile strength of the multilayer polyester film is 50 MPa or lower at a maximum, and the difference between its maximum value and minimum value is 20 MPa or smaller; and a method for producing the multilayer polyester film.
    Type: Grant
    Filed: February 10, 2003
    Date of Patent: July 3, 2007
    Assignee: Teijin Limited
    Inventors: Tetsuo Yoshida, Tetsuo Ichihashi
  • Patent number: 7179521
    Abstract: A multilayer shrink film and methods of making same comprising high speed polyethylenic outer layers along with one or more cyclic-olefin copolymer (COC) containing inner layers. The multilayer shrink films of the invention are produced using film biaxial orienting means, have haze values of 5 or less and Young's modulus of 50,000 psi or greater and superior hot slip properties. In order to achieve the desired modulus, films of the present invention comprise from 10% to 30% COC and from 2% to 25% softening olefin copolymer. Preferably the film comprises large proportion of linear low density polyethylene (LLDPE). Suitable COCs for use in the invention are limited to single site catalyzed COC.
    Type: Grant
    Filed: March 3, 2004
    Date of Patent: February 20, 2007
    Assignee: Central Products Company
    Inventors: Trevor Arthurs, Shane Taghavi
  • Patent number: 7128861
    Abstract: In a method for producing hollow fiber membranes which comprises melt kneading a mixture comprising polyvinylidene fluoride and an organic liquid or a mixture comprising polyvinylidene fluoride, an organic liquid and an inorganic fine powder, extruding the kneaded mixture to form hollow fibers, and extracting the organic liquid or the organic liquid and the inorganic fine powder from the hollow fibers, which includes the steps of drawing the hollow fibers before or after termination of the extraction and then shrinking the fibers. According to this method, it is possible to stably produce hollow fiber membranes having dense pores and having a high water permeation performance, excellent endurance and stain resistance, and which are suitable for filtration uses such as removal of turbidity of water.
    Type: Grant
    Filed: March 5, 2002
    Date of Patent: October 31, 2006
    Assignee: Asahi Kasei Chemicals Corporation
    Inventors: Katsuhiko Hamanaka, Tetsuo Shimizu
  • Patent number: 7041243
    Abstract: The invention discloses a 5-layer co-extruded biaxial-oriented polypropylene synthetic paper which is a 5-layer laminated structure with thickness between 30–300 ?m comprising the uppermost layer (A) of paper sheet or resin, the second layer (B) of paper sheet or resin, the intermediate foamed layer (C), the forth layer (D) of paper sheet or resin and the bottom layer (E) of paper sheet or resin which is to improve the rigidity and stiffness covering power, strength between layers, glossiness of paper surface, paper thickness and the printability of the conventional synthetic paper.
    Type: Grant
    Filed: November 28, 2003
    Date of Patent: May 9, 2006
    Assignee: Nan Ya Plastics Corp.
    Inventor: Allen Fong-Chin Lin
  • Patent number: 6991758
    Abstract: A method and a device for production of a web with good breathing properties, for example having a nonwoven web based on plastic filaments and/or plastic fibers and a plastic film, applied on one side of the nonwoven web and containing at least one mineral filler. For the production of the good breathing properties, the web is stretched in the longitudinal direction of the same, in two successive steps, and an embossing is carried out, at least in certain sectors of the surface, between the two steps which effect the stretching in the longitudinal direction.
    Type: Grant
    Filed: September 5, 2002
    Date of Patent: January 31, 2006
    Assignee: Reifenhauser GmbH & Co. Maschinenfabrik
    Inventors: Klemens Krumm, Klaus Reifenhauser
  • Patent number: 6969556
    Abstract: There is described a substantially planar, self supporting, sheet or film (optionally oriented) which comprises at least one layer comprising a first material which is very highly crystalline polymer (preferably polypropylene of 99% or greater isotacity) together with at least one second material in an amount sufficient to improve one or more of the barrier properties, mechanical properties and/or optical properties of the sheet. The second material comprises a (a) nucleating agent; (b) a polymeric material having a ring and ball softening point from about 110° C. to about 170° C. and/or (c) a hydrogenated resin such as dicyclopentadiene hydrogenated resin, a hydrogenated mixed monomer resin; and/or a resin obtainable from a mixture of a-methyl styrene, indene and/or vinyl toluene monomers. Processes for making such films and compositions for use in the process are also described. Such films are useful in shrink wrap applications for example wrapping tobacco products.
    Type: Grant
    Filed: October 17, 2001
    Date of Patent: November 29, 2005
    Assignee: UCB, S.A.
    Inventor: Michael Jeschke
  • Patent number: 6949296
    Abstract: The substrates of the present invention comprise a polyimide base polymer derived at least in part from non-rigid rod monomers together with optionally rigid rod monomers where the substrates are cured under low tension. The resulting polyimide materials have been found to provide advantageous properties (e.g. balanced molecular orientation, good dimensional stability, and flatness) particularly useful for electronics type applications.
    Type: Grant
    Filed: April 4, 2003
    Date of Patent: September 27, 2005
    Assignee: E. I. du Pont de Nemours and Company
    Inventors: Meredith L. Dunbar, James R. Edman
  • Patent number: 6946192
    Abstract: The application discloses a transparent, biaxially oriented polyester film having a base layer at least 80% by weight of which is composed of a thermoplastic polyester, and having at least one outer layer, wherein the outer layer is composed of a polymer, or of a mixture of polymers, which comprises at least 40% by weight of ethylene 2,6-naphthalate units and up to 40% by weight of ethylene terephthalate units and/or units from cycloaliphatic or aromatic diols and/or dicarboxylic acids, with the proviso that the Tg2 value of the polyester film is above the Tg2 value of the base layer but below the Tg2 value of the outer layer, and at least one film surface has a surface tension of from 35 to 65 mN/m and/or has been provided with a functional coating of thickness from 5 to 100 nm. The film has low atmospheric oxygen transmission. It is particularly suitable for packaging uses, specifically for packaging foods and other consumable items, and for laminating, metallizing and printing.
    Type: Grant
    Filed: August 12, 2003
    Date of Patent: September 20, 2005
    Assignee: Mitsubishi Polyester Film GmbH
    Inventors: Herbert Peiffer, Cynthia Bennett, Guenther Crass, Gottfried Hilkert, Werner Roth
  • Patent number: 6893730
    Abstract: Oxygen barrier films having a greatly improved dynamic coefficient of friction, and specifically, oxygen barrier films having an exceptionally low dynamic coefficient of friction, reduced moisture sensitivity and good oxygen barrier properties over a wide range of relative humidities. The low coefficient of friction is obtained by using film layers which are blends of a polyamide component and a high density polyethylene which surround an oxygen barrier layer, such as an ethylene vinyl alcohol layer.
    Type: Grant
    Filed: September 24, 2002
    Date of Patent: May 17, 2005
    Assignee: Honeywell International Inc.
    Inventors: Jeffrey D. Moulton, Simon J. Porter
  • Patent number: 6890884
    Abstract: Disclosed is a thermal dye-transfer dye-image receiving element comprising a thermal dye-transfer receiver element comprising a dye-receiving layer 1; beneath layer 1, a microvoided layer 2 containing a continuous phase polyester matrix having dispersed therein a mixture of crosslinked organic microbeads and non-crosslinked polymer particles that are immiscible with the polyester matrix; beneath layer 2, a substrate layer 3 comprised of a voided or non-voided polyester material; and beneath layer 3, a composite support 4. The invention provides a receiver exhibiting an improved combination of dye-transfer efficiency and robustness.
    Type: Grant
    Filed: February 26, 2003
    Date of Patent: May 10, 2005
    Assignee: Eastman Kodak Company
    Inventors: Thomas M. Laney, Teh-Ming Kung
  • Patent number: 6824864
    Abstract: The present invention relates to bioriented polyethylene films having high water vapor transmission rates (WVTR) and methods for preparing the same. The film comprises a base layer and skin layers. The base layer comprises highly cavitated polyethylene, such as medium density polyethylene (MDPE) or high density polyethylene (HDPE). The cavitating agent in the base layer may be calcium carbonate. At least one skin layer comprises (i) a copolymer of ethylene and at least one other monomer and (ii) a hydrocarbon resin, such as a cyclopentadiene resin. This copolymer (i) may be an ethylene-propylene copolymer or an ethylene-propylene-butene-1 terpolymer. The film may have unidirectional tear properties in the machine direction. This film is particularly useful for packaging food products, such as pieces of candy.
    Type: Grant
    Filed: October 23, 2001
    Date of Patent: November 30, 2004
    Assignee: ExxonMobil Oil Corporation
    Inventor: Michael John Bader
  • Patent number: 6824878
    Abstract: A thermoplastic film comprising a core layer comprising a polyolefin wherein the core layer comprises the interior of the film; a first transition layer comprising a polyolefin and a silicone additive, wherein the first transition layer is exterior to the core layer; and a first skin layer comprising a polyolefin wherein the first skin layer is exterior to the first transition layer and the core layer.
    Type: Grant
    Filed: June 12, 2001
    Date of Patent: November 30, 2004
    Assignee: ExxonMobil Oil Corporation
    Inventors: Robert A. Migliorini, Karen A. Sheppard
  • Patent number: 6814913
    Abstract: A tray-type package is disclosed which includes a polyester support member, a product contained on the support member, and a lidding film containing the product and sealed to the periphery of the support member, the lidding film including a sealant layer of a polyester copolymer having greater than about 50% by mole of glycol polymerization units. Preferably, the support member is a foamed or nonfoamed polyethylene terephthalate (PET) tray and the lidding film is a multilayer film which includes a glycol-modified PET sealant layer. Also disclosed is a lidding film having a sealant layer of a blend of a glycol-modified PET and at least one further polymeric component.
    Type: Grant
    Filed: November 14, 2002
    Date of Patent: November 9, 2004
    Assignee: Cryovac, Inc.
    Inventor: Walter B. Mueller
  • Patent number: 6811638
    Abstract: The present invention provides a process for heat treatment of non-woven composite elastic material including a non-woven elastic layer; a non-woven gatherable layer. The process includes stretching the material, heating the material and cooling the material. The material has a softer more cloth-like feel.
    Type: Grant
    Filed: December 28, 2001
    Date of Patent: November 2, 2004
    Assignee: Kimberly-Clark Worldwide, Inc.
    Inventors: Kenneth B. Close, David J. Baer, Charles A. Smith, Stephen Primm, Walter A. Mattingly, Scott R. Lange
  • Patent number: 6797458
    Abstract: This invention relates to a poly(ethylene terephthalate)-based photographic multilayer film base having improved properties with regard to cutting and finishing operations compared to conventional PET film base. A specified amount of monomeric units derived from 1,4-cyclohexanedimethanol (CHDM) is used in at least two layers of the multilayer structure, such that the multilayer film base has a specified cutting related property.
    Type: Grant
    Filed: December 20, 2002
    Date of Patent: September 28, 2004
    Assignee: Eastman Kodak Company
    Inventors: YuanQiao Rao, Jehuda Greener, Yeh-Hung Lai, Dennis J. Massa
  • Patent number: 6794050
    Abstract: Transparent, biaxially oriented polyester films having a base layer composed of at least 5% by weight of a thermoplastic polyester and from 10 to 95% by weight of a cycloolefin copolymer having a glass transition temperature of less than 120° C., possess very good water vapor barrier properties and low haze at the same time. These films are especially suitable for packaging foods and other consumables.
    Type: Grant
    Filed: May 20, 2003
    Date of Patent: September 21, 2004
    Assignee: Mitsubishi Polyester Film GmbH
    Inventors: Herbert Peiffer, Gottfried Hilkert
  • Patent number: 6790405
    Abstract: An embossed, cast polyolefin film or an embossed, oriented polyolefin film includes: (a) a core layer including a propylene polymer; (b) an embossed outer layer on one side of the core layer, the embossed outer layer including an olefin polymer capable of being embossed; and (c) an additional outer layer on a side of the core layer opposite to the embossed outer layer, the additional outer layer including an olefin polymer. The embossed film can then be metallized to produce a shiny, metallic film having a prismatic or holographic appearance.
    Type: Grant
    Filed: December 5, 2001
    Date of Patent: September 14, 2004
    Assignee: ExxonMobil Oil Corporation
    Inventors: Robert Andrew Migliorini, Christopher Nothnagle, Salvatore James Pellingra, Jr.
  • Publication number: 20040173944
    Abstract: Methods of making multilayer structures useful for packaging bone-in meat or other like products are provided. More specifically, the multilayer structures made by the methods provided have sufficient rigidity and strength to contain bone-in meat or other like products, while also maintaining good oxygen barrier properties. In addition, the multilayer structures made by the methods provided can easily seal to themselves or to other structures to provide the packages for the products. Moreover, the multilayer structures made by the methods provided may be biaxially oriented and heat-shrinkable.
    Type: Application
    Filed: December 12, 2003
    Publication date: September 9, 2004
    Inventors: Chad D. Mueller, Michael J. Douglas, Duane H. Buelow, Robert J. Blemberg, Roberto P. Castellani
  • Patent number: 6787218
    Abstract: The invention relates to a transparent, biaxially oriented polyester film with a base layer B, at least 80% by weight of which is composed of a thermoplastic polyester, and with at least one outer layer A. The outer layer A is composed of a copolymer or a mixture of polymers/copolymers which contains ethylene 2,6-naphthalate units in a range of from 90 to 98% by weight and up to 10% by weight of ethylene terephthalate units, and/or units derived from cycloaliphatic or aromatic diols and/or dicarboxylic acids. Its thickness is more than 0.7 &mgr;m and makes up less than 25% by weight of the total film and the Tg2 value of the polyester film is above the Tg2 value of the base layer, but below the Tg2 value of the polyester for the outer layer. The transparent film has low permeability to atmospheric oxygen and exhibits very good adhesion between the individual layers. It is particularly suitable for packaging purposes, specifically for packaging foods or other consumable items.
    Type: Grant
    Filed: July 20, 2001
    Date of Patent: September 7, 2004
    Assignee: Mitsubishi Polyester Film GmbH
    Inventors: Herbert Peiffer, Gottfried Hilkert, Richard Lee Davis
  • Patent number: 6787217
    Abstract: A thermoplastic film label composite that includes an outer skin layer that has a printable, untreated, cavitated surface which may be utilized for printing and affixing the label to a substrate. The invention further provides a film label composite printed on both its front- and back-side, and a method of manufacturing the same.
    Type: Grant
    Filed: October 29, 2002
    Date of Patent: September 7, 2004
    Assignee: ExxonMobil Oil Corporation
    Inventors: Jo Ann H. Squier, Robert Wayne Osgood, Jr., Karen B. Perez, David Randall Williams
  • Publication number: 20040164444
    Abstract: This invention relates to a process for making an image-recording element, for example a dye-receiving element for thermal dye transfer, that includes a support having on one side thereof a image-receiving layer and, between the image-receiving layer and the support, a tie layer comprising a thermoplastic antistat polymer. In one embodiment, the process comprises (a) forming a first melt of a polymer for the surface layer and a second melt comprising a thermoplastic antistat polymer in a polymeric binder; (b) coextruding the two melts onto a polyolefin support; (c) stretching the coextruded layers to reduce the thickness; (d) applying the coextruded melts to a support while simultaneously reducing the temperature below the Tg of the composition of the surface layer.
    Type: Application
    Filed: February 26, 2003
    Publication date: August 26, 2004
    Applicant: Eastman Kodak Company
    Inventors: Eric E. Arrington, Thomas M. Laney
  • Patent number: 6776933
    Abstract: A method of manufacturing a security item comprises coextruding at least two polymer plastic materials (6,7) with different characteristics so as to form a substrate so that neither material are biaxially oriented, and providing security indicia (14) on the substrate.
    Type: Grant
    Filed: October 6, 2000
    Date of Patent: August 17, 2004
    Assignee: De La Rue International Limited
    Inventors: Charles Edward Chatwin, Christopher John Fice
  • Publication number: 20040146670
    Abstract: Multilayer medical devices, apparatuses for making such devices, and methods of making such devices are disclosed.
    Type: Application
    Filed: January 27, 2003
    Publication date: July 29, 2004
    Inventors: Albert Chin, John Jianhua Chen, Thomas A. Svatek, Ronald A. Sahatjian
  • Patent number: 6767618
    Abstract: A multi-layered stretched resin film comprises a base layer (A) comprising more than 90 wt % of a polyolefinic resin and less than 10 wt % of an inorganic fine powder and/or an organic filler; and an amorphous resin-containing layer (B), comprising 0 to 85 wt % of a second polyolefinic resin, which may be the same or different than the first polyolefinic resin, and 15 to 100 wt % of an amorphous resin. The amorphous resin-containing layer (B) is disposed on at least one side of the base layer (A), and has a porosity of 5% or less. Such multi-layered stretched resin films are resistant to waving or curling caused by exposure to the vehicle component of offset printing inks during offset printing, and therefore have excellent printing properties.
    Type: Grant
    Filed: February 4, 2002
    Date of Patent: July 27, 2004
    Assignee: Yupo Corporation
    Inventors: Atsushi Ishige, Kazuhisa Kitamura
  • Patent number: 6767492
    Abstract: A die apparatus, a method of using the die apparatus to produce co-extruded polymeric articles, and co-extruded polymeric articles produced using the die apparatus and method are disclosed. The die apparatus includes a hollow vane configured to extrude a material into a chamber within the die, thereby producing a co-extruded web. The co-extruded web has a plurality of distinct, discontinuous phases in the cross-web direction, the phases having a uniform width as shown by a coefficient of variation of less than 8 percent for any three consecutive phases. The phases are substantially continuous down-web and are surrounded by a matrix having two or more layers.
    Type: Grant
    Filed: June 27, 2002
    Date of Patent: July 27, 2004
    Assignee: 3M Innovative Properties Company
    Inventors: Scott G Norquist, Dennis L Krueger, Alan J. Sipinen, Thomas P Hanschen, Ronald P Leseman
  • Publication number: 20040130054
    Abstract: A plastic closure that comprises a cap having a base with a peripheral skirt defining the cap interior and threads on the skirt for securing the closure to a container. A liner is secured to the interior of the cap, preferably by being compression molded in situ on the base. The liner consists essentially of a multiplicity of alternating layers of a matrix polymer material such as EVA and a barrier material such as EVOH to resist transmission of gas, water vapor and/or flavorants through the liner. The matrix polymer material preferably is preblended with a compatibilizer material such as a maleic anhydride grafted polymer that ties the matrix polymer material to the barrier material.
    Type: Application
    Filed: October 7, 2003
    Publication date: July 8, 2004
    Inventor: David B. Riffer
  • Patent number: 6737226
    Abstract: A process for making polyester film base material comprising more than 65 mol % of 1,4-cyclohexanedimethanol (CHDM) of the total glycol component in the polyester material. The film base is prepared by sequentially carrying out the following steps: (a) casting a molten polyester resin in a machine direction onto a casting surface to form a continuous sheet, (b) drafting the sheet by stretching in the machine direction at a stretch ratio of from 2 to 4, and at a temperature ranging from 70° C. to 130° C., (c) tentering the sheet in the transverse direction by stretching at a stretch ratio of from 2 to 4, and at a temperature ranging from 70° C. to 130° C. to obtain a biaxially oriented film, (d) heat-setting the oriented film at an actual temperature of from 160° C. to 200° C., and (e) cooling the heat-set film without substantial detentering to obtain a biaxially oriented, heat-set polyester-based film having a cutting index of 1 to 1.
    Type: Grant
    Filed: October 24, 2002
    Date of Patent: May 18, 2004
    Assignee: Eastman Kodak Company
    Inventors: Yuanqiao Rao, Jehuda Greener, Michael R. Brickey
  • Patent number: 6730406
    Abstract: The invention relates to a co-extruded, biaxially oriented polyester film consisting of a base layer and at least one outer layer. The film contains at least one flame-retardant agent, at least one UV-stabilizer and has a matt outer layer which contains a mixture and/or a blend of two components (I) and (II), whereby component (I) is substantially a polyethylene terephthalate homopolymer, or a polyethylene terephthalate copolymer, or a mixture of polyethylene terephthalate homopolymers or polyethylene terephthalate copolymers, and component (II) is a polymer containing at least one sulphonate group.
    Type: Grant
    Filed: July 18, 2002
    Date of Patent: May 4, 2004
    Assignee: Mitsubishi Polyester Film GmbH
    Inventors: Ursula Murschall, Ulrich Kern, Guenther Crass, Gottfried Hilkert